MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identification
SolaChrome HR庐 Cyan Ink
Product Name:
Commonly used in the following printer(s):
DisplayMaker 72s
Product Number: 0900992 series part number
Chemical Name: Solvent-based Inkjet Printing Fluid
Chemical Family: Glycol Ether/Polymer/Pigment Blend
CAS Number: Blend
Company Identification
MacDermid ColorSpan Corporation
7090 Shady Oak Road
Eden Prairie, MN 55344 USA
In case of exposure, please contact local Poison Control Center
Emergency phone for spills, leaks, fire, exposure or accident call
CHEMTREC: 1-800-424-9300 or 1-703-527-3887
Product information: (800) 925-0563
Revision Date: 01/08/04
2. COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENTS CAS No. CONTENTS EINECS SYMBOL RISK No.
N-METHYL-2-PYRROLIDONE 872-50-4 3-7 % 212-828-1 Xi 36/38
2-METHOXY-1-METHYLETHYL ACETATE 108-65-6 5-10 % 203-603-9 Xi 10,36
CYCLOHEXANONE 108-94-1 5-10 % 203-631-1 Xn 10,20
2-(2-ETHOXYETHOXY)ETHYL ACETATE 112-15-2 0.5-1.5 % 203-940-1 Xi 36/38
2-BUTOXYETHYL ACETATE 112-07-2 60-100 % 203-933-3 Xn 20/21
3. HAZARDS IDENTIFICATION
Harmful by inhalation and in contact with skin. Irritating to eyes and skin.
Hazardous Materials Identification System (HMIS) Codes:
Health Hazard (Blue): 2
Flammability Hazard (RED): 2
Physical Hazard (Yellow): 0
Personal Protection Equipment: B 鈥? eye protection and gloves
SolaChrome HR庐 Cyan Ink MSDS, Page 1 of 5
4. FIRST AID MEASURES
EYES: Make sure to remove any contact lenses from the eyes before rinsing. Promptly
wash eyes with plenty of water while lifting the eyelids. Continue to rinse for at
least 15 minutes and get prompt medical attention.
SKIN CONTACT: Remove affected person from source of contamination. Wash off
promptly and flush contaminated skin with water. Promptly remove clothing if soaked
through and flush skin with water. Get prompt medical attention.
INGESTION: Rinse mouth thoroughly. Drink plenty of water. DO NOT induce vomiting.
Get medical attention immediately.
INHALATION: Move the exposed person to fresh air at once. Perform artificial
respiration if breathing has stopped. If respiratory problems, artificial
respiration/oxygen. Keep the affected person warm and at rest. Get prompt medical
attention.
GENERALITIES: Give nothing by mouth to an unconscious person. If breathing is
irregular or has stopped, give artificial respiration. In all cases of doubt or if
symptoms persist, seek medical attention and show this sheet to the doctor.
ANTIDOTE: No specific antidote exists. Treat symptomatically.
5. FIRE FIGHTING MEASURES
NFPA RATING
EXTINGUISHING MEDIA: Water spray, fog or mist.
FLAMMABILITY
Carbon dioxide (CO2). Powder. Dry chemicals, sand,
dolomite etc. Foam.
SPECIAL FIRE FIGHTING PROCEDURES: Use pressurized
2
air masks if substance is involved in a fire. Cool
containers exposed to flames with water until well 2 0
HEALTH REACTIVITY
after the fire is out. Keep run-off water out of
sewers and water sources. Dike for water control.
UNUSUAL FIRE & EXPLOSION HAZARDS: Not available.
CONDITIONS OF FLAMMABILITY: Heat, sparks, or
OTHER
flame. Liquid is a Class III-A combustible.
UPPER FLAMMABLE LIMIT: Not available.
LOWER FLAMMABLE LIMIT: Not available.
AUTO-IGNITION TEMPERATURE: Not available.
EXPLOSION DATA 鈥? SENSITIVITY TO MECHANICAL IMPACT: Not available.
EXPLOSION DATA 鈥? SENSITIVITY TO STATIC DISCHARGE: Not available.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS DURING SPILL: Avoid contact with skin or eyes. Avoid breathing
vapors.
ENVIRONMENTAL PRECAUTIONS: Do not allow to enter drains or effluent systems.
