FUDGE SPEED POWDER BLEACH (PROFESSIONAL USE ONLY)
ChemWatch Material Safety Data Sheet CHEMWATCH 4580-57
Issue Date: Tue 8-Aug-2000 CD 2003/3 Page 1 of 10
IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS ACCORDING TO WORKSAFE AUSTRALIA CRITERIA.
SUPPLIER
Company:
Sabre Corporation P/L
Address:
75 South Creek Road
Dee Why
NSW, 2099
AUS
Telephone: (+61 2) 9982 0100
Fax: (+61 2) 9972 0747
CHEMWATCH HAZARD RATINGS
Flammability:
Toxicity:
Body Contact:
Reactivity:
Chronic:
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
SYNONYMS
SHIPPING NAME
NONE
Product Name: Fudge Speed Powder Bleach (Professional Use Only)
Other Names:
CAS RN No(s): None
UN Number: None
Packing Group: None
Dangerous Goods Class: None
Subsidiary Risk: None
Hazchem Code: None
Poisons Schedule Number: None
USE
Powder bleach.
Product must not be used for bleaching eyelashes or eyebrows.
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FUDGE SPEED POWDER BLEACH (PROFESSIONAL USE ONLY)
ChemWatch Material Safety Data Sheet CHEMWATCH 4580-57
Issue Date: Tue 8-Aug-2000 CD 2003/3 Page 2 of 10
IDENTIFICATION ...
PHYSICAL DESCRIPTION/PROPERTIES
APPEARANCE
Powder with a characteristic odour; dispersible and partly soluble in water.
Oxidising agent.
Boiling Point (掳C): Not applicable.
Melting Point (掳C): Not available
Vapour Pressure (kPa): Not available
Specific Gravity: Not available
Flash Point (掳C): Not applicable
Lower Explosive Limit (%): Not applicable
Upper Explosive Limit (%): Not applicable
Solubility in Water (g/L): Partlymiscible
INGREDIENTS
NAME CAS RN %
potassium persulfate 7727-21-1 15-20
ammonium persulfate 7727-54-0 15-20
sodium metasilicate, anhydrous 6834-92-0 15-20
sodium persulfate 7775-27-1 4-8
cetyltrimethylammonium bromide 57-09-0 1-5
conditioners, emulsifiers, chelating agent
solubilisers, pigments nonhazardous bal.
HEALTH HAZARD
ACUTE HEALTH EFFECTS
SWALLOWED
The material is highly discomforting to the gastro-intestinal tract and may be
harmful if swallowed
Sulfates are not well absorbed orally, but can cause diarrhoea.
Ingestion may result in nausea, abdominal irritation, pain and vomiting
EYE
The dust is highly discomforting to the eyes and may be corrosive and may cause
burns
The material may produce severe irritation to the eye causing pronounced
inflammation. Repeated or prolonged exposure to irritants may produce
conjunctivitis.
SKIN
The material is moderately discomforting to the skin and may be capable of
causing allergic skin reactions
Open cuts, abraded or irritated skin should not be exposed to this material
Solution of material in moisture on the skin, or perspiration, may markedly
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FUDGE SPEED POWDER BLEACH (PROFESSIONAL USE ONLY)
ChemWatch Material Safety Data Sheet CHEMWATCH 4580-57
Issue Date: Tue 8-Aug-2000 CD 2003/3 Page 3 of 10
HEALTH HAZARD ...
increase skin corrosion and accelerate tissue destruction
The material may accentuate any pre-existing skin condition
The material may cause severe skin irritation after prolonged or repeated
exposure and may produce on contact skin redness, swelling, the production of
vesicles, scaling and thickening of the skin. Repeated exposures may produce
severe ulceration.
INHALED
The dust is moderately discomforting to the upper respiratory tract
Persons with impaired respiratory function, airway diseases and conditions such
as emphysema or chronic bronchitis, may incur further disability if excessive
concentrations of particulate are inhaled.
Dust inhalation may cause nose, throat, mucous membrane and respiratory
tract irritation, coughing, shortness of breath and chest discomfort.
CHRONIC HEALTH EFFECTS
Principal routes of exposure are by accidental skin and eye contact and
inhalation of generated dusts.
