FUDGE FUEL
ChemWatch Material Safety Data Sheet CHEMWATCH 4720-43
Issue Date: Mon 31-Jan-2005 CD 2004/4 Page 1 of 12
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
FUDGE FUEL
SYNONYMS
PRODUCT USE
Leave-in restructuring treatment.
SUPPLIER
Company: Sabre Corporation P/L
Address:
75 South Creek Road
Dee Why
NSW, 2099
AUSTRALIA
Telephone: (+61 2) 9982 0100
Fax: 02 9972 0747
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
According to the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK
SAFETY
Do not breathe gas/fumes/vapour/spray.
Wear eye/face protection.
Take off immediately all contaminated clothing.
In case of contact with eyes, rinse with plenty of water and contact Doctor or
Poisons Information Centre.
If you feel unwell contact Doctor or Poisons Information Centre. (Show the label
if possible).
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FUDGE FUEL
ChemWatch Material Safety Data Sheet CHEMWATCH 4720-43
Issue Date: Mon 31-Jan-2005 CD 2004/4 Page 2 of 12
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
propylene glycol 57-55-6 40-60
decamethylcyclopentasiloxane 541-02-6 5-15
PEG/PPG-18/18 dimethicone 5-15
paraffin oils 8012-95-1. 5-15
imidazolidinyl urea 39236-46-9 <0.5^
5-chloro-2-methyl-4-isothiazolin-3-one 26172-55-4 <0.0015
2-methyl-4-isothiazolin-3-one 2682-20-4 <0.0015
other nonhazarodus ingredients, as 0-40
sodium chloride 7647-14-5 ^
sorbitan monostearate 1338-41-6 ^
perfume
colourants
water 7732-18-5
Section 4 - FIRST AID MEASURES
SWALLOWED
鈥? If swallowed do NOT induce vomiting.
鈥? If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
鈥? Observe the patient carefully.
鈥? Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconscious.
鈥? Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
鈥? Seek medical advice.
EYE
If this product comes in contact with the eyes:
鈥? Wash out immediately with fresh running water.
鈥? Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
鈥? If pain persists or recurs seek medical attention.
鈥? Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
Wipe off excess with absorbent tissue or towel.
Seek medical attention if swelling/redness/blistering or irritation occurs.
INHALED
鈥? If fumes or combustion products are inhaled remove from contaminated area.
鈥? Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
Propylene glycol is primarily a CNS depressant in large doses and may cause
hypoglycaemia, lactic acidosis and seizures.
鈥? The usual measures are supportive care and decontamination (Ipecac/ lavage/
activated charcoal/ cathartics), within 2 hours of exposure should suffice.
鈥? Check the anion gap, arterial pH, renal function and glucose levels.
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FUDGE FUEL
ChemWatch Material Safety Data Sheet CHEMWATCH 4720-43
Issue Date: Mon 31-Jan-2005 CD 2004/4 Page 3 of 12
Section 4 - FIRST AID MEASURES ...
Ellenhorn and Barceloux: Medical Toxicology
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
鈥? Foam.
鈥? Dry chemical powder.
鈥? BCF (where regulations permit).
鈥? Carbon dioxide.
鈥? Water spray or fog - Large fires only.
FIRE FIGHTING
鈥? Alert Fire Brigade and tell them location and nature of hazard.
鈥? Wear breathing apparatus plus protective gloves.
鈥? Prevent, by any means available, spillage from entering drains or water
course.
鈥? Use water delivered as a fine spray to control fire and cool adjacent area.
鈥? Avoid spraying water onto liquid pools.
鈥? Do not approach containers suspected to be hot.
鈥? Cool fire exposed containers with water spray from a protected location.
鈥? If safe to do so, remove containers from path of fire.
FIRE/EXPLOSION HAZARD
鈥? Combustible.
鈥? Slight fire hazard when exposed to heat or flame.
鈥? Heating may cause expansion or decomposition leading to violent rupture of
containers.
鈥? On combustion, may emit toxic fumes of carbon monoxide (CO).
鈥? May emit acrid smoke.
鈥? Mists containing combustible materials may be explosive.
