MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identification
SolaChrome® Inks
Product Name:
Commonly used in the following printer(s):
DisplayMaker 110S
Product Numbers: 0900873 Series P/N to include the following colors and their
densities: Cyan, Magenta, Yellow, Black
Chemical Name: Solvent-based Inkjet Printing Fluid
Chemical Family: Glycol Ether/Polymer/Pigment Blend
CAS Number: Blend
Company Identification
MacDermid ColorSpan Corporation
7090 Shady Oak Road
Eden Prairie, MN 55344 USA
In case of exposure, please contact local Poison Control Center
Emergency phone for spills, leaks, fire, exposure or accident call
CHEMTREC: 1-800-424-9300 or 1-703-527-3887
Product information: (800) 925-0563
Revision Date: 03/31/03
2. COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL NAME CAS # EINECS # Proportion EXPOSURE LIMITS IN AIR
ACGIH-TLV OSHA-PEL NIOSH OTHER
TWA STEL TWA STEL IDLH
mg/m3
(% v/v) mg/m3 mg/m3 mg/m3 mg/m3 mg/m3
Alkyl Glycol Ether Compound Proprietary 60�70 NE NE NE NE NE NIOSH REL:
TWA = 33 (skin)
DFG MAK:
TWA = 130 (skin)
PEAK = 2•MAK 30
min. average value
Pregnancy Risk
Group: C
Aliphatic Ether Alcohol Proprietary 15�25 NE NE NE NE NE NE
Ester Compound
Glycol Ether Acetate Proprietary 5�15 NE NE NE NE NE NE
Compound
Red Pigment Proprietary 0�10 NE NE NE NE NE NE
Yellow Pigment Proprietary 0�10 NE NE NE NE NE NE
Violet Pigment Proprietary 0�10 NE NE NE NE NE NE
SolaChrome® Ink MSDS, Page 1 of 14
CHEMICAL NAME CAS # EINECS # Proportion EXPOSURE LIMITS IN AIR
ACGIH-TLV OSHA-PEL NIOSH OTHER
TWA STEL TWA STEL IDLH
mg/m3
(% v/v) mg/m3 mg/m3 mg/m3 mg/m3 mg/m3
Polymer with Chloroprene Proprietary 1�5 NE NE NE NE NE NE
and Ethyenyl Acetate
Blue Pigment Proprietary 0�5 NE NE NE NE NE NE
Acetic Acid Vinyl Ester Proprietary 0�5 NE NE NE NE NE NE
Polymer
Black Pigment Proprietary 0�5 3.5 NE 3.5 NE 1750 NIOSH REL:
TWA = 3.5
Carcinogen:IARC-
2B, NIOSH-X, TLV-
A4
Other components each present in less than 1 Balance None of the other components contribute significant
percent concentration (0.1% concentration additional hazards at the concentrations present in
for potential carcinogens, reproductive this product. All pertinent hazard information has
toxins, respiratory tract sensitizers, and been provided in this document, per the
mutagens). requirements of the Federal Occupational Safety and
Health Administration Standard (29 CFR 1910.1200),
U.S. State equivalent Standards; Canadian Workplace
Hazardous Materials Identification System Standards
(CPR 4); and the applicable Council Directives of
the European Community.
NE = Not Established. See Section 16 for Definitions of Terms Used.
3. HAZARDS IDENTIFICATION
This product is a clear, combustible liquid that has a distinct
EMERGENCY OVERVIEW:
odor and comes in a variety of colors (black, magenta, cyan, yellow). Health Hazards:
The primary health hazard associated with this product is the potential for moderate
irritation of contaminated tissue. Inhalation exposure may result in adverse effects
on the central nervous system. Inhalation of high concentration levels or prolonged
inhalation and ingestion may be harmful or fatal. The ink may stain skin, eyes, other
contaminated tissue, and objects. Flammability Hazards: This product must be
substantially preheated for ignition to become a potential hazard. Reactivity Hazards:
This product is not reactive. Environmental Hazards: This product may have adverse
effects when released into the environment. Emergency Recommendations: Emergency
responders must wear the personal protective equipment suitable for the situation to
which they are responding.
SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of occupational
overexposure are inhalation and contact with skin and eyes. The symptoms of overexposure
to this product, via route of entry, are as follows:
INHALATION: This product does not normally present a
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
significant inhalation hazard under anticipated
circumstances of use. If inhalation of vapors, mists,
or sprays of this product occurs, irritation of the (BLUE) 2
HEALTH HAZARD
nose, throat, and other tissues of the respiratory
system result. Symptoms of severe overexposure,
especially as may occur in poorly ventilated areas,
FLAMMABILITY HAZARD (RED) 2
may include central nervous system effects (e.g.,
headaches, dizziness, anesthesia, drowsiness, and
unconsciousness), coughing, nausea, abdominal pain,
vomiting, and inflammation of the gums. Chronic
PHYSICAL HAZARD (YELLOW) 0
inhalation exposure may cause headache, throat
irritation, low backache, and smptoms described under
“Other Health Effects�.
B
PROTECTIVE EQUIPMENT
CONTACT WITH SKIN or EYES: Due to the colorants,
skin contact may discolor contaminated areas. Skin
EYES HANDS BODY
RESPIRATORY
contact may cause redness, pain, or itching in
sensitive individuals. Repeated or prolonged skin
overexposure may cause dermatitis (dry, red skin). SEE SECTION 8 SEE SECTION 8
Eye contact with this product can moderately irritate
the eyes, causing pain, tearing, and redness. For Routine Industrial Use and Handling Applications
SolaChrome® Ink MSDS, Page 2 of 14
Because the eye tissue may be stained, vision may be temporarily blurred. There are some
reports that the Alkyl Glycol Ether Compound component of this product may cause allergic
skin reaction in susceptible individuals. Symptoms may include dryness, redness, itching,
rash or welts.
SKIN ABSORPTION: The Alkyl Glycol Ether Compound component of this product is suspected to
be absorbed through the skin, especially if the skin is abraded or affected by dermatitis
or eczema.
INGESTION: Though not anticipated to be a significant route of occupational exposure,
ingestion of large quantities of this product may cause stomach pains, nausea, vomiting,
and discoloration of the mouth, teeth, and tissues of the throat. If large quantities are
ingested, respiratory arrest or cardiovascular collapse could cause death. In humans, a
dose of 100 mL of the Alkyl Glycol Ether Compound component may cause death. If the victim
survives, kidney failure may develop within the next several days.
INJECTION: Accidental injection of this liquid (as may occur by a puncture with a
contaminated object) will cause local pain, irritation, and redness.
OTHER HEALTH EFFECTS: In acute poisoning from products containing Alkyl derivatives of
Ethylene Glycol, such as the 2-Buoxyethyl Acetate component of this product, there is often
renal injury, albuminuria (abnormal presence of serum albumin in the urine), and hematuria
(presence of blood in the urine). Other symptoms of overexposure to products that contain
Alkyl Glycol Ether Compound may include nausea, vomiting, diarrhea, prominent headache, and
delayed abdominal and lower back pain. Observations in animal tests indicate the
possibility of pulmonary edema, intravascular hemolysis, and bone marrow depression.