Persulfate exposure commonly manifests itself in the form of a skin rash, eczema
and respiratory conditions such as asthma. Allergy may develop after repeated
exposures.
Sensitisation may give severe responses to very low levels of exposure, i.e.
hypersensitivity. Sensitised persons should not be allowed to work in situations
where exposure may occur.
FIRST AID
SWALLOWED
If poisoning occurs, contact a doctor or Poisons Information Centre.
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
路 Observe the patient carefully.
路 Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconsciousness
路 Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
路 Seek medical advice.
EYE
If this product comes in contact with the eyes:
路 Immediately hold eyelids apart and flush the eye continuously with running
water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
路 Continue flushing until advised to stop by the Poisons Information Centre or a
doctor, or for at least 15 minutes.
路 Transport to hospital or doctor without delay.
路 Removal of contact lenses after an eye injury should only be undertaken by
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FUDGE SPEED POWDER BLEACH (PROFESSIONAL USE ONLY)
ChemWatch Material Safety Data Sheet CHEMWATCH 4580-57
Issue Date: Tue 8-Aug-2000 CD 2003/3 Page 4 of 10
HEALTH HAZARD ...
skilled personnel.
SKIN
If skin contact occurs:
路 Immediately remove all contaminated clothing, including footwear
路 Flush skin and hair with running water (and soap if available).
路 Seek medical attention in event of irritation.
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
路 Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
路 Transport to hospital, or doctor.
ADVICE TO DOCTOR
Treat symptomatically.
PRECAUTIONS FOR USE
EXPOSURE STANDARDS
None assigned. Refer to individual constituents.
ODOUR SAFETY FACTOR (OSF)
OSF=1.1 (ammonium persulfate)
Exposed individuals are NOT reasonablyexpected to be warned, by smell, that the
Exposure Standard is being exceeded.
Odour SafetyFactor (OSF) is determined to fall into either Class C, D or E.
The Odour SafetyFactor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed
individuals are aware by
smell that the Exposure
Standard (TLV-TWA for
example) is being
reached, even when
distracted by working
activities
B 26-550 As "A" for 50-90% of
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FUDGE SPEED POWDER BLEACH (PROFESSIONAL USE ONLY)
ChemWatch Material Safety Data Sheet CHEMWATCH 4580-57
Issue Date: Tue 8-Aug-2000 CD 2003/3 Page 5 of 10
PRECAUTIONS FOR USE ...
persons being distracted
C 1-26 As "A" for less than 50%
of persons being
distracted
D 0.18-1 10-50% of persons aware
of being tested perceive
by smell that the
Exposure Standard is
being reached
E <0.18 As "D" for less than 10%
of persons aware of being
tested
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
and concentration:
Composite Exposure Standard for Mixture (TWA) :2.381 mg/m鲁.
Operations which produce a spray/mist or fume/dust, introduce particulates to
the breathing zone.
If the breathing zone concentration of ANYof the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m鲁 Mixture Conc (%)
sodium metasilicate, anhydrous 1.9048 20 0
cetyltrimethylammonium bromide 0.4762 5 0
INGREDIENT DATA
For each of the following
POTASSIUMPERSULFATE:
SODIUMPERSULFATE:
TLVTWA: 0.1 mg/m鲁 [ACGIH]
persulfates, as persulfates
TLVTWA: 0.1 mg/m鲁
Persulfates produce irritation of the respiratory tract.
AMMONIUMPERSULFATE:
TLVTWA: 0.1 mg/m鲁 [ACGIH]
persulfates, as persulfates
TLVTWA: 0.1 mg/m鲁
Persulfates produce irritation of the respiratory tract.
SODIUMMETASILICATE, ANHYDROUS:
CEL TWA: 2 mg/m鲁 [Manufacturer]
CETYLTRIMETHYLAMMONIUMBROMIDE:
No exposure limits set by NOHSC or ACGIH
Dusts not otherwise classified, as inspirable dust;
ES TWA: 10 mg/m鲁
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FUDGE SPEED POWDER BLEACH (PROFESSIONAL USE ONLY)
ChemWatch Material Safety Data Sheet CHEMWATCH 4580-57
Issue Date: Tue 8-Aug-2000 CD 2003/3 Page 6 of 10
PRECAUTIONS FOR USE ...