Combustion products include.
carbon dioxide (CO2).
other pyrolysis products typical of burning organic material
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids,
chlorine bleaches, pool chlorine etc. as ignition may result
HAZCHEM
None
Personal Protective Equipment
PERSONAL PROTECTION EQUIPMENT
Breathing apparatus.
Chemical splash suit.
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FUDGE FUEL
ChemWatch Material Safety Data Sheet CHEMWATCH 4720-43
Issue Date: Mon 31-Jan-2005 CD 2004/4 Page 4 of 12
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
Slippery when spilt.
鈥? Remove all ignition sources.
鈥? Clean up all spills immediately.
鈥? Avoid breathing vapours and contact with skin and eyes.
鈥? Control personal contact by using protective equipment.
鈥? Contain and absorb spill with sand, earth, inert material or vermiculite.
鈥? Wipe up.
鈥? Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Slippery when spilt.
Moderate hazard.
鈥? Clear area of personnel and move upwind.
鈥? Alert Fire Brigade and tell them location and nature of hazard.
鈥? Wear breathing apparatus plus protective gloves.
鈥? Prevent, by any means available, spillage from entering drains or water
course.
鈥? No smoking, naked lights or ignition sources.
鈥? Increase ventilation.
鈥? Stop leak if safe to do so.
鈥? Contain spill with sand, earth or vermiculite.
鈥? Collect recoverable product into labelled containers for recycling.
鈥? Absorb remaining product with sand, earth or vermiculite.
鈥? Collect solid residues and seal in labelled drums for disposal.
鈥? Wash area and prevent runoff into drains.
鈥? If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
None under normal operating conditions.
鈥? Limit all unnecessary personal contact.
鈥? Wear protective clothing when risk of exposure occurs.
鈥? Use in a well-ventilated area.
鈥? When handling DO NOT eat, drink or smoke.
鈥? Always wash hands with soap and water after handling.
鈥? Avoid physical damage to containers.
鈥? Use good occupational work practice.
鈥? Observe manufacturer's storing and handling recommendations.
DO NOT allow clothing wet with material to stay in contact with skin
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FUDGE FUEL
ChemWatch Material Safety Data Sheet CHEMWATCH 4720-43
Issue Date: Mon 31-Jan-2005 CD 2004/4 Page 5 of 12
Section 7 - HANDLING AND STORAGE ...
SUITABLE CONTAINER
鈥? Metal can or drum
鈥? Packaging as recommended by manufacturer.
鈥? Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents
STORAGE REQUIREMENTS
鈥? Store in original containers.
鈥? Keep containers securely sealed.
鈥? No smoking, naked lights or ignition sources.
鈥? Store in a cool, dry, well-ventilated area.
鈥? Store away from incompatible materials and foodstuff containers.
鈥? Protect containers against physical damage and check regularly for leaks.
鈥? Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA TWA STEL STEL Peak Peak
ppm mg/m鲁 ppm mg/m鲁 ppm mg/m鲁
_________________________ ________________ _____ _____ _____ _____ _____ _____
Australian Exposure Propane-1,2-diol: 10
Standards particulates
only
Australian Exposure Propane-1,2-diol: 150 474
Standards total (vapour &
particulates)
Australian Exposure Oil mist, 5
Standards refined mineral
No data available for decamethylcyclopentasiloxane as (CAS: 541-02-6) / (CAS: 26172-55-4)
/ (CAS: 2682-20-4) / (CAS: 7732-18-5)
Not available. Refer to individual constituents.
INGREDIENT DATA
PROPYLENE GLYCOL:
ES TWA: 150 ppm, 474 mg/m鲁 (total vapour and particulates)
ES TWA: 10 mg/m鲁 (particulates only)
OES TWA: 150 ppm, 474 mg/m鲁 (total, vapour and particulates)
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FUDGE FUEL
ChemWatch Material Safety Data Sheet CHEMWATCH 4720-43
Issue Date: Mon 31-Jan-2005 CD 2004/4 Page 6 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
OES TWA: 10 mg/m鲁 (particulates)
Saturated vapour concentration @ 20 deg C.= 65.8 ppm, 204.6 mg/m鲁; i.e
higher concentrations can only occur as aerosols or at higher temperatures.
