EC SAFETY DATA SHEET 2001/58/EG
_______________________________________________________________________________________________
Product name Vinacryl 4333 EU/EN
MSDS number 85364 Revision Date Jun.15.2005
Revision Number 0.02*** Issuing date Jul.25.2007***
_______________________________________________________________________________________________
1. Identification of the substance/preparation and the company/undertaking
Product name
Vinacryl 4333
Manufacturer, importer, supplier
Celanese Emulsions
De Asselen Kuil 20
NL-6161 RD Geleen
Netherlands
Product Information
PS-Emulsions@celanese.de***
Emergency telephone number
+49 (0)69-305 6418***
End use:
For industrial use only***
2. Composition/information on ingredients
Chemical characterization Water-borne polymer emulsion., Basis: , Butylacrylate , Methyl methacrylate,
(Meth)acrylic acid, N-Methylolacrylamide***.
3. Hazards identification
Statements of hazard The product does not require a hazard warning label in accordance with EC
Directives.
Frequent contact can lead to skin and eye irritation, especially if product is allowed to
dry out
Observe the usual precautions when handling chemicals.***
4. First aid measures
General Information Remove contaminated, soaked clothing immediately and dispose of safely***
Inhalation Move to fresh air. If symptoms persist, call a physician.
Skin Wash off with soap and water. If symptoms persist, call a physician.
Eyes Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Call a physician immediately***
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EC SAFETY DATA SHEET 2001/58/EG
_______________________________________________________________________________________________
Product name Vinacryl 4333 EU/EN
MSDS number 85364 Revision Date Jun.15.2005
Revision Number 0.02*** Issuing date Jul.25.2007***
_______________________________________________________________________________________________
Ingestion If swallowed, seek medical advice immediately and show this container or label. If
conscious, drink plenty of water. Do not induce vomiting without medical advice.
Notes to physician
Main symptoms None known.
Treatment Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
foam. dry powder. carbon dioxide (CO2). water spray***
Extinguishing media which must not be used for safety reasons
Do not use a solid water stream as it may scatter and spread fire.
Special exposure hazards arising from the substance or preparation itself, its combustion products, or released
gases
Under conditions giving incomplete combustion, hazardous gases produced may consist of
carbon monoxide
carbon dioxide (CO2)
Combustion gases of organic materials must in principle be graded as inhalation poisons***
Special protective equipment for fire-fighters
Wear self contained breathing apparatus for fire fighting if necessary.
Environmental precautions
Dike and collect water used to fight fire***
Other Information
This is a water-based product and presents no particular fire or explosion hazard.
6. Accidental release measures
Personal precautions
Contaminated surfaces will be extremely slippery. Avoid contact with the skin and the eyes.
Environmental precautions
Do not allow material to contaminate ground water system. Do not flush into surface water or sanitary sewer system.
Methods for cleaning Up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable,
closed containers for disposal. Contaminated equipment (brushes, rags) must be cleaned immediately with water.
Dispose of in accordance with local regulations***
7. Handling and storage
Handling
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EC SAFETY DATA SHEET 2001/58/EG
_______________________________________________________________________________________________
Product name Vinacryl 4333 EU/EN
MSDS number 85364 Revision Date Jun.15.2005
Revision Number 0.02*** Issuing date Jul.25.2007***
_______________________________________________________________________________________________
Advice on safe handling
Product may contain hazardous volatile ingredients which could accumulate in the unvented headspace of drums or
containers. Open containers in ventilated area. Do not breathe vapor.
Protection - fire and explosion:
No special protective measures against fire required.
Storage
Material storage
Protect from frost. To maintain product quality, do not store in heat or direct sunlight. Keep at temperatures between
5 and 35 掳C (40 and 95*** F)***
Technical measures/Storage conditions
Keep tightly closed in a dry and cool place. No special technical protective measures required.
Incompatible products
No special restrictions on storage with other products.
German storage class
12: Non-combustible liquids.
8. Exposure controls / personal protection
National occupational exposure limits (Germany)
No exposure limits established.***
ACGIH Exposure Limits
No exposure limits established.***
Exposure controls
Engineering measures Provide adequate ventilation. Where reasonably practicable this should be achieved
by the use of local exhaust ventilation and good general extraction***
Personal protective equipment
General advice Avoid contact with skin and eyes.
