Search    ENTER KEYWORD
MSDS Material Safety Data Sheet
CAS

123-72-8

File Name: palomar_edu---butyraldehyde.asp
 
                        PRODUCT #: 20711        NAME: BUTYRALDEHYDE

                      MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                           Printed Monday, March 10, 1903 4:08PM



Sigma Chemical Co.          Aldrich Chemical Co., Inc.    Fluka Chemical Corp.

P.O. Box 14508              1001 West St. Paul            1001 West St. Paul

St. Louis, MO 63178         Milwaukee, WI 53233           Milwaukee, WI 53233

Phone: 314-771-5765         Phone: 414-273-3850           Phone: 414-273-3850









SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -

    CATALOG #:            20711

    NAME:                 BUTYRALDEHYDE

SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -

    CAS #:    123-72-8

    MF: C4H8O

    EC NO: 204-646-6

  SYNONYMS

    ALDEHYDE BUTYRIQUE (FRENCH) * ALDEIDE BUTIRRICA (ITALIAN) * BUTAL *

    BUTALDEHYDE * BUTALYDE * BUTANAL * N-BUTANAL (CZECH) * BUTANALDEHYDE *

     BUTYL ALDEHYDE * N-BUTYL ALDEHYDE * BUTYRAL * BUTYRALDEHYD (GERMAN) *

     BUTYRALDEHYDE (DOT) * N-BUTYRALDEHYDE * BUTYRIC ALDEHYDE * NCI-

    C56291 * UN1129 (DOT) *

SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -

  LABEL PRECAUTIONARY STATEMENTS

    FLAMMABLE (USA)

    HIGHLY FLAMMABLE (EU)

    CORROSIVE

    CAUSES BURNS.

    POSSIBLE SENSITIZER.

    STENCH.

    KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.

    IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF

    WATER AND SEEK MEDICAL ADVICE.

    TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.

    WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE

    PROTECTION.

SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -

    IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS

    AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED

    CLOTHING AND SHOES.

    IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL

    RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.

    IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.

    CALL A PHYSICIAN.

    REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY.

SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -

  EXTINGUISHING MEDIA

    CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.

    WATER MAY BE EFFECTIVE FOR COOLING, BUT MAY NOT EFFECT EXTINGUISHMENT.

  SPECIAL FIREFIGHTING PROCEDURES

    WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO

    PREVENT CONTACT WITH SKIN AND EYES.

    EXTREMELY FLAMMABLE.

    USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.

  UNUSUAL FIRE AND EXPLOSIONS HAZARDS

    VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND

    FLASH BACK.

    CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS.



                                           Page 1

                       PRODUCT #: 20711        NAME: BUTYRALDEHYDE

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                          Printed Monday, March 10, 1903 4:08PM



    FORMS EXPLOSIVE MIXTURES IN AIR.

SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -

    EVACUATE AREA.

    SHUT OFF ALL SOURCES OF IGNITION.

    WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY

    RUBBER GLOVES.

    COVER WITH AN ACTIVATED CARBON ADSORBENT, TAKE UP AND PLACE IN CLOSED

    CONTAINERS. TRANSPORT OUTDOORS.

    VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.

SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -

    REFER TO SECTION 8.

SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -

    WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT

    GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.

    USE ONLY IN A CHEMICAL FUME HOOD.

    SAFETY SHOWER AND EYE BATH.

    USE NONSPARKING TOOLS.

    DO NOT BREATHE VAPOR.

    DO NOT GET IN EYES, ON SKIN, ON CLOTHING.

    AVOID PROLONGED OR REPEATED EXPOSURE.

    WASH THOROUGHLY AFTER HANDLING.

    KEEP TIGHTLY CLOSED.

    KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.

    STORE IN A COOL DRY PLACE.

SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -

  APPEARANCE AND ODOR

    COLORLESS LIQUID

  PHYSICAL PROPERTIES

    FLASHPOINT                 23F

                               -5C

    EXPLOSION LIMITS IN AIR:

      UPPER                                    11.8%

      LOWER                                    2%

    AUTOIGNITION TEMPERATURE:         390 F          198C

    VAPOR PRESSURE:       90MM 20 C

    SPECIFIC GRAVITY:       0.800

    VAPOR DENSITY:      2.5

SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -

  STABILITY

    STABLE.

  CONDITIONS TO AVOID

    HEAT

    PROTECT FROM LIGHT.

  INCOMPATIBILITIES

    OXIDIZING AGENTS

    STRONG BASES

    STRONG REDUCING AGENTS

    STRONG ACIDS

  HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS

    TOXIC FUMES OF:

    CARBON MONOXIDE, CARBON DIOXIDE

  HAZARDOUS POLYMERIZATION

    MAY UNDERGO AUTOPOLYMERIZATION.

SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -

  ACUTE EFFECTS

    HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN.

    MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES



                                          Page 2

                       PRODUCT #: 20711        NAME: BUTYRALDEHYDE

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                          Printed Monday, March 10, 1903 4:08PM



    AND UPPER RESPIRATORY TRACT, EYES AND SKIN.

    INHALATION MAY RESULT IN SPASM, INFLAMMATION AND EDEMA OF THE

    LARYNX AND BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY EDEMA.

    SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING,

    WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND

    VOMITING.

    PROLONGED OR REPEATED EXPOSURE MAY CAUSE ALLERGIC REACTIONS IN CERTAIN

    SENSITIVE INDIVIDUALS.

    TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND

    TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.

  RTECS #: ES2275000

    BUTYRALDEHYDE

  IRRITATION DATA

    SKN-RBT 410 MG OPEN MLD                       UCDS** 7/20/1965

    SKN-RBT 2 MG/24H SEV                          85JCAE -,270,1986

    EYE-RBT 75 UG OPEN SEV                        AMIHBC 4,119,1951

    EYE-RBT 20 MG/24H MOD                         85JCAE -,270,1986

    SKN-GPG 100% MOD                              FCTXAV 17,731,1979

  TOXICITY DATA

    ORL-RAT LD50:2490 MG/KG                       NTIS** OTS0516688

    IPR-RAT LD50:800 MG/KG                        FCTXAV 17,731,1979

    SCU-RAT LD50:10 GM/KG                         APTOA6 6,299,1950

    IHL-MUS LC50:44610 MG/M3/2H                   85GMAT -,30,1982

    IPR-MUS LD50:1140 MG/KG                       FCTXAV 17,731,1979

    SCU-MUS LD50:2700 MG/KG                       APTOA6 6,299,1950

    SKN-RBT LD50:3560 UL/KG                       UCDS** 7/20/1965

    IHL-MAM LC50:38 GM/M3                         GISAAA 51(5),61,1986

  ADDITIONAL INFORMATION

    ORAL-RAT LD50: 5900MG/KG

    ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES

    (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR

    COMPLETE INFORMATION.

SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -

    DATA NOT YET AVAILABLE.

SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -

    BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND

    SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY

    FLAMMABLE.

    OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -

    CONTACT FLUKA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.

SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -

  EUROPEAN INFORMATION

    EC INDEX NO:      605-006-00-2

    HIGHLY FLAMMABLE

    CORROSIVE

    R 11

    HIGHLY FLAMMABLE.

    S9

    KEEP CONTAINER IN A WELL-VENTILATED PLACE.

    S 29

    DO NOT EMPTY INTO DRAINS.

    S 33

    TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES.

  REVIEWS, STANDARDS, AND REGULATIONS

    OEL=MAK

    OEL-RUSSIA:STEL 5 MG/M3;SKIN JAN 1993



                                          Page 3

                       PRODUCT #: 20711        NAME: BUTYRALDEHYDE

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                          Printed Monday, March 10, 1903 4:08PM



    NOHS 1974: HZD M0281; NIS 3; TNF 91; NOS 9; TNE 1258

    NOES 1983: HZD M0281; NIS 2; TNF 38; NOS 6; TNE 5392; TFE 950

    EPA TSCA SECTION 8(B) CHEMICAL INVENTORY

    EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES

    EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997

    NIOSH CURRENT INTELLIGENCE BULLETIN #55, SEPTEMBER 1991

    NIOSH ANALYTICAL METHOD, 1994: ALDEHYDES, SCREENING, 2539

  U.S. INFORMATION

    THIS PRODUCT IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS.

SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -

    THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO

    BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,

    FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING

    OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR

    PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.

    COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,

    FLUKA CHEMIE AG

    LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY









                                          Page 4
Search    ENTER KEYWORD
ALL Chemical Property And Toxicity Analysis PAGES IN THIS GROUP
NAMECAS
palomar_edu---azobenzene.asp 103-33-3
palomar_edu---azocarmine_b.asp 25360-72-9
palomar_edu---barium_carbonate.asp 513-77-9
palomar_edu---barium_dioxide.asp 1304-29-6
palomar_edu---bariver.asp N/A
palomar_edu---bcg_reagent.asp 76-60-8
palomar_edu---benzoic_acid.asp 65-85-0
palomar_edu---benzoin.asp 119-53-9
palomar_edu---benzopurpurin_4b.asp 992-59-6
palomar_edu---benzoyl_peroxide.asp 94-36-0
palomar_edu---borane_tetrahydrofuran_complex_solution.asp 14044-65-6 109-99-9
palomar_edu---boric_acid.asp 10043-35-3
palomar_edu---boron_tribromide.asp 10294-33-4
palomar_edu---bromobenzene.asp 108-86-1
palomar_edu---bromothymol_blue.asp 76-59-5
palomar_edu---bromotrichloromethane.asp 75-62-7
palomar_edu---buffer_solution_1.asp N/A
palomar_edu---burnishine_roller_cleaner.asp N/A
palomar_edu---butylamine.asp 109-73-9
palomar_edu---butyl_acetate.asp 123-86-4
palomar_edu---butyl_methyl_ether.asp 628-28-4
palomar_edu---butyraldehyde.asp 123-72-8
palomar_edu---cadmium_foil_0.5mm.asp 7440-43-9
palomar_edu---cadmium_sticks.asp 7440-43-9
palomar_edu---caffeine.asp 58-08-2
palomar_edu---calcium_acetate.asp 62-54-4
palomar_edu---calcium_carbonate.asp 471-34-1
palomar_edu---calcium_chloride_dihydrate.asp 10035-04-8
palomar_edu---calcium_hypochlorite.asp 7778-54-3
palomar_edu---casein_enzymatic.asp N/A
palomar_edu---catechol.asp 120-80-9
palomar_edu---celite_500.asp 61790-53-2
palomar_edu---cellulose_powder.asp 9004-34-6
palomar_edu---ceramic_rutile..asp N/A
palomar_edu---chloramine.asp 127-52-6
palomar_edu---chloramine_t_hydrate.asp 127-65-1
palomar_edu---chloroform-d.asp 865-49-6
palomar_edu---chlorophenol.asp 95-57-8
palomar_edu---chloroplatinic.asp 16941-12-1
palomar_edu---chromiumiii_nitrate_nonahydrate.asp 7789-02-8
palomar_edu---chromium_oxide.asp N/A
palomar_edu---citric_acid_anhydrous.asp 77-92-9
palomar_edu---cobaltii_nitrate.asp 10026-22-9
palomar_edu---cobaltous_carbonate.asp 513-79-1
palomar_edu---cobalt_carbonate.asp 513-79-1
palomar_edu---cobalt_oxide.asp N/A
palomar_edu---copperi_oxide.asp 1317-39-1
palomar_edu---copperii_chloride.asp 7447-39-4
palomar_edu---cornish_stone.asp N/A
palomar_edu---crotonic_acid.asp 107-93-7

Free MSDS Search ( Providing 250,000+ Material Properties )
Chemcas.com | Ads link:HBCCHEM.INC