PRODUCT #: 20870 NAME: CADMIUM STICKS
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Monday, March 10, 1903 4:10PM
Sigma Chemical Co. Aldrich Chemical Co., Inc. Fluka Chemical Corp.
P.O. Box 14508 1001 West St. Paul 1001 West St. Paul
St. Louis, MO 63178 Milwaukee, WI 53233 Milwaukee, WI 53233
Phone: 314-771-5765 Phone: 414-273-3850 Phone: 414-273-3850
SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
CATALOG #: 20870
NAME: CADMIUM STICKS
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS #: 7440-43-9
MF: CD
EC NO: 231-152-8
SYNONYMS
CADMIUM (ACGIH:OSHA) * CADMIUM DUST FUME (OSHA) * CADMIUM POWDER * C.
I. 77180 * COLLOIDAL CADMIUM * KADMIUM (GERMAN) *
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
LABEL PRECAUTIONARY STATEMENTS
HIGHLY TOXIC (USA)
TOXIC (EU)
MAY CAUSE CANCER.
VERY TOXIC BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
DANGER:
CONTAINS CADMIUM.
CANCER HAZARD.
AVOID CREATING DUST.
CAN CAUSE LUNG AND KIDNEY DISEASE.
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE).
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER.
DO NOT BREATHE DUST.
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE
PROTECTION.
SENSITIVE TO AIR
KEEP TIGHTLY CLOSED.
STORE UNDER NITROGEN.
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN IMMEDIATELY.
DISCARD CONTAMINATED CLOTHING AND SHOES.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
EXTINGUISHING MEDIA
CARBON DIOXIDE.
DRY CHEMICAL POWDER.
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS
Page 1
PRODUCT #: 20870 NAME: CADMIUM STICKS
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Monday, March 10, 1903 4:10PM
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -
EVACUATE AREA.
WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
REFER TO SECTION 8.
ADDITIONAL INFORMATION
THIS MATERIAL IN POWDERED FORM IS INCOMPATABLE WITH: SULFUR, SELENIUM,
TELLURIUM, ZINC, HYDRAZOIC ACID AND AMMONIUM NITRATE.
SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT
GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.
SAFETY SHOWER AND EYE BATH.
USE ONLY IN A CHEMICAL FUME HOOD.
AVOID CONTACT AND INHALATION.
AVOID PROLONGED OR REPEATED EXPOSURE.
WASH THOROUGHLY AFTER HANDLING.
CARCINOGEN.
HIGHLY TOXIC.
KEEP TIGHTLY CLOSED.
AIR SENSITIVE
STORE UNDER NITROGEN.
STORE IN A DRY AREA.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
APPEARANCE AND ODOR
SILVER SHOT
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
INCOMPATIBILITIES
OXIDIZING AGENTS
ACIDS
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
NATURE OF DECOMPOSITION PRODUCTS NOT KNOWN.
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
ACUTE EFFECTS
MAY BE FATAL IF INHALED.
HARMFUL IF SWALLOWED.
MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN.
PROLONGED EXPOSURE CAN CAUSE:
STOMACH PAINS, VOMITING, DIARRHEA.
LUNG IRRITATION, CHEST PAIN AND EDEMA WHICH MAY BE FATAL.
CHRONIC EFFECTS
CARCINOGEN.
