FUDGE HEAD PAINT PROFESSIONAL - OXIDANT
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-24
Issue Date: Tue 8-May-2001 CD 2003/3 Page 1 of 9
IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS ACCORDING TO WORKSAFE AUSTRALIA CRITERIA.
SUPPLIER
Company:
Sabre Corporation P/L
Address:
75 South Creek Road
Dee Why
NSW, 2099
AUS
Telephone: (+61 2) 9982 0100
Fax: (+61 2) 9972 0747
CHEMWATCH HAZARD RATINGS
Flammability:
Toxicity:
Body Contact:
Reactivity:
Chronic:
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
SYNONYMS
SHIPPING NAME
NONE
Product Name: Fudge Head Paint Professional - Oxidant
Other Names:
CAS RN No(s): None
UN Number: None
Packing Group: None
Dangerous Goods Class: None
Subsidiary Risk: None
Hazchem Code: None
Poisons Schedule Number: None
USE
Hair colour product. Not for use on eyelashes or eyebrows.
PHYSICAL DESCRIPTION/PROPERTIES
continued...
FUDGE HEAD PAINT PROFESSIONAL - OXIDANT
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-24
Issue Date: Tue 8-May-2001 CD 2003/3 Page 2 of 9
IDENTIFICATION ...
APPEARANCE
Ivory white emulsion with characteristic odour; mixes with water.
Viscosity 155 mPas.
Boiling Point (掳C): Not available
Melting Point (掳C): Not available
Vapour Pressure (kPa): Not available.
Specific Gravity: Not available
Flash Point (掳C): Not applicable
Lower Explosive Limit (%): Not applicable
Upper Explosive Limit (%): Not applicable
Solubility in Water (g/L): Miscible
INGREDIENTS
NAME CAS RN %
hydrogen peroxide 7722-84-1 <6
cetostearyl alcohol 67762-27-0 <5^
phosphoric acid 7664-38-2 <1^
additives unregulated, including balance
conditioners, emuilsifiers, chelating agents
solubilisers
HEALTH HAZARD
ACUTE HEALTH EFFECTS
SWALLOWED
Considered an unlikely route of entry in commercial/industrial environments
The liquid is discomforting to the gastro-intestinal tract and may be harmful if
swallowed
Ingestion may result in nausea, abdominal irritation, pain and vomiting
EYE
The liquid is discomforting to the eyes
Symptoms of exposure may be delayed.
The material may be irritating to the eye, with prolonged contact causing
inflammation. Repeated or prolonged exposure to irritants may produce
conjunctivitis.
SKIN
The liquid is discomforting to the skin
Skin contact may cause bleaching.
The material may cause skin irritation after prolonged or repeated exposure and
may produce on contact skin redness, swelling, the production of vesicles,
scaling and thickening of the skin.
continued...
FUDGE HEAD PAINT PROFESSIONAL - OXIDANT
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-24
Issue Date: Tue 8-May-2001 CD 2003/3 Page 3 of 9
HEALTH HAZARD ...
INHALED
Not normally a hazard due to non-volatile nature of product
CHRONIC HEALTH EFFECTS
Principal route of exposure is usually by skin contact.
Prolonged or repeated skin contact may cause drying with cracking, irritation
and possible dermatitis following.
As with any chemical product, contact with unprotected bare skin; inhalation of
vapour, mist or dust in work place atmosphere; or ingestion in any form, should
be avoided by observing good occupational work practice.
FIRST AID
SWALLOWED
If poisoning occurs, contact a doctor or Poisons Information Centre.
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
路 Observe the patient carefully.
路 Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconsciousness
路 Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
路 Seek medical advice.
EYE
If this product comes in contact with the eyes:
路 Wash out immediately with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
路 If pain persists or recurs seek medical attention.
路 Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin contact occurs:
路 Immediately remove all contaminated clothing, including footwear
路 Flush skin and hair with running water (and soap if available).
路 Seek medical attention in event of irritation.
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
路 Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
continued...
FUDGE HEAD PAINT PROFESSIONAL - OXIDANT
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-24
Issue Date: Tue 8-May-2001 CD 2003/3 Page 4 of 9
HEALTH HAZARD ...
