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FREMONTTNDUSTRIES, INC. PHONE: $12t 445-4121
Va$eyIndustriat
Btvd.N.
d90 FAX: ( 6 r2 ) 4 9 6 - 3 0 2 7
Box67
tto. EMERGENCY
PHONE:16121 445-4121
Shakopee, 55379
MN (800)424-9300
CHEMTREC:
FREMONT119
9
slcTtoN I GENERAL
TNFORMATTON
NAMEON LABELfldentiry): fnfMONt gtrs
CHEMICAL FAMILY: Base
HMIS HAZARD CODES: Health(3 )Flammability(0)Reactivity( t
)
NFPAHAZARD coDES: Herlth (3 ) Flammability( Reactivity
0) (0) specialHazard:NA
HAZARDRATINGSCALE: 4 = severe 3 = Serious 2 = Moderate t = stigtt 0 = Minimal
SECTION
II HAZARDOUS
INGREDIENTS
PRINCIPALHAZARDOUS COMPOUNDS PERCENT OSHA ACGIH
(CHEMICAL& COMMONNAME(S) (OIrTIONAL) PEL cAs #
TLV
SodiumDimethyldithiocsrbamatc 40 NE NE t42-59-6
DisodiumEthyleneBis-Dithiocarbamate 40 NE NE L28-O+L
*EthyleneThiourea <2 NE NE 96-45-7
NA = Not Applicable NE = Not Established
SECTION
III PHYSICAL
DATA
BOILINGPOINT('F): NA GRAVITY (H2O= 1): 0.88
SPECIFIC
VAPOR PRESSURE (mm Hg): NA
SOLUBILITY IN WATER: Completc EVAPORATION RATE (BuAc = t): >1
MELTING POINT ('F): 248o(decomposed)
]luo*-r,."npowder characteristicodor.
with surtur
alf3rl?i[t"Ttffi?;
SECTIONIV FIREAND EXPLOSIONHAZARD DATA
FLASH POINT(McthodUscd): NE (T.C.C.)
FLAMMABLE LMITS: LEL: NE UEL: NE
EXTINGUISHINGMEDIA: Warer, foam.
AUTO.IGNITION TEMPERATURE: NE
sPEclAL FIRE FIGHTING PRoCEDURES: Wear all protectiveequipment. wear self-contained
breathingapparatus
when exposed
while
extinguishing
fue.
UNUSUAL FIRE AND EXPLoSION HAZARDS: Produceis slightly flammableas supplied. Exposures remperatures
ro above120oFcould
release
llammable toxic gases.Wear self-contained
and breathingapparatus
while extingui.tringnr".-
SECTIONV REACTIVITYDATA
STABILITY: Unsablc _ Stable X
CONDITIONSTO AVOID: Acid conditions.
INCOMPATIBILITY (Materials Avoid): Strongacids.
to
HAZARDOUSPOLYMERIZATION: Will Not Occur X May Occur_
CONDITIONSTO AVOID: None
HAZARDOUS DECOMPOSffiON PRODUCTS: Fire may result in the release of oxides of carbon, nitrogen
and sulfur. Thermal
decomposition release
may gasessuchas amines carbondisulfrde.
of
SECTION
VI HEALTHHAZARDOATA
ROUTE(S) ENTRY: Inhalation
OF and skin conlacr.
HAZARDS: - Irritation to eyes, mucous membranes, skin, respiratory tract. May cause
Acute nausea.
l*o
Chronic - Product contains 12% ethylenethioureadetermined to be a teratogen, oncogen and carcinogen in
laboratory animals.
FREMONT
INDUSTRIES,
INC. 9542-22,
Rev.A Page 1 of 3
ffiil+EHtilil:r .:'.. ':l .'' I
: ,.'::::::,:,.'.',,,'',,','.i',.l
SAFETY..DATA.SHEET''
PHONE: 6 1 2 )
( 445-4121
(612)
FAX: 496-3027
EMERGENCY
PHONE: 6 1 2 )
( 445-4121
(800t 424-9300
CHEMTREC:
FREMONT 19
91
SECTIONVl HEALTH HAZARD DATA (continued)
CHEMICAL LISTED AS CARCINOGENOR POTENTTALC.q,RCINOGEN. Yes X Ethylene Thiourea (<2%) No _
NATIONAL TO)ilCOLOGY PROGRAM: yes X No _
I.A.R.C. MONOGRAPHS: Ye.s No 1 OSHA: Yes _
_ No X
SIGNSAND SYMPTOMSoF EXPOSURE: Irritation of skin, cyes,respiratorytracr. Nausea,
vomiting.
