Fb +
Cog
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SAFETYDATA SHEET
MATERIAL
FOR INDUSTRIAL
USE
DESCRIPTION:
18-460
AlkydResin
Lab Sate9 Supply Inc
1. Ghemical
Product and Companyldentification
DESCRIPTION: 18460 Alkyd Resin
PRODUCTCODE: 351672
PRODUCTTYPE: Alkyd OilNo-BakeResin
APPLIGATION: Foundry
Manufacturer/S ier Information
uppl
MSDSprepared by:
For EmergencyMedicalAssistance
HA lntemational,
LLC
Services
Call Health& SafetyInformation
630Oakmont Lane
1-866-303-6949
Westmont,lL
60559
information, (630)575-5722, (630)575-
or
call
Foradditionat
healthand safetyor regulatory
5705.
'Hazardsldentification
2.
2.1 EmergencyOverview
Appearance Black liquid
Odor Solvent
CAUTION!
COMBUSTIBLE LIQUID
unstable hightemperatures may reactwithwater.
Maybecome at or
irritation nose,throatand lungs.
Maybe harmful inhaled.
if of
Maycause
Cancausecentralnervoussystemdepression.
Gauseseye irritation.
NORTH
AMERICAN GUlDE,2000, 128
NO:
EMERGENCY
RESPONSE
HMISRating
HEALTH = I (moderate)
FLAMMABILITY = 2 (moderate)
REACTIVITY = 1 (stight)
*
CHRONIC =
HMrSorafingsinvolve data interpretations may vary from companyto company. They areintendedonly for the
that
rapid,generalidentificationof the magnitudeof the specifichazard. To deal adequatelywith fne safe handlingof this
material,all the informationcontainedrn fhis MSDSmust be considered.
2.2 Potential Health Effects
lmmediateHazards
Not expected be harmful
INGESTION: to undernormalconditions use.
of
lf accidentally burns irritation mucous membranes,
swallowed, or to
esophagus Gl tractcan result.
or
INHALATION: Liquid vapormaycauseirritation nose,
May be harmful inhaled.
if of
or
throat and lungs.
Can causecentral nervous depression.
system
May causeirritation prolonged repeated contact.
on or
SKIN:
Causesirritation.
EYES:
6474247-g HydrotreatedLightDistillate(petroleum)
Cancausecentral headache,
may include
neryous systemdepression.
Signsand symptoms
dizziness,
nausea, unconsciousness evenasphyxiation.
vomiting, and
MediumAtiphaticSolventNaphtha(petroleum)
6474248-7
Cancausecentral may includeheadache,
nervous Signsandsymptoms
systemdepression.
dizziness-,
nausea,
vomiting, andevenasphyxiation.
unconsciousness
64742-94-5 HeavyAromatic SolventNaphtha(petroleum)
headache,
may include
Cancausecentral Signsand symptoms
nervoussystemdepression.
dizziness,
nausea, unconsciousness evenasphyxiation.
vomiting, and
DelayedHazards
il74247A HydrotreatedLightDistillate(petroleum)
Thismatedalhas
POSSIBLE based animaldata.
on
CANCER HMARD. Maycause cancer
not beenlistedby NTP,classified IARCnor regulated OSHAas a carcinogen.
by
by
Maycause liverdamage basedon animaldata.
Maycause kidney damage basedon animaldata.
MediumAliphatic SolventNaphtha(petroleum)
647424,8-7
Maycause kidney damagebasedon animaldata.
- See Footnote end of section
at
91-20鈧? Naphthalene
has
This material
POSSIBLE basedon anirnaldata.
CANCER HAZARD.Maycausecancer
2B).This material not listedby
(Group is
beenclassified IARCas an animalcarcinogen
by
NTPnor regulated OSHAas a carcinogen.
by
68955-83-9 Fafty Acids, C9-13-neo,-
CobaltSalts
has
POSSIBLE Thismaterial
on
CANCER HMARD. Maycause based animaldata.
cancer
beenlistedby NTP,classified IARCand/orregulated OSHAas an animalcarcinogen.
by
by
Footnote: of the dateof issuance thisdocument, material notbeenlistedby NTP,classified IARCnor
As by
has
of this
regulated OSHAas a carcinogen.
by
3. Gomposition,
Informationon Ingredients
The ingredients
listedbelowhavebeenassociated one or more immediate and/or
with
delayed(.)
healthhazards. and levelof
dependsuponduration
Riskof damageand effects
exposure.BEFORE READ
HANDLING, EXPOSURE THESEINGREDIENTS,
TO
USING, OR
AND UNDERSTAND MSDS THE
% by weight
30.0 . 50.0
67989-61-1 LinseedOil, Polymerwith lsophthalic Acid and
Pentaerythritol
6474247A *HydrotreatedLight Distillate(petroleum) 10.0 . 30.0
page 3/9
64742-88-T*Medium - 10.0
(petroleum)
AliphaticSolventNaphtha 5.0
5.0 - 10.0
64742-94-5 HeavyAromatic SolventNaphtha(petroleum)
91-20-3 *Naphthalene 0.1 - 1.0
68955-83-9 *FattyAcids, C9-13-neo,- 0.1 - 1.0
CobaltSalts
Any applicable Canadian trade secrct numbers will be listed in Section 15.2.
