SAFETY DATA SHEET
Version-2
Based on Directive 2001/58/EC of the Commission of the European Communities
FULLCURE 720
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation:
Synonyms: none
CAS No. : N.A.
EC index No. : NFPA code : N.D.
N.A.
EINECS No. : Molecular weight : N.A.
N.A.
RTECS No. : Formula : N.A.
N.A.
1.2 Use of the substance or the preparation:
Toner
1.3 Company/undertaking identification:
Objet Geometries Ltd - Europe
Leuvensesteenweg 388
B-1932 Sint-Stevens-Woluwe
Tel. : +32 2 717 65 02
Fax : +32 2 717 65 00
Email: info@2objet.com, www.2objet.com
1.4 Telephone number for emergency:
See 1.3
2. Composition/information on ingredients
Hazardous ingredients CAS No. Conc. in Hazard Risks
% symbol
EINECS/ELINCS No. (R-phrases)
Acrylic Monomer Proprietary <40 Xn 22-41-43-48/22
(2) (1)
exo-1,7,7- 5888-33-5 < 40 Xi 43 (1)
trimethylbicyclo[2.2.1]hept-2-yl
227-561-6
acrylate
urethane acrylate oligomer N.D. 1-20 Xi 36/38 (1)
acrylate oligomer N.D. 1-20 Xi 38-43 (1)
epoxy acrylate 154608-99-8 1-20 Xn 20/22-36/37/38-43
(1)
-
acrylate oligomer N.D. < 20 Xi 36/38 (1)
Photoinitiator Proprietary <1 Xi 43-53 (1)
(1) For R-phrases in full: see heading 16
(2) Objet Proprietary information
3. Hazards identification
- Classified dangerous in accordance with Directives 67/548/EEC and
1999/45/EC
- In normal conditions of use, the components cannot be released
4. First aid measures
4.1 Eye contact:
- Consult a doctor/medical service if irritation persists
- Rinse immediately with plenty of water for 15 minutes
- Do not apply neutralizing agents
Printing date : 09-2005 1/8
Compiled by : Objet
MSDS established : 07-04-2003 Revision date : 10-02-2005
Reason for revision : see heading 2
FULLCURE 720
4.2 Skin contact:
- Consult a doctor/medical service if irritation persists
- Soap may be used
- Wash immediately with lots of water
4.3 After inhalation:
- Consult a doctor/medical service if breathing problems develop
- Remove the victim into fresh air
- Unconscious: maintain adequate airway and respiration
4.4 After ingestion:
- Consult a doctor/medical service if you feel unwell
- Immediately give lots of water to drink
- Never give water to an unconscious person
- Do not induce vomiting
5. Fire-fighting measures
5.1 Suitable extinguishing media:
- Water spray
- AFFF foam
- BC powder
- Carbon dioxide
5.2 Unsuitable extinguishing media:
- No data available
5.3 Special exposure hazards:
- Combustible
- On burning: release of toxic and corrosive gases/vapours (nitrous vapours,
carbon monoxide - carbon dioxide)
5.4 Instructions:
- If exposed to fire cool the closed containers by spraying with water
- Dilute toxic gases with water spray
5.5 Special protective equipment for firefighters:
- Heat/fire exposure: compressed air/oxygen apparatus
- Protective clothing for exposure to chemicals
6. Accidental release measures
6.1 Personal protection/precautions:
See heading 8.2/8.3/13
6.2 Environmental precautions:
- Contain leaking substance
6.3 Methods for cleaning up:
- Take up liquid spill into absorbent material, e.g.: sand
- Scoop absorbed substance into closing containers
- Clean contaminated surfaces with an excess of water
- Wash clothing and equipment after handling
7. Handling and storage
7.1 Handling:
Accidental release of the contents:
- Observe very strict hygiene - avoid contact
- Remove contaminated clothing immediately
- Clean contaminated clothing
7.2 Storage:
- Keep container tightly closed
- Keep out of direct sunlight
- Store in a dry area
- Store in a dark area
- Keep away from: heat sources
Printing date : 09-2005 2/8
FULLCURE 720
Storage temperature : N.D. 掳C
Quantity limits : N.D. kg
Storage life : N.D. days
Materials for packaging :
- suitable : no data available
- to avoid : no data available
7.3 Specific uses:
- See information supplied by the manufacturer
8. Exposure controls/Personal protection
8.1 Exposure limit values:
TLV-TWA : not listed
TLV-STEL : not listed
TLV-Ceiling : not listed
OES-LTEL : not listed
OES-STEL : not listed
MEL-LTEL : not listed
MEL-STEL : not listed
MAK : not listed
TRK : not listed
MAC-TGG 8 h : not listed
MAC-TGG 15 min. : not listed
MAC-Ceiling : not listed
VME-8 h : not listed
VLE-15 min. : not listed
GWBB-8 h : not listed
GWK-15 min. : not listed
Momentary value : not listed
EC : not listed
EC-STEL : not listed
Sampling methods:
- No data available
8.2 Exposure controls:
8.2.1 Occupational exposure controls:
Accidental release of the contents:
- Work under local exhaust/ventilation
8.2.2 Environmental exposure controls: see heading 13
8.3 Personal protection:
8.3.1 respiratory protection:
- Not required for normal conditions of use
8.3.2 hand protection:
- Accidental release of the contents: Gloves
Suitable materials: No data available
- Breakthrough time: N.D.