Odour Threshold: Practically odourless.
A small number of individuals show skin irritation or sensitisation from
repeated or prolonged exposure to propylene glycol. A workplace
environmental exposure limit (WEEL) has been established by AIHA and is
thought to be protective against systemic effects.
DECAMETHYLCYCLOPENTASILOXANE:
No exposure limits set by NOHSC or ACGIH
CEL TWA: 5 ppm, 75 mg/m鲁 [GE Silicones]
CEL TWA: 10 ppm, 150 mg/m鲁 [Dow Corning]
PARAFFIN OILS:
oil mist, mineral
TLV TWA: 5 mg/m鲁; STEL: 10 mg/m鲁.
NOTICE OF INTENDED CHANGE.
TLV TWA 0.2 mg/m鲁 inhalable fraction highly refined A4
NOTE: This substance has been classified by the ACGIH as A4
NOT classifiable as causing cancer in humans.
ES TWA: 5 mg/m鲁 (oil mist, refined mineral)
Human exposure to oil mist alone has not been demonstrated to cause health
effects except at levels above 5 mg/m鲁 (this applies to particulates sampled by
a method that does not collect vapour). It is not advisable to apply this
standard to oils containing unknown concentrations and types of additive.
5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE:
CEL TWA: 0.1 mg/m鲁; STEL: 0.3 mg/m鲁 total isothiazolines [Manufacturer]
MAK value: 0.2 mg/m鲁
Designated S in List of MAK values: Danger of sensitization.
MAK Group D: Classification as to the effect of the substance on the developing
embryo/foetus is not yet possible because although data may indicate a trend,
they are not sufficient for a final evaluation.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
2-METHYL-4-ISOTHIAZOLIN-3-ONE:
CEL TWA: 0.1 mg/m鲁; STEL: 0.3 mg/m鲁 total isothiazolines [Manufacturer]
MAK value: 0.05 mg/m鲁
Designated S in List of MAK values: Danger of sensitization.
MAK Group D: Classification as to the effect of the substance on the developing
embryo/foetus is not yet possible because although data may indicate a trend,
they are not sufficient for a final evaluation.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
WATER:
No exposure limits set by NOHSC or ACGIH
PERSONAL PROTECTION
EYE
No special equipment for minor exposure i.e. when handling small quantities.
鈥? OTHERWISE:
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FUDGE FUEL
ChemWatch Material Safety Data Sheet CHEMWATCH 4720-43
Issue Date: Mon 31-Jan-2005 CD 2004/4 Page 7 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
鈥? Safety glasses with side shields.
鈥? Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them.
HANDS/FEET
No special equipment needed when handling small quantities.
OTHERWISE: Wear chemical protective gloves, eg. PVC.
OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
鈥? Overalls.
鈥? Barrier cream.
鈥? Eyewash unit.
ENGINEERING CONTROLS
None under normal operating conditions.
General exhaust is adequate under normal operating conditions. Local exhaust
ventilation may be required in specific circumstances. If risk of overexposure
exists, wear approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.
Air contaminants generated in the workplace possess varying "escape" velocities
which, in turn, determine the "capture velocities" of fresh circulating air
required to effectively remove the contaminant.
Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., 0.25-0.5 m/s (50-100 f/min)
evaporating from tank (in still air).
aerosols, fumes from pouring 0.5-1 m/s (100-200 f/min.)
operations, intermittent container
filling, low speed conveyer transfers,
welding, spray drift, plating acid
fumes, pickling (released at low
velocity into zone of active
generation)
direct spray, spray painting in shallow 1-2.5 m/s (200-500 f/min.)
booths, drum filling, conveyer loading,
crusher dusts, gas discharge (active
generation into zone of rapid air
motion)
grinding, abrasive blasting, tumbling, 2.5-10 m/s (500-2000 f/min.)
high speed wheel generated dusts
(released at high initial velocity into
zone of very high rapid air motion).
