Annex F
138 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
REAGENT M.S.D.S
Section 1 - Product and Company Identification
ACETONE
Product Identification: ACETONE
Date of MSDS: 12/03/1990 Technical Review Date: 03/
04/1993
FSC: 6810 NIIN: LIIN: 00N040268
Submitter: N EN
Status Code: C
MFN: 01
Article: N
Kit Part: N
Manufacturer’s Information
Manufacturer’s Name: SYSTEMS SCIENTIFIC
LABORATORIES INC
Manufacturer’s Address1: 1295 BOULAVARD WAY
Manufacturer’s Address2: WALNUT CREEK, CA
94595
Manufacturer’s Country: US
General Information Telephone: 415-937-6748
Emergency Telephone: 415-937-6748
Emergency Telephone: 415-937-6748
MSDS Preparer’s Name: JAMES P. GILLEENY
Proprietary: N
Reviewed: N
Published: Y
CAGE: 3R697
Special Project Code: N
Contractor Information
Contractor’s Name: SYSTEMS SCIENTIFIC
LABORATORIES INC
Contractor’s Address1: 1295 BOULAVARD WAY
Contractor’s Address2: WALNUT CREEK, CA 94595
Contractor’s Telephone: 415-937-6748
Contractor’s CAGE: 3R697
Section 2 - Compositon/Information on Ingredients
ACETONE
Ingredient Name: ACETONE (SARA III)
Ingredient CAS Number: 67-64-1 Ingredient CAS
Code: M
RTECS Number: AL3150000 RTECS Code: M
=WT: =WT Code:
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
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Annex F
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text: N/K
% Enviromental Weight:
Other REC Limits: N/K
OSHA PEL: 1000PPM OSHA PEL Code: M
OSHA STEL: OSHA STEL Code:
ACGIH TLV: 750PPM/1000STEL;9293 ACGIH TLV Code: M
ACGIH STEL: N/P ACGIH STEL Code:
EPA Reporting Quantity: 5000 LBS
DOT Reporting Quantity: 5000 LBS
Ozone Depleting Chemical: N
Section 3 - Hazards Identification, Including Emergency Overview
ACETONE
Health Hazards Acute & Chronic: CAUSES EYE IRRITATION. AVOID REPEATED SKIN CONTACT.
AMMONIA IS A RESPIRATORY AND EYE IRRITANT. AMMONIUM FLUORIDE IS HIGHLY TOXIC &
CAUSES IRRITATION TO EYES, SKIN AND RESPIRATORY TRACT.
Signs & Symptoms of Overexposure:
SEE HEALTH HAZARDS.
Medical Conditions Aggravated by Exposure:
NONE SPECIFIED BY MANUFACTURER.
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route of Entry Indicators:
Inhalation: YES
Skin: NO
Ingestion: YES
Carcenogenicity Indicators
NTP: NO
IARC: NO
OSHA: NO
Carcinogenicity Explanation: NOT RELEVANT.
140 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Section 4 - First Aid Measures
ACETONE
First Aid:
EYE:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. CALL MD. INHAL:MOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) (FP N). INGEST:CALL MD IMMEDIATELY (FP N).
SKIN:FLUSH WITH COPIOUS AMOUNTS OF WAT ER FOR AT LEAST 15 MINUTES. CALL MD (FPN).
Section 5 - Fire Fighting Measures
ACETONE
Fire Fighting Procedures:
WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N).
Unusual Fire or Explosion Hazard:
NONE SPECIFIED BY MANUFACTURER.
Extinguishing Media:
CO*2, DRY CHEMICAL, ALCOHOL FOAM.
Flash Point: Flash Point Text: 0F,-18C
Autoignition Temperature:
Autoignition Temperature Text: N/A
Lower Limit(s): 12.8%
Upper Limit(s): 2.6%
Section 6 - Accidental Release Measures
ACETONE
Spill Release Procedures:
COLLECT IN SUITABLE CONTAINER.
Section 7 - Handling and Storage
ACETONE
Handling and Storage Precautions:
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
ACETONE
Repiratory Protection:
NIOSH/MSHA APPROVED DUST MASK.
Ventilation:
LOCAL AND MECHANICAL (GENERAL) EXHAUST ACCEPTABLE.
Protective Gloves:
RUBBER GLOVES.
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.
Work Hygenic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Health & Safety Information: NONE SPECIFIED BY MANUFACTURER.
Section 9 - Physical & Chemical Properties
ACETONE
HCC:
141
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Annex F
NRC/State License Number:
Net Property Weight for Ammo:
Boiling Point: Boiling Point Text: 133F,56C
Melting/Freezing Point: Melting/Freezing Text: N/K
Decomposition Point: Decomposition Text: N/K
Vapor Pressure: 186 Vapor Density: 2
Percent Volatile Organic Content:
Specific Gravity: 0.79
Volatile Organic Content Pounds per Gallon:
pH: N/K
Volatile Organic Content Grams per Liter:
Viscosity: N/P
Evaporation Weight and Reference: 14.5 (BUTYL ACETATE=1)
Solubility in Water: COMPLETE
Appearance and Odor: COLORLESS LIQUID
Percent Volatiles by Volume: 100
Corrosion Rate: N/K
Section 10 - Stability & Reactivity Data
ACETONE
Stability Indicator: YES
Materials to Avoid:
CONTACT WITH ACID FORMS HYDROGEN FLUORIDE. CONTACT WITH CAUSTIC LIBERATES
AMMONIA.
Stability Condition to Avoid:
NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:
ON HEATING, LIBERATES AMMONIA AND HYDROGEN FLUORIDE.
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
NOT RELEVANT.
Section 11 - Toxicological Information
ACETONE
Toxicological Information:
N/P
Section 12 - Ecological Information
ACETONE
Ecological Information:
N/P
Section 13 - Disposal Considerations
ACETONE
Waste Disposal Methods:
DISPOSE OF BY MEANS AS TO COMPLY WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.
CONTACT AN APPROVED AND LICENSED DISPOSAL AGENCY.