DAMAGE TO THE LUNGS
DAMAGE TO THE KIDNEYS
TARGET ORGAN(S):
LUNGS
KIDNEYS
RTECS #: EU9800000
CADMIUM
TOXICITY DATA
IHL-HMN LCLO:39 MG/M3/20M AIHAAP 31,180,1970
UNR-MAN LDLO:15 MG/KG 85DCAI 2,73,1970
ORL-RAT LD50:2330 MG/KG 85PDAD -,67,1978
IHL-RAT LC50:25 MG/M3/30M SAIGBL 16,212,1974
Page 2
PRODUCT #: 20870 NAME: CADMIUM STICKS
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Monday, March 10, 1903 4:10PM
UNR-RAT LD50:1140 MG/KG GTPZAB 22(5),6,1978
ORL-MUS LD50:890 MG/KG 41HTAH -,14,1978
IPR-MUS LD50:5700 UG/KG TXAPA9 37,403,1976
UNR-MUS LD50:890 MG/KG GTPZAB 22(5),6,1978
TARGET ORGAN DATA
LUNGS, THORAX OR RESPIRATION (TUMORS)
KIDNEY, URETER, BLADDER (PROTEINURIA)
BLOOD (LYMPHOMA INCLUDING HODGKIN'S DISEASE)
MUSCULO-SKELETAL (TUMORS)
PATERNAL EFFECTS (SPERMATOGENESIS)
EFFECTS ON FERTILITY (PRE-IMPLANTATION MORTALITY)
EFFECTS ON EMBRYO OR FETUS (FETOTOXICITY)
EFFECTS ON EMBRYO OR FETUS (FETAL DEATH)
EFFECTS ON EMBRYO OR FETUS (OTHER EFFECTS TO EMBYRO OR FETUS)
SPECIFIC DEVELOPMENTAL ABNORMALITIES (CENTRAL NERVOUS SYSTEM)
SPECIFIC DEVELOPMENTAL ABNORMALITIES (EYE, EAR)
SPECIFIC DEVELOPMENTAL ABNORMALITIES (CRANIOFACIAL)
SPECIFIC DEVELOPMENTAL ABNORMALITIES (BODY WALL)
SPECIFIC DEVELOPMENTAL ABNORMALITIES (BLOOD AND LYMPHATIC SYSTEMS)
SPECIFIC DEVELOPMENTAL ABNORMALITIES (UROGENITAL SYSTEM)
TUMORIGENIC EFFECTS (TESTICULAR TUMORS)
EFFECTS ON NEWBORN (VIABILITY INDEX)
EFFECTS ON NEWBORN (GROWTH STATISTICS)
EFFECTS ON NEWBORN (GERM CELL EFFECTS)
EFFECTS ON NEWBORN (BIOCHEMICAL AND METABOLIC)
EFFECTS ON NEWBORN (BEHAVIORAL)
TUMORIGENIC (CARCINOGENIC BY RTECS CRITERIA)
TUMORIGENIC (NEOPLASTIC BY RTECS CRITERIA)
TUMORIGENIC (EQUIVOCAL TUMORIGENIC AGENT BY RTECS CRITERIA)
TUMORIGENIC (TUMORS AT SITE OF APPLICATION)
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
(RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE INFORMATION.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
MATERIAL IN THE ELEMENTAL STATE SHOULD BE RECOVERED FOR REUSE OR
RECYCLING.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
CONTACT FLUKA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
EUROPEAN INFORMATION
TOXIC
R 45
MAY CAUSE CANCER.
R 26/27/28
VERY TOXIC BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
S 45
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE).
S 26
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
S 28
AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER.
S 22
Page 3
PRODUCT #: 20870 NAME: CADMIUM STICKS
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Monday, March 10, 1903 4:10PM
DO NOT BREATHE DUST.
S 36/37/39
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE
PROTECTION.
