C OLGATE -P ALMOLIVE Company
MATERIAL SAFETY DATA SHEET
This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product.
Palmolive Automatic Dishwashing Detergent Solid
Effective Date: August 18, 2006
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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
COLGATE-PALMOLIVE COMPANY
EMERGENCY TELEPHONE NUMBER: For emergency
Commercial Customer Group
involving spill, leak, fire, exposure or accident, call
191 East Hanover Avenue
CHEMTREC (800) 424-9300, day or night
Morristown NJ 07960-3151
For MEDICAL EMERGENCIES involving this product call
PRODUCT NAME: Palmolive Solid Automatic
(888) 489-3861
Dishwashing Detergent Solid
CAS NUMBER: Not applicable 鈥? product is a mixture
GENERAL USE: Formulated solid detergent for machine
dishwashing.
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The following components, present at a concentration of >
2. COMPOSITION/INFORMATION ON INGREDIENTS
or = 0.1%, are listed as carcinogens or potential carcinogens
by either the National Toxicology Program (NTP), the
OSHA-REGULATED COMPONENTS (present at a
International Agency for Research on Cancer (IARC) or
concentration of > or = 1%):
OSHA:
Component CAS# % PEL TLV
Component CAS# % PEL TLV
Not Applicable
Not Applicable
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3. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
EYE CONTACT: Causes severe irritation on direct contact.
SKIN CONTACT: Causes skin irritation on prolonged or repeated contact.
INGESTION: Harmful if swallowed.
INHALATION: Inhalation of dust may cause respiratory tract irritation.
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4. FIRST AID MEASURES
EYE CONTACT: Flush eyes with large amounts of water for 15 minutes. Get medical attention if irritation persists.
SKIN CONTACT: Rinse area with plenty of water. Get medical attention if irritation persists.
INGESTION: Drink 1-2 glasses of water. Get medical attention.
INHALATION: Remove victim to fresh air. Get medical attention if symptoms persist.
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5. FIRE FIGHTING MEASURES
Palmolive Automatic Dishwashing Detergent Solid 1
Flash Point (Method): Not Applicable
Extinguishing Media: Water spray, all-purpose dry chemical.
SPECIAL FIRE FIGHTING PROCEDURES: Self-contained breathing apparatus and protective clothing should be worn when
fighting chemical fires.
Contains sodium dichloroisocyanurate dihydrate which reacts with water to from chlorine bleach.
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6. ACCIDENTAL RELEASE MEASURES
Collect and remove to disposal container without creating a dust condition. Spill area may be slippery. Flush with plenty of
water.
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7. HANDLING AND STORAGE
Store in a tightly closed container in a cool, dry, well-ventilated area.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
GENERAL CONTROLS: Avoid eye and skin contact.
PROTECTIVE CLOTHING: The use of safety goggles and protective gloves is recommended.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Tablets
pH (1% solution): 10.8 +/- 0.3
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10. STABILITY AND REACTIVITY
GENERAL: This product is stable. Hazardous polymerization will not occur.
INCOMPATIBLE MATERIALS: Product contains sodium dichloroisocyanurate which reacts with water to form chlorine bleach.
HAZARDOUS DECOMPOSITION: None known.
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11. TOXICOLOGICAL INFORMATION
This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety
Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into
consideration available safety-related information including information on individual ingredients, similar ingredients, similar
formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the
statements in Section 3 of the MSDS.
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12. ECOLOGICAL INFORMATION
Not Available
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13. DISPOSAL CONSIDERATIONS
Any disposal practice must be in compliance with local, state, and federal laws and regulations (contact local or state environmental
agency for specific rules). Do not dump into sewers, any body of water or onto the ground.
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14. TRANSPORTATION
Not regulated as a DOT hazardous material.
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15. REGULATORY INFORMATION
Palmolive Automatic Dishwashing Detergent Solid 2
New Jersey Right to Know Hazardous Substance List:
This product contains the following components subject to
RCRA (40 CFR 261, Subpart D): Not Applicable
reporting requirements: Pentasodium triphosphate, sodium
dichloroisocyanurate
CLEAN WATER ACT:
Contains pentasodium triphosphate which is a Section
Pennsylvania Hazardous Substance List:
311 material.
This product contains the following components subject to
reporting requirements: Pentasodium triphosphate, sodium
CLEAN AIR ACT:
sulfate, sodium dichloroisocyanurate
Not Applicable
Massachusetts Substance List:
SARA:
This product contains the following components subject to
Sections 301-304 (Threshold planning quantity - TPQ) 40 reporting requirements: Pentasodium triphosphate, sodium
CFR 355: No TPQ for any component. sulfate, sodium dichloroisocyanurate
Not Applicable
Canada: Workplace Hazardous materials Information
Section 313 (Toxic chemical release reporting) 40 CFR System (WHMIS)-listed material. This product contains
372: The following chemicals must be reported under the following components subject to reporting
SARA 313: Not Applicable requirements: Sodium carbonate, sodium
dichloroisocyanurate
CERCLA: Section 102 (Reportable Quantity - RQ) 40
CFR 302: The Reportable Quantity (RQ) for this product TSCA Section 8(b) Inventory Status: All ingredients in
to the environment is 14,925 lbs. based on the presence this product are listed on the TSCA Inventory or are not
of Pentasodium triphosphate (33.5%). Releases greater required to be listed on the TSCA Inventory.
than or equal to 14,925 lbs. must be reported to the
National Response Center (NRC) immediately: 800-424-
8802.
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16. OTHER INFORMATION
Effective Date: August 18, 2006
Supersedes MSDS dated November 26, 2003
MSDS Status: Revised Sections, 1,15
The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company
to be correct based on its knowledge and information as of the date noted. Colgate makes no representation,
guarantee or warranty, expressed or implied, as to the accuracy, reliability or completeness of the information
and assumes no responsibility for injury, damage or loss resulting from the use of the material.
Palmolive Automatic Dishwashing Detergent Solid 3
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