FORM NO. MSDS #22-D
NFPA Ratings
DATE REVISED: 05/09/2006
Fire
0 Reactivity
Health
Material Safety Data Sheet
2 0
(Essentially Similar to U.S. Department of Labor Suggested
Hazard Ratings
Form For Hazard Communication Compliance)
Special
4 = Extreme
3 = High
2 = Moderate
1 = Slight
I. Product Identification
0 = Insignificant
Product Type - ALL-STATE PHOS-COPPER BRAZING ALLOYS
Manufacturer - THE ESAB GROUP, INC. Telephone No. - 1-717-637-8911
Website: 1-800-933-7070
www.esabna.com
Address - 801 Wilson Avenue Emergency No. - 1-717-637-8911
Hanover, PA 17331 (CHEMTREC) 1-800-424-9300
Product Description: This Phos-Copper alloy consists of bare rods cut or cast in standard lengths and is
intended to be used for brazing of certain base materials.
NOMINAL COMPOSITION (Wt .%)
All-State No. 3 Bare 鉃?
All-State Product Trade Name
Aluminum 0.01 鈥? 0.05
Carbon 2.5 鈥? 4.0
Chromium 0.01 鈥?0.9
Copper 0.01 鈥? 0.90
Iron 86.3 鈥? 96.2
Manganese 0.2 鈥? 1.1
Molybdenum 0.01 鈥? 1.0
Nickel 0.01 鈥? 1.5
Phosphorous 0.01 鈥? 0.8
Silicon 1.0 鈥? 3.5
Sulphur 0.02 鈥? 0.18
Titanium 0.01 鈥? 0.06
鉃? See Note 3 in Section VI
THE ESAB GROUP requests the users of these products to study this Material Safety Data Sheet (MSDS) and the product label and
become fully aware of the product hazards and safety information. To promote the safe use of these products a user should (1) notify
and train its employees, agents and contractors concerning the information on this MSDS and any product hazards and safety
information, (2) furnish this same information to each of its customers for these products, and (3) request that such customers notify and
train their employees and customers, for these products, of the same product hazards and safety information.
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Product Identity: ALL-STATE PHOS-COPPER BRAZING ALLOYS
FORM NO. MSDS #22-D
DATE REVISED: 05/09/2006
II. Hazardous Ingredients
IMPORTANT: This section covers the materials from which this product is manufactured. The fumes and gases produced during
normal use of these products are covered in Section V. The term HAZARDOUS should be interpreted as a term required and
defined by Laws, Statutes, or Regulations, and does not necessarily imply the existence of any hazard when the products are used as
directed by THE ESAB GROUP.
ACGIH TLV OSHA - PEL
3 3 3
Material (CAS No.) SARA TWA (mg/m ) TWA (mg/m ) STEL (mg/m )
Aluminum (7429-90-5) * 5 (Welding Fume) 5 (Welding Fume) --
Carbon (7440-44-0) 3.5 (Carbon Black) 3.5 (Carbon Black) --
Chromium (Cr) (7440-47-3) * 0.5 (Metal) 1 (Metal) --
0.05 (CrVI inorganic compounds as 0.005 (CrVI inorganic compounds as
Cr , water soluble) CrVI, water soluble)
C 0.1 (as CrO3)
0.005 (CrVI inorganic compounds as
0.01 (CrVI inorganic compounds as
CrVI, water insoluble)
Cr, water insoluble)
C 0.1 (as CrO3)
Copper (7440-50-8) * 1 (Dust) 1 (Dust) --
0.2 (Fume) 0.1 (Fume)
Iron (7439-89-6) 5 (Oxide Fume) 10 (Total Particulate) --
Manganese (7439-96-5) * 0.2 1 (Fume) 3
Molybdenum (7439-98-7) 3 (Respirable) 15 (Dust, insoluble) --
0.5 (Respirable, soluble) 5 (Soluble)
Nickel (7440-02-0) * 0.1 (Soluble) 0.1 (Soluble) --
Phosphorous (Yellow) (7723-14-0) * 0.1 0.1 --
Silicon (7440-21-3) 10 (Dust) 5 (Respirable) --
Sulfur (7704-34-9) None Established None Established --
Titanium (7440-32-6) 10 (TiO2) 5 (TiO2 - Respirable) --
NOTE: In the ingredients table, an asterisk (*) after the CAS number indicates a toxic chemical subject to the reporting requirements
of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (SARA) and 40 CFR Part 372.
In the table above 鈥淐鈥? indicates 鈥淐eiling Limit鈥?.
III. Physical Data
As shipped, these products are nonflammable, non-explosive, non-reactive, and non-hazardous.
Physical State: GAS ( ) LIQUID ( ) SOLID (X)
Odor and Appearance: Solid, silver gray colored bare wire. Odorless.
Specific Gravity: 7.86 for iron
IV. Fire & Explosion Hazard
Flammable/Explosive: NO (X) YES ( )
Under what conditions: Only the packaging for this product will burn.
Extinguishing Media: This product will not burn; however, welding arcs and sparks can ignite combustible and flammable materials.