Section 14 - MSDS Transport Information
ACETONE
Transport Information:
N/P
142 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Section 15 - Regulatory Information
ACETONE
SARA Title III Information:
N/P
Federal Regulatory Information:
N/P
State Regulatory Information:
N/P
Section 16 - Other Information
ACETONE
Other Information:
N/P
HAZCOM Label Information
Product Identification: ACETONE
CAGE: 3R697
Assigned Individual: N
Company Name: SYSTEMS SCIENTIFIC LABORATORIES INC
Company PO Box:
Company Street Address1: 1295 BOULAVARD WAY
Company Street Address2: WALNUT CREEK, CA 94595 US
Health Emergency Telephone: 415-937-6748
Label Required Indicator: Y
Date Label Reviewed: 03/04/1993
Status Code: C
Manufacturer’s Label Number:
Date of Label: 03/04/1993
Year Procured: N/K
Organization Code: G
Chronic Hazard Indicator: N
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: YES
Signal Word: DANGER
Health Hazard: None
Contact Hazard: Slight
Fire Hazard: Severe
Reactivity Hazard: None
Section 1 - Product and Company Identification
AMMONIUM MOLYBDATE, 12215
Product Identification: AMMONIUM MOLYBDATE, 12215
Date of MSDS: 01/27/1989 Technical Review Date: 02/03/1995
FSC: 6810 NIIN: LIIN: 00N057008
Submitter: N EN
Status Code: C
MFN: 01
Article: N
Kit Part: N
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Annex F
Manufacturer’s Information
Manufacturer’s Name: JOHNSON MATTHEY CATALOG CO
Manufacturer’s Address1: 30 BOND ST
Manufacturer’s Address2: WARD HILL, MA 01835-0747
Manufacturer’s Country: US
General Information Telephone: 508-521-6300
Emergency Telephone: 800-424-9300 (CHEMTREC)
Emergency Telephone: 800-424-9300 (CHEMTREC)
MSDS Preparer’s Name: N/P
Proprietary: N
Reviewed: N
Published: Y
CAGE: 0JVJ1
Special Project Code: N
Contractor Information
Contractor’s Name: JOHNSON MATTHEY CATALOG CO INC ALFA AESAR
Contractor’s Address1: 30 BOND ST
Contractor’s Address2: WARD HILL, MA 01835-0747
Contractor’s Telephone: 978-521-6300
Contractor’s CAGE: 0JVJ1
Section 2 - Compositon/Information on Ingredients
AMMONIUM MOLYBDATE, 12215
Ingredient Name: AMMONIUM MOLYBDATE
Ingredient CAS Number: 27546-07-2 Ingredient CAS Code: M
RTECS Number: RTECS Code: X
=WT: =WT Code:
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text: 100
% Enviromental Weight:
Other REC Limits: N/K
144 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
OSHA PEL: 5 MG/M3 (MFR) OSHA PEL Code: M
OSHA STEL: OSHA STEL Code:
ACGIH TLV: 5 MG/M3 (MFR) ACGIH TLV Code: M
ACGIH STEL: N/P ACGIH STEL Code:
EPA Reporting Quantity:
DOT Reporting Quantity:
Ozone Depleting Chemical:
Section 3 - Hazards Identification, Including Emergency Overview
AMMONIUM MOLYBDATE, 12215
Health Hazards Acute & Chronic: ACUTE: INGESTION: MAY BE HARMFUL; EFFECTS NOT KNOWN. SKIN/
EYES/INHALATION: MAY CAUSE IRRITATION. CHRONIC: INGESTION: LARGE DOSES OF A SIMILAR
COMPOUND HAS PRODUCED KIDNEY DAMAGE IN EXPERIMENTAL ANIMAL S. SKIN/EYES/
INHALATION: NONE KNOWN.
Signs & Symptoms of Overexposure:
SEE HEALTH HAZARDS.
Medical Conditions Aggravated by Exposure:
NONE KNOWN.
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route of Entry Indicators:
Inhalation: NO
Skin: NO
Ingestion: YES
Carcenogenicity Indicators
NTP: NO
IARC: NO
OSHA: NO
Carcinogenicity Explanation: NOT RELEVANT
Section 4 - First Aid Measures
AMMONIUM MOLYBDATE, 12215
First Aid:
INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) (FP
N). INGEST: OBTAIN MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING, FLOOD SKIN
WITH LARGE AMOUNTS OF WATER. IF IRRITATION PERSISTS, SEEK MEDICAL ATTENTION. EYES:
IMMEDIATELY FLUSH EYES, INCLUDING UNDER EYELIDS, WITH LARGE AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. CALL MD.
Section 5 - Fire Fighting Measures
AMMONIUM MOLYBDATE, 12215
Fire Fighting Procedures:
USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). IF WITHOUT RISK,
REMOVE MATERIAL FROM FIRE AREA. COOL CONTAINER W/WATER FROM MAXIMUM DISTANCE.
Unusual Fire or Explosion Hazard:
145
©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
NONE SPECIFIED BY MANUFACTURER.
Extinguishing Media:
USE WATER, CARBON DIOXIDE, DRY CHEMICAL EXTINGUISHING AGENTS, DRY SAND OR DRY
GROUND DOLOMITE.
Flash Point: Flash Point Text: N/A
Autoignition Temperature:
Autoignition Temperature Text: N/A
Lower Limit(s): N/A
Upper Limit(s): N/A
Section 6 - Accidental Release Measures
AMMONIUM MOLYBDATE, 12215
Spill Release Procedures:
WEARING FULL PROTECTIVE EQUIPMENT, COVER SPILL WITH DRY SAND OR VERMICULITE. MIX
WELL AND CAREFULLY TRANSFER TO A CONTAINER.
Section 7 - Handling and Storage
AMMONIUM MOLYBDATE, 12215
Handling and Storage Precautions:
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
AMMONIUM MOLYBDATE, 12215
Repiratory Protection:
NIOSH/MSHA APPROVED HIGH EFFICIENCY PARTICLE RESPIRATOR.
Ventilation:
LABORATORY FUME HOOD.
Protective Gloves:
RUBBER GLOVES.
Eye Protection: ANSI APPROVED SAFETY GOGGLES.
Other Protective Equipment: LAB COAT & APRON, FLAME & CHEMICAL RESISTANT COVERALLS,
EYEWASH CAPABLE OF SUSTAINED FLUSHING, SAFETY DRENCH (SUPDAT)
Work Hygenic Practices: WASH THOROUGHLY AFTER USE.
Supplemental Health & Safety Information: OTHER PROT EQUIP: SHOWER & HYGIENIC FACILITIES FOR
WASHING.
