PRODUCT #: 81080 NAME: HEXACHLOROPLATINIC ACID HYDRATE, ~38% PT
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 11, 1903 10:18AM
Sigma Chemical Co. Aldrich Chemical Co., Inc. Fluka Chemical Corp.
P.O. Box 14508 1001 West St. Paul 1001 West St. Paul
St. Louis, MO 63178 Milwaukee, WI 53233 Milwaukee, WI 53233
Phone: 314-771-5765 Phone: 414-273-3850 Phone: 414-273-3850
SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
CATALOG #: 81080
NAME: HEXACHLOROPLATINIC ACID HYDRATE, ~38% PT
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS #: 16941-12-1
MF: CL6H2PT.AQ
EC NO: 241-010-7
SYNONYMS
CHLOROPLATINIC ACID * CHLOROPLATINIC(IV) ACID * CHLOROPLATINIC ACID,
SOLID (DOT) * DIHYDROGEN HEXACHLOROPLATINATE * DIHYDROGEN
HEXACHLOROPLATINATE(2-) * HEXACHLOROPLATINIC ACID *
HEXACHLOROPLATINIC(IV) ACID * HEXACHLOROPLATINIC(4+) ACID, HYDROGEN- *
HYDROGEN HEXACHLOROPLATINATE(4+) * NSC 4958 * PLATINIC CHLORIDE *
PLATINUM CHLORIDE (H2PTCL6) * SPEIER'S CATALYST * UN2507 (DOT) *
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
LABEL PRECAUTIONARY STATEMENTS
CORROSIVE
CAUSES BURNS.
MAY CAUSE SENSITIZATION BY INHALATION AND SKIN CONTACT.
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE
PROTECTION.
DO NOT BREATHE DUST.
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES.
ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS
WITH FINGERS.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN IMMEDIATELY.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
EXTINGUISHING MEDIA
NONCOMBUSTIBLE.
USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -
EVACUATE AREA.
WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
Page 1
PRODUCT #: 81080 NAME: HEXACHLOROPLATINIC ACID HYDRATE, ~38% PT
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 11, 1903 10:18AM
SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL.
AVOID RAISING DUST.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
REFER TO SECTION 8.
SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT
GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.
USE ONLY IN A CHEMICAL FUME HOOD.
SAFETY SHOWER AND EYE BATH.
FACESHIELD (8-INCH MINIMUM).
DO NOT BREATHE DUST.
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
AVOID PROLONGED OR REPEATED EXPOSURE.
WASH THOROUGHLY AFTER HANDLING.
KEEP TIGHTLY CLOSED.
STORE IN A COOL DRY PLACE.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
APPEARANCE AND ODOR
SOLID.
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
INCOMPATIBILITIES
BASES
MAY DECOMPOSE ON EXPOSURE TO LIGHT.
MAY DECOMPOSE ON EXPOSURE TO MOIST AIR OR WATER.
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
TOXIC FUMES OF:
HYDROGEN CHLORIDE GAS
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
ACUTE EFFECTS
MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION.
MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES
AND UPPER RESPIRATORY TRACT, EYES AND SKIN.
INHALATION MAY RESULT IN SPASM, INFLAMMATION AND EDEMA OF THE
LARYNX AND BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY EDEMA.
SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING,
WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND
VOMITING.
MAY CAUSE ALLERGIC RESPIRATORY AND SKIN REACTIONS.
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND
TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
RTECS #: TP1500000
PLATINATE(2-), HEXACHLORO-, DIHYDROGEN, (OC-6-11)-
TOXICITY DATA
IVN-RAT LD50:49 MG/KG NTIS** PB291-731
IPR-MUS LD50:29097 MG/KG COREAF 256,1043,1963
TARGET ORGAN DATA
SENSE ORGANS AND SPECIAL SENSES (OTHER OLFACTION EFFECTS)
BEHAVIORAL (TREMOR)
GASTROINTESTINAL (HYPERMOTILITY, DIARRHEA)
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
(RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE INFORMATION.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
CATALYSTS AND EXPENSIVE METALS SHOULD BE RECOVERED FOR REUSE
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PRODUCT #: 81080 NAME: HEXACHLOROPLATINIC ACID HYDRATE, ~38% PT
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 11, 1903 10:18AM
OR RECYCLING.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
CONTACT FLUKA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
EUROPEAN INFORMATION
CORROSIVE
R 34
CAUSES BURNS.
R 42/43
MAY CAUSE SENSITIZATION BY INHALATION AND SKIN CONTACT.
S 26
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
S 27
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
S 36/37/39
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE
PROTECTION.
S 22
DO NOT BREATHE DUST.
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
ACGIH TLV-TWA 0.002 MG(PT)/M3 DTLVS* TLV/BEI,1996
MSHA STANDARD-AIR:TWA 0.002 MG(PT)/M3
DTLVS* 3,213,1971
OSHA PEL (GEN INDU):8H TWA 0.002 MG(PT)/M3
CFRGBR 29,1910.1000,1994
OSHA PEL (CONSTRUC):8H TWA 0.002 MG(PT)/M3
CFRGBR 29,1926.55,1994
OSHA PEL (SHIPYARD):8H TWA 0.002 MG(PT)/M3
CFRGBR 29,1915.1000,1993
OSHA PEL (FED CONT):8H TWA 0.002 MG(PT)/M3
CFRGBR 41,50-204.50,1994
OEL-ARAB REPUBLIC OF EGYPT:TWA 0.002 MG(PT)/M3 (DUST) JAN 1993
OEL-AUSTRALIA:TWA 0.002 MG(PT)/M3 JAN 1993
OEL-BELGIUM:TWA 0.002 MG(PT)/M3 JAN 1993
OEL-DENMARK:TWA 0.002 MG(PT)/M3 JAN 1993
OEL-FINLAND:TWA 0.002 MG(PT)/M3 JAN 1993
OEL-GERMANY:TWA 0.002 MG(PT)/M3 JAN 1993
OEL-HUNGARY:STEL 0.002 MG(PT)/M3 JAN 1993
OEL-THE NETHERLANDS:TWA 0.002 MG(PT)/M3 JAN 1993
OEL-THE PHILIPPINES:TWA 0.002 MG(PT)/M3 JAN 1993
OEL-SWITZERLAND:TWA 0.002 MG(PT)/M3 JAN 1993
OEL-UNITED KINGDOM:TWA 0.002 MG(PT)/M3 JAN 1993
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV
NOHS 1974: HZD M4727; NIS 2; TNF 73; NOS 3; TNE 249
NOES 1983: HZD M4727; NIS 3; TNF 62; NOS 4; TNE 1819; TFE 1134
EPA GENETOX PROGRAM 1988, POSITIVE: B SUBTILIS REC ASSAY
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
Page 3
PRODUCT #: 81080 NAME: HEXACHLOROPLATINIC ACID HYDRATE, ~38% PT
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 11, 1903 10:18AM
COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,
FLUKA CHEMIE AG
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY
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