8.3.3 eye protection:
- Accidental release of the contents: Safety glasses
8.3.4 skin protection:
- Accidental release of the contents: Protective clothing
Suitable materials: No data available
Printing date : 09-2005 3/8
FULLCURE 720
9. Physical and chemical properties
9.1 General information:
Appearance (at 20掳C) : Toner cartridge
Odour : N.D.
Colour : N.D.
9.2 Important health, safety and environmental information:
pH value : N.D.
掳C
Boiling point/boiling range : N.D.
掳C
Flashpoint : N.D.
vol% ( 掳C)
Explosion limits : N.D.
hPa
Vapour pressure (at 20掳C) : N.D.
hPa
Vapour pressure (at 50掳C) : N.D.
Relative density (at 20掳C) : N.D.
Water solubility : N.D.
Soluble in : N.D.
Relative vapour density : N.D.
Pa.s
Viscosity : N.D.
Partition coefficient n-octanol/water : N.D.
Evaporation rate
ratio to butyl acetate : N.D.
ratio to ether : N.D.
9.3 Other information:
掳C
Melting point/melting range : N.D.
掳C 3
Auto-ignition point : N.D.
g/m
Saturation concentration : N.D.
10. Stability and reactivity
10.1 Conditions to avoid/reactivity:
- Unstable on exposure to heat
- Unstable on exposure to light
10.2 Materials to avoid:
- Keep away from: heat sources
10.3 Hazardous decomposition products:
- Polymerizes on exposure to light
- On burning: release of toxic and corrosive gases/vapours (nitrous vapours,
carbon monoxide - carbon dioxide)
Printing date : 09-2005 4/8
FULLCURE 720
11. Toxicological information
11.1 Acute toxicity:
4-acryloylmorpholine
LD50 oral rat mg/kg
: 588
LD50 dermal rat mg/kg
: > 2000
LD50 dermal rabbit mg/kg
: N.D.
LC50 inhalation rat mg/l/4 h
: N.D.
LC50 inhalation rat ppm/4 h
: N.D.
11.2 Chronic toxicity:
EC carc. cat. : not listed
EC muta. cat. : not listed
EC repr. cat. : not listed
Carcinogenicity (TLV) : not listed
Carcinogenicity (MAC) : not listed
Carcinogenicity (VME) : not listed
Carcinogenicity (GWBB) : not listed
Carcinogenicity (MAK) : not listed
Mutagenicity (MAK) : not listed
Teratogenicity (MAK) : not listed
IARC classification : not listed
11.3 Routes of exposure:
- In normal conditions of use, the hazardous contents cannot be released
11.4 Acute effects/symptoms:
- The following symptoms may appear when the components are released:
- AFTER SKIN CONTACT
- Tingling/irritation of the skin
- AFTER EYE CONTACT
- Irritation of the eye tissue
- Redness of the eye tissue
11.5 Chronic effects:
- May produce an allergic reaction
- The following symptoms may appear when the components are released:
- ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
- Skin rash/inflammation
Printing date : 09-2005 5/8
FULLCURE 720
12. Ecological information
12.1 Ecotoxicity:
- No data available
12.2 Mobility:
- Volatile organic compounds (VOC): N.D.%
For other physicochemical properties see heading 9
12.3 Persistence and degradability:
- biodegradation BOD5 : % ThOD
N.D.
- water : - N.D.
-
- soil : T 陆: days
N.D.