路 Transport to hospital, or doctor.
ADVICE TO DOCTOR
Treat symptomatically.
PRECAUTIONS FOR USE
EXPOSURE STANDARDS
ES TWA is NOHSC Exposure Standard Australia
OES is British Occupational Exposure Standard
TLVTWA is USAACGIH Exposure Standard
None assigned. Refer to individual constituents.
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m鲁): 1.4 mg/m鲁
If the breathing zone concentration of ANYof the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m鲁 Mixture Conc: (%)
hydrogen peroxide 1 1.4 6
Operations which produce a spray/mist or fume/dust, introduce particulates to
the breathing zone.
If the breathing zone concentration of ANYof the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
At the "Composite Exposure Standard for Mixture" (TWA) (mg/m鲁): 6 mg/m鲁
Component Breathing Zone ppm Breathing Zone mg/m鲁 Mixture Conc (%)
INGREDIENT DATA
HYDROGEN PEROXIDE:
TLVTWA: 1 ppm A3 [ACGIH]
PEL TWA: 1 ppm, 1.4 mg/m鲁 [OSHAZ1]
TLVTWA: 1 ppm, 1.4 mg/m鲁 A3
CAUTION: This substance has been classified by the ACGIH as A3 Animal Carcinogen
(at relativelyhigh doses)
ES TWA: 1 ppm, 1.5 mg/m鲁
OES TWA: 1 ppm, 1.4 mg/m鲁; STEL: 2 ppm, 2.8 mg/m鲁
MAK value: 1 ppm, 1.4 mg/m鲁
MAK Category I Peak Limitation: For local irritants Allows excursions of twice
the MAK value for 5 minutes at a time, 8 times per shift.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
IDLH Level: 75 ppm
NOTE: Detector tubes for hydrogen peroxide, measuring in excess of 0.1 ppm,
continued...
FUDGE HEAD PAINT PROFESSIONAL - OXIDANT
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-24
Issue Date: Tue 8-May-2001 CD 2003/3 Page 5 of 9
PRECAUTIONS FOR USE ...
are available commercially.
Exposure at or below the TLV-TWA is thought to minimise irritation and
bleaching of hair.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of
overexposure exists, wear SAA approved respirator. Correct fit is essential to
obtain adequate protection. Provide adequate ventilation in warehouse or closed
storage areas. Air contaminants generated in the workplace possess varying
"escape" velocities which, in turn, determine the "capture velocities" of fresh
circulating air required to effectivelyremove the contaminant.
Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., 0.25-0.5 m/s (50-100 f/min)
evaporating from tank (in still air)
aerosols, fumes from pouring 0.5-1 m/s (100-200 f/min.)
operations, intermittent container
filling, low speed conveyer transfers,
welding, spray drift, plating acid
fumes, pickling (released at low
velocity into zone of active
generation)
direct spray, spray painting in shallow 1-2.5 m/s (200-500 f/min)
booths, drum filling, conveyer loading,
crusher dusts, gas discharge (active
generation into zone of rapid air
motion)
grinding, abrasive blasting, tumbling, 2.5-10 m/s (500-2000 f/min.)
high speed wheel generated dusts
(released at high initial velocity into
zone of veryhigh rapid air motion).
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or 1: Disturbing room air currents
favourable to capture
2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
nuisance value only
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in 4: Small hood - local control only
motion
Simple theory shows that air velocity falls rapidlywith distance away from the
opening of a simple extraction pipe. Velocity generallydecreases with the
square of distance from the extraction point (in simple cases). Therefore the
air speed at the extraction point should be adjusted, accordingly, after
reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.) for
extraction of solvents generated in a tank 2 meters distant from the extraction
continued...
FUDGE HEAD PAINT PROFESSIONAL - OXIDANT
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-24
Issue Date: Tue 8-May-2001 CD 2003/3 Page 6 of 9
PRECAUTIONS FOR USE ...
point. Other mechanical considerations, producing performance deficits within
the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or
used.
Refer also to protective measures for the other component used with the product.
Read both MSDS before using; store and attach MSDS together.