Use the extinguishing media recommended for the burning materials and fire situation. See ANSI Z49.1 鈥淪afety in Welding and
Cutting鈥? and 鈥淪afe Practices鈥? Code: SP, published by the American Welding Society, P. O. Box 351040, Miami, FL 33135, and
NFPA 51B 鈥淐utting and Welding Processes,鈥? published by the National Fire Protection Association, Batterymarch Park, Quincy, MA
02269 for additional fire prevention and protection information.
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Product Identity: ALL-STATE PHOS-COPPER BRAZING ALLOYS
FORM NO. MSDS #22-D
DATE REVISED: 05/09/2006
V. Reactivity Data
Stability: Stable (X) Unstable ( ) Polymerization will not occur.
Incompatible products: Iron may cause violent decomposition of hydrogen peroxide (52% by weight or greater).
Hazardous decomposition products: Brazing fumes and gases cannot be classified simply. The composition and quantity of both
are dependent upon the material being worked, the process, procedures, and consumables used. Other conditions which also
influence the composition and quantity of the fumes and gases to which workers may be exposed include: coatings on the material
being worked (such as paint, plating or galvanizing), the number of welding operations and the volume of the work area, the quality
and amount of ventilation, the position of the worker鈥檚 head with respect to the fume plume, as well as the presence of contaminants
in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning or painting activities). When the materials are consumed,
the fume and gas decomposition products generated are different in percent and form from the ingredients listed in Section II.
Decomposition products of normal operation include those originating from the volatilization, reaction, or oxidation of the ingredients,
plus those from the material being worked and the coatings etc. noted above.
Reasonably expected decomposition products from normal use of these products include a complex of the oxides of the materials
listed in Section II, as well as carbon monoxide, carbon dioxide, ozone and nitrogen oxides (refer to 鈥淐haracterization of Arc Welding
Fume鈥? available from the American Welding Society). THE FUME LIMIT FOR COPPER, NICKEL, MANGANESE, AND CHROMIUM
MAY BE REACHED BEFORE THE GENERAL LIMIT FOR WELDING FUMES OF 5 mg/m鲁 IS REACHED. MONITOR FUMES FOR
COPPER, NICKEL, MANGANESE, AND CHROMIUM LEVELS. A SIGNIFICANT AMOUNT OF THE CHROMIUM IN THE FUMES
CAN BE HEXAVALENT CHROMIUM, WHICH HAS A VERY LOW EXPOSURE LIMIT, 0.005 mg/m3 (5碌g/m3 ). The only way to
determine the true identity of the decomposition products is by sampling and analysis. The composition and quantity of the fumes
and gases to which a worker may be overexposed can be determined from a sample obtained from inside the welder鈥檚 helmet, if
worn, or in the workers breathing zone. See ANSI/AWS F1.1 鈥淢ethod for Sampling Airborne Particles Generated by Welding and
Allied Processes,鈥? available from the American Welding Society.
VI. Physical and Health Hazard Data
Electric arc working may create one or more of the following health or physical hazards. Fumes and gases can be dangerous to your
health. Electric shock can kill you. Arc rays can injure eyes and burn skin. Noise can damage hearing. Brazing alloys are frequently
used with a fluoride-type flux. If applicable, flux fume should be considered in evaluation of hazards.
Route of overexposure: The primary route of entry of the decomposition products is by inhalation. Skin contact, eye contact, and
ingestion are possible. Absorption by skin contact is unlikely. When these products are used as recommended by THE ESAB
GROUP, and ventilation maintains exposure to the decomposition products below the limits recommended in this section,
overexposure is unlikely.
Effects of acute (short-term) overexposure to the gases, fumes, and dusts may include irritation of the eyes, lungs, nose, and
throat. Some toxic gases associated with welding may cause pulmonary edema, asphyxiation, and death. Acute overexposure may
include signs and symptoms such as watery eyes, nose and throat irritation, headache, dizziness, difficulty in breathing, frequent
coughing, or chest pain. The presence of copper in fume can cause metal fume fever. Short term symptoms may include a metallic
taste in the mouth, dryness or irritation of the throat followed by coughing, shortness of breath, nausea, fever, body ache, and chills.
Symptoms usually disappear within 24 hours. The presence of chromium/chromate in fume can cause irritation of nasal membranes
and skin. Prolonged or repeated overexposure to iron oxide produced in grinding or welding may cause siderosis.
Pre-existing Medical Conditions Aggravated by Overexposure: Individuals with allergies or impaired respiratory function may
have symptoms worsened by exposure to welding fumes; however, such reaction cannot be predicted due to the variation in
composition and quantity of the decomposition products.