Section 9 - Physical & Chemical Properties
AMMONIUM MOLYBDATE, 12215
HCC: N1
NRC/State License Number:
Net Property Weight for Ammo:
Boiling Point: Boiling Point Text: N/K
Melting/Freezing Point: Melting/Freezing Text: N/K
Decomposition Point: Decomposition Text: N/K
Vapor Pressure: 0 Vapor Density: N/A
Percent Volatile Organic Content:
Specific Gravity: N/K
Volatile Organic Content Pounds per Gallon:
pH: N/K
146 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Volatile Organic Content Grams per Liter:
Viscosity: N/P
Evaporation Weight and Reference: 0 (BUTYL ACETATE=1)
Solubility in Water: SOLUBLE
Appearance and Odor: WHITE POWDER; ODOR NOT KNOWN.
Percent Volatiles by Volume: 0
Corrosion Rate: N/K
Section 10 - Stability & Reactivity Data
AMMONIUM MOLYBDATE, 12215
Stability Indicator: YES
Materials to Avoid:
ALKALI METALS, ACIDS.
Stability Condition to Avoid:
THERMAL DECOMPOSITION.
Hazardous Decomposition Products:
MOLYBDENUM OXIDES.
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
NOT RELEVANT
Section 11 - Toxicological Information
AMMONIUM MOLYBDATE, 12215
Toxicological Information:
N/P
Section 12 - Ecological Information
AMMONIUM MOLYBDATE, 12215
Ecological Information:
N/P
Section 13 - Disposal Considerations
AMMONIUM MOLYBDATE, 12215
Waste Disposal Methods:
CONSULT STATE, LOCAL OR FEDERAL EPA REGULATIONS FOR PROPER DISPOSAL.
Section 14 - MSDS Transport Information
AMMONIUM MOLYBDATE, 12215
Transport Information:
N/P
Section 15 - Regulatory Information
AMMONIUM MOLYBDATE, 12215
SARA Title III Information:
N/P
Federal Regulatory Information:
N/P
State Regulatory Information:
N/P
Section 16 - Other Information
147
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Annex F
AMMONIUM MOLYBDATE, 12215
Other Information:
N/P
HAZCOM Label Information
Product Identification: AMMONIUM MOLYBDATE, 12215
CAGE: 0JVJ1
Assigned Individual: N
Company Name: JOHNSON MATTHEY CATALOG CO INC ALFA AESAR
Company PO Box:
Company Street Address1: 30 BOND ST
Company Street Address2: WARD HILL, MA 01835-0747 US
Health Emergency Telephone: 800-424-9300 (CHEMTREC)
Label Required Indicator: Y
Date Label Reviewed: 02/03/1995
Status Code: C
Manufacturer’s Label Number:
Date of Label: 02/03/1995
Year Procured: N/K
Organization Code: G
Chronic Hazard Indicator: Y
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: YES
Signal Word: CAUTION
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Section 1 - Product and Company Identification
CALCIUM OXALATE MONOHYDRATE, 901150.000
Product Identification: CALCIUM OXALATE MONOHYDRATE, 901150.000
Date of MSDS: 02/11/1992 Technical Review Date: 09/05/1995
FSC: 6810 NIIN: LIIN: 00N063221
Submitter: N EN
Status Code: C
MFN: 01
Article: N
Kit Part: N
Manufacturer’s Information
Manufacturer’s Name: TA INSTRUMENTS
Manufacturer’s Address1: 109 LUKENS DRIVE
Manufacturer’s Address2: NEW CASTLE, DE 19720
Manufacturer’s Country: US
General Information Telephone: 302-695-5533
Emergency Telephone: 302-695-5533
Emergency Telephone: 302-695-5533
MSDS Preparer’s Name: SR SAUERBRUNN
Proprietary: N
Reviewed: N
Published: Y
CAGE: 0MJS5
Special Project Code: N
148 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Contractor Information
Contractor’s Name: TA INSTRUMENTS
Contractor’s Address1: 109 LUKENS DRIVE
Contractor’s Address2: NEW CASTLE, DE 19720
Contractor’s Telephone: 302-695-5533
Contractor’s CAGE: 0MJS5
Section 2 - Compositon/Information on Ingredients
CALCIUM OXALATE MONOHYDRATE, 901150.000
Ingredient Name: CALCIUM OXALATE MONOHYDRATE
Ingredient CAS Number: Ingredient CAS Code: X
RTECS Number: RTECS Code: X
=WT: =WT Code:
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text: N/K
% Enviromental Weight:
Other REC Limits: N/K
OSHA PEL: N/K (FP N) OSHA PEL Code: M
OSHA STEL: OSHA STEL Code:
ACGIH TLV: N/K (FP N) ACGIH TLV Code: M
ACGIH STEL: N/P ACGIH STEL Code:
EPA Reporting Quantity:
DOT Reporting Quantity:
Ozone Depleting Chemical:
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Annex F
Section 3 - Hazards Identification, Including Emergency Overview
CALCIUM OXALATE MONOHYDRATE, 901150.000
Health Hazards Acute & Chronic: TOXIC BY ORAL OR INHALATION ROUTES. CORROSIVE TO MOUTH.
Signs & Symptoms of Overexposure:
SEE HEALTH HAZARDS.
Medical Conditions Aggravated by Exposure:
NONE SPECIFIED BY MANUFACTURER.
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route of Entry Indicators:
Inhalation: YES
Skin: NO
Ingestion: YES
Carcenogenicity Indicators
NTP: NO
IARC: NO
OSHA: NO
Carcinogenicity Explanation: NOT RELEVANT.
Section 4 - First Aid Measures
CALCIUM OXALATE MONOHYDRATE, 901150.000
First Aid:
SKIN: FLUSH AREA W/WATER. CALL MD. EYE: FLUSH W/POTABLE WATER FOR AT LEAST 15 MINUTES.
SEE MD(FP N). INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING(GIVE O*2/ARTF RESP)(FP N).
INGEST: CALL MD IMMEDIATEL Y(FP N).
Section 5 - Fire Fighting Measures
CALCIUM OXALATE MONOHYDRATE, 901150.000
Fire Fighting Procedures:
WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT(FP N).
Unusual Fire or Explosion Hazard:
NONE SPECIFIED BY MANUFACTURER.
Extinguishing Media:
WATER, CO*2, CHEMICAL OR SAND.