Chronic exposure to this product may adversely affect the kidneys and liver.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. In the event of
overexposure, the following symptoms may be observed:
ACUTE: The ink may stain hair, skin, and other contaminated tissue. Acute exposure to low
concentrations of this product via skin contact, eye contact, and inhalation may irritate
contaminated tissue. Inhalation of higher levels may cause significant irritation and
adverse effects on the central nervous system. Ingestion of small amounts will cause
nausea, vomiting, abdominal pain, and adverse effects on the central nervous system.
Ingestion of large amounts may be fatal or cause kidney failure.
CHRONIC: Chronic skin exposure to this product may cause dermatitis or allergic reaction
in susceptible individuals. Chronic exposure to this product can adversely affect the
kidneys and liver. Based on animal data, exposure to products containing Alkyl Glycol
Ether Compound may cause adverse reproductive effects. Refer to Section 11 (Toxicology
Information) for additional data.
TARGET ORGANS: ACUTE: Skin, respiratory system, eyes, kidneys. CHRONIC: Skin, kidneys,
reproductive system.
4. FIRST AID MEASURES
Contaminated individuals must be taken for medical attention if any adverse effect
occurs. Rescuers should be taken for medical attention if necessary. Take a copy of the
label and MSDS to health professional with victim.
SKIN EXPOSURE: If this product contaminates the skin, immediately begin decontamination
with running water and soap. The minimum recommended flushing time is 15 minutes. Remove
exposed or contaminated clothing, taking care not to contaminate eyes. The contaminated
individual must seek medical attention if any adverse effect occurs.
EYE EXPOSURE: If vapors, sprays, or mists of this product enter the eyes, open the
contaminated individual’s eyes while under gently running water. Use sufficient force to
open eyelids. Have the contaminated individual "roll" eyes. Minimum flushing is for 15
minutes. The contaminated individual must seek medical attention if any adverse effect
occurs.
INHALATION: If vapors, sprays, or mists of this product are inhaled, remove the
contaminated individual to fresh air. If necessary, remove or cover gross contamination to
avoid exposure to rescuers. Seek medical attention if adverse effect occurs.
INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST
CURRENT INFORMATION. DO NOT INDUCE VOMITING, unless directed by medical personnel. Have
victim rinse mouth with water if conscious. Never induce vomiting or give diluents (milk
or water) to someone who is unconscious, having convulsions, or unable to swallow. If
vomiting occurs, lean patient forward or place on left side (head-down position if
possible) to maintain an open airway and prevent aspiration.
SolaChrome® Ink MSDS, Page 3 of 14
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin, respiratory, liver, or kidney disorders
may be aggravated by prolonged overexposures to this product.
RECOMMENDATIONS TO PHYSICIANS: Treatment should include gastric lavage for removal of
residual Alkyl Glycol Ether Compound, correction of dehydration and shock, and management
of fluid balance in the presence of pulmonary edema, which might be due to the toxic
effects of Alkyl Glycol Ether Compound metabolites or the sodium overload. In addition,
hypocalcemia should be corrected with calcium chloride, depending on serum calcium
levels. Prompt diagnosis and initiation of treatment, including ethanol therapy and
hemodialysis, is necessary to ameliorate the effects of Alkyl Glycol Ether Compound
ingestion.
5. FIRE FIGHTING MEASURES
FLASH POINT: 72.0°C (161.6°F) [estimated]
AUTOIGNITION TEMPERATURE: Not established
FLAMMABLE LIMITS (in air by volume, %): Lower (LEL): Not established
Upper (UEL): Not established
FIRE EXTINGUISHING MATERIALS:
Water Spray: YES (for cooling) Foam: YES
NFPA RATING
Carbon Dioxide: YES Halon: YES
FLAMMABILITY
Dry Chemical: YES Other: Any "A" Class
UNUSUAL FIRE AND EXPLOSION HAZARDS: This product is a
2
Class IIIA combustible liquid. This product must be
substantially preheated for ignition to become a 2 0
HEALTH REACTIVITY
potential hazard. There are some reports that the Alkyl
Glycol Ether Compound component of this product may cause
allergic skin reaction in susceptible individuals and so
this product poses a contact hazard to fire-fighters.
OTHER
When involved in a fire, this material may decompose and
produce irritating vapors and toxic gases (e.g., carbon
oxides, nitrogen oxides, copper oxides).
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: Not sensitive under normal conditions. Vapors
of this product may ignite by static discharge if this product is exposed to extremely high
temperatures.
SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection.
Structural firefighters must wear Self-Contained Breathing Apparatus and full protective
equipment. Due to the presence of colorants, the runoff water from these products can
discolor contaminated objects. If possible, prevent runoff water from entering storm
drains, bodies of water, or other environmentally sensitive areas. If necessary, rinse
fire-response equipment with soapy water before returning to service.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: For incidental spills (e.g., less than 1 L of liquid from a
bottle), wear rubber gloves, splash goggles, and appropriate body protection. Non-
sparking tools should be used. Trained personnel following pre-planned procedures should
handle non-incidental releases (e.g., 10 L of liquid leaking from a crate of several
containers). In the event of a non-incidental spill, clear the area and protect people.
The minimum personal protective equipment for response to a non-incidental spill is as
follows: rubber gloves, rubber boots, face shield, and Tyvek suit. Control sources of
ignition before cleaning up. The minimum level of personal protective equipment for
releases in which the level of oxygen is less than 19.5% or is unknown must be Level B:
triple-gloves (rubber gloves and nitrile gloves over latex gloves), chemical resistant
suit and boots, hard hat, and Self-Contained Breathing Apparatus. Absorb spilled liquid
with polypads or other suitable absorbent materials. Rinse area thoroughly with soapy
water after liquid has dried. Decontaminate the area thoroughly. If necessary, discard
all stained response equipment or rinse with soapy water before returning such equipment
to service. Place all spill residue in an appropriate container and seal. Dispose of in
accordance with applicable U.S. Federal, State, or local procedures, or appropriate
SolaChrome® Ink MSDS, Page 4 of 14
standards of Canada, Australia, or EC Member States (see Section 13, Disposal
Considerations).
7. HANDLING AND STORAGE
WORK AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN
YOU. Wash thoroughly after handling this product. Do not eat, drink, smoke, or apply
cosmetics while handling this product. Avoid breathing vapors or mists generated by this
product. Use in a well-ventilated location. Remove contaminated clothing immediately.
STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained
to handle it safely. Keep away from heat, sparks, and other sources of ignition. Keep
container tightly closed when not in use. Use non-sparking tools. Bond and ground
containers during transfers of material. If this product is transferred into another
container, only use portable containers and dispensing equipment (e.g., faucet, pump, drip
can) approved for combustible liquids. Store containers in a cool, dry location, away from
direct sunlight, sources of intense heat, or where freezing is possible. Material should be
stored in secondary containers or in a diked area as appropriate. Store containers away
from incompatible chemicals (see Section 10, Stability and Reactivity). Containers should
be separated from oxidizing materials by a minimum distance of 20 ft. or by a barrier of
non-combustible material at least 5 ft. high having a fire-resistance rating of at least
0.5 hours. Storage areas should be made of fire resistant materials. Post warning and “NO
SMOKING� signs in storage and use areas, as appropriate. Have appropriate extinguishing
equipment in the storage area (e.g., sprinkler system, portable fire extinguishers).