4. First Aid Measures
largequantities water.lf
of
lf accidentally
INGESTION: swallowed,dilute drinking
by
the individual drowsy unconscious, notgiveanything mouth.by
is or do
poison room
lmmediately centeror hospital
emergency
contact control
vomiting for anyotheradditional
for advice whether induce
to
on or
treatment directions.
give
INHALATION: respiration,
lf inhaled,
remove freshair. lf not breathing, artificial
to
preferablymouth-to-mouth. a physician.
Call
SKIN: ln caseof irritation,
flushwithwater.
flusheyeswithplenty waterfor at least15 minutes.
EYES: lmmediately of
irrigation ensurewatercontact
to
Eyelidsshouldbe heldapartduring
with entiresurface eyesand lids.Calla physician.
of
5. Fire FightingMeasures
foamor CO2.Watermay be
SuitableExtinguishing
Media: In caseof fire,usedry chemical,
ineffective, shouldbe usedto keepfire-exposed containers
but cool.
with.oil
may
COMBUSTIBLE. Keepawayfromheat,sparks flame. Wastesoaked
and
Placerags,steelwool or wastein a sealed
spontaneouslycatchfire if improperly
discarded.
water-filled
metalcontainer.
Liquid vapormaycausea flashfireor
UNUSUAL FIREANDEXPLOSION and
HAZARDS:
thanair and maysettlein low placesor spreadlong
igniteexplosively.
Vaporis heavier
may linger. Closed
atmospheres
distances a sourceof ignition
to and flashback.Explosive
products.
contalners rupture
can and releasetoxicvaporsor decomposition
6. Accidental ReleaseMeasures
(e.9.sand,
Eliminate ignition
all spillwithinertmaterial
sources. absorb
Containand/or
vermiculite), placein a suitable container. largespills,use watersprayto disperse
then For
waterways sewers.Use
vaporsand flushspillarea.Preventrunofffromentering or
appropriate (PPE).
Personal Protective
Equipment
7. Handlingand Storage
7.1 Handling
with good industrialhygieneand safety practices.These practices
Handle in accordance
include avoidingunnecessary exposureand removalof the materialfrom eyes, skin and
clothing. Wash thoroughly after handling. Always use appropriate Personal Protective
(PPE).
Equipment
page 4/9
Avoid breathingvapor. Use with adequateventilation.
INHALATION:
Avoid prolongedor repeatedcontactwith skin and clothing.
SKIN:
EYES: Avoid contact with eyes.
Storage
7.2
Keepcontainer of sun and awayfromheat.
out
residues. NOTcut,torchor reusewithout
product
Emptycontainer maycontain DO
commercial cleaning.
Neveruseair pressure emptycontainers.
to
usingpumps an inertgas,suchas nitrogen.
Do notuseairto unload or
bulktrucks.Unload
Keepawayfromheat,sparks, flameand otherignition sources.
Storeat ambient temperature.
Usewithadequate ventilation.
Do not storenearstrongoxidizing chemicals.
Protectfromdirectsunlight.
No smoking openflamesin storage area.
or
place.
Keepcontainers tightlyclosedin a dry,cooland well-ventilated
(SeeNFPA30 and OSHA
liquids
Storein an areadesignated storage flammable
of
for
29CFR1910.106.
Protection
ExposureControls/Personal
8.