Flash Point: Flash Point Text: N/K
Autoignition Temperature:
Autoignition Temperature Text: N/A
Lower Limit(s): N/K
Upper Limit(s): N/K
Section 6 - Accidental Release Measures
CALCIUM OXALATE MONOHYDRATE, 901150.000
Spill Release Procedures:
NO SPECIAL PROCEDURES.
Section 7 - Handling and Storage
CALCIUM OXALATE MONOHYDRATE, 901150.000
Handling and Storage Precautions:
150 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
CALCIUM OXALATE MONOHYDRATE, 901150.000
Repiratory Protection:
NIOSH/MSHA APPROVED FILTER MASK RECOMMENDED FOR USE W/LGE AIRBORNE QUANTITIES.
Ventilation:
LOCAL EXHAUST.
Protective Gloves:
IMPERVIOUS GLOVES(FP N).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS(FP N).
Other Protective Equipment: EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA(FP N).
Work Hygenic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Health & Safety Information: NONE SPECIFIED BY MANUFACTURER.
Section 9 - Physical & Chemical Properties
CALCIUM OXALATE MONOHYDRATE, 901150.000
HCC:
NRC/State License Number:
Net Property Weight for Ammo:
Boiling Point: Boiling Point Text: N/K
Melting/Freezing Point: Melting/Freezing Text: N/K
Decomposition Point: Decomposition Text: N/K
Vapor Pressure: N/K Vapor Density: N/K
Percent Volatile Organic Content:
Specific Gravity: 2.12
Volatile Organic Content Pounds per Gallon:
pH: N/K
Volatile Organic Content Grams per Liter:
Viscosity: N/P
Evaporation Weight and Reference: 0
Solubility in Water: INSOLUBLE
Appearance and Odor: WHITE CRYSTALLINE POWDER.
Percent Volatiles by Volume: 0
Corrosion Rate: N/K
Section 1 - Product and Company Identification
CALCIUM OXIDE
Product Identification: CALCIUM OXIDE
Date of MSDS: 03/25/1992 Technical Review Date: 04/04/1994
FSC: 6810 NIIN: 00-964-0105
Submitter: D DG
Status Code: C
MFN: 01
Article: N
Kit Part: N
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Annex F
Manufacturer’s Information
Manufacturer’s Name: J.T.BAKER CHEMICAL CO
Manufacturer’s Address1: 222 RED SCHOOL LANE
Manufacturer’s Address2: PHILLIPSBURG, NJ 08865
Manufacturer’s Country: US
General Information Telephone: 800-JTBAKER
Emergency Telephone: 201-859-2151/800-424-9300(CHEMTR)
Emergency Telephone: 201-859-2151/800-424-9300(CHEMTR)
MSDS Preparer’s Name: N/P
Proprietary: N
Reviewed: Y
Published: Y
CAGE: DO870
Special Project Code: N
Item Description
Item Name: CALCIUM OXIDE,ANALYZED REAGENT
Item Manager:
Specification Number: NK
Type/Grade/Class: NK
Unit of Issue: BT Quantitative Expression: 10000000025KG
Unit of Issue Quantity: 6
Type of Container:
Contractor Information
Contractor’s Name: CHEMICAL COMMODITIES AGENCY, INC.
Contractor’s Address1: 27447 PACIFIC STREET
Contractor’s Address2: HIGHLAND, CA 92346-2640
Contractor’s Telephone: 909-864-2310
Contractor’s CAGE: 60777
Contractor Information
Contractor’s Name: J.T.BAKER CHEMICAL CO.
Post Office Box: N/K
Contractor’s Address1: 222 RED SCHOOL LANE
Contractor’s Address2: PHILLIPSBURG, NJ 08865-2219
Contractor’s Telephone: 201-859-2151
Contractor’s CAGE: DO870
Contractor Information
Contractor’s Name: MALLINCKRODT BAKER, INC. (FORMERLY J.T. BAKER INC)
Contractor’s Address1: 222 RED SCHOOL LANE
Contractor’s Address2: PHILLIPSBURG, NJ 08865-2219
Contractor’s Telephone: 800-582-2537
Contractor’s CAGE: 70829
Section 2 - Compositon/Information on Ingredients
CALCIUM OXIDE
Ingredient Name: CALCIUM OXIDE
Ingredient CAS Number: 1305-78-8 Ingredient CAS Code: M
RTECS Number: EW3100000 RTECS Code: M
=WT: =WT Code:
152 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text: 99-100
% Enviromental Weight:
Other REC Limits: N/K
OSHA PEL: 5 MG/M3 OSHA PEL Code: M
OSHA STEL: OSHA STEL Code:
ACGIH TLV: 2 MG/M3; 9192 ACGIH TLV Code: M
ACGIH STEL: N/P ACGIH STEL Code:
EPA Reporting Quantity:
DOT Reporting Quantity:
Ozone Depleting Chemical: N
Section 3 - Hazards Identification, Including Emergency Overview
CALCIUM OXIDE
Health Hazards Acute & Chronic: ACUTE-IRRITATION TO UPPER RESPIRATORY PASSAGES. CHEMICAL
BURNS OR SEVERE IRRITATION TO EYES, NOSE, MOIST SKIN. HARMFUL IF SWOLLOWED, MAY CAUSE
BURNS TO MOUTH AND STOMACH. TARGET ORGANS:RESPIRATORY SYS TEM, LUNGS, KIDNEYS, AND
BLOOD.
Signs & Symptoms of Overexposure:
SKIN: BURNS OR IRRITATION ESPECIALLY TO PERSPIRING PERSON. EXCESS COUGHING DUE TO
IRRITATION TO UPPER RESPIRATORY SYSTEM. VOMITING, STOMACHACHE, DIARRHEA.
Medical Conditions Aggravated by Exposure:
BRONCHITIS OR PNEUMONIA. EYES AND “OPEN CUTS� ARE PARTICULARLY VULNERABLE.
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route of Entry Indicators:
Inhalation: YES
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Annex F
Skin: NO
Ingestion: YES
Carcenogenicity Indicators
NTP: NO
IARC: NO
OSHA: NO
Carcinogenicity Explanation: NOT RELEVANT
Section 4 - First Aid Measures
CALCIUM OXIDE
First Aid:
SKIN:WASH OFF ALL LIME DUST WITH EXCESS WATER. APPLY CREAM OR OINTMENT. EYE:FLUSH
IMMEDIATELY W/ LG AMTS OF WATER FOR AT LEAST 15 MIN & SEE MEDICAL DOCTOR IMMEDIATELY.