Inspect all incoming containers before storage to ensure containers are properly labeled
and not damaged. Refer to NFPA 30, Flammable and Combustible Liquids Code, for additional
information on storage. Empty containers may contain residual liquid or vapors that are
combustible; therefore, empty containers should be handled with care. Never perform any
welding, cutting, soldering, drilling, or other hot work on an empty container or piping
until all liquid, vapors, and residue have been cleared.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices
indicated in Section 6 (Accidental Release Measures). Make certain that application
equipment is locked and tagged-out safely, if necessary. Collect all rinsates and dispose
of according to applicable U.S. Federal, State, or local procedures and appropriate
Canadian standards.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure
levels are maintained below the limits provided in Section 2 (Composition and Information
on Ingredients). Use local exhaust ventilation. Normal office ventilation conforming to
the American Society of Heating, Refrigerating, and Air Conditioning Engineers (ASHRAE)
Standards is adequate under normal circumstances of use. Persons using this product should
consult a qualified Ventilation Engineer and/or Industrial Hygienist if concerns about
exposures arise. If necessary, refer to Australian National Code of Practice for the
Control of Workplace Hazardous Substances [NOHSC: 2007 (1994)] for further information.
As with all products that contain chemicals, ensure proper decontamination equipment (e.g.,
eyewash/safety shower stations) are available near areas where this product is used as
necessary.
INTERNATIONAL OCCUPATIONAL EXPOSURE LIMITS: In addition to the exposure limit values cited
in Section 2 (Composition and Information on Ingredients), other exposure limits have been
established by various countries for the components of this mixture, as provided below (no
listing for a component indicates no values are available): Note: All limits given are
1993 and 1999 values; refer to current country limits for complete information.
The Philippines: TWA = 3.5 mg/m3
BLACK PIGMENT:
Australia: TWA = 3 mg/m3 Russia: STEL = 4 mg/m3
Belgium: TWA = 3.5 mg/m3 Sweden: TWA = 3 mg/m3
Denmark: TWA = 3.5 mg/m3 United Kingdom: TWA= 3.5mg/m3;STEL= 7 mg/m3
Finland: TWA = 3.5 mg/m3; STEL = 7 mg/m3 In Bulgaria, Columbia, Jordan, Korea, New
France: TWA = 3.5 mg/m3 Zealand, Singapore, and Vietnam check
The Netherlands: TWA = 3.5 mg/m3 ACGIH TLV.
SolaChrome® Ink MSDS, Page 5 of 14
Switzerland: MAK-W = 20 ppm (135 mg/m3),
ALKYL GLYCOL ETHER COMPOUND:
Austria: MAK = 20 ppm (135 mg/m3), Skin, KZG-W = 40 ppm (270 mg/m3), Skin, JAN
JAN 1999 1999
Germany: MAK = 20 ppm (135 mg/m3), Skin, United Kingdom: LTEL = 10 ppm (54 mg/m3),
JAN 1999 Skin, JAN 1993
Poland: MAC (TWA) = 100 mg/m3, JAN 1999 United Kingdom: LTEL = 5 ppm (24 mg/m3),
Sweden: TWA 10 ppm (70 mg/m3), STEL = 20 Skin, JAN 1993
ppm (140 mg/m3), Skin, JAN 1999
RESPIRATORY PROTECTION: None needed under normal circumstances of use. If necessary, use
only respiratory protection authorized in the U.S. Federal OSHA Respiratory Protection
Standard (29 CFR 1910.134), equivalent U.S. State standards, Canadian CSA Standard Z94.4-
93, the European Standard EN149, and EC member states, or the Australian Standard 1716-
Respiratory Protective Devices and Australian Standard 1715-Selection, Use, and
Maintenance of Respiratory Protective Devices. Oxygen levels below 19.5% are considered
IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full
facepiece, supplied air respirator with auxiliary self-contained air supply is required
under U.S. Federal OSHA’s Respiratory Protection Standard (1910.134-1998) or the
regulations of various U.S. States, Canada, Australia, or EC Member States. The NIOSH
Respiratory Guidelines for the Alkyl Glycol Ether Compound component are given for
additional information.
ALKYL GLYCOL ETHER COMPOUND
CONCENTRATION RESPIRATORY PROTECTION
Up to 50 ppm: Any Chemical Cartridge Respirator with organic vapor cartridge(s) or
any Supplied-Air Respirator (SAR).
Up to 125 ppm: Any SAR operated in a continuous-flow mode or any Powered, Air-
Purifying Respirator with organic vapor cartridge(s).
Up to 250 ppm: Any Chemical Cartridge Respirator with a full facepiece and organic
vapor cartridge(s), any Air-Purifying, Full-Facepiece Respirator (gas
mask) with a chin-style, front- or back-mounted organic vapor canister,
any Powered, Air-Purifying Respirator with a tight-fitting facepiece
and organic vapor cartridge(s), any Self-Contained Breathing Apparatus
(SCBA) with a full facepiece, or any SAR with a full facepiece.
Up to 700 ppm: Any SAR that has a full facepiece and is operated in a pressure-demand
or other positive-pressure mode.
Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Any SCBA that
has a full facepiece and is operated in a pressure-demand or other
positive-pressure mode or any SAR that has a full facepiece and is
operated in a pressure-demand or other positive-pressure mode in
combination with an auxiliary SCBA operated in pressure-demand or other
positive-pressure mode.
Escape: Any Air-Purifying, Full-Facepiece Respirator (gas mask) with a chin-
style, front- or back-mounted organic vapor canister or any appropriate
escape-type SCBA.
HAND PROTECTION: Wear butyl rubber gloves for routine use to prevent staining. Check
gloves for leaks. If necessary, refer to U.S. OSHA 29 CFR 1910.138, Australian Standard
2161-Industrial Safety Gloves and Mittens and appropriate Standards of the EC and Canada
for further information.
EYE PROTECTION: None needed under normal circumstances of use. Splash goggles or safety
glasses should be worn during operations in which sprays of liquid may occur. If
necessary, refer to U.S. OSHA 29 CFR 1910.133, the European Standard EN166, or the
Australian Standard 1337-Eye Protection for Industrial Applications and Australian
Standard 1336-Recommended Practices for Eye Protection in the Industrial Environment for
further information.
BODY PROTECTION: None needed under normal circumstances of use. Use body protection
appropriate for task (e.g., rubber apron when cleaning equipment; Tyvek suit and rubber
boots during non-incidental spill response). If necessary, refer to Australian Standard
3765-Clothing for Protection Against Hazardous Chemicals for further information. If a
hazard of injury to the feet exists due to falling objects, rolling objects, where objects
may pierce the soles of the feet or where employee’s feet may be exposed to electrical
hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136.
SolaChrome® Ink MSDS, Page 6 of 14
9. PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT: 183.5°C (362.3°F)[estimated] MELTING/FREEZING POINT: Not established
VAPOR PRESSURE, mm Hg @ 20°C: Not established pH: Not applicable
VAPOR DENSITY (air = 1): Not established SOLUBILITY IN WATER: Insoluble
EVAPORATION RATE (n-BuAc = 1): Not established ODOR THRESHOLD: Not established
SPECIFIC GRAVITY (water = 1): Not established
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not established
APPEARANCE, ODOR AND COLOR: This product is a clear liquid that has a distinct odor and
comes in a variety of colors (cyan, magenta, yellow, black).
HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance of this product may be a
distinguishing characteristic.
10. STABILITY AND REACTIVITY
STABILITY: Stable.
DECOMPOSITION PRODUCTS: If exposed to extremely high temperatures, this product can
decompose to generate carbon oxides, nitrogen oxides, and copper oxides.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong oxidizers, strong bases.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Exposure to or contact with extremely high temperatures, incompatible
chemicals.
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: Specific toxicology data available for components greater than 1% in
concentration are as follows.
ACETIC ACID VINYL ESTER POLYMER:
Currently, there are no data for this compound.
ALKYL GLYCOL ETHER COMPOUND:
Open Irritation Test (skin, rabbit) = 500 mg; Mild
Standard Draize Test (eye, rabbit) = 500 mg/24 hours; Mild
LD50 (oral, rat) = 2400 mg/kg; Kidney, Ureter, Bladder: hematuria, other changes in urine
composition
LD50 (oral, mouse) = 3200 mg/kg
LD50 (skin, rabbit) = 1500 mg/kg; Kidney, Ureter, Bladder: hematuria, other changes in
urine composition; Blood: normocytic anemia
LDLo (skin, guinea pig) = 5 mL/kg
BLACK PIGMENT:
Mutation in microorganisms (Salmonella typhimurium, bacteria) = 1 mg/plate
DNA adduct (inhalation, mouse) = 6200 µg/m3/16 hours/12 weeks/intermittent
TCLo (inhalation, rat) = 50 mg/m3/6 hours/90 days/intermittent; Lungs, Thorax, or
Respiration: other changes
TCLo (inhalation, rat) = 11600 µg/m3/18 hours/2 years/intermittent; Tumorigenic:
Carcinogenic by RTECS criteria; Lungs, Thorax, or Respiration: tumor
YELLOW PIGMENT:
Currently, there are no data for this compound.
BLUE PIGMENT:
LD (oral, rat) >15 g/kg
LD (intraperitoneal, rat) > 3 g/kg; Kidney, Ureter, Bladder: urine volume decreased,
proteinuria
LD (oral, rat) > 2000 mg/kg
RED PIGMENT:
LD50 (oral, rat) > 5000 mg/kg
GLYCOL ETHER ACETATE COMPOUND:
Open Irritation Test (skin, rabbit) = 500 mg; mild
Standard Draize Test (eye, rabbit) = 500 mg; moderate
TDLo (oral, rat) = 96 g/kg; Kidney, Ureter, Bladder: other changes in urine composition;
Nutritional and Gross Metabolic: weight loss or decreased weight gain; Related to Chronic
Data: death
TCLo (inhalation, rat) = 480 mg/m3/6 hours/2 weeks/intermittent; Lungs, Thorax, or
Respiration: other changes; Lungs, Thorax, or Respiration: changes in lung weight
SolaChrome® Ink MSDS, Page 7 of 14
SUSPECTED CANCER AGENT: The components of this product are listed by agencies tracking
carcinogenic potential as follows:
BLACK PIGMENT: ACGIH-TLV-A4: (Not Classifiable as a Human Carcinogen); IARC-2B (Possibly
Carcinogenic to Humans); MAK-3 (Substances that Cause Concern They Could Be Carcinogenic
for Man, But Which Cannot Be Assessed Conclusively Because of Lack of Data); NIOSH-Ca
(Potential Occupational Carcinogen with no Further Designation)
BLUE PIGMENT (as a copper compound-dusts and mists): EPA-D (Not Classifiable as to
Human Carcinogenicity)
The remaining components of this product are not found on the following lists: FEDERAL
OSHA Z LIST, NTP, IARC, and CAL/OSHA and therefore are not considered to be, nor
suspected to be, a cancer-causing agent by these agencies.
IRRITANCY OF PRODUCT: Skin contact will be moderately irritating. Contact with the eyes
will be irritating and may cause temporary visual impairment.
SENSITIZATION TO THE PRODUCT: The Alkyl Glycol Ether Compound component of this product is
suspected to be a skin sensitizer which may cause allergic skin reaction in susceptible
individuals.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of
this product and its components on the human reproductive system.
Mutagenicity: This product is not reported to produce mutagenic effects in humans.
Animal mutation data are available for the Black Pigment and the Polymer with
Chloroprene & Ethyenyl Acetate components of this product; these data were obtained
during clinical studies on specific animal tissues exposed to high doses of this
compound.
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in
humans.
A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that
the changes will propagate through generational lines. An embryotoxin is a chemical that
causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in
humans), but the damage does not propagate across generational lines. A teratogen is a
chemical that causes damage to a developing fetus, but the damage does not propagate across
generational lines. A reproductive toxin is any substance that interferes in any way with
the reproductive process.
BIOLOGICAL EXPOSURE INDICES: Currently, there are no Biological Exposure Indices (BEIs)
established for the components of this product.
12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: This product is relatively stable under ambient environmental
conditions. Additional environmental data are available as follows:
ALKYL GLYCOL ETHER COMPOUND:
Terrestrial Fate: Based on a recommended classification scheme, an estimated Koc value
of 22, determined from a measured water solubility and a recommended regression-derived
equation, indicates that Alkyl Glycol Ether Compound will have very high mobility in
soil. Volatilization of Alkyl Glycol Ether Compound may occur from moist soil surfaces
given an estimated Henry's Law constant of 5.3X10-6 atm-cu m/mole, calculated from
experimental values for vapor pressure and water solubility. Volatilization from dry
soil surfaces is not expected to be environmentally important based on a measured vapor
pressure of 0.375 mm Hg. Based on limited screening data, the dominant removal
process for Alkyl Glycol Ether Compound in soil is expected to be biodegradation.
Total degradation using the Zahn-Wellens screening method exceeded 90% with a measured
rate of 12%/day.
Aquatic Fate: Based on a recommended classification scheme, an estimated Koc value of
22, Alkyl Glycol Ether Compound should not adsorb to suspended solids and sediment in
water. Alkyl Glycol Ether Compound may volatilize from water surfaces based on its
estimated Henry's Law constant, experimental values for vapor pressure, and water
solubility. Estimated half-lives for a model river and model lake are 9 and 70 days,
respectively. According to a classification scheme, an estimated BCF value of 3, from
a measured water solubility, suggests that bioconcentration in aquatic organisms is
low. Based on limited screening data, the dominant removal process for Alkyl Glycol
SolaChrome® Ink MSDS, Page 8 of 14
Ether Compound in water is expected to be biodegradation. Total degradation using the
Zahn-Wellens screening method exceeded 90% with a measured rate of 12%/day.
Atmospheric Fate: According to a model of gas/particle partitioning of semivolatile
organic compounds in the atmosphere, Alkyl Glycol Ether Compound (which has a measured
vapor pressure of 0.375 mm Hg at 25°C), will exist solely as a vapor in the ambient
atmosphere. Vapor-phase Alkyl Glycol Ether Compound is degraded in the atmosphere by
reaction with photochemically-produced hydroxyl radicals; the half-life for this
reaction in air is estimated to be about 18 hours.
Biodegradation: Alkyl Glycol Ether Compound was determined to be "completely"
biodegradable using the Zahn-Wellens screening method; total degradation exceeded 90%
with a measured rate of 12%/day under the test conditions; no observable lag period was
required before onset of degradation.