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
ACGIH TLV-SUSPECTED HUMAN CARCINOGEN DTLVS* TLV/BEI,1996
ACGIH TLV-TWA 0.01 MG(CD)/M3 DTLVS* TLV/BEI,1996
IARC CANCER REVIEW:ANIMAL SUFFICIENT EVIDENCE IMEMDT 2,74,1973
IARC CANCER REVIEW:ANIMAL SUFFICIENT EVIDENCE IMEMDT 11,39,1976
IARC CANCER REVIEW:HUMAN SUFFICIENT EVIDENCE IMEMDT 58,119,1993
IARC CANCER REVIEW:HUMAN LIMITED EVIDENCE IMSUDL 7,139,1987
IARC CANCER REVIEW:ANIMAL LIMITED EVIDENCE IMEMDT 58,119,1993
IARC CANCER REVIEW:GROUP 1 IMEMDT 58,119,1993
MSHA STANDARD-AIR:TWA 0.2 MG/M3
DTLVS* 3,35,1971
OSHA PEL (GEN INDU):SEE CFR 29,1910.1027
CFRGBR 29,1910.1000,1994
OSHA PEL (CONSTRUC):SEE CFR 29,1926.1127
CFRGBR 29,1926.55,1994
OSHA PEL (SHIPYARD):SEE CFR 29,1915.1027
CFRGBR 29,1915.1000,1993
OSHA PEL (FED CONT):8H TWA 0.2 MG(CD)/M3
CFRGBR 41,50-204.50,1994
OEL-ARAB REPUBLIC OF EGYPT:TWA 0.05 MG/M3 JAN 1993
OEL-AUSTRALIA:TWA 0.05 MG/M3 JAN 1993
OEL-BELGIUM:TWA 0.05 MG/M3 JAN 1993
OEL-DENMARK:TWA 0.01 MG/M3 JAN 1993
OEL-FINLAND:TWA 0.02 MG/M3;CARCINOGEN JAN 1993
OEL-GERMANY;CARCINOGEN JAN 1993
OEL-INDIA:TWA 0.05 MG/M3 JAN 1993
OEL-JAPAN:TWA 0.05 MG/M3 JAN 1993
OEL-THE NETHERLANDS:TWA 0.02 MG/M3;STEL 0.1 MG/M3 JAN 1993
OEL-THE PHILIPPINES:TWA 0.2 MG/M3 JAN 1993
OEL-RUSSIA:TWA 0.01 MG/M3;STEL 0.05 MG/M3 JAN 1993
OEL-SWEDEN:TWA 0.02 MG/M3;CARCINOGEN JAN 1993
OEL-SWITZERLAND:TWA 0.05 MG/M3 JAN 1993
OEL-THAILAND:TWA 0.2 MG/M3;STEL 0.5 MG/M3 JAN 1993
OEL-TURKEY:TWA 0.2 MG/M3 JAN 1993
OEL-UNITED KINGDOM:TWA 0.01 MG/M3 JAN 1993
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV
NIOSH REL TO CADMIUM, DUST AND FUME-AIR:CA LOWEST FEASIBLE CONC.
NIOSH* DHHS #92-100,1992
NOHS 1974: HZD T0608; NIS 1; TNF 48; NOS 1; TNE 96
NOHS 1974: HZD 15570; NIS 41; TNF 1256; NOS 50; TNE 14717
NOES 1983: HZD T0608; NIS 2; TNF 25; NOS 3; TNE 335; TFE 22
NOES 1983: HZD X2776; NIS 5; TNF 248; NOS 6; TNE 3893; TFE 1887
NOES 1983: HZD X5979; NIS 2; TNF 95; NOS 2; TNE 486
NOES 1983: HZD 15570; NIS 77; TNF 4811; NOS 64; TNE 88968; TFE 14541
ATSDR TOXICOLOGY PROFILE (NTIS** PB/89/194476)
EPA GENETOX PROGRAM 1988, POSITIVE/LIMITED: CARCINOGENICITY-MOUSE/RAT
EPA GENETOX PROGRAM 1988, INCONCLUSIVE: IN VIVO CYTOGENETICS-HUMAN
LYMPHOCYTE
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES
ON EPA IRIS DATABASE
Page 4
PRODUCT #: 20870 NAME: CADMIUM STICKS
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Monday, March 10, 1903 4:10PM
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997
NIOSH CURRENT INTELLIGENCE BULLETIN 42, 1984
NIOSH ANALYTICAL METHOD, 1994: CADMIUM AND COMPOUNDS, AS CD, 7048
NIOSH ANALYTICAL METHOD, 1994: ELEMENTS BY ICP, 7300
NIOSH ANALYTICAL METHOD, 1994: ELEMENTS IN BLOOD OR TISSUE, 8005
NIOSH ANALYTICAL METHOD, 1994: METALS IN URINE, 8310
NTP 7TH ANNUAL REPORT ON CARCINOGENS, 1992 : ANTICIPATED TO BE
CARCINOGEN
OSHA ANALYTICAL METHOD #ID-125G
U.S. INFORMATION
THIS PRODUCT IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT IS OR CONTAINS CHEMICAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER.
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,
FLUKA CHEMIE AG
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY
Page 5
|