INHAL:REMOVE TO, IF NOT BREATHIN G GIVE CPR/OXYGEN. INGEST:DRINK LARGE AMOUNTS OF
WATER, ORANGE JUICE, FOLLOWED BY EGG WHITE IN WATER. CALL PHYSICIAN IMMEDIATELY.
Section 5 - Fire Fighting Measures
CALCIUM OXIDE
Fire Fighting Procedures:
NONE IDENTIFIED.
Unusual Fire or Explosion Hazard:
CONTACT WITH MOISTURE OR WATER MAY GENERATE SUFFICIENT HEAT TO IGNITE COMBUSTIBLES.
Extinguishing Media:
NON-COMBUSTIBLE. USE MEDIA SUITABLE FOR SURROUNDING FIRES.
Flash Point: Flash Point Text: NOT APPLICABLE
Autoignition Temperature:
Autoignition Temperature Text: N/A
Lower Limit(s): N/A
Upper Limit(s): N/A
Section 6 - Accidental Release Measures
CALCIUM OXIDE
Spill Release Procedures:
WEAR SELF CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. VENTILATE AREA.
SHOVEL MATERIAL INTO DRY CONTAINERS. FLUSH RESIDUE WITH WATER.
Section 7 - Handling and Storage
CALCIUM OXIDE
Handling and Storage Precautions:
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
CALCIUM OXIDE
Repiratory Protection:
IN DUSTY LOCATIONS, USE NIOSH/MSHA APPROVED RESPIRATORS.
Ventilation:
APPLY ADEQUATE VENTILATION TO KEEP DUST BELOW TLV. VENT DUST TO “COLLECTOR�.
Protective Gloves:
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Annex F
RUBBER GLOVES.
Eye Protection: SAFETY GOGGLES.
Other Protective Equipment: LONG SLEEVED SHIRT W/BUTTON COLLAR & LONG PANTS EXTENDING
OVER HIGH TOP WORK BOOTS.EMERG EYE WASH AND DELUGE SHOWER.
Work Hygenic Practices: WASH WELL WITH WATER UPON COMPLETION OF SHIFT.
Supplemental Health & Safety Information: NONE SPECIFIED BY MANUFACTURER.
Section 9 - Physical & Chemical Properties
CALCIUM OXIDE
HCC: B3
NRC/State License Number: N/R
Net Property Weight for Ammo: N/R
Boiling Point: Boiling Point Text: 5162F,2850C
Melting/Freezing Point: Melting/Freezing Text: N/A
Decomposition Point: Decomposition Text: N/K
Vapor Pressure: N/A Vapor Density: N/A
Percent Volatile Organic Content:
Specific Gravity: 3.34
Volatile Organic Content Pounds per Gallon:
pH: N/K
Volatile Organic Content Grams per Liter:
Viscosity: N/A
Evaporation Weight and Reference: NOT APPLICABLE
Solubility in Water: NEGLIGIBLE, <0.1%
Appearance and Odor: WHITE OR GREY SOLID, ODORLESS.
Percent Volatiles by Volume: N/K
Corrosion Rate: N/K
Section 10 - Stability & Reactivity Data
CALCIUM OXIDE
Stability Indicator: NO
Materials to Avoid:
WATER AND ACIDS.
Stability Condition to Avoid:
MOISTURE AND WATER.
Hazardous Decomposition Products:
NONE
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
NOT RELEVANT
Section 11 - Toxicological Information
CALCIUM OXIDE
Toxicological Information:
N/P
Section 12 - Ecological Information
CALCIUM OXIDE
Ecological Information:
N/P
Section 13 - Disposal Considerations
CALCIUM OXIDE
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Annex F
Waste Disposal Methods:
DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL REGULATIONS.
Section 14 - MSDS Transport Information
CALCIUM OXIDE
Transport Information:
N/P
Section 15 - Regulatory Information
CALCIUM OXIDE
SARA Title III Information:
N/P
Federal Regulatory Information:
N/P
State Regulatory Information:
N/P
Section 16 - Other Information
CALCIUM OXIDE
Other Information:
N/P
HMIS Transportation Information
Product Identification: CALCIUM OXIDE
Transporation ID Number: 95087
Responsible Party CAGE: DO870
Date MSDS Prepared: 03/25/1992
Date MSDS Reviewed: 04/04/1994
MFN: 04/04/1994
Submitter: D DG
Status Code: C
Container Information
Unit of Issue: BT
Container Quantity: 6
Type of Container:
Net Unit Weight: 2.5 KG
Article without MSDS: N
Technical Entry NOS Shipping Number:
Radioactivity: N/R
Form:
Net Explosive Weight:
Coast Guard Ammunition Code:
Magnetism: N/P
AF MMAC Code:
DOD Exemption Number:
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Annex F
Limited Quantity Indicator:
Multiple Kit Number: 0
Kit Indicator: N
Kit Part Indicator: N
Review Indicator: Y
Additional Data:
REGULATED BY IMO ONLY IN BULK QUANTITIES.
Department of Transportation Information
DOT Proper Shipping Name: CALCIUM OXIDE
DOT PSN Code: CRE
Symbols: A
DOT PSN Modifier:
Hazard Class: 8
UN ID Number: UN1910
DOT Packaging Group: III
Label: CORROSIVE
Special Provision(s):
Packaging Exception:
Non Bulk Packaging: 213
Bulk Packaging: 240
Maximimum Quanity in Passenger Area: 25 KG
Maximimum Quanity in Cargo Area: 100 KG
Stow in Vessel Requirements: A
Requirements Water/Sp/Other:
IMO Detail Information
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
IMO PSN Code: ZZZ
IMO PSN Modifier:
IMDG Page Number: N/R
UN Number: N/R
UN Hazard Class: N/R
IMO Packaging Group: N/R
Subsidiary Risk Label: N/R
EMS Number: N/R
Medical First Aid Guide Number: N/R
IATA Detail Information
IATA Proper Shipping Name: CALCIUM OXIDE
IATA PSN Code: EZP
IATA PSN Modifier:
IATA UN Id Number: 1910
IATA UN Class: 8
Subsidiary Risk Class:
UN Packaging Group: III
IATA Label: CORROSIVE
Packaging Note for Passengers: 822
Maximum Quantity for Passengers: 25KG
Packaging Note for Cargo: 823
Maximum Quantity for Cargo: 100KG
Exceptions:
AFI Detail Information
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Annex F
AFI Proper Shipping Name: CALCIUM OXIDE
AFI Symbols:
AFI PSN Code: EZP
AFI PSN Modifier:
AFI UN Id Number: UN1910
AFI Hazard Class: 8
AFI Packing Group: III
AFI Label:
Special Provisions: P5
Back Pack Reference: A12.4
HAZCOM Label Information
Product Identification: CALCIUM OXIDE
CAGE: DO870
Assigned Individual: Y
Company Name: J.T.BAKER CHEMICAL CO.