VIOLET PIGMENT:
Terrestrial Fate: The insolubility of Quinacridone red will cause it to collect in soils
and sediments.
Aquatic Fate: Due to its insolubility, Quinacridone may reside in the water column for a
substantial period, long enough to become part of deep sea sediments.
Biodegradation: Biodegradation is expected to be slow. The strong crystal lattice (e.g.
low sol) is partially responsible.
Bioconcentration: Quinacridone should not bioconcentrate, since it is insoluble, and
therefore, will not be taken up into the body.
ALIPHATIC ETHER ALCOHOL ESTER COMPOUND:
Biological Oxygen Demand (BOD) = 5% (3.63 gO2/g); 20% (1.05 gO2/g); Theoretical OD: 1.82
gO2/g
EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product may be harmful to plant or animal
life, especially if large volumes of this product are released. Plants may be discolored
and damaged (depending on the severity of the contamination).
EFFECT OF CHEMICAL ON AQUATIC LIFE: This product may be harmful to aquatic plant or animal
life, especially if large volumes of this product are released into a body of water.
Additional aquatic toxicity data are available as follows:
ALKYL GLYCOL ETHER COMPOUND: ALKYL GLYCOL ETHER COMPOUND (continued):
EC10 (Pseudomonas putida bacteria) 17 EC100 (Daphnia magna Straus giant water
hours = 720 mg/L flea) 24 hours = 320 mg/L
EC50 (Pseudomonas putida-bacteria) 17 EC0 (Daphnia magna Straus giant water
hours = 960 mg/L flea) 48 hours = 10 mg/L
EC90 (Pseudomonas putida-bacteria) 17 EC50 (Daphnia magna Straus giant water
hours = 1,200 mg/L flea) 48 hours = 37 mg/L
EC50 (Scenedesmus subspicatus algae) 72 EC100 (Daphnia magna Straus giant water
flea) 48 hours = 320 mg/L
hours = > 500 mg/L
EC0 (Daphnia magna Straus giant water ALIPHATIC ETHER ALCOHOL ESTER COMPOUND:
flea) 24 hours = 58 mg/L LC50 (Pimephales promelas fathead minnow)
EC50 (Daphnia magna Straus giant water /96 hours = 161 mg/L
flea) 24 hours = 150 mg/L LC50 (Daphnia) 48 hours = 408 mg/L
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S.
Federal, State, and local regulations or with regulations of Canada, Australia, or EC
Member States. This product, if unaltered by use, may be disposed of by treatment at a
permitted facility or as advised by your local hazardous waste regulatory authority.
EPA WASTE NUMBER: Not applicable to wastes consisting only of this product
14. TRANSPORTATION INFORMATION
THIS PRODUCT IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF
TRANSPORTATION.
PROPER SHIPPING NAME: Combustible liquid, n.o.s. (Alkyl Glycol Ether
Compound, Aliphatic Ether Alcohol Ester Compound)
HAZARD CLASS NUMBER and DESCRIPTION: Not Applicable(combustible liquid has no Class
Number)
UN IDENTIFICATION NUMBER: NA 1993
PACKING GROUP: III
SolaChrome® Ink MSDS, Page 9 of 14
DOT LABEL(S) REQUIRED: None
EMERGENCY RESPONSE GUIDEBOOK NUMBER, 2000: 128
MARINE POLLUTANT: No component of this product is designated by the DOT to be a Marine
Pollutant (per Appendix B to 49 CFR 172.101).
TRANSPORT CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is not
considered as dangerous goods, per regulations of Transport Canada.
INTERNATIONAL AIR TRANSPORT ASSOCIATION SHIPPING INFORMATION (IATA): This product is not
considered as dangerous goods.
INTERNATIONAL MARITIME ORGANIZATION SHIPPING INFORMATION (IMO): This product is not
considered as dangerous goods.
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
(ADR): This product is not considered by the United Nations Economic Commission for
Europe to be dangerous goods.
AUSTRALIAN FEDERAL OFFICE OF ROAD SAFETY CODE FOR THE TRANSPORTATION OF DANGEROUS GOODS BY
ROAD OR RAIL: This product is not considered as dangerous goods, per regulations of the
Australian Federal Office of Road Safety.
15. REGULATORY INFORMATION
ADDITIONAL UNITED STATES REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: The components of this product are subject to the
reporting requirements of Sections 302, 304 and 313 of Title III of the Superfund
Amendments and Reauthorization Act, as follows:
CHEMICAL NAME SARA 302 SARA 304 SARA 313
(40 CFR 355, (40 CFR Table (40 CFR
Appendix A) 302.4) 372.65)
Alkyl Glycol Ether Compound, No Yes N230
Aliphatic Ether Alcohol Ester
Compound and Glycol Ether Acetate
Compound (in generic Glycol Ether
category)
U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities
for the components of this product. The default Federal MSDS submission and inventory
requirement filing threshold of 10,000 lb (4,540 kg) may apply, per 40 CFR 370.20.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Alkyl Glycol Ether Compound, Aliphatic Ether Alcohol
Ester Compound and Glycol Ether Acetate Compound = Under the generic Glycol Ether
category, this compound does not have a RQ assigned, but is considered a CERCLA Hazardous
Waste.
U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA
Inventory or are excepted from listing.
U.S. HAZARDOUS AIR POLLUTANT (HAPs): No component of this product is listed by the EPA
under the Clean Air Act [CAA 112(r)] as a HAP and so no component of this product has a
Threshold Quantity under this regulation.
OTHER U.S. FEDERAL REGULATIONS: OSHA Standard for Flammable and Combustible Liquids (29
CFR 1910.106). Depending on specific operations involving the use of the this product, the
regulations of the Process Safety Management of Highly Hazardous Chemicals may be
applicable (29 CFR 1910.119). Under this regulation, the components of this product
are/are not listed in Appendix A (provided Threshold Quantities for Listed Substances);
however, any process that involves a flammable or combustible liquid on-site, in one
location, in quantities of 10,000 lb. (4,553 kg) or greater is covered under this
regulation unless it is used as a fuel.
U.S. STATE REGULATORY INFORMATION: Components of this product are covered under specific
State regulations, as denoted below:
Alaska - Designated Toxic and Hazardous Substances: Black Pigment
California - Permissible Exposure Limits for Chemical Contaminants: Black Pigment
Florida - Substance List: None
Illinois - Toxic Substance List: Black Pigment
Kansas - Section 302/313 List: None
Massachusetts - Substance List: Black Pigment
Michigan - Critical Materials Register: None
SolaChrome® Ink MSDS, Page 10 of 14
Minnesota - List of Hazardous Substances: Black Pigment
Missouri - Employer Information/Toxic Substance List: Black Pigment
New Jersey - Right to Know Hazardous Substance List: Black Pigment
North Dakota - List of Hazardous Chemicals, Reportable Quantities: None
Pennsylvania - Hazardous Substance List: Black Pigment
Rhode Island - Hazardous Substance List: Black Pigment
Texas - Hazardous Substance List: Black Pigment
West Virginia - Hazardous Substance List: Black Pigment
Wisconsin � Toxic and Hazardous Substances: Black Pigment
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): No component of
this product is on the California Proposition 65 lists.
