MATERIAL SAFETY DATA SHEET
COLOREX 鈥? PAP-CG
SECTION 1: CHEMICAL PRODUCT & COMPANY IDENTIFICATION
CHEMICAL COMPOUNDS INC.
MANUFACTURER
29-75 RIVERSIDE AVE.
NEWARK, NJ 07104
January 26, 2005
REVISION DATE
4-Amino-Phenol
CHEMICAL NAME
p-AMINOPHENOL
CTFA ADOPTED NAME
C6H7NO
EMPIRICAL FORMULA
SECTION 2: COMPOSITION, INFORMATION ON INGREDIENTS
CAS # EINECS/ELINCS Molecular Weight
123-30-8 214-616-2 109.14
STRUCTURAL FORMULA:
OH
NH 2
Synonyms: ACTIVOL * P-AMINOFENOL (CZECH) * 4-AMINO-1-HYDROXYBENZENE * 4-
AMINOPHENOL * AZOL * BASF URSOL P BASE * BENZOFUR P * CERTINAL * C.I.
76550 * C.I. OXIDATION BASE 6A * CITOL * DURAFUR BROWN RB * FOURAMINE
P * FOURRINE 84 * FOURRINE P BASE * FURRO P BASE * P-HYDROXYANILINE *
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4-HYDROXYANILINE * NAKO BROWN R * PARANOL * PELAGOL GREY P BASE *
PELAGOL P BASE * RENAL AC * RODINAL * TERTRAL P BASE * UNAL
SECTION 3: HAZARDS IDENTIFICATION
LABEL PRECAUTIONARY STATEMENTS
TOXIC (USA)
HARMFUL (EU)
HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
MAY CAUSE SENSITIZATION BY INHALATION AND SKIN CONTACT.
POSSIBLE RISK OF IRREVERSIBLE EFFECTS.
POSSIBLE MUTAGEN/TERATOGEN.
TARGET ORGAN(S):
BLOOD, KIDNEYS
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
WEAR SUITABLE PROTECTIVE CLOTHING.
DO NOT BREATHE DUST.
AIR AND LIGHT SENSITIVE
STORE UNDER NITROGEN.
SECTION 4: FIRST AID MEASURES
Eyes; flush immediately with plenty of cold water for
EMERGENCY AND FIRST AID PROCEDURES
15 minutes. Get prompt medical attention.
Skin; wash exposed skin with soap and water. Get
medical attention if irritation occurs.
Inhalation: remove to fresh air; administer oxygen if
breathing is difficult. If breathing has stopped, apply
artificial respiration & seek immediate medical
attention.
Ingestion; seek medical attention. Do not induce
vomiting, immediately transport the individual to a
hospital.
SECTION 5: FIREFIGHTING MEASURES
N/A
FLASH POINT (Deg. C)
N/A
FLAMMABLE LIMITS
Dry Chemical, Carbon Dioxide, or Halon
EXTINGUISHING MEDIA
Wear proper protective equipment and a self-
SPECIAL FIRE FIGHTING PROCEDURES
contained breathing apparatus
Dust clouds in the air may combust liberating
UNUSUAL FIRE AND EXPLOSION HAZARDS
explosive mixtures with the air
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SECTION 6: ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Ventilate the area. Wear proper protective equipment and shovel /sweep up spilled material. Remove all
sources of ignition. Place in a DOT approved container for disposal, according to regulatory agencies鈥?
procedures.
WASTE DISPOSAL METHOD
Dispose via treatment system in accordance with appropriate local, state, & federal regulations. Do not
flush to surface water or sanitary sewer system.
SECTION 7: HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
Use adequate ventilation when transferring product from bags or drums. Wear respiratory protection if
ventilation is inadequate or not available. Use respiratory, eye and skin protection when contact is expected.
Use clean plastic or stainless steel scoops only. Store in a cool, clean, dry place away from point sources of
heat e.g. radiant heaters or steam pipes.
OTHER PRECAUTIONS:
Workers should shower and wear a fresh change of clothing after each shift. Wash all exposed areas with
soap and water before eating and after handling material. In case of fire or decomposition, deluge with
plenty of water to control decomposition.
SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION
Dust mask (3M # 8710 Dust & Mist Respirator)
RESPIRATORY PROTECTION
NIOSH/MSHA Approved
Local exhaust as needed
VENTILATION
Chemical Resistant Rubber or Neoprene
PROTECTION GLOVES
NIOSH/MSHA Approved Dust goggles/Safety glasses
EYE PROTECTION
Impervious & disposal clothing
OTHER PROTECTIVE EQUIPMENT
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Pure White Powder
APPEARANCE
N/A
SPECIFIC GRAVITY
N/A
BOILING POINT
187 Deg. C
MELTING POINT (Deg. C, min.)
N/A
VAPOR PRESSURE (mm Hg.)
Slightly Soluble in water
SOLUBILITY IN WATER
NOT REACTIVE
REACTIVITY IN WATER
N/A
EVAPORATION RATE
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SECTION 10: STABILITY AND REACTIVITY
Stable
STABILITY
Extreme heat
CONDITIONS TO AVOID
Strong acids, oxidants and alkalis
INCOMPATIBILITY
Oxides of carbon, nitrogen and aromatic amines and
HAZARDOUS DECOMPOSITION PRODUCTS
amine derivatives
Will not occur
HAZARDOUS POLYMERIZATION
SECTION 11: TOXICOLOGICAL INFORMATION
Rat - 375 mg./kg.
LD50 (Species/ orally)
Not Available
NTP Carcinogenesis Study
Moderately toxic via subcutaneous routes. Highly toxic
TOXICITY EVALUATION
via ingestion. It has been reported to cause of contact
dermatitis and bronchial asthma. An allergen.
SECTION 12: ECOLOGICAL INFORMATION
DATA NOT YET AVAILABLE
SECTION 13: DISPOSAL CONSIDERATION
DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A
CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
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SECTION 14: TRANSPORTATION INFORMATION
Not listed
EXTRAORDINARILY HAZARDOUS
SUBSTANCE
(N.J.A.C. 7:31-2)
Not listed
SARA TITLE III
SECTION 302-303
(40 CFR 355)
ACUTE - YES
SARA TITLE III
CHRONIC - YES
HAZARD CLASSIFICATIONS
FIRE - NO
SECTION 311, 312
REACTIVITY - NO
(40 CFR 370)
PRESSURE 鈥? NO
Not listed
SARA TITLE III
SECTION 313 REPORTING
(40 CFR 372)
Listed
U.S. TSCA STATUS
YES
DOT REGULATED
p-AMINOPHENOL
PROPER SHIPPING NAME
6.1, UN 2512, PACKING GROUP III
HAZARD CLASS
TOXIC
DOT LABEL REQUIRED
Health - 3
NFPA Rating 1
Fire - 1
3 1
Reactivity - 1
1
Special - 1
(Personal Protective Equip.)
SECTION 15: REGULATORY INFORMATION
EUROPEAN INFORMATION
EC INDEX NO: 612-033-00-3
HARMFUL
R 20/22
HARMFUL BY INHALATION AND IF SWALLOWED.
R 68
POSSIBLE RISK OF IRREVERSIBLE EFFECTS.
R 50/53
VERY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE
EFFECTS IN THE AQUATIC ENVIRONMENT.
S 28
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AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER.
S 36/37
WEAR SUITABLE PROTECTIVE CLOTHING AND GLOVES.
S 60
THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS
HAZARDOUS WASTE.
S 61
AVOID RELEASE TO THE ENVIRONMENT. REFER TO SPECIAL INSTRUCTIONS/
MATERIAL SAFETY DATA SHEETS.
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
OEL-RUSSIA:STEL 1 MG/M3 JAN 1993
OEL-POLAND: MAC(TWA) 5 MG/M3 (DUDT), JAN1999
NOES 1983: HZD A1481; NIS 4; TNF 5320; NOS 6; TNE 49882; TFE 37110
EPA GENETOX PROGRAM 1988, POSITIVE: SPERM MORPHOLOGY-MOUSE
EPA GENETOX PROGRAM 1988, NEGATIVE: HISTIDINE REVERSION-AMES TEST
EPA GENETOX PROGRAM 1988, INCONCLUSIVE: MAMMALIAN MICRONUCLEUS
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, DECEMBER 1999
SECTION 16: ADDITIONAL INFORMATION
The information and recommendations set forth herein are presented in good faith and believed to be as correct as of the date hereof,
Chemical Compounds Inc. makes no representations as to the completeness or accuracy thereof. Information is supplied upon the
condition that the receiving will make their own determination as to its suitability for their purposes prior to use. In no event will
Chemical Compounds Inc. be responsible for damage of any nature whatsoever resulting from the use of or the reliance upon
information.
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