Company PO Box: N/K
Company Street Address1: 222 RED SCHOOL LANE
Company Street Address2: PHILLIPSBURG, NJ 08865-2219 US
Health Emergency Telephone: 201-859-2151/800-424-9300(CHEMTR)
Label Required Indicator: Y
Date Label Reviewed: 04/04/1994
Status Code: C
Manufacturer’s Label Number: N/K
Date of Label: 04/04/1994
Year Procured: 1994
Organization Code: F
Chronic Hazard Indicator: N/P
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: YES
Signal Word: WARNING
Health Hazard: Slight
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: Moderate
Section 1 - Product and Company Identification
CHROMIC ACID
Product Identification: CHROMIC ACID
Date of MSDS: 02/01/1993 Technical Review Date: 05/22/1999
FSC: 6810 NIIN: 00-264-6517
Submitter: D DG
Status Code: C
MFN: 01
Article: N
Kit Part: N
Manufacturer’s Information
Manufacturer’s Name: VAN WATERS AND ROGERS INC
Manufacturer’s Address1: 1600 NORTON BLDG.
Manufacturer’s Address2: SEATTLE, WA 98104-1564
Manufacturer’s Country: US
General Information Telephone: 408-435-8700
Emergency Telephone: 408-435-8700/800-424-9300(CHEMTREC)
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Annex F
Emergency Telephone: 408-435-8700/800-424-9300(CHEMTREC)
MSDS Preparer’s Name: C.A.EISENHART
Proprietary: N
Reviewed: Y
Published: Y
CAGE: 87664
Special Project Code: N
Item Description
Item Name: CHROMIUM TRIOXIDE,TECHNICAL
Item Manager: S9G
Specification Number: NK
Type/Grade/Class: NK
Unit of Issue: CN Quantitative Expression: 00000000005LB
Unit of Issue Quantity: B
Type of Container:
Contractor Information
Contractor’s Name: CHEMICAL COMMODITIES AGENCY, INC.
Contractor’s Address1: 27447 PACIFIC STREET
Contractor’s Address2: HIGHLAND, CA 92346-2640
Contractor’s Telephone: 909-864-2310
Contractor’s CAGE: 60777
Contractor Information
Contractor’s Name: VAN WATERS AND ROGERS INC., UNIVAR CORP.
Contractor’s Address1: 1600 NORTON BLDG. 801 2ND AVENUE
Contractor’s Address2: SEATTLE, WA 98104-1564
Contractor’s Telephone: 206-447-5911/800-424-9300(CHEMTREC)
Contractor’s CAGE: 87664
Section 2 - Compositon/Information on Ingredients
CHROMIC ACID
Ingredient Name: CHROMIUM (VI) OXIDE
Ingredient CAS Number: 1333-82-0 Ingredient CAS Code: M
RTECS Number: GB6650000 RTECS Code: M
=WT: =WT Code:
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
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Annex F
% High Volume: % High Volume Code:
% Text: >99
% Enviromental Weight:
Other REC Limits: N/K
OSHA PEL: C, 0.1 MG/M3 (CRO3) OSHA PEL Code: M
OSHA STEL: OSHA STEL Code:
ACGIH TLV: 0.05 MG/M3(CR); 8990 ACGIH TLV Code: M
ACGIH STEL: N/P ACGIH STEL Code:
EPA Reporting Quantity:
DOT Reporting Quantity:
Ozone Depleting Chemical: N
Section 3 - Hazards Identification, Including Emergency Overview
CHROMIC ACID
Health Hazards Acute & Chronic: ACUTE-EYE:DUST IS EXTREMELY CORROSIVE;CAN CAUSE SEVERE
DAMAGE.SKIN:IRRITATION.INHAL:IRRITATION OF THE NASAL SEPTUM & RESPIRATORY
TRACT.INGESTION:CAN CAUSE EXTREME TISSUE DESTRUCTION,KIDNEY FAILURE & D
EATH.CHRONIC-EYE:CONJUNCTIVITIS.SKIN:ESPEC. BROKEN,MAY CAUSE “CHROME SORE�.
Signs & Symptoms of Overexposure:
EYES:CORROSIVE,SEVERE DAMAGE,PERMANENT
INJURY,BLINDNESS;SKIN:BURNS,IRRITATION,CHROME SORES,SKIN SENSITIZATION, KIDNEY FAIL
SEPTUM & RESPIRATORY TRACT,ASTHMA-LIKE SYMPTOMS;INGESTION: TISSUE DISTRUCTION
,SEVERE INJURY,DELAYED TOXIC EFFECTS,KIDNEY OR LIVER FAILURE.
Medical Conditions Aggravated by Exposure:
CONTACT WITH BROKEN SKIN CAN CAUSE “CHROME SORES�.SKIN CAN BECOME SENSITIZED AND
MASSIVE OVER-EXPOSURE TO SOLUTIONS CAN ABSORB HARMFUL AMOUNTS, LEADING TO KIDNEY
FAILURE AND DEATH.
LD50 LC50 Mixture: NIOSH:.025MG(CR4)/M3;10HR TWA=.05MG
Route of Entry Indicators:
Inhalation: NO
Skin: YES
Ingestion: NO
Carcenogenicity Indicators
NTP: YES
IARC: YES
OSHA: NO
Carcinogenicity Explanation: CR (VI) COMPOUNDS ARE CONSIDERED SUSPECT CARCINOGENS.
Section 4 - First Aid Measures
CHROMIC ACID
First Aid:
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Annex F
EYE:IMMEDIATELY FLUSH WITH RUNNING WATER FOR 15 MIN.GET MEDICAL
ATTENTION.SKIN:IMMEDIATELY FLUSH WITH RUNNING WATER FOR 15 MIN.DESTROY
CONTAMINATED SHOES.CALL A DOCTOR.INHALATION:REMOVE TO FRESH AIR.G IVE CPR IF
NEEDED.CALL A PHYSICIAN.INGESTION:DON’T INDUCE VOMITING.IF CONSCIOUS,GIVE LOTS OF
WATER/MILK.GET IMMEDIATE MEDICAL ATTENTION.