ANSI LABELING (Z129.1): CAUTION! COMBUSTIBLE LIQUID AND VAPOR. MAY CAUSE SKIN AND EYE
IRRITATION. INHALATION AND INGESTION MAY BE HARMFUL. MAY CAUSE CENTRAL NERVOUS SYSTEM
EFFECTS. MAY CAUSE ALLERGIC SKIN REACTION IN SUSCEPTIBLE INDIVIDUALS. MAY DISCOLOR
CONTAMINATED SKIN, EYES, HAIR, AND CLOTHES. FOR INDUSTRIAL USE ONLY. KEEP OUT OF REACH OF
CHILDREN. Use with adequate ventilation. Keep away from heat, sparks, or open flame.
Avoid contact of liquid with skin, eyes, and clothing. Avoid exposure to vapors, mists, or
sprays. Wash thoroughly after handling. Wear appropriate hand and eye protection. FIRST-
AID: In case of contact, immediately flush skin with plenty of water. Remove contaminated
clothing and shoes. If inhaled, remove to fresh air. If swallowed, do not induce
vomiting. Get medical attention if irritation develops or persists or if any other adverse
effect occurs. IN CASE OF FIRE: Use water fog, dry chemical, or CO2, or alcohol foam. IN
CASE OF SPILL: Absorb spill with inert materials (e.g., polypads, dry sand). Rinse area
with soapy water. Consult Material Safety Data Sheet for additional information.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are listed on the DSL
Inventory or are excepted.
OTHER CANADIAN REGULATIONS: Not applicable.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITY SUBSTANCES LISTS: The components of this
product are not on the CEPA Priority Substances Lists.
CANADIAN WHMIS SYMBOLS: Class B3: Combustible Liquid
Class D2B: Materials Causing Other Toxic Effects-Chronic Toxic
Effects Sensitization
EUROPEAN COMMUNITY INFORMATION:
EC LABELING/CLASSIFICATION: This product is considered to be dangerous according to
current European Community Guidelines. This product meets the definition of EC hazard
class Xn (Harmful).
EC CLASSIFICATION: Xn
EC RISK PHRASES: Harmful by inhalation and in contact with skin. May cause sensitization
by skin contact.[R: 20/21-43]
EC SAFETY PHRASES: Keep out of reach of children.* Do not breathe vapour or spray. In
case of contact with eyes, rinse immediately with plenty of water and seek medical
advice. Wear suitable gloves and eye/face protection. [S:(2-)* 23, 26, 37/39] *This
safety phrase can be omitted from the label when the substance or preparation is sold
for industrial use only.
EUROPEAN COMMUNITY ANNEX II HAZARD SYMBOL: Xn
SolaChrome® Ink MSDS, Page 11 of 14
AUSTRALIAN INFORMATION FOR PRODUCT:
AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES (AICS) STATUS: The components of this product
are listed on the AICS.
LIST OF DESIGNATED SUBSTANCES: Not applicable.
STANDARD FOR THE UNIFORM SCHEDULING OF DRUGS AND POISONS: Schedule 6
LABELING AND CLASSIFICATION: The following hazard classification data have been selected,
based a review of the regulation [NOHSC: 10005 (1994)]:
CLASSIFICATION: Harmful. [Xn].
RISK PHRASES: Harmful by inhalation and in contact with skin. May cause sensitization by
skin contact. [R: 20/21-43]
SAFETY PHRASES: Keep out of reach of children.* Do not breathe vapour/spray. In case of
contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear
suitable gloves and eye/face protection. [S:(2-)* 23, 26, 37/39] *This safety phrase
can be omitted from the label when the substance or preparation is sold for industrial
use only.
HAZARD SYMBOL:
ADDITIONAL LABELING: POISON. NOT TO BE TAKEN. KEEP OUT OF REACH OF CHILDREN.
JAPANESE INFORMATION FOR PRODUCT:
JAPANESE MINISTER OF INTERNATIONAL TRADE AND INDUSTRY (MITI) STATUS: The components of
this product are not listed as Class I Specified Chemical Substances, Class II Specified
Chemical Substances, or Designated Chemical Substances by the Japanese MITI.
16. OTHER INFORMATION
The data in this Material Safety Data Sheet relates only to the specific material
designated herein. It does not relate to use in combination with any other material or
in any process.
The information contained herein is based upon data obtained from the manufacturer and/or
recognized technical sources. This information is believed to be correct, but does not
purport to be all inclusive and shall be used only as a guide. Since the condition of
handling and use are beyond our control, MacDermid ColorSpan Corporation assumes no
liability for loss or injury resulting from the use of this product or the information
herein. All chemicals may present unknown health hazards and should be used with caution.
No representation or warranties, either expressed or implied, of merchantability, fitness
for a particular purpose or any other nature are made hereunto with respect to the
information contained herein or the product to which the information refers. User must be
familiar with and follow generally accepted safe handling procedures of chemicals, and is
solely responsible for any effects caused by its misuse or mixing of this chemical with
any other substance. It is the user's responsibility to determine the suitability of this
information for the adoption of necessary safety precautions and/or compliance with
federal, state, and local laws and regulations.
SolaChrome® Ink MSDS, Page 12 of 14
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following:
HEALTH HAZARD (continued): 4 (Severe Hazard: Life-threatening;
CAS #: This is the Chemical Abstract Service Number that uniquely
major or permanent damage may result from single or repeated exposure.
identifies each constituent.
Skin Irritation: Not appropriate. Do not rate as a �4�, based on skin irritation
EXPOSURE LIMITS IN AIR:
alone. Eye Irritation: Not appropriate. Do not rate as a �4�, based on eye
CEILING LEVEL: The concentration that shall not be exceeded during any irritation alone. Oral Toxicity LD50 Rat: < 1 mg/kg. Dermal Toxicity LD50Rat
part of the working exposure. or Rabbit: < 20 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: < 0.05 mg/L).
LOQ: Limit of Quantitation. FLAMMABILITY HAZARD:
MAK: Federal Republic of Germany Maximum Concentration Values in the 0 (Minimal Hazard-Materials that will not burn in air when exposure to a
workplace.
temperature of 815.5°C [1500°F] for a period of 5 minutes.); 1 (Slight
NE: Not Established. When no exposure guidelines are established, an
Hazard-Materials that must be pre-heated before ignition can occur.
entry of NE is made for reference.
Material require considerable pre-heating, under all ambient temperature
NIC: Notice of Intended Change.
conditions before ignition and combustion can occur, Including: Materials
NIOSH CEILING: The exposure that shall not be exceeded during any part
that will burn in air when exposed to a temperature of 815.5°C (1500°F)
of the workday. If instantaneous monitoring is not feasible, the ceiling shall
for a period of 5 minutes or less; Liquids, solids and semisolids having a
be assumed as a 15-minute TWA exposure (unless otherwise specified)
flash point at or above 93.3°C [200°F] (e.g. OSHA Class IIIB, or; Most
that shall not be exceeded at any time during a workday.
ordinary combustible materials [e.g. wood, paper, etc.]; 2 (Moderate
NIOSH RELs: NIOSH’s Recommended Exposure Limits.
