Safety Data Sheet
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
YATES ROSE GUN READY TO USE
Product Name:
Supplier: Yates, A Division of Orica New Zealand Limited
Street Address: The Gate Industrial Park, 373 Neilson St
Onehunga, Auckland
New Zealand
Telephone Number: +64 9 636 2800
Facsimile: +64 9 636 2802
Emergency Telephone: CHEMCALL 0800 243 622 (ALL HOURS)
2. HAZARDS IDENTIFICATION
Classified as a Dangerous Good according to NZS 5433:1999 Transport of Dangerous Goods on Land.
Classified as hazardous according to criteria in the HS (Minimum Degrees of Hazard) Regulations 2001.
Subclasses: Subclass 9.1 Category B - Substances that are ecotoxic in the aquatic environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Product Description: Combination insecticide and fungicide to control various pests and diseases on roses and
ornamentals. White liquid.
Components / CAS Number Proportion Risk Phrases
Tau-fluvalinate 0.1 g/L R22 R38 R50/53
102851-06-9
Myclobutanil 0.05 g/L R22 R36 R51/53 R63
88671-89-0
Water and other non- to 100% -
hazardous components
-
4. FIRST AID MEASURES
For advice, contact a Poisons Information Centre (Phone eg. Australia 131 126; New Zealand 0 800 764766) or a doctor.
Inhalation: Remove victim from area of exposure - avoid becoming a casualty. Seek medical advice if effects
persist.
Skin Contact: If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running
Product Name: YATES ROSE GUN READY TO USE
Substance No: 000000020924 Issued: 24/08/2007 Version: 2
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Safety Data Sheet
water.
Eye Contact: If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing
until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
Ingestion: Rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water. Seek
medical advice.
Medical attention Treat symptomatically.
and special
treatment:
5. FIRE FIGHTING MEASURES
Hazards from combustion Non-combustible material.
products:
Suitable Extinguishing Media: Not combustible, however, if material is involved in a fire use: Media applicable to
surrounding fire.
Hazchem Code: 2X
6. ACCIDENTAL RELEASE MEASURES
Methods and materials for Contain - prevent run off into drains and waterways. Use absorbent (soil, sand or other
containment and clean up: inert material). Collect and seal in properly labelled containers. If contamination of sewers
or waterways has occurred advise local emergency services.
7. HANDLING AND STORAGE
Precautions for safe handling: Keep out of reach of children. Avoid skin and eye contact and breathing in vapour, mists
and aerosols.
Conditions for safe storage: Store in the closed, original container in a dry, cool, well-ventilated area out of direct
sunlight. Store away from foodstuffs. Keep containers closed when not in use - check
regularly for leaks.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits:
No value assigned for this specific material by the New Zealand Occupational Safety and Health Service (OSH).
Engineering controls:
Natural ventilation should be adequate under normal use conditions. Keep containers closed when not in use.
Product Name: YATES ROSE GUN READY TO USE
Substance No: 000000020924 Issued: 24/08/2007 Version: 2
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Safety Data Sheet
Personal Protective Equipment:
Avoid contact with eyes and skin and breathing in spray mist. Wash hands and exposed skin thoroughly after use.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid
Colour: White
Solubility: Miscible in water.
Specific Gravity: 1.00 approx.
Relative Vapour Density (air=1): N Av
Vapour Pressure (20 掳C): N Av
Flash Point (掳C): N App
Boiling Point/Range (掳C): 100 (water)
pH: N Av
Evaporation Rate: N Av
10. STABILITY AND REACTIVITY
Chemical stability: Stable under normal conditions of use.
11. TOXICOLOGICAL INFORMATION
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product
label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:
Ingestion: No adverse effects expected, however, large amounts may cause nausea and vomiting.
Eye contact: May be an eye irritant.
Skin contact: Contact with skin may result in irritation.
Inhalation: Breathing in mists or aerosols may produce respiratory irritation.
Long Term Effects:
No information available for the product.
Toxicological Data:
No LD50 data available for the product. However, for constituent(s) (1):
Oral LD50 (rat): 261-282 mg/kg (tau-fluvalinate); 1870-2090 (myclobutanil)
Dermal LD50 (rabbit): >2000 mg/kg (tau-fluvalinate); >5000 mg/kg (myclobutanil)
12. ECOLOGICAL INFORMATION
Product Name: YATES ROSE GUN READY TO USE
Substance No: 000000020924 Issued: 24/08/2007 Version: 2
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Safety Data Sheet
Ecotoxicity Avoid contaminating waterways and fishponds. Do not allow spray to drift onto aquatic
environments, other crops or desirable plants or outside the target area. For Tau-
fluvalinate (1):
Aquatic toxicity:
Very toxic to aquatic organisms.
48hr LC50 (Daphnia magna): 0.001 mg/L
96hr LC50 (rainbow trout): 0.0027 mg/L
13. DISPOSAL CONSIDERATIONS
Disposal methods: Refer to local government authority for disposal recommendations. Rinse empty
container, puncture and recycle or dispose of safely with domestic rubbish.
14. TRANSPORT INFORMATION
Road and Rail Transport
Classified as a Dangerous Good according to NZS 5433:1999 Transport of Dangerous Goods on Land.
UN No: 3082
Class-primary 9 Miscellaneous Dangerous Goods
Packing Group: III
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS TAU-
FLUVALINATE AND MYCLOBUTANIL)
Hazchem Code: 2X
Marine Transport
Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for
transport by sea; DANGEROUS GOODS.
UN No: 3082
Class-primary: 9 Miscellaneous Dangerous Goods
Packing Group: III
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS TAU-
FLUVALINATE AND MYCLOBUTANIL)
Air Transport
Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods
Regulations for transport by air; DANGEROUS GOODS.
UN No: 3082
Class-primary: 9 Miscellaneous Dangerous Goods
Product Name: YATES ROSE GUN READY TO USE
Substance No: 000000020924 Issued: 24/08/2007 Version: 2
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Safety Data Sheet
Packing Group: III
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS TAU-
FLUVALINATE AND MYCLOBUTANIL)
15. REGULATORY INFORMATION
Classification: Classified as hazardous according to criteria in the HS (Minimum Degrees of Hazard) Regulations
2001.
Subclasses: Subclass 9.1 Category B - Substances that are ecotoxic in the aquatic environment.
16. OTHER INFORMATION
(1) In: 'The Pesticide Manual'. 13th Edition. Ed. CDS Tomlin. British Crop Protection Society, 2003.
Reason(s) for Issue:
Revised Primary MSDS
Change to Transport Information
This material safety data sheet has been prepared by SH&E Shared Services, Orica.This MSDS summarises to our best
knowledge at the date of issue, the chemical health and safety hazards of the material and general guidance on how to
safely handle the material in the workplace. Since Orica Limited cannot anticipate or control the conditions under which
the product may be used, each user must, prior to usage, assess and control the risks arising from its use of the material.
If clarification or further information is needed, the user should contact their Orica representative or Orica Limited at the
contact details on page 1. Orica Limited's responsibility for the material as sold is subject to the terms and conditions of
sale, a copy of which is available upon request.
Product Name: YATES ROSE GUN READY TO USE
Substance No: 000000020924 Issued: 24/08/2007 Version: 2
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