MEDICAL CONDMONS GENERALLY AGGRAVATED BY EXPoSURE: NE
EMERGENCYAND FIRST AID PROCEDURES:
EYES: wash eyeswith large amounts water for at least15 minures. call physician.
of
sKIN: wash affectedskin with soapand water. call physicianif irritationpersists.
INHALATION: Removcto fresh air. seek medical as,ention irritation persists.
if
INGESTION: Give copious&mounts water and obtainmedicalattention
of immediately.
SECTIONVII PRECAUTIONS
FOR SAFE HANDLINGAND USE
^*T:o:"'*|INcAsEMATERIALIsRELEAsEDoRsPILL@absorbentmaterial"naGllT[I-IilI
cautlon to svoid sliPpcry conditions. Follow all Local, State and Fcderal regulations for disposal. Do not discharge into lakes
and streams.
!
wAsTE DISPOSALMETHOD: Hazardous
waste. Disposeof in accordance
with Federal,Stateand Local resulations.
PRECAUTIoNSTo BE TAKEN IN HANDLING AND STORING: wear safetygogglesor faceshield,rubber
gloves,hat, full cover clorhing
andNIOSH approvcddust maskwhen handling.
OTHERPRECAUTIoNS: Storc away from strongacids. Use with adequate
ventilation. Washcontaminated
clothinsbeforere-usc.
SECTION
VIII SPECIAL
PROTECTION
INFORMATION CONTROL
AND TVTCASUNTS
RESPIRATORY
PRoTEcTIoN(specify
Type): NIosH/MsHAapproved au.t
r"r tnirtr Crc-zrc-?az,i.e.3M #9920).
"no
VENTILATION: LOCALEXHAUST: Yes
MECHANICAL (General): Yes SPECIAL: NA OTHER: NA
PROTECTIVEGLOVES: Rubberglovcs.
EYE PROTECTION: Safetygogglesor facc shicld.
oTHER PRoTECTIVE CLoTI{ING OR EQUIPMENT: Full cover clolhing,includinglong sleeves,
pants,gloves,boots,and har.
WoRK/HYGIENIC PRACTICES: Store away from food. Wash after handlingand before eating. Follow
normal hygienic practicesfor
handlingchemicals.
FREMONT
INDUSTRIES,
INC. 9542-22,
Rev.A Page 2 of 3
.fiff.
'fi.ffi "..'''.'.l.........1...........'....;'',.....
PHONE: { 6 1 2 )445-4121
FAX: ( 6 1 2 )496-3027
EMERGENCY
PHONE: ( 6 1 2 )445-4121
55379 CHEMTREC: (8001424-9300
FREMONT 19
91
SECTION
IX REGULATORY
TNFORMATION
CERCLA 40 CFR 302.4: EthyleneThiourea- Re =@
SARA TITLE trI:
Section30213o4': EthyleneThiourea - Re = l0 lbs. TRe = NE
Section3lll3l2 HazardCategory: Acute, chronic
313: *Denotcschemicalsubject rcportingreguirements Section
Section to of 313 SARA Title III and 40 CFR 3:/2.65
ThresholdQuantity= 10,(XX)lbs.lycar
rrvp.rw uJ \vpuunau lssue lJatc Supersedes
we believe the information contained herein, including data, recommendations and
other items set forth are reliable, but they are given without
warranty of any kind, expresscd or implied, as to the accuracy, completeness, dependability,
or reliability thereoi except that such information
is, to the best of Frcmont's knowledge and belief, accurate as of thc datc indicated.
FREMONTINDUSTRIES,
INC. 9542-22,Rev.
A Page3 of 3
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