Hygiene measures Wash hands before breaks and at the end of workday. When using, do not eat, drink
or smoke. Take off all contaminated clothing immediately. Wash contaminated
clothing before re-use.
Eye protection safety glasses.
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EC SAFETY DATA SHEET 2001/58/EG
_______________________________________________________________________________________________
Product name Vinacryl 4333 EU/EN
MSDS number 85364 Revision Date Jun.15.2005
Revision Number 0.02*** Issuing date Jul.25.2007***
_______________________________________________________________________________________________
Hand protection
Chemicals resistant gloves***
Suitable material rubber gloves
Type These types of protective gloves are offered by various manufacturers. Please note
the manufacturers麓 detailed statements, especially about the minimum thickness and
the minimum breakthrough time. Consider also the particular working conditions
under which the gloves are being used***
9. Physical and chemical properties
Appearance
Form liquid***
Colour white***
Odor acrylic-like ***
Flash point Not applicable***
Melting point/range 0掳C***
Boiling point/range 100掳C***
pH 6.25 - 7.5
Viscosity 200 mPa*s
vapor pressure 22.66 hPa @ 25掳C***
Water solubility miscible***
10. Stability and reactivity
Stability Stable under recommended storage conditions
Conditions to avoid Do not freeze
Materials to avoid materials that react with water.
Thermal decomposition This cross-linked polymer will release formaldehyde in application processes
involving the use of greater than 100 掳C (212 F).
Hazardous reactions No hazards to be especially mentioned.
11. Toxicological information
Toxicological data are not available. Observe the usual hygienic measures for handling chemicals.
12. Ecological information
Ecotoxicological data are not available. According to experience, the material has no harmful effect on the environment.
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EC SAFETY DATA SHEET 2001/58/EG
_______________________________________________________________________________________________
Product name Vinacryl 4333 EU/EN
MSDS number 85364 Revision Date Jun.15.2005
Revision Number 0.02*** Issuing date Jul.25.2007***
_______________________________________________________________________________________________
13. Disposal considerations
Product information Disposal required in compliance with all waste management related state and local
regulations. The choice of the appropriate method of disposal depends on the
product composition by the time of disposal as well as the local statutes and
possibilities for disposal. Diluted solution may be introduced into a biological
purification plant, with permission of the responsible authorities
Uncleaned empty packaging Contaminated packaging should be emptied as far as possible and after appropriate
cleansing may be taken for reuse. Regulations concerning reuse or disposal of used
packaging materials must be observed.
European Waste Catalogue Allocation of a waste code number, according to the European Waste Catalogue
(EWC), should be carried out in agreement with the regional waste disposal
company.
14. Transport information
ADR/RID Not regulated
ADNR Not regulated
ICAO/IATA not restricted
IMDG Not regulated
15. Regulatory information
Labelling in accordance with EC directives
The product does not require a hazard warning label in accordance with EC directives/the relevant national laws.***
Water Hazard Class (WGK):
WGK Class 1
WGK Source Classification based on addendum 4 (VwVwS)
16. Other information
For further information, see:
For more information, consult the Technical Data Sheet (www.celanese-emulsions.com)***
Other Information:
Traces of residual monomers can be found in the product:. Butylacrylate . Methyl methacrylate. N-methylolacrylamide.
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EC SAFETY DATA SHEET 2001/58/EG
_______________________________________________________________________________________________
Product name Vinacryl 4333 EU/EN
MSDS number 85364 Revision Date Jun.15.2005
Revision Number 0.02*** Issuing date Jul.25.2007***
_______________________________________________________________________________________________
Changes against the previous version are marked by ******
Sources of key data used to compile the datasheet
Information contained in this safety data sheet is based on Celanese owned data and public sources deemed valid or
acceptable. The absence of data elements required by ANSI or 2001/58/EC indicates, that no data meeting these
requirements is available.
Further information
This information is based on our present state of knowledge. It shall describe our products regarding safety requirements
and shall not be construed as a guarantee or statement of condition and/or quality
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