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or 1: Disturbing room air currents
favourable to capture
2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
nuisance value only.
3: Intermittent, low production. 3: High production, heavy use
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FUDGE FUEL
ChemWatch Material Safety Data Sheet CHEMWATCH 4720-43
Issue Date: Mon 31-Jan-2005 CD 2004/4 Page 8 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
4: Large hood or large air mass in 4: Small hood-local control only
motion
Simple theory shows that air velocity falls rapidly with distance away from the
opening of a simple extraction pipe. Velocity generally decreases with the
square of distance from the extraction point (in simple cases). Therefore the
air speed at the extraction point should be adjusted, accordingly, after
reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min) for
extraction of solvents generated in a tank 2 meters distant from the extraction
point. Other mechanical considerations, producing performance deficits within
the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or
used.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Orange siliconic emulsion with an apple odour; slightly mixes with
water.
PHYSICAL PROPERTIES
Liquid.
Does not mix with water.
Molecular Weight: Not Applicable Boiling Range (掳C): Not Available
Melting Range (掳C): Not Available Specific Gravity (water=1): Not Available
Solubility in water (g/L): Partly Miscible pH (as supplied): Not Available
pH (1% solution): Not Available Vapour Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapour Density (air=1): Not Available Flash Point (掳C): >61
Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available
Autoignition Temp (掳C): Not Available Decomposition Temp (掳C): Not Available
State: Liquid
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
鈥? Presence of incompatible materials.
鈥? Product is considered stable.
鈥? Hazardous polymerisation will not occur.
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ChemWatch Material Safety Data Sheet CHEMWATCH 4720-43
Issue Date: Mon 31-Jan-2005 CD 2004/4 Page 9 of 12
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION ...
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Considered an unlikely route of entry in commercial/industrial environments.
Ingestion may result in nausea, abdominal irritation, pain and vomiting
EYE
The material may cause skin irritation after prolonged or repeated exposure and
may produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling epidermis. Histologically
there may be intercellular oedema of the spongy layer (spongiosis) and
intracellular oedema of the epidermis.
SKIN
Not considered to cause discomfort through normal use.
The material may cause skin irritation after prolonged or repeated exposure and
may produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling the epidermis.
Histologically there may be intercellular oedema of the spongy layer
(spongiosis) and intracellular oedema of the epidermis.
INHALED
Not normally a hazard due to non-volatile nature of product
CHRONIC HEALTH EFFECTS
As with any chemical product, contact with unprotected bare skin; inhalation of
vapour, mist or dust in work place atmosphere; or ingestion in any form, should
be avoided by observing good occupational work practice.
Fudge Fuel
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
PROPYLENE GLYCOL:
Not available. Refer to individual constituents.
DECAMETHYLCYCLOPENTASILOXANE:
Liver changes, spleen changes recorded.
TOXICITY IRRITATION
Oral (rat) LD50: >24134 mg/kg
Skin (rabbit): 500 mg/24h - mild 500 mg/24h - mild
Eye (rabbit): 500
PARAFFIN OILS:
TOXICITY IRRITATION
Oral (mouse) LD50: 22000 mg/kg Skin (rabbit): 100 mg/24h mild
Equivocal tumorigen by RTECS criteria Eye (rabbit): 500 mg moderate
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FUDGE FUEL
ChemWatch Material Safety Data Sheet CHEMWATCH 4720-43
Issue Date: Mon 31-Jan-2005 CD 2004/4 Page 10 of 12
Section 11 - TOXICOLOGICAL INFORMATION ...
5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE:
No significant acute toxicological data identified in literature search.
Bacterial mutagen
Considered to be the major sensitiser in Kathon CG (1)
(1). Bruze etal - Contact Dermatitis 20: 219-39, 1989
2-METHYL-4-ISOTHIAZOLIN-3-ONE:
None available.
Bacterial mutagen
Considered to be a minor sensitiser in Kathon CG (1)
(1). Bruze etal - Contact Dermatitis 20: 219-39, 1989
WATER:
No significant acute toxicological data identified in literature search.