Exposure
Guidelines
8.1
6798961-1 Linseed ic Acid and
TLV Noneestablished
ACGIH
OSHAPEL Noneestablished
Distillate
200 mg/m3 Skin;A3 - ConfirmedAnimal
ACGIHTLV 8-hrTWA
with Unknown
Carcinogen
Relevance Humans
to
Oilmist,mineral
OSHAPEL None
Established
64742{,8-7 Solvent
Medium
100 ppm 525 mg/m3 as Stoddard Solvent
ACGIHTLV 8-hrTWA
500 ppm 2,900 as Stoddard Solvent
OSHAPEL B-hrTWA
mg/m3
TWA 100 ppm 525 mg/m3 as Stoddard Solvent; 1989
Remanded
PEL remanded, but in effect
in some states
64742-94-5 Aromatic Solvent
ACGIHTLV None
Established
mineral
Oilmist,
OSHAPEL 5 mg/m3
8-hrTWA
91-20-3
10 ppm 52 mg/m3 Skin
8-hrTWA
ACGIH TLV
STEL(15 min) 15 ppm 79 mg/m3
10 ppm 50 mg/m3
8-hr TWA
OSHA PEL
15 ppm
Remanded 75 mg/m3
STEL
68955{3-9 Fatty Acids, C9-13-neo,-
Cobalt Salts
0.02mgim3 (as inorganic Co);
compound
ACGIHTLV | 8-hrTWA
Page 5/9
A3 - ConfirmedAnimal
Carcinogenwith Unknown
Relevance Humans
to
None
OSHAPEL
Established
ExposureGontrols
8.2
ENGINEERING may be usedto
CONTROLS:The following exposurecontroltechniques
effectivelyminimizeemployee exposure:local exhaust ventilation,enclosedsystem design,
processisolationand remote control in combinationwith appropriateuse of personal
protectiveequipmentand prudentwork practices.These techniquesmay not necessarily
addressall issues pertainingto your operations.We, therefore,recommendthat you consult
with experts of your choice to determinewhether or not your programsare adequate.
contaminants generated
lf airbome whenthe material heatedor handled,
is sufficient
are
ventilation volumeand air flowpattems shouldbe provided keepair contaminant
in to
concentrationlevelsbelowacceptable criteria.
8.3 PersonalProtection
criteria, NIOSH(42 CFRPart84)
Whereair contaminants exceed use
can acceptable
basedon the form
protection
approved respiratory equipment. shouldbe selected
Respirators
and concentration contaminants air in accordance OSHAlawsand regulations or
in with
of
respiratory
standards guidelines,
otherapplicable including regarding
or ANSIstandards
glovesas required prevent
protection. gogglesif contact likely. skin
to
Use is Wearimpervious
contact.
Physicaland ChemicalProperties
9.
Appearance Blackliquid
Odor Solvent
Odorthreshold Not available
pH Notapplicable
149- 260'C (300- 500'F)
point,760
Boiling mm Hg
Flashpoint 52'C (126"F) Tag ClosedCup
Evaporation rate Notapplicable
1.0% (v)
Lowerexplosionlimit
6.0 % (v)
Upperexplosion limit
Vaporpressure 2 0 m mH g@ 7 0 ' C ( 1 5 8 F )
"
Vapordensity Not available
0.94- 0.96
gravity
Specific
Solubility water
in Negligible
partitioncoeffi
Octanol/water cient Not available
Autoignitiontemperature Notapplicable
111-2O3cPs Brookfield
Viscosity
1 0 . Stabilityand Reactivity
ChemicalStability
Normally
stable,but may becomeunstable hightemperatures may reactwith water.
or
at
IncompatibleMaterials
Page
Strong
oxidizers.
Hazardous
DecompositionProducts
CO,CO2,particulate including
matter,
hydrocarbons otherorganic
and compounds
benzo[a]pyrene.
Possibilityof HazardousReactions
polymerization not expected occur.
Hazardous is to
11. Toxicological
Information
See Section3 Hazards ldentificationinformation.
Linseed Oil, Polymer with lsophthalic Acid and Pentaerythritol
67989-61-l
LC50: Not available
LD50: Not available
6474247-g Hydrotreated LightDistillate(petroleum)
LC50: rat=21.4 mglll4 h (vendor)
LD50: Not available
Medium Aliphatic Solvent Naphtha (petroleum)
U74288-7
LC50: rat=700 mglll4 h (vendor)
LD50: Not available
Heavy Aromatic Solvent Naphtha (petroleum)
il742-94-S
LC50: Not available
LD50: Not available
91-20A Naphthalene
LC50: Not available
1,250mg/kg (RTECS)
LD50: Oral-rat=
68955{3-9 Fatty Acids, G9-13-neo,-
GobaltSalts
LC50: Not available
LD50:Notavailable
EcologicalInformation
12.
Notdetermined
1 3 . DisposalConsiderations
and
and dispose according local,state/provincial,
Recover free liquid.Absorbresidue to
of
vapors.DO NOTcut,puncture
federalrequirements. Emptycontainer:Maycontainexplosive
or weldon or nearby.
Transportlnformation
14.
14.1 U.S.Departmentof Transportation(DOT)
Thedataprovided this sectionis for information and may not be specific your
to
in only
package regulations
to
sizeor modeof transport.You will needto applythe appropriate
properly your shipment transportation.
classify for
(Petroleum
Distillates)
Propershippingname FLAMMABLE
LlQUlD,
N.O.S.