Hazard-Materials that must be moderately heated or exposed to relatively
PEL-Permissible Exposure Limit: OSHA’s Permissible Exposure Limits.
high ambient temperatures before ignition can occur. Materials in this
This exposure value means exactly the same as a TLV, except that it is
degree would not, under normal conditions, form hazardous atmospheres
enforceable by OSHA. The OSHA Permissible Exposure Limits are based
in air, but under high ambient temperatures or moderate heating may
in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal
release vapor in sufficient quantities to produce hazardous atmospheres
Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the
in air, Including: Liquids having a flash-point at or above 37.8°C [100°F];
vacated PELs are indicated. The phrase, “Vacated 1989 PEL,� is placed
Solid materials in the form of course dusts that may burn rapidly but that
next to the PEL that was vacated by Court Order.
generally do not form explosive atmospheres; Solid materials in a fibrous
SKIN: Used when a there is a danger of cutaneous absorption.
or shredded form that may burn rapidly and create flash fire hazards (e.g.
STEL-Short Term Exposure Limit: Short Term Exposure Limit, usually a
cotton, sisal, hemp; Solids and semisolids that readily give off flammable
15-minute time-weighted average (TWA) exposure that should not be
vapors.); 3 (Serious Hazard- Liquids and solids that can be ignited under
exceeded at any time during a workday, even if the 8-hr TWA is within the
almost all ambient temperature conditions. Materials in this degree
TLV-TWA, PEL-TWA or REL-TWA.
produce hazardous atmospheres with air under almost all ambient
TLV-Threshold Limit Value: An airborne concentration of a substance that
temperatures, or, unaffected by ambient temperature, are readily ignited
represents conditions under which it is generally believed that nearly all
under almost all conditions, including: Liquids having a flash point below
workers may be repeatedly exposed without adverse effect. The duration
22.8°C [73°F] and having a boiling point at or above 38°C [100°F] and
must be considered, including the 8-hour.
below 37.8°C [100°F] [e.g. OSHA Class IB and IC]; Materials that on
TWA-Time Weighted Average: Time Weighted Average exposure
account of their physical form or environmental conditions can form
concentration for a conventional 8-hr (TLV, PEL) or up to a 10-hr (REL)
explosive mixtures with air and are readily dispersed in air [e.g., dusts of
workday and a 40-hr workweek.
combustible solids, mists or droplets of flammable liquids]; Materials that
IDLH-Immediately Dangerous to Life and Health: This level represents a
burn extremely rapidly, usually by reason of self-contained oxygen [e.g.
concentration from which one can escape within 30-minutes without
dry nitrocellulose and many organic peroxides]);
suffering escape-preventing or permanent injury.
4 (Severe Hazard-Materials that will rapidly or completely vaporize at
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD atmospheric pressure and normal ambient temperature or that are readily
RATINGS: This rating system was developed by the National Paint and dispersed in air, and which will burn readily, including: Flammable gases;
Coating Association and has been adopted by industry to identify the Flammable cryogenic materials; Any liquid or gaseous material that is
degree of chemical hazards. liquid while under pressure and has a flash point below 22.8°C [73°F] and
HEALTH HAZARD: a boiling point below 37.8°C [100°F] [e.g. OSHA Class IA; Material that
0 (Minimal Hazard: No significant health risk, irritation of skin or eyes not
ignite spontaneously when exposed to air at a temperature of 54.4°C
anticipated. Skin Irritation: Essentially non-irritating. PII or Draize = �0�.
[130°F] or below [e.g. pyrophoric]).
Eye Irritation: Essentially non-irritating, or minimal effects which clear in <
PHYSICAL HAZARD:
24 hours [e.g. mechanical irritation]. Draize = �0�. Oral Toxicity LD50 Rat:
0 (Water Reactivity: Materials that do not react with water. Organic
< 5000 mg/kg. Dermal Toxicity LD50Rat or Rabbit: < 2000 mg/kg.
Peroxides: Materials that are normally stable, even under fire conditions
Inhalation Toxicity 4-hrs LC50 Rat: < 20 mg/L.); 1 (Slight Hazard: Minor
and will not react with water. Explosives: Substances that are Non-
reversible Injury may occur; slightly or mildly irritating. Skin Irritation:
Explosive. Unstable Compressed Gases: No Rating. Pyrophorics: No
Slightly or mildly irritating. Eye Irritation: Slightly or mildly irritating. Oral
Rating. Oxidizers: No �0� rating allowed. Unstable Reactives:
Toxicity LD50 Rat: > 500-5000 mg/kg. Dermal Toxicity LD50Rat or Rabbit:
Substances that will not polymerize, decompose, condense or self-react.);
> 1000-2000 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 2-20 mg/L); 2
1 (Water Reactivity: Materials that change or decompose upon exposure
(Moderate Hazard: Temporary or transitory injury may occur. Skin
to moisture. Organic Peroxides: Materials that are normally stable, but
Irritation: Moderately irritating; primary irritant; sensitizer. PII or Draize >
can become unstable at high temperatures and pressures. These
0, < 5. Eye Irritation: Moderately to severely irritating and/or corrosive;
materials may react with water, but will not release energy. Explosives:
reversible corneal opacity; corneal involvement or irritation clearing in 8-21
Division 1.5 & 1.6 substances that are very insensitive explosives or that
days. Draize > 0, < 25. Oral Toxicity LD50 Rat: > 50-500 mg/kg. Dermal
do not have a mass explosion hazard. Compressed Gases: Pressure
Toxicity LD50Rat or Rabbit: > 200-1000 mg/kg. Inhalation Toxicity LC50 4-
below OSHA definition. Pyrophorics: No Rating. Oxidizers: Packaging
hrs Rat: > 0.5-2 mg/L.);3 (Serious Hazard: Major injury likely unless
Group III; Solids: any material that in either concentration tested, exhibits
prompt action is taken and medical treatment is given; high level of
a mean burning time less than or equal to the mean burning time of a 3:7
toxicity; corrosive. Skin Irritation: Severely irritating and/or corrosive; may
potassium bromate/cellulose mixture and the criteria for Packing Group I
destroy dermal tissue, cause skin burns, dermal necrosis. PII or Draize >
and II are not met. Liquids: any material that exhibits a mean pressure
5-8 with destruction of tissue. Eye Irritation: Corrosive, irreversible
rise time less than or equal to the pressure rise time of a 1:1 nitric acid
destruction of ocular tissue; corneal involvement or irritation persisting for
(65%)/cellulose mixture and the criteria for Packing Group I and II are not
more than 21 days. Draize > 80 with effects irreversible in 21 days. Oral
met. Unstable Reactives: Substances that may decompose, condense or
Toxicity LD50 Rat: > 1-50 mg/kg. Dermal Toxicity LD50Rat or Rabbit: >
self-react, but only under conditions of high temperature and/or pressure
20-200 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 0.05-0.5 mg/L.);
and have little or no potential to cause significant heat generation or
explosive hazard. Substances that readily undergo hazardous
polymerization in the absence of inhibitors.);
(continued on following page)
SolaChrome® Ink MSDS, Page 13 of 14
DEFINITIONS OF TERMS (Continued)
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD FLAMMABILITY LIMITS IN AIR: Much of the information related to fire
and explosion is derived from the National Fire Protection Association
RATINGS (continued):
(NFPA). Flash Point - Minimum temperature at which a liquid gives off
PHYSICAL HAZARD (continued):
sufficient vapors to form an ignitable mixture with air. Autoignition
2 (Water Reactivity: Materials that may react violently with water.