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. Local exhaust
ventilation may be required in specific circumstances. If risk of overexposure
exists, wear approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.
Air contaminants generated in the workplace possess varying "escape" velocities
which, in turn, determine the "capture velocities" of fresh circulating air
required to effectivelyremove the contaminant.
Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., 0.25-0.5 m/s (50-100 f/min)
evaporating from tank (in still air).
aerosols, fumes from pouring 0.5-1 m/s (100-200 f/min.)
operations, intermittent container
filling, low speed conveyer transfers,
welding, spray drift, plating acid
fumes, pickling (released at low
velocity into zone of active
generation)
direct spray, spray painting in shallow 1-2.5 m/s (200-500 f/min.)
booths, drum filling, conveyer loading,
crusher dusts, gas discharge (active
generation into zone of rapid air
motion)
grinding, abrasive blasting, tumbling, 2.5-10 m/s (500-2000 f/min.)
high speed wheel generated dusts
(released at high initial velocity into
zone of veryhigh rapid air motion).
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or 1: Disturbing room air currents
favourable to capture
2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
nuisance value only.
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in 4: Small hood-local control only
motion
Simple theory shows that air velocity falls rapidlywith distance away from the
opening of a simple extraction pipe. Velocity generallydecreases with the
square of distance from the extraction point (in simple cases). Therefore the
air speed at the extraction point should be adjusted, accordingly, after
reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min) for
extraction of solvents generated in a tank 2 meters distant from the extraction
point. Other mechanical considerations, producing performance deficits within
the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or
used.
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FUDGE SPEED POWDER BLEACH (PROFESSIONAL USE ONLY)
ChemWatch Material Safety Data Sheet CHEMWATCH 4580-57
Issue Date: Tue 8-Aug-2000 CD 2003/3 Page 7 of 10
PRECAUTIONS FOR USE ...
PERSONAL PROTECTION
EYE
Safetyglasses with side shields; or as required, Chemical goggles. Contact
lenses pose a special hazard; soft lenses may absorb irritants and all lenses
concentrate them.
HANDS/FEET
Wear protective gloves, eg. PVC.
OTHER
Overalls
Impervious apron
Eyewash unit.
RESPIRATOR
Protection Factor Half-Face Full-Face Powered Air
Respirator Respirator Respirator
10 xES P1 Air-line* -- PAPR-P1 -
50 xES Air-line** P2 PAPR-P2
100 xES - P3 -
Air-line* -
100+ xES - Air-line** PAPR-P3
* - Negative pressure demand ** - Continuous flow
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and SafetyAdvisor.
SAFE HANDLING
STORAGE AND TRANSPORT
SUITABLE CONTAINER
Plastic container
路 Check that containers are clearly labelled
STORAGE INCOMPATIBILITY
Avoid storage with organic material, reducing agents such as waving lotions,
combustible materials, acids, alkalis and metal powders.
Do not use metallic bowls or stirrers.
Do not store after mixing with developer and lightener lotion. The container
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FUDGE SPEED POWDER BLEACH (PROFESSIONAL USE ONLY)
ChemWatch Material Safety Data Sheet CHEMWATCH 4580-57
Issue Date: Tue 8-Aug-2000 CD 2003/3 Page 8 of 10
SAFE HANDLING ...
may rupture.
STORAGE REQUIREMENTS
路 Store in original containers in an isolated/detached store away from other
materials.
路 Keep containers securely sealed as supplied.
路 WARNING: Gradual decomposition during storage in sealed containers may lead to
a large pressure build-up and subsequent explosion.
路 No smoking, naked lights, heat or ignition sources.
路 Store under cover and away from sunlight.
路 Always store below 35 deg.C
路 Store away from flammable or combustible materials, debris and waste.
路 Store away from incompatible materials and foodstuffs containers.
路 DO NOT stack on wooden floors or wooden pallets.
路 Protect containers against physical damage.
路 Check regularly for spills and leaks.
路 Observe manufacturer's storage and handling recommendations.
路 Keep locked up.
路 Restrictions may apply on quantities and to other materials permitted in the
same location.
TRANSPORTATION
No restrictions.