SPILL CLEANUP METHODS: Clean-up personnel should use respiratory and/or liquid
contact protection. Extinguish all ignition sources. Avoid sparks, flames, heat and
smoking. Ventilate. Collect and contain spilled material in a chemical absorbent
(clay-based material, universal binder, etc.).
7. HANDLING AND STORAGE
HANDLING: Keep away from heat, sparks, ignition sources and open flame. Avoid any
contact with skin and eyes. Avoid breathing vapors, ventilate well. Use approved
respirator if air contamination is above accepted level. Wear splash goggles and
latex or rubber gloves and also a rubber apron when handling large quantities.
STORAGE: Keep containers tightly closed. Store away from traffic and out of reach
of children. Store isolated from oxidizing materials.
Storage temperature: Standard room temperature (68 degrees Fahrenheit).
SolaChrome HR庐 Cyan Ink MSDS, Page 2 of 5
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
INGREDIENT NAME CAS No. STD LT EXP(8 hrs) ST EXP(15 min)
2-METHOXY-1-METHYLETHYL ACETATE 108-65-6 OES 274 mg/m3 822 mg/m3
N-METHYL-2-PYRROLIDONE 872-50-4 OES 25 ppm(Sk) 75 ppm(Sk)
CYCLOHEXANONE 108-94-1 OES 10 ppm(Sk) 20 ppm(Sk)
2-BUTOXYETHYL ACETATE 112-07-2 OES Not Available
2-(2-ETHOXYETHOXY)ETHYL ACETATE 112-15-2 OES Not Available
OES = Occupational Exposure Standard
PROTECTIVE EQUIPMENT:
PROCESS CONTROL MEASURES: Use engineering controls to reduce air contamination to
permissible exposure level. Provide eyewash station.
VENTILATION: Provide adequate general and local exhaust ventilation.
PROTECTIVE GLOVES: Appropriate protective gloves must be used if there is a risk of
direct contact or splash.
EYE PROTECTION: Wear splash-proof eye goggles to prevent any possibility of eye
contact. Available emergency eyewash station is recommended.
OTHER PROTECTION: Wear appropriate clothing to prevent any possibility of liquid
contact and repeated or prolonged vapor contact.
WORK/HYGIENIC PRACTICES: Avoid contamination of food, drink, etc. No smoking when
handling. Wash at the end of each work shift and before eating. Promptly remove
any clothing that becomes wet. Isolate contaminated clothing and wash before reuse.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
COLOR: Cyan
ODOR: Characteristic, Fruity, Solvent
ODOR THRESHOLD: Not available.
pH VALUE: Not applicable. Product does not dissociate in water
SOLUBILITY: Soluble in most organic solvents. Not readily soluble in water.
SOLUBILITY VALUE (g/100g H2O/20掳C):<50
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not available.
SPECIFIC GRAVITY (Water=1): 0.95 - 0.99 @ 25 掳C
VAPOR DENSITY (air=1): >1
VAPOR PRESSURE: <10mmHg @ 25 掳C
EVAPORATION RATE: 0.05 - 0.5(BuAc=1)
VISCOSITY: 5 - 15 cps @ 25 掳C
FREEZING POINT: Not available.
BOILING POINT (掳C): 140 - 200 @ 760mmHg
FLASH POINT (掳C): 63 FLASH POINT METHOD: Closed cup
10. STABILITY AND REACTIVITY
STABILITY: Normally stable.
CONDITIONS TO AVOID: Avoid contact with strong oxidizing agents. Reacts strongly
with oxidizers. Upon exposure to air, product may slowly degrade, forming
peroxides, which can be unstable.
HAZARDOUS POLYMERIZATION: Not applicable.
HAZARDOUS DECOMPOSITION PRODUCTS: Peroxides.
11. TOXICOLOGICAL INFORMATION
HEALTH HAZARDS,GENERAL: Prolonged and repeated contact with solvents over a long
period of time may lead to permanent health problems.
INHALATION: Harmful by inhalation.
SKIN: Harmful in contact with skin.
HEALTH WARNINGS: Narcotic effect. CNS depressant.
TARGET ORGANS: Blood. Central nervous system. Skin.
SolaChrome HR庐 Cyan Ink MSDS, Page 3 of 5
MEDICAL CONSIDERATIONS: Convulsive disorders, CNS problems. Skin disorders and
allergies.
TOXICITY DATA:
Unless otherwise specified:
SENSITIZATION TO PRODUCT: Not available.
CARCINOGENICITY: Not available.