Section 12 - ECOLOGICAL INFORMATION
Refer to data for ingredients, which follows:
PROPYLENE GLYCOL:
Hazardous Air Pollutant: No
log Kow (Prager 1995): -0.92
log Kow (Sangster 1997): -0.92
log Pow (Verschueren 1983): 4.7
BOD5: 0.955 (2.2
BOD20: 1.225
ThOD: 1.685
log Kow : -1.41- -0.3
Half-life (hr) air : 32
Henry's atm m3 /mol: 1.20E-08
BOD 5 if unstated: 0.995,2.2%
ThOD : 1.685
BCF : <1
Bioacculmulation : not sig
processes Abiotic: photoxid
DECAMETHYLCYCLOPENTASILOXANE:
No data for decamethylcyclopentasiloxane.
PARAFFIN OILS:
No data for paraffin oils.
5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE:
Octanol/water Coefficient = 0.401 (log P)
Biodegradation (aquatic metabolism)
half life t1/2 anerobic = 4.8 hours
half life t1/2 aerobic = 17.3 hours
as mixed isothiazolinones
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FUDGE FUEL
ChemWatch Material Safety Data Sheet CHEMWATCH 4720-43
Issue Date: Mon 31-Jan-2005 CD 2004/4 Page 11 of 12
Section 12 - ECOLOGICAL INFORMATION ...
Rainbow trout LC50(96 hr) = 0.19 mg/L.
Bluegill Sunfish LC50(96hr) = 0.28 mg/L.
Daphnia EC50(48hr) = 0.16 mg/L.
Algal Selenastrum EC50: 0.018 mg/L.
2-METHYL-4-ISOTHIAZOLIN-3-ONE:
The material is classified as an ecotoxin* because the Fish LC50 (96 hours) is
less than or equal to 0.1 mg/l
* Classification of Substances as Ecotoxic (Dangerous to the Environment)
Appendix 8, Table 1
Compiler's Guide for the Preparation of International Chemical Safety Cards:
1993 Commission of the European Communities
Octanol/ water coefficient = -0.486 (log P)
Biodegradation (aquatic metabolism)
half life t1/2 (aerobic) =9.1 hours
as mixed isothiazolinones
Rainbow trout LC50(96hr): = 0.19 mg/L.
Bluegill sunfish LC50(96hr): = 0.28 ml/L.
Daphnia EC50(48hr): = 0.16 mg/L.
Algal (Selenastrum) EC50: 0.018 mg/L.
WATER:
No data for water.
Section 13 - DISPOSAL CONSIDERATIONS
鈥? Consult manufacturer for recycling options and recycle where possible .
鈥? Consult State Land Waste Management Authority for disposal.
鈥? Incinerate residue at an approved site.
鈥? Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
Shipping Name:
None
Dangerous Goods Class: None
UN/NA Number: None
ADR Number: None
Packing Group: None
Additional Shipping Information:
International Transport Regulations:
IMO: None
HAZCHEM
None
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ChemWatch Material Safety Data Sheet CHEMWATCH 4720-43
Issue Date: Mon 31-Jan-2005 CD 2004/4 Page 12 of 12
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
None
REGULATIONS
propylene glycol (CAS: 57-55-6) is found on the following regulatory lists:
Australian Inventory of Chemical Substances (AICS)
decamethylcyclopentasiloxane (CAS: 541-02-6) is found on the following regulatory lists:
Australian Inventory of Chemical Substances (AICS)
paraffin oils (CAS: 8012-95-1) is found on the following regulatory lists:
Australian Inventory of Chemical Substances (AICS)
5-chloro-2-methyl-4-isothiazolin-3-one (CAS: 26172-55-4) is found on the following regulatory lists:
Australian Inventory of Chemical Substances (AICS)
2-methyl-4-isothiazolin-3-one (CAS: 2682-20-4) is found on the following regulatory lists:
Australian Inventory of Chemical Substances (AICS)
water (CAS: 7732-18-5) is found on the following regulatory lists:
Australian Inventory of Chemical Substances (AICS)
Section 16 - OTHER INFORMATION
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Mon 31-Jan-2005
Print Date: Mon 31-Jan-2005
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