Section 5 - Fire Fighting Measures
CHROMIC ACID
Fire Fighting Procedures:
FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN
FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire or Explosion Hazard:
PRODUCT MAY CAUSE FIRE IF IT DRYS ON CLOTHING,WOOD,COMBUSTIBLES.CONTACT WITH
FLAMMABLE MATERIALS MAY CAUSE IMMEDIATE FIRE OR EXPLOSION,ESPECIALLY IF HEATED.
Extinguishing Media:
DRY CHEMICAL OR CO2. DO NOT USE WATER.(UNDER CERTAIN CONDITIONS CONTACT WITH WATER
CAN CAUSE STEAM EXPLOSIONS).
Flash Point: Flash Point Text: NONE
Autoignition Temperature:
Autoignition Temperature Text: N/A
Lower Limit(s): N/R
Upper Limit(s): N/R
Section 6 - Accidental Release Measures
CHROMIC ACID
Spill Release Procedures:
WEAR RESPIRATOR EQUIPPED WITH PARTICULATE FILTERS AND EYE PROTECTION. SWEEP UP AND
DISPOSE OF IN DOT APPROVED WASTE CONTAINERS.
Section 7 - Handling and Storage
CHROMIC ACID
Handling and Storage Precautions:
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
CHROMIC ACID
Repiratory Protection:
NIOSH APPROVED CARTRIDGE RESPIRATOR FOR ACID MISTS.
Ventilation:
LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE OF MAINTAINING DUST EMISSIONS AT THE
POINT OF USE BELOW THE PEL.
Protective Gloves:
PVC GLOVES WITH GAUNTLETS.
Eye Protection: CHEMICAL GOGGLES & FULL FACESHIELD.
Other Protective Equipment: ACID RESISTANT SLICKER SUIT WITH PVC APRON & BOOTS. EYEWASH
STATION & SAFETY SHOWER.
Work Hygenic Practices: REMOVE CONTAMINATED CLOTHING IMMEDIATELY.DO NOT LAUNDER AT
HOME.AVOID WEARING LEATHER SHOES & GLOVES.TAKE SHOWER DAILY.
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Annex F
Supplemental Health & Safety Information: NOTE TO PHYSICIAN:MASSIVE OVEREXPOSURE TO
SOLUTIONS COULD LEAD TO KIDNEY FAILURE AND DEATH.EARLY RENAL DIALYSIS IS
RECOMMENDED.ONE GRAM ASCORBIC ACID (ORAL/IV) FOLLOWED BY 100 MG T.I.D. FOR 14 DAYS.SK
IN ULCERS MAY BE TREATED BY REMOVAL FROMEXPOSURE,DAILY CLEANSING & DEBRIDEMENT, &
ANTIBIOTIC CREAM.
Section 9 - Physical & Chemical Properties
CHROMIC ACID
HCC: D3
NRC/State License Number: NONE
Net Property Weight for Ammo: NONE
Boiling Point: Boiling Point Text: N/R
Melting/Freezing Point: Melting/Freezing Text: 387F (197C)
Decomposition Point: Decomposition Text: UNKNOWN
Vapor Pressure: N/R Vapor Density: N/R
Percent Volatile Organic Content:
Specific Gravity: 2.7
Volatile Organic Content Pounds per Gallon:
pH: N/K
Volatile Organic Content Grams per Liter:
Viscosity: N/P
Evaporation Weight and Reference: N/R
Solubility in Water: 62.5%
Appearance and Odor: DARK RED FLAKES, NO ODOR
Percent Volatiles by Volume: N/K
Corrosion Rate: UNKNOWN
Section 10 - Stability & Reactivity Data
CHROMIC ACID
Stability Indicator: YES
Materials to Avoid:
REDUCING AGENTS,COMBUSTIBLE MATERIALS SUCH AS OILS OR GREASES,WATER AND ORGANICS.
Stability Condition to Avoid:
NONE.
Hazardous Decomposition Products:
CHROMIC OXIDE
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
NONE
Section 11 - Toxicological Information
CHROMIC ACID
Toxicological Information:
N/P
Section 12 - Ecological Information
CHROMIC ACID
Ecological Information:
N/P
Section 13 - Disposal Considerations
CHROMIC ACID
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Annex F
Waste Disposal Methods:
DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL
LAWS AND REGULATIONS.
Section 14 - MSDS Transport Information
CHROMIC ACID
Transport Information:
N/P
Section 15 - Regulatory Information
CHROMIC ACID
SARA Title III Information:
N/P
Federal Regulatory Information:
N/P
State Regulatory Information:
N/P
Section 16 - Other Information
CHROMIC ACID
Other Information:
N/P
HMIS Transportation Information
Product Identification: CHROMIC ACID
Transporation ID Number: 63259
Responsible Party CAGE: 87664
Date MSDS Prepared: 02/01/1993
Date MSDS Reviewed: 08/05/1993
MFN: 08/05/1993
Submitter: D DG
Status Code: C
Container Information
Unit of Issue: CN
Container Quantity: B
Type of Container:
Net Unit Weight: 5 POUNDS
Article without MSDS: N
Technical Entry NOS Shipping Number:
Radioactivity:
Form:
Net Explosive Weight:
Coast Guard Ammunition Code:
Magnetism: N/P
AF MMAC Code:
DOD Exemption Number:
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Annex F
Limited Quantity Indicator:
Multiple Kit Number: 0
Kit Indicator: N
Kit Part Indicator: N
Review Indicator: Y
Additional Data:
Department of Transportation Information
DOT Proper Shipping Name: CHROMIC ACID, SOLID
DOT PSN Code: DJH
Symbols: D
DOT PSN Modifier:
Hazard Class: 5.1
UN ID Number: NA1463
DOT Packaging Group: II
Label: OXIDIZER, CORROSIVE
Special Provision(s):
Packaging Exception:
Non Bulk Packaging: 212
Bulk Packaging: 242
Maximimum Quanity in Passenger Area: 5 KG
Maximimum Quanity in Cargo Area: 25 KG
Stow in Vessel Requirements: A
Requirements Water/Sp/Other:
IMO Detail Information
IMO Proper Shipping Name: CHROMIC ACID, SOLID
IMO PSN Code: EIT
IMO PSN Modifier:
IMDG Page Number: SEE 5145
UN Number: 1463
UN Hazard Class: 5.1
IMO Packaging Group: II
Subsidiary Risk Label: CORROSIVE
EMS Number: 5.1-05
Medical First Aid Guide Number: 700
IATA Detail Information
IATA Proper Shipping Name: CHROMIUM TRIOXIDE, ANHYDROUS
IATA PSN Code: GVR
IATA PSN Modifier:
IATA UN Id Number: 1463
IATA UN Class: 5.1
Subsidiary Risk Class: 8
UN Packaging Group: II
IATA Label: OXIDIZER & CORROSIVE
Packaging Note for Passengers: 508
Maximum Quantity for Passengers: 5KG
Packaging Note for Cargo: 511
Maximum Quantity for Cargo: 25KG
Exceptions:
AFI Detail Information
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Annex F
AFI Proper Shipping Name: CHROMIC ACID, SOLID
AFI Symbols: D
AFI PSN Code: GUD
AFI PSN Modifier: CHROMIC ACID, SOLID; ALSO SEE CHROMIUM TRIOXIDE, ANHYDROUS
AFI UN Id Number: NA1463
AFI Hazard Class: 5.1
AFI Packing Group: II
AFI Label: 8
Special Provisions: P5
Back Pack Reference: A9.8
HAZCOM Label Information
Product Identification: CHROMIC ACID
CAGE: 87664
Assigned Individual: N
Company Name: VAN WATERS AND ROGERS INC., UNIVAR CORP.