12.4 Bioaccumulative potential:
- log Pow : N.D.
- BCF : N.D.
-
12.5 Other adverse effects:
- WGK : N.V.T
.
- Effect on the ozone layer : Not dangerous for the ozone layer
(1999/45/EC)
- Greenhouse effect : no data available
- Effect on waste water purification : no data available
13. Disposal considerations
13.1 Provisions relating to waste:
- Waste material code (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of
16/2/2001): 08 03 17* (waste printing toner containing dangerous
substances)
- Hazardous waste (91/689/EEC)
13.2 Disposal methods:
- Refer to manufacturer/supplier for information on recovery/recycling
- Remove to an authorized waste treatment plant
13.3 Packaging/Container:
- No available data
Printing date : 09-2005 6/8
FULLCURE 720
14. Transport information
14.1 Classification of the substance in compliance with UN Recommendations
UN number :
CLASS :-
SUB RISKS :
PACKING :
PROPER SHIPPING NAME :
14.2 ADR (transport by road)
CLASS : NOT SUBJECT
PACKING :
CLASSIFICATION CODE :
DANGER LABEL TANKS :
DANGER LABEL PACKAGES :
14.3 RID (transport by rail)
CLASS : NOT SUBJECT
PACKING :
CLASSIFICATION CODE :
DANGER LABEL TANKS :
DANGER LABEL PACKAGES :
14.4 ADNR (transport by inland waterways)
CLASS : NOT SUBJECT
PACKING :
CLASSIFICATION CODE :
DANGER LABEL TANKS :
DANGER LABEL PACKAGES :
14.5 IMDG (maritime transport)
CLASS : NOT SUBJECT
SUB RISKS :
PACKING :
MFAG :
EMS :
MARINE POLLUTANT :
14.6 ICAO (air transport)
CLASS : NOT SUBJECT
SUB RISKS :
PACKING :
PACKING INSTRUCTIONS PASSENGER AIRCRAFT :
PACKING INSTRUCTIONS CARGO AIRCRAFT :
Printing date : 09-2005 7/8
FULLCURE 720
15. Regulatory information
Classified dangerous in accordance with Directives 67/548/EEC and 1999/45/EC.
In normal conditions of use, the components cannot be released because of the
form in which the article or preparation is placed on the market.
Contains: acrylate oligomer; epoxy acrylate; exo-1,7,7-
trimethylbicyclo[2.2.1]hept-2-yl acrylate ; phenyl bis(2,4,6-
trimethylbenzoyl)-phosphine oxide; 4-acryloylmorpholine. May produce an
allergic reaction
16. Other information
The information provided on this MSDS is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe
handling, use, processing, storage, transportation, disposal and release and is not to be considered
as a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other material or in
any process, unless specified in the text.
= NOT APPLICABLE
N.A.
= NOT DETERMINED
N.D.
= INTERNAL CLASSIFICATION (NFPA)
(*)
Exposure limits:
: Threshold Limit Value - ACGIH USA 2004
TLV
: Occupational Exposure Standards - United Kingdom 2003
OES
: Maximum Exposure Limits - United Kingdom 2003
MEL
: Maximale Arbeitsplatzkonzentrationen - Germany 2002
MAK
: Technische Richtkonzentrationen - Germany 2002
TRK
: Maximale aanvaarde concentratie - The Netherlands 2004
MAC
: Valeurs limites de Moyenne d鈥橢xposition - France 1999
VME
: Valeurs limites d鈥橢xposition 脿 court terme - France 1999
VLE
GWBB : Grenswaarde beroepsmatige blootstelling - Belgium 2002
: Grenswaarde kortstondige blootstelling - Belgium 2002
GWK
: Indicative occupational exposure limit values - directive 2000/39/EC
EC
Chronic toxicity:
: List of the carcinogenic substances and processes - The Netherlands 2004
K
Full text of any R-phrases referred to under heading 2:
R20/22 : Harmful by inhalation and if swallowed
R22 : Harmful if swallowed
R36/37/38 : Irritating to eyes, respiratory system and skin
R36/38 : Irritating to eyes and skin
R38 : Irritating to skin
R41 : Risk of serious damage to eyes
R43 : May cause sensitisation by skin contact
R48/22 : Harmful: danger of serious damage to health by prolonged exposure if swallowed
R53 : May cause long-term adverse effects in the aquatic environment
Printing date : 09-2005 8/8
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