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MSDS Material Safety Data Sheet
CAS

7732-18-5
111-76-2
67-63-0

File Name: msds_orica_com---shess-en-cds-020-000000021144.asp
              Safety Data Sheet

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

PROACTIVE GLASS CLEANER
Product Name:

Recommended Use: Glass cleaner.


Supplier: Selleys - A Division of ORICA NEW ZEALAND LIMITED
Street Address: The Gate Industrial Park, 373 Neilson St
Onehunga, Auckland
New Zealand
Telephone Number: +64 9 820 4852
Facsimile: 0 800 804 583
Emergency Telephone: 0 800 734 607 (ALL HOURS)


2. HAZARDS IDENTIFICATION

Not classified as a Dangerous Good under NZS 5433:1999 Transport of Dangerous Goods on Land.

Classified as hazardous according to criteria in the HS (Minimum Degrees of Hazard) Regulations 2001.

Subclasses: Subclass 6.3 Category B - Substances that are mildly irritating to the skin.


3. COMPOSITION/INFORMATION ON INGREDIENTS
Components / CAS Number Proportion Risk Phrases
Water >60% -
7732-18-5
2-Butoxyethanol 1-<10% R20/21/22, R36/38
111-76-2
Isopropyl alcohol 1-<10% R11, R36, R67
67-63-0
Ingredients determined not to to 100% -
be hazardous
-


4. FIRST AID MEASURES

Inhalation: Remove victim from area of exposure - avoid becoming a casualty. Seek medical advice if effects
persist.

Skin Contact: If skin or hair contact occurs, immediately remove any contaminated clothing and wash skin and
hair thoroughly with running water. A component of this material can be absorbed through the skin
with resultant toxic effects. Seek immediate medical assistance.


Product Name: PROACTIVE GLASS CLEANER
Substance No: 000000021144 Issued: 12/12/2005 Version: 1
Page 1 of 6
Safety Data Sheet


Eye Contact: If in eyes, wash out immediately with water. In all cases of eye contamination it is a sensible
precaution to seek medical advice.

Ingestion: Rinse mouth with water. If swallowed, give a glass of water to drink. If vomiting occurs give further
water. Seek medical advice.

Medical attention Treat symptomatically.
and special
treatment:


5. FIRE FIGHTING MEASURES

Hazards from combustion Not combustible, however following evaporation of the water component of the
products: material, the residual material can burn if ignited. On burning will emit toxic fumes.

Precautions for fire fighters and Fire fighters to wear self-contained breathing apparatus and suitable protective
special protective equipment: clothing if risk of exposure to vapour or products of combustion.

Suitable Extinguishing Media: Not combustible, however, if material is involved in a fire use: Water fog (or if
unavailable fine water spray), foam, dry agent (carbon dioxide, dry chemical powder).


6. ACCIDENTAL RELEASE MEASURES

Emergency procedures: If contamination of sewers or waterways has occurred advise local emergency services.

Methods and materials for SMALL SPILLS: Slippery when spilt. Avoid accidents, clean up immediately. Wipe up
containment and clean up: with rag or absorbent paper.
LARGE SPILLS: Slippery when spilt. Avoid accidents, clean up immediately. Wear
protective equipment to prevent skin and eye contact. Contain - prevent run off into drains
and waterways. Use absorbent (soil, sand or other inert material). Collect and seal in
properly labelled containers or drums for disposal. Wash area down with excess water.


7. HANDLING AND STORAGE

Precautions for safe handling: Avoid eye contact and repeated or prolonged skin contact.

Conditions for safe storage: Store in cool place and out of direct sunlight. Store away from incompatible materials
described in Section 10. Keep containers closed when not in use - check regularly for
leaks.


8. EXPOSURE CONTROLS/PERSONAL PROTECTION


Product Name: PROACTIVE GLASS CLEANER
Substance No: 000000021144 Issued: 12/12/2005 Version: 1
Page 2 of 6
Safety Data Sheet

Occupational Exposure Limits:
No value assigned for this specific material by the New Zealand Occupational Safety and Health Service (OSH).
However, Workplace Exposure Standard(s) for constituent(s):

2-Butoxyethanol: WES-TWA 25 ppm, 121 mg/m3, skin
Isopropyl alcohol: WES-TWA 400 ppm, 983 mg/m3; WES-STEL 500 ppm, 1,230 mg/m3

As published by the New Zealand Occupational Safety and Health Service (OSH).

WES - TWA (Workplace Exposure Standard - Time Weighted Average) - The eight-hour, time-weighted average
exposure standard is designed to protect the worker from the effects of long-term exposure.

WES - STEL (Workplace Exposure Standard - Short Term Exposure Limits) - The 15 minute average exposure standard.
Applies to any 15 minute period in the working day and is designed to protect the worker against adverse effects of
irritation, chronic or irreversible tissue change, or narcosis that may increase the likelihood of accidents. The WES-STEL
is not an alternative to the WES-TWA; both short-term and eight-hour, time-weighted average exposures should be
determined.

