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MSDS Material Safety Data Sheet
CAS

7732-18-5

File Name: msds_orica_com---shess-en-cds-030-000000001968.asp
Material Safety Data Sheet

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Product Name: 989-85741 956/3 HYDROBAN CLEAR

Recommended Use: Water repellent for cementitious substrates. Applied by brush, spray or flood coating.

Supplier: Orica Australia Pty Ltd
ABN: 004 117 828
Street Address: McNaughton Road
Clayton South 3169
Australia
Telephone Number: +61 3 9263 5058
Facsimile: +61 3 9263 5671

+61 3 9663 2130
Emergency Telephone:


2. HAZARDS IDENTIFICATION

Based on available information, not classified as hazardous according to criteria of ASCC; NON-HAZARDOUS
SUBSTANCE.

Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport by
Road and Rail; NON-DANGEROUS GOODS.

Poisons None allocated.
Schedule:


3. COMPOSITION/INFORMATION ON INGREDIENTS
Components / CAS Number Proportion Risk Phrases
Water >60% -
7732-18-5
Alkyltrialkoxy silane 1-<10% -
-


4. FIRST AID MEASURES

Inhalation: Remove victim from area of exposure - avoid becoming a casualty. Remove contaminated clothing
and loosen remaining clothing. Allow patient to assume most comfortable position and keep warm.
Keep at rest until fully recovered. Seek medical advice if effects persist.

Skin Contact: If skin contact occurs, remove contaminated clothing and wash skin with running water. If irritation
occurs seek medical advice.

Eye Contact: If in eyes, wash out immediately with water. In all cases of eye contamination it is a sensible
precaution to seek medical advice.


Product Name: 989-85741 956/3 HYDROBAN CLEAR
Substance No: 000000001968 Issued: 05/04/2007 Version: 3
Page 1 of 5
Material Safety Data Sheet


Ingestion: Rinse mouth with water. If swallowed, give a glass of water to drink. If vomiting occurs give further
water. Seek medical assistance. Seek medical advice.

Medical attention Treat symptomatically.
and special
treatment:


5. FIRE FIGHTING MEASURES

Hazards from combustion Not combustible, however following evaporation of the water component of the
products: material, the residual material can burn if ignited. On burning will emit toxic fumes.

Precautions for fire fighters and Fire fighters to wear self-contained breathing apparatus and suitable protective
special protective equipment: clothing if risk of exposure to vapour or products of combustion.

Suitable Extinguishing Media: Not combustible, however, if material is involved in a fire use: Water fog (or if
unavailable fine water spray), foam, dry agent (carbon dioxide, dry chemical powder).


6. ACCIDENTAL RELEASE MEASURES

Emergency procedures: If contamination of sewers or waterways has occurred advise local emergency services.

Methods and materials for Slippery when spilt. Avoid accidents, clean up immediately. Wear protective equipment to
containment and clean up: prevent skin and eye contact. Contain - prevent run off into drains and waterways. Use
absorbent (soil, sand or other inert material). Collect and seal in properly labelled
containers or drums for disposal.


7. HANDLING AND STORAGE

Conditions for safe storage: Store in cool place and out of direct sunlight. Keep containers closed when not in use -
check regularly for leaks.


Precautions for safe handling: Avoid skin and eye contact and breathing in vapour, mists and aerosols.


8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits:
No value assigned for this specific material by the National Occupational Health and Safety Commission. However,
Exposure Standard(s) for hydrolysis product:

Ethyl alcohol: 8hr TWA = 1880 mg/m3 (1000 ppm)
Methyl alcohol: 8hr TWA = 262 mg/m3 (200 ppm), 15 min STEL = 328 mg/m3 (250 ppm), Sk



Product Name: 989-85741 956/3 HYDROBAN CLEAR
Substance No: 000000001968 Issued: 05/04/2007 Version: 3
Page 2 of 5
Material Safety Data Sheet

As published by the National Occupational Health and Safety Commission.

TWA - The time-weighted average airborne concentration over an eight-hour working day, for a five-day working week
over an entire working life.

STEL (Short Term Exposure Limit) - the average airborne concentration over a 15 minute period which should not be
exceeded at any time during a normal eight hour work day. According to current knowledge this concentration should
neither impair the health of, nor cause undue discomfort to, nearly all workers.

`Sk' Notice - absorption through the skin may be a significant source of exposure. The exposure standard is invalidated if
such contact should occur.

These Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric
contamination should be kept to as low a level as is workable. These exposure standards should not be used as fine
dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative toxicity.




Engineering controls:
Provide adequate ventilation. If using indoors, keep windows and doors open during use. Keep containers closed when
not in use.

Personal Protective Equipment:
The selection of PPE is dependant on a detailed risk assessment. The risk assessment should consider the work
situation, the physical form of the chemical, the handling methods, and environmental factors.

Orica Personal Protection Guide No. 1, 1998: B - OVERALLS, SAFETY SHOES, SAFETY GLASSES, GLOVES.

Wear overalls, safety glasses and impervious gloves. Always wash hands before smoking, eating, drinking or using the
toilet. Wash contaminated clothing and other protective equipment before storage or re-use.
If risk of inhalation exists, wear organic vapour/particulate respirator meeting the requirements of AS/NZS 1715 and
AS/NZS 1716.


9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Colour: Milky white
Odour: Alcohol
Solubility: Miscible with water.
Specific Gravity: 0.994 @20掳C
Relative Vapour Density (air=1): >1
Vapour Pressure (20 掳C): N Av
Flash Point (掳C): N App
Flammability Limits (%): N App
Autoignition Temperature (掳C): N App
% Volatile by Volume: N Av
Solubility in water (g/L): Complete
Melting Point/Range (掳C): N App
Boiling Point/Range (掳C): 100 (water)


Product Name: 989-85741 956/3 HYDROBAN CLEAR
Substance No: 000000001968 Issued: 05/04/2007 Version: 3
Page 3 of 5
Material Safety Data Sheet

Decomposition Point (掳C): N Av
pH: 7-7.5
Viscosity: N Av
Evaporation Rate: N Av


10. STABILITY AND REACTIVITY

Chemical stability: Stable under normal conditions of use.

Conditions to avoid: Avoid exposure to extremes of temperature.

Incompatible materials: Incompatible with oxidising agents.

Hazardous decomposition Formaldehyde. Oxides of carbon. Silicon dioxide.
products:

Hazardous reactions: Hydrolyses slowly in water liberating ethanol and methanol.


11. TOXICOLOGICAL INFORMATION

No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product
label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:

Ingestion: No adverse effects expected, however, large amounts may cause nausea and vomiting.

Eye contact: May be an eye irritant.

Skin contact: Contact with skin may result in irritation.

Inhalation: Breathing in mists or aerosols may produce respiratory irritation.

Long Term Effects:
No information available for the product.

Toxicological Data:
No LD50 data available for the product.


12. ECOLOGICAL INFORMATION

Ecotoxicity Avoid contaminating waterways.


13. DISPOSAL CONSIDERATIONS

Disposal methods: Refer to Waste Management Authority. Dispose of material through a licensed waste
contractor. Normally suitable for disposal at approved land waste site.

Product Name: 989-85741 956/3 HYDROBAN CLEAR
Substance No: 000000001968 Issued: 05/04/2007 Version: 3
Page 4 of 5
Material Safety Data Sheet


14. TRANSPORT INFORMATION
Road and Rail Transport
Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport by
Road and Rail; NON-DANGEROUS GOODS.


Marine Transport
Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for
transport by sea; NON-DANGEROUS GOODS.


Air Transport
Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods
Regulations for transport by air; NON-DANGEROUS GOODS.


15. REGULATORY INFORMATION

Classification: Based on available information, not classified as hazardous according to criteria of ASCC; NON-
HAZARDOUS SUBSTANCE.
Poisons Schedule: None allocated.

All the constituents of this material are listed on the Australian Inventory of Chemical Substances (AICS).


16. OTHER INFORMATION

This material safety data sheet has been prepared by SH&E Shared Services, Orica.




Reason(s) for Issue:
5 Yearly Revised Primary MSDS

This MSDS summarises to our best knowledge at the date of issue, the chemical health and safety hazards of the
material and general guidance on how to safely handle the material in the workplace. Since Orica Limited cannot
anticipate or control the conditions under which the product may be used, each user must, prior to usage, assess and
control the risks arising from its use of the material.

If clarification or further information is needed, the user should contact their Orica representative or Orica Limited at the
contact details on page 1.

Orica Limited's responsibility for the material as sold is subject to the terms and conditions of sale, a copy of which is
available upon request.




Product Name: 989-85741 956/3 HYDROBAN CLEAR
Substance No: 000000001968 Issued: 05/04/2007 Version: 3
Page 5 of 5

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