REPRODUCTIVE TOXICITY: Not available.
TERATOGENICITY: Not available.
MUTAGENICITY: Not available.
NAME OF TOXICOLOGICALLY SYNERGISTIC PRODUCTS: Not available.
N-METHYL-2-PYRROLIDONE 872-50-4
LD50(Rat,Oral) 3914 mg/kg LD50(Rabbit,Skin) 8000 mg/kg
REPRODUCTIVE TOXICITY: Based upon chronic exposure, the ability to cause
defects in developing organisms has been observed.
MUTAGENICITY: Based on chronic exposure, the ability to induce genetic
changes in DNA has been observed.
2-METHOXY-1-METHYLETHYL ACETATE
LD50(Rat)Oral 108-65-6 LD50(Rabbit)Skin >5000 mg/kg
8532 mg/kg
CYCLOHEXANONE
LD50(Rat)Oral 108-94-1 LD50(Rabbit)Skin 1 ml/kg
1620 ul/kg
CARCINOGENICITY: Based upon chronic exposure, the ability to cause cancer,
according to the Registry of Toxic Effects of Chemical Substances (RTECS),
has been observed.
REPRODUCTIVE TOXICITY: Based upon chronic exposure, the ability to cause
defects in developing organisms has been observed.
TERATOGENICITY: Based upon chronic exposure, the ability to cause
tetragenetic effects has been observed.
2-(2-ETHOXYETHOXY)ETHYL ACETATE
LD50(Rat)Oral 112-15-2 LD50(Rabbit)Skin 15100 mg/kg
11000 mg/kg
2-BUTOXYETHYL ACETATE
LD50(Rat)Oral 112-07-2 LD50(Rabbit)Skin 1500 mg/kg
2400 mg/kg
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL HAZARDS: Little danger to the environment.
13. DISPOSAL CONSIDERATIONS
The advice in this paragraph is of a general nature only. This product must be
disposed of via a licensed contractor and shall be disposed of in accordance with
federal, provincial, state, and local environmental control regulations. This
product, if unaltered by use, may be disposed of by treatment at a permitted facility
or as advised by your local hazardous waste regulatory authority. Do not allow this
strongly colored product to enter an effluent system. Dispose of containers as
special waste.
GENERAL/CLEANING: Refer to Section 7 before handling the product or containers.
European Waste Catalogue Number (EWC) 08 03 12
14. TRANSPORTATION INFORMATION
GENERAL: Not regulated.
SolaChrome HR庐 Cyan Ink MSDS, Page 4 of 5
15. REGULATORY INFORMATION
LABEL FOR SUPPLY:
HARMFUL
RISK PHRASES:
R-20/21 Harmful by inhalation and in contact with skin.
R-36/38 Irritating to eyes and skin.
SAFETY PHRASES:
S-24/25 Avoid contact with skin and eyes.
S-26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S-36/37 Wear suitable protective clothing and gloves.
S-60 This material and its container must be disposed of as hazardous waste.
EC DIRECTIVES: Dangerous Preparations Directive 1999/45 and its amendments.
UK REGULATORY REFERENCES: Chemicals (Hazard Information and Packaging for Supply)
Regulations 2002 (CHIP 3), S.I. 2002 No. 1689.
16. OTHER INFORMATION
R-PHRASES (Full Text):
R-10 Flammable.
R-20 Harmful by inhalation.
R-36 Irritating to eyes.
R-20/21 Harmful by inhalation and in contact with skin.
R-36/38 Irritating to eyes and skin.
The data in this Material Safety Data Sheet relates only to the specific material
designated herein. It does not relate to use in combination with any other
material or in any process. The information contained herein is based upon data
obtained from the manufacturer and/or recognized technical sources. This
information is believed to be correct, but does not purport to be all-inclusive and
shall be used only as a guide. Since the condition of handling and use are beyond
our control, MacDermid ColorSpan Corporation assumes no liability for loss or
injury resulting from the use of this product or the information herein. All
chemicals may present unknown health hazards and should be used with caution. No
representation or warranties, either expressed or implied, of merchantability,
fitness for a particular purpose or any other nature are made hereunto with respect
to the information contained herein or the product to which the information refers.
It is the user's responsibility to determine the suitability of this information
for the adoption of necessary safety precautions and/or compliance with federal,
provincial, state, and local laws and regulations.
SolaChrome HR庐 Cyan Ink MSDS, Page 5 of 5
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