UN/NA number 1993
Glass 3
Packinggroup ill
Label 3
Page 7t9
RQ Ingredients
Transportation DangerousGoods(TDG)
14.2 Canadian of
(Petroleum
Propershippingname Distillates)
N.O.S.
FLAMMABLE
LlQUlD,
UN number: 1993
Class Class3
group
Packing ill
Label 3
14.3 OtherRegulations
o ADRIRID
Propershippingname N.O.S.
FLAMMABLE
LIQUID,
UN Number 1993
Glass Class3
ClassificationCode F1
Packinggroup ill
HazardldentificationNo. 30
(Kemler Gode)
Label 3
o IMO/IMDG
(Petroleum
Distillates)
N.O.S.
contains
Propershippingname FLAMMABLE
LlQUlD,
UNNumber 1993
Class Class3
group
Packing ltl
Label 3
.IATA (Commercial)
(Petroleum
Distillates)
contains
Propershippingname LlQUlD,
N.O.S.
FLAMMABLE
UN/lDnumber 1993
Class Class3
Packinggroup ill
Label 3
o IATA (Passenger)
(Petroleum
Distillates)
Propershippingname N.O.S.
contains
FLAMMABLE
LlQUlD,
UN/ID number 1993
Glass Class3
Packinggroup ill
Label 3
(Selected
15. Regulatorylnformation Regulations)
15.1 U.S.FederalRegulations
OSHAHazardsCommunicationStandard29GFR1 200
910.1
This materialis a "health hazard" and/or a "physicalhazard" as determinedwhen reviewed
accordingto the requirementsof the OccupationalSafety and Health Administration29 CFR
Part 19 10. 1200 " Hazard Communication' Standard.
SARA Title lll: Section 3111312
Page 8/9
healthhazard
lmmediate
healthhazard
Delayed
Firehazard
SARA Title lll: Section 313 and 40 CFR Parl372
This productcontainsthe followingtoxic chemical(s)subjectto the reportingrequirementsof
Amendmentsand Reauthorization of 1986' and
Act
Section313 of Title lll of the Supe-rfund
SubpartC-SupplierNotificationRequirementof 40 CFR Part 372.
o.70%
N450
Manganese
Compounds
0.70%
N450
Manganese
Compounds
0.21o/o
N096
Compounds
Cobalt
0.31%
N096
Compounds
Cobalt
TSCASection8(b) lnventory
chemicalsubstances listedon the TSCAlnventory. relyon certifications
We
are
All reportable
substances manufactured us.
by
not
fromour suppliers chemical
for
of compliance
Regulations
15.2 Ganadian
MaterialsInformationSystem(WHMIS)
WorkplaceHazardous
This producthas been classifiedin accordancewith the hazard criteriaof the Controlled
requiredby the CPR.
(CPR)and the MSDS containsallthe information
ProductsRegulation
Class83
ClassD2A
ClassD2B
ProtectionAct (CEPA)
CanadianEnvironmental
Substances (DSL)or
List
substances listedon the Domestic
are
chemical
All reportable
requirements.
notification
with CEPAnew substance
comply
otherwise
NationalPollutantReleaseInventory(NPRI)
requirements the
of
subiect the reporting
to
This product chemical(s)
contains following
the
Release
Pollutant
16(1),National
Protection (CEPA) subsection
Act
Environmental
Canadian
Inventory.
Nonerequired.
{ 6. Other Information
User'sResponsibility
29CFR1910.1200 the Workplace
and
Standard
Communication
TheOSHAHazard
on
contained
thatthe information
(WHMIS) require
lnformation System
Hazardous Materials
andtrainyourworkersregarding
Educate
yourworkers.
thesesheetsbe madeavailable to
this productproperly.
Consult
lnitruct yourworkers handle
to
OSHAand WHMISprecautions.
associated use of this productand its
with
guardagainsihazards
to
experts
w1happropriate
ingredients.
Page9/9
Disclaimer
CONCERNING PRODUCT
THE
EXPRESS IMPLIED,
OR
MAKES WARRANTY,
NO
SELLER
thAt
CXCEPT
FORANY PURPOSE,
THEREOF
ORTHEMERCHANTABILITY FITNESS OR
doesnotinfringe
product
specifications, thatthe
and
the product
shallconform contracted
to
patent. claimof any kindshallbe greater amount
in
No
Statesor Canadian
anyvalidUnited
In
product respect whichdamages claimed'
are
of
in
priceof the quantiiy of
thanthe purchase
claim
Buyer's
whether
damages,
or consequential
no eventshallSellerbe liablefor incidental
negligence otherwise.
or
breachof warranty,
is basedon contract,
|