`Sk' Notice - absorption through the skin may be a significant source of exposure. The exposure standard is invalidated if
such contact should occur.

These Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric
contamination should be kept to as low a level as is workable. These exposure standards should not be used as fine
dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative toxicity.




Engineering controls:
Natural ventilation should be adequate under normal use conditions. Keep containers closed when not in use.


Personal Protective Equipment:
Selleys Factory Safe Handling Code: Green
MANUFACTURE, PACKAGING AND TRANSPORT: Green - Wear clean overalls, safety boots, general purpose gloves
(PVC) and safety spectacles. Always wash hands before smoking, eating, drinking or using the toilet.
FOR CONSUMER USE: Avoid contact with eyes. Wash hands after use. Rubber gloves are recommended if handling
often.
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Colour: Clear Blue
Odour: Mild
Solubility: Miscible in water.
Specific Gravity: 0.97 @20掳C
Relative Vapour Density (air=1): N Av
Vapour Pressure (20 掳C): N Av
Flash Point (掳C): N App


Product Name: PROACTIVE GLASS CLEANER
Substance No: 000000021144 Issued: 12/12/2005 Version: 1
Page 3 of 6
Safety Data Sheet

Flammability Limits (%): N App
Autoignition Temperature (掳C): N App
% Volatile by Weight: >90
Melting Point/Range (掳C): N App
Boiling Point/Range (掳C): 100
Decomposition Point (掳C): N Av
pH: 7.6
Viscosity: N Av
Evaporation Rate: N Av


10. STABILITY AND REACTIVITY

Chemical stability: Stable under normal conditions of use.

Conditions to avoid: Avoid contact with foodstuffs.

Incompatible materials: Incompatible with oxidising agents.

Hazardous decomposition Oxides of carbon.
products:

Hazardous reactions: None known.


11. TOXICOLOGICAL INFORMATION

No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product
label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:

Ingestion: No adverse effects expected, however, large amounts may cause nausea and vomiting.

Eye contact: May be an eye irritant.

Skin contact: Contact with skin may result in irritation. Will have a degreasing action on the skin. Repeated or
prolonged skin contact may lead to irritant contact dermatitis. Component/s of this material can be
absorbed through the skin with resultant toxic effects.

Inhalation: Breathing in mists or aerosols may produce respiratory irritation.

Long Term Effects:
No information available for the product.

Toxicological Data:
No LD50 data available for the product.




Product Name: PROACTIVE GLASS CLEANER
Substance No: 000000021144 Issued: 12/12/2005 Version: 1
Page 4 of 6
Safety Data Sheet

12. ECOLOGICAL INFORMATION

Ecotoxicity Avoid contaminating waterways.


13. DISPOSAL CONSIDERATIONS

Disposal methods: Refer to Waste Management Authority. Normally suitable for disposal at approved land
waste site.


14. TRANSPORT INFORMATION
Road and Rail Transport
Not classified as a Dangerous Good under NZS 5433:1999 Transport of Dangerous Goods on Land.




Marine Transport
Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for
transport by sea; NON-DANGEROUS GOODS.

Air Transport
Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods
Regulations for transport by air; NON-DANGEROUS GOODS.


15. REGULATORY INFORMATION

Classification: Classified as hazardous according to criteria in the HS (Minimum Degrees of Hazard) Regulations
2001.

Subclasses: Subclass 6.3 Category B - Substances that are mildly irritating to the skin.


16. OTHER INFORMATION

This material safety data sheet has been prepared by SH&E Shared Services, Orica.
For further copies of this sheet or other product information contact Selleys Proprietary Limited Customer Service.
Phone: 1300 555 205 (Australia wide)
Fax: 1300 555 305 (Australia wide)
Phone: 9 820 4852 (New Zealand)
Fax: 0800 804 583 (New Zealand)




Product Name: PROACTIVE GLASS CLEANER
Substance No: 000000021144 Issued: 12/12/2005 Version: 1
Page 5 of 6
Safety Data Sheet

Reason(s) for Issue:
First Issue Primary MSDS

This MSDS summarises to our best knowledge at the date of issue, the chemical health and safety hazards of the
material and general guidance on how to safely handle the material in the workplace. Since Orica Limited cannot
anticipate or control the conditions under which the product may be used, each user must, prior to usage, assess and
control the risks arising from its use of the material.

If clarification or further information is needed, the user should contact their Orica representative or Orica Limited at the
contact details on page 1.

Orica Limited's responsibility for the material as sold is subject to the terms and conditions of sale, a copy of which is
available upon request.




Product Name: PROACTIVE GLASS CLEANER
Substance No: 000000021144 Issued: 12/12/2005 Version: 1
Page 6 of 6

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