PERSONAL PROTECTION
EYE
Safetyglasses with side shields; or as required, Chemical goggles. Contact
lenses pose a special hazard; soft lenses may absorb irritants and all lenses
concentrate them.
HANDS/FEET
Wear protective gloves, eg. PVC.
OTHER
Overalls.
Eyewash unit.
RESPIRATOR
Respiratory protection is required when ANY"Worst Case" vapour-phase
concentration is exceeded (see Computer Prediction in "Exposure Standards").
Protection Factor (Min) Half-Face Respirator Full-Face Respirator
10 xES AB-AUS -
AB-PAPR-AUS -
50 xES - AB-AUS
- AB-PAPR-AUS
100 xES - AB-2
- AB-PAPR-2
^ - Full-face
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and SafetyAdvisor.
SAFE HANDLING
STORAGE AND TRANSPORT
continued...
FUDGE HEAD PAINT PROFESSIONAL - OXIDANT
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-24
Issue Date: Tue 8-May-2001 CD 2003/3 Page 7 of 9
SAFE HANDLING ...
SUITABLE CONTAINER
Plastic container
路 Check that containers are clearly labelled
STORAGE INCOMPATIBILITY
Avoid storage with reducing agents and combustible materials.
Avoid metallic bowls and stirrers.
Contaminated product generates oxygen gas. Pressure in container may build
up to dangerous levels.
STORAGE REQUIREMENTS
Protect from light.
路 Store in original containers.
路 Keep containers securely sealed.
路 Store in a cool, dry, well-ventilated area.
路 Store away from incompatible materials and foodstuff containers.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.
TRANSPORTATION
No restrictions.
SPILLS AND DISPOSAL
MINOR SPILLS
Slippery when spilt.
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Contain and absorb spill with sand, earth, inert material or vermiculite.
路 Wipe up.
路 Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Slippery when spilt.
Minor hazard.
路 Clear area of personnel.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Control personal contact by using protective equipment as required.
路 Prevent spillage from entering drains or water ways.
路 Contain spill with sand, earth or vermiculite.
路 Collect recoverable product into labelled containers for recycling.
路 Absorb remaining product with sand, earth or vermiculite and place in
appropriate containers for disposal.
路 Wash area and prevent runoff into drains or waterways.
路 If contamination of drains or waterways occurs, advise emergency services.
continued...
FUDGE HEAD PAINT PROFESSIONAL - OXIDANT
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-24
Issue Date: Tue 8-May-2001 CD 2003/3 Page 8 of 9
SAFE HANDLING ...
DISPOSAL
路 Recycle wherever possible or consult manufacturer for recycling options.
路 Consult State Land Waste Management Authority for disposal.
路 Bury residue in an authorised landfill.
路 Recycle containers if possible, or dispose of in an authorised landfill.
FIRE FIGHTERS' REPORT
EXTINGUISHING MEDIA
There is no restriction on the type of extinguisher which may be used.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear breathing apparatus plus protective gloves for fire only.
路 Prevent, by any means available, spillage from entering drains or water
courses.
路 Use fire fighting procedures suitable for surrounding area.
路 DO NOT approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
路 Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
路 Non combustible.
路 Not considered to be a significant fire risk.
路 Expansion or decomposition on heating may lead to violent rupture of
containers.
路 Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
路 May emit acrid smoke.
Other decomposition products include carbon dioxide (CO2) and nitrogen oxides
(NOx)
FIRE INCOMPATIBILITY
Avoid contact with combustible materials.
HAZCHEM
None
CONTACT POINT
COMPANYCONTACT
(+61 2) 9982 0100
AUSTRALIAN POISONS INFORMATION CENTRE
24 HOUR SERVICE: 13 11 26
continued...
FUDGE HEAD PAINT PROFESSIONAL - OXIDANT
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-24
Issue Date: Tue 8-May-2001 CD 2003/3 Page 9 of 9
CONTACT POINT ...
POLICE, FIRE BRIGADE OR AMBULANCE: 000
NEWZEALAND POISONS INFORMATION CENTRE
24 HOUR SERVICE: 0800 764 766
NZ EMERGENCYSERVICES: 111
End of Report
Issue Date: Tue 8-May-2001
Print Date: Mon 22-Sep-2003
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
|