Effects of chronic (long-term) overexposure to air contaminants may lead to their accumulation in the lungs, a condition which
may be seen as dense areas on chest X-rays. The severity of the change is proportional to the length of the exposure. The changes
seen are not necessarily associated with symptoms or signs of reduced lung function or disease. In addition, the changes on X-rays
may be caused by non-work factors such as smoking, etc. Inhalation of too much iron oxide fume over a long time can cause
siderosis, sometimes called 鈥渋ron pigmentation鈥? of the lung. It can be seen on a chest x-ray but causes little or no disability. Long
term exposure to brazing fume, gases or dust may contribute to pulmonary irritation or pneumoconiosis. Long term overexposure to
nickel fumes may also cause pulmonary fibrosis and edema. Overexposure to manganese compounds may affect the central
nervous system, symptoms of which are languor, sleepiness, muscular weakness, emotional disturbances and spastic gait. The effect
of manganese on the central nervous system is irreversible. Copper poisoning has been reported in the literature from exposure to
high levels of copper. Liver damage can occur due to copper accumulation in the liver; the damage is characterized by cell
destruction and cirrhosis. High levels of copper may cause central nervous system damage characterized by nerve fiber separation
and cerebral degeneration. Overexposure to phosphorus may cause necrosis of the mandible, termed 鈥減hossy jaw鈥?. Nickel and
chromium are considered carcinogenic.
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Product Identity: ALL-STATE PHOS-COPPER BRAZING ALLOYS
FORM NO. MSDS #22-D
DATE REVISED: 05/09/2006
Exposure limits for the ingredients are listed in Section II. The ACGIH and the 1989 OSHA TWA for welding fume is 5 mg/m鲁. At
times the limit for a particular hazardous chemical is reached before the limit for welding fumes. TLV-TWAs should be used as a
guide in the control of health hazards and not as fine lines between safe and excessive concentrations. As noted in Section V, the
brazing fume is a mixture of many components. Therefore, a statutory computation of the equivalent exposure is required. The
equivalent exposure value for the brazing fume mixture shall always be less than one. When these products are used as
recommended by THE ESAB GROUP, and the preventive measures taught in this MSDS are followed, overexposure to hazardous
substances will not occur.
Emergency First Aid Measures: In case of emergency, call for medical aid. Employ first aid technique recommended by the Red
Cross. IF BREATHING IS DIFFICULT, give oxygen and call for a physician. FOR ELECTRIC SHOCK, disconnect and turn off the
power. If not breathing, begin artificial respiration, preferably mouth-to-mouth. If no detectable pulse, begin Cardio Pulmonary
Resuscitation (CPR). Immediately call a physician. FOR ARC BURN, apply cold, clean compresses and call a physician.
Carcinogenic Assessment (NTP Annual Report, IARC Monographs, Other): Nickel and Chromium must be considered possible
carcinogens under OSHA (29 CFR 1910.1200). IARC has indicated Nickel, Chromium, and certain of their compounds are probably
carcinogenic for humans, but the compounds cannot be specified precisely. Their conclusions were drawn from operations different
from brazing. Regardless, exposure level must be kept below those levels specified in Section II.
鉃? WARNING: This product contains or produces a chemical known to the State of California to cause cancer and birth defects (or
other reproductive harm). (California Health & Safety Code 搂25249.5 et seq.)
VII. Precautions for Safe Handling and
Use/Applicable Control Measures
Read and understand the manufacturer鈥檚 instructions and the precautionary label on this product. See American National Standard
Z-49.1, 鈥淪afety in Welding and Cutting,鈥? published by the American Welding Society, P. O. Box 351040, Miami, FL 33135 and OSHA
Publication 2206 (29 C.F.R. 1910), U.S. Government Printing Office, Superintendent of Documents, P.O. Box 371954, Pittsburgh, PA
15250-7954 for more detail on many of the following:
Ventilation: Use enough ventilation, local exhaust at the arc, or both, to keep the exposure within legal limits. In the worker鈥檚
breathing zone and the general area, fumes and gases must be kept below the TLVs and the equivalent exposure must
compute to less than one. Train the welder to keep his head out of the fumes.
Respiratory Protection: Use respirable fume respirator or air supplied respirator when welding in confined space or where
local exhaust or ventilation does not keep exposure below TLVs.
Eye Protection: Wear helmet or use face shield with filter lens. As a rule of thumb, start with a shade which is too dark to see
the weld zone. Then go to the next lighter shade which gives sufficient view of the weld zone. Provide protective screens and
flash goggles, if necessary, to shield others.
Protective Clothing: Wear head, hand, and body protection which help to prevent injury from radiation, sparks and electrical
shock. See ANSI Z-49.1. At a minimum, this includes welder鈥檚 gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial clothing. Train the welder not to touch live electrical
parts and to insulate himself from work and ground.
Storage: Keep dry to reduce rusting.
Procedure for Cleanup of Spills or Leaks: NOT APPLICABLE
Waste Disposal Method: Prevent waste from contaminating surrounding environment. Discard any product, residue,
disposable container, or liner in an environmentally acceptable manner, in full compliance with Federal, State and Local
regulations.
The opinions expressed in this MSDS are those of qualified experts within THE ESAB GROUP. We believe that the information
contained herein is current as of the date of this MSDS. Since the use of this information and these opinions and the conditions of
use of these products are not within the control of THE ESAB GROUP, it is the user鈥檚 obligation to determine the conditions of safe
use of these products.
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