Temperature: The minimum temperature required to initiate combustion in
Organic Peroxides: Materials that, in themselves, are normally unstable
air with no other source of ignition. LEL - the lowest percent of vapor in air,
and will readily undergo violent chemical change, but will not detonate.
by volume, that will explode or ignite in the presence of an ignition source.
These materials may also react violently with water. Explosives: Division
UEL - the highest percent of vapor in air, by volume, that will explode or
1.4 � Explosive substances where the explosive effect are largely
ignite in the presence of an ignition source.
confined to the package and no projection of fragments of appreciable
TOXICOLOGICAL INFORMATION:
size or range are expected. An external fire must not cause virtually
Human and Animal Toxicology: Possible health hazards as derived
instantaneous explosion of almost the entire contents of the package.
Compressed Gases: Pressurized and meet OSHA definition but < 514.7 from human data, animal studies, or from the results of studies with
similar compounds are presented. Definitions of some terms used in this
psi absolute at 21.1°C (70°F) [500 psig]. Pyrophorics: No Rating.
section are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the
Oxidizers: Packing Group II Solids: any material that, either in
exposed animals; LC50 - Lethal Concentration (gases) which kills 50% of
concentration tested, exhibits a mean burning time of less than or equal to
the exposed animals; ppm concentration expressed in parts of material
the mean burning time of a 2:3 potassium bromate/cellulose mixture and
per million parts of air or water; mg/m3 concentration expressed in weight
the criteria for Packing Group I are not met. Liquids: any material that
of substance per volume of air; mg/kg quantity of material, by weight,
exhibits a mean pressure rise time less than or equal to the pressure rise
administered to a test subject, based on their body weight in kg. Other
of a 1:1 aqueous sodium chlorate solution (40%)/cellulose mixture and the
measures of toxicity include TDLo, the lowest dose to cause a symptom
criteria for Packing Group I are not met. Unstable Reactives: Substances
and TCLo the lowest concentration to cause a symptom; TDo, LDLo, and
that may polymerize, decompose, condense, or self-react at ambient
LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to
temperature and/or pressure, but have a low potential for significant heat
cause lethal or toxic effects. Cancer Information: The sources are:
generation or explosion. Substances that readily form peroxides upon
IARC - the International Agency for Research on Cancer; NTP - the
exposure to air or oxygen at room temperature); 3 (Water Reactivity:
National Toxicology Program, RTECS - the Registry of Toxic Effects of
Materials that may form explosive reactions with water. Organic
Chemical Substances, OSHA and CAL/OSHA. IARC and NTP rate
Peroxides: Materials that are capable of detonation or explosive reaction,
chemicals on a scale of decreasing potential to cause human cancer with
but require a strong initiating source, or must be heated under
rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used. Other
confinement before initiation; or materials that react explosively with
Information: BEI - ACGIH Biological Exposure Indices, represent the
water. Explosives: Division 1.2 � Explosive substances that have a fire
levels of determinants which are most likely to be observed in specimens
hazard and either a minor blast hazard or a minor projection hazard or
collected from a healthy worker who has been exposed to chemicals to
both, but do not have a mass explosion hazard. Compressed Gases:
the same extent as a worker with inhalation exposure to the TLV.
Pressure > 514.7 psi absolute at 21.1°C (70°F) [500 psig]. Pyrophorics:
No Rating. Oxidizers: Packing Group I Solids: any material that, in either ECOLOGICAL INFORMATION:
concentration tested, exhibits a mean burning time less than the mean EC is the effect concentration in water. BCF = Bioconcentration Factor,
burning time of a 3.:2 potassium bromate/cellulose mixture. Liquids: Any which is used to determine if a substance will concentrate in lifeforms
material that spontaneously ignites when mixed with cellulose in a 1:1 which consume contaminated plant or animal matter. TLm = median
ratio, or which exhibits a mean pressure rise time less than the pressure threshold limit; Coefficient of Oil/Water Distribution is represented by log
rise time of a 1:1 perchloric acid (50%)/cellulose mixture. Unstable Kow or log Koc and is used to assess a substance’s behavior in the
Reactives: Substances that may polymerize, decompose, condense or environment.
self-react at ambient temperature and/or pressure and have a moderate
REGULATORY INFORMATION:
potential to cause significant heat generation or explosion.); 4 (Water
U.S. and CANADA:
Reactivity: Materials that react explosively with water without requiring
ACGIH: American Conference of Governmental Industrial Hygienists, a
heat or confinement. Organic Peroxides: Materials that are readily
professional association which establishes exposure limits.
capable of detonation or explosive decomposition at normal temperature
This section explains the impact of various laws and regulations on the
and pressures. Explosives: Division 1.1 & 1.2-explosive substances that
material. EPA is the U.S. Environmental Protection Agency. NIOSH is
have a mass explosion hazard or have a projection hazard. A mass
the National Institute of Occupational Safety and Health, which is the
explosion is one that affects almost the entire load instantaneously.
research arm of the U.S. Occupational Safety and Health Administration
Compressed Gases: No Rating. Pyrophorics: Add to the definition of
(OSHA). WHMIS is the Canadian Workplace Hazardous Materials
Flammability �4�. Oxidizers: No �4� rating. Unstable Reactives:
Information System. DOT and TC are the U.S. Department of
Substances that may polymerize, decompose, condense or self-react at
Transportation and the Transport Canada, respectively. Superfund
ambient temperature and/or pressure and have a high potential to cause
Amendments and Reauthorization Act (SARA); the Canadian
significant heat generation or explosion.). PPE Rating B: Hand and eye
Domestic/Non-Domestic Substances List (DSL/NDSL); the U.S. Toxic
protection is required for routine chemical use. PPE Rating C: Hand, eye,
Substance Control Act (TSCA); Marine Pollutant status according to the
and body protection may be required for routine chemical use.
DOT; the Comprehensive Environmental Response, Compensation, and
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD Liability Act (CERCLA or Superfund); and various state regulations. This
RATINGS: section also includes information on the precautionary warnings which
HEALTH HAZARD: 0 (material that on exposure under fire conditions would appear on the material’s package label. OSHA - U.S. Occupational
offer no hazard beyond that of ordinary combustible materials); 1 (materials Safety and Health Administration.
that on exposure under fire conditions could cause irritation or minor EUROPEAN and INTERNATIONAL:
residual injury); 2 (materials that on intense or continued exposure under The DFG: This is the Federal Republic of Germany’s Occupation Health
fire conditions could cause temporary incapacitation or possible residual Agency, similar to the U.S. OSHA. EC is the European Community
injury); 3 (materials that can on short exposure could cause serious (formerly known as the EEC, European Economic Community). EINECS:
temporary or residual injury); 4 (materials that under very short exposure This is the European Inventory of Now-Existing Chemical Substances.
could cause death or major residual injury). The ARD is the European Agreement Concerning the International
FLAMMABILITY HAZARD AND REACTIVITY HAZARD: Refer to Carriage of Dangerous Goods by Road and the RID are the International
definitions for “Hazardous Materials Identification System�. Regulations Concerning the Carriage of Dangerous Goods by Rail. AICS
is the Australian Inventory of Chemical Substances. MITI is the Japanese
Minister of International Trade and Industry
SolaChrome® Ink MSDS, Page 14 of 14
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