SPILLS AND DISPOSAL
MINOR SPILLS
路 Clean up all spills immediately.
路 No smoking, naked lights, ignition sources.
路 Avoid all contact with any organic matter including fuel, solvents, sawdust,
paper or cloth and other incompatible materials, as ignition may result.
路 Avoid breathing dust or vapours and all contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Contain and absorb spill with dry sand, earth, inert material or vermiculite.
路 DO NOT use sawdust as fire may result.
路 Scoop up solid residues and seal in labelled drums for disposal.
路 Neutralise/decontaminate area.
MAJOR SPILLS
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear full body protective clothing with breathing apparatus.
路 Prevent, by any means available, spillage from entering drains or water
courses.
路 No smoking, flames or ignition sources.
路 Increase ventilation.
路 Contain spill with sand, earth or other clean, inert materials.
路 NEVER USE organic absorbents such as sawdust, paper or cloth.
路 Use spark-free and explosion-proof equipment.
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FUDGE SPEED POWDER BLEACH (PROFESSIONAL USE ONLY)
ChemWatch Material Safety Data Sheet CHEMWATCH 4580-57
Issue Date: Tue 8-Aug-2000 CD 2003/3 Page 9 of 10
SAFE HANDLING ...
路 Collect any recoverable product into labelled containers for possible
recycling.
路 Avoid contamination with organic matter to prevent subsequent fire and
explosion.
路 DO NOT mix fresh with recovered material.
路 Collect residues and seal in labelled drums for disposal.
路 Wash area and prevent runoff into drains.
路 Decontaminate equipment and launder all protective clothing before storage and
re-use.
路 If contamination of drains or waterways occurs advise emergency services.
DISPOSAL
Small quantities (less than a cupful) can be flushed down the drain with
excess water.
路 Recycle wherever possible or consult manufacturer for recycling options.
路 Consult State Land Waste Authority for disposal.
路 Bury or incinerate residue at an approved site.
路 Recycle containers if possible, or dispose of in an authorised landfill.
FIRE FIGHTERS' REPORT
EXTINGUISHING MEDIA
Carbon dioxide.
Foam.
Flooding quantities of water only.
Aqueous solution can be more reactive than solid. Rapid dilution is needed.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear full body protective clothing with breathing apparatus.
路 Prevent, by any means available, spillage from entering drains or water
courses.
路 Fight fire from a safe distance, with adequate cover.
路 Extinguishers should be used only by trained personnel.
路 Use water delivered as a fine spray to control fire and cool adjacent area.
路 DO NOT approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
路 If fire gets out of control withdraw personnel and warn against entry.
路 Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
路 Will not burn but increases intensity of fire.
路 Heating may cause expansion or decomposition leading to violent rupture of
containers.
路 Heat affected containers remain hazardous.
路 Contact with combustibles such as wood, paper, oil or finely divided metal may
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FUDGE SPEED POWDER BLEACH (PROFESSIONAL USE ONLY)
ChemWatch Material Safety Data Sheet CHEMWATCH 4580-57
Issue Date: Tue 8-Aug-2000 CD 2003/3 Page 10 of 10
SAFE HANDLING ...
produce spontaneous combustion or violent decomposition.
路 May emit irritating, poisonous or corrosive fumes.
Decomposes on heating and produces toxic fumes of carbon dioxide (CO2) , sulfur
oxides (SOx) , nitrogen oxides (NOx) , caustic compounds and ammonia
FIRE INCOMPATIBILITY
Avoid any contamination of this material as it is very reactive and any
contamination is potentially hazardous
Avoid contact with organic materials / compounds as ignition may result
HAZCHEM
None
CONTACT POINT
COMPANYCONTACT
(+61 2) 9982 0100
AUSTRALIAN POISONS INFORMATION CENTRE
24 HOUR SERVICE: 13 11 26
POLICE, FIRE BRIGADE OR AMBULANCE: 000
NEWZEALAND POISONS INFORMATION CENTRE
24 HOUR SERVICE: 0800 764 766
NZ EMERGENCYSERVICES: 111
End of Report
Issue Date: Tue 8-Aug-2000
Print Date: Mon 22-Sep-2003
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
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