Company PO Box:
Company Street Address1: 1600 NORTON BLDG. 801 2ND AVENUE
Company Street Address2: SEATTLE, WA 98104-1564 US
Health Emergency Telephone: 408-435-8700/800-424-9300(CHEMTREC)
Label Required Indicator: Y
Date Label Reviewed: 08/05/1993
Status Code: C
Manufacturer’s Label Number: UNKNOWN
Date of Label: 08/05/1993
Year Procured: 1993
Organization Code: F
Chronic Hazard Indicator: Y
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: YES
Signal Word: DANGER
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: None
Section 1 - Product and Company Identification
FERRIC CHLORIDE, ANHYDROUS
Product Identification: FERRIC CHLORIDE, ANHYDROUS
Date of MSDS: 10/11/1993 Technical Review Date: 05/17/1996
FSC: 6810 NIIN: 00-682-6677
Submitter: D DG
Status Code: C
MFN: 01
Article: N
Kit Part: N
Manufacturer’s Information
Manufacturer’s Name: POLY RESEARCH CORPORATION
Manufacturer’s Address1: 125 CORPORATE DRIVE
Manufacturer’s Address2: HOLTSVILLE, NY 11742
Manufacturer’s Country: US
General Information Telephone: 516-242-1020
Emergency Telephone: 800-424-9300
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Annex F
Emergency Telephone: 800-424-9300
MSDS Preparer’s Name: UNKNOWN
Proprietary: N
Reviewed: Y
Published: Y
CAGE: 64713
Special Project Code: N
Item Description
Item Name: FERRIC CHLORIDE,ANHYDROUS,TECHNICAL
Item Manager: S9G
Specification Number: MIL-F-14580
Type/Grade/Class: NK
Unit of Issue: DR Quantitative Expression: 00000000135LB
Unit of Issue Quantity: L
Type of Container: DRUM
Contractor Information
Contractor’s Name: POLY RESEARCH CORPORATION
Contractor’s Address1: 125 CORPORATE DRIVE
Contractor’s Address2: HOLTSVILLE, NY 11742-2007
Contractor’s Telephone: 516-758-0460
Contractor’s CAGE: 64713
Section 2 - Compositon/Information on Ingredients
FERRIC CHLORIDE, ANHYDROUS
Ingredient Name: FERRIC CHLORIDE (SARA III)
Ingredient CAS Number: 7705-08-0 Ingredient CAS Code: M
RTECS Number: LJ9100000 RTECS Code: M
=WT: =WT Code:
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text: 99
% Enviromental Weight:
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Annex F
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 1 MG (FE)/M3 OSHA PEL Code: M
OSHA STEL: OSHA STEL Code:
ACGIH TLV: 1 MG (FE)/M3; 9394 ACGIH TLV Code: M
ACGIH STEL: N/P ACGIH STEL Code:
EPA Reporting Quantity: 1000 LBS
DOT Reporting Quantity: 1000 LBS
Ozone Depleting Chemical: N
Section 3 - Hazards Identification, Including Emergency Overview
FERRIC CHLORIDE, ANHYDROUS
Health Hazards Acute & Chronic: EYE CONTACT: MAY CAUSE IRRITATION AND MAY BE CORROSIVE
AND RESULT IN PERMANENT VISUAL LOSS. SKIN CONTACT: A MODERATE SKIN IRRITANT. CONTACT
CAN CAUSE IRRITATION OR CORROSIVE CHEMICAL BURNS TO HUMAN TI SSUE. INHALATION:
IRRITANT. INGESTION: MAY CAUSE SEVERE LIVER AND/OR KIDNEY DAMAGE.
Signs & Symptoms of Overexposure:
SEE HEALTH HAZARDS.
Medical Conditions Aggravated by Exposure:
PERSONS WITH A HISTORY OF EYE, SKIN AND RESPIRATORY DISORDERS MAY BE AT INCREASED RISK
FROM EXPOSURE.
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route of Entry Indicators:
Inhalation: YES
Skin: YES
Ingestion: YES
Carcenogenicity Indicators
NTP: NO
IARC: NO
OSHA: NO
Carcinogenicity Explanation: NONE
Section 4 - First Aid Measures
FERRIC CHLORIDE, ANHYDROUS
First Aid:
EYE: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15-20 MINUTES. GET MEDICAL ATTENTION.
SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. INHALATION: REMOVE
TO FRESH AIR. GIVE OXYGEN IF BREA THING IS DIFFICULT. GIVE ARTIFICIAL RESPIRATION IF VICTIM
IS NOT BREATHING. INGESTION:DO NOT INDUCE VOMITING. DRINK COPIOUS AMOUNTS OF WATER.
GET IMMEDIATE MEDICAL ATTENTION.
Section 5 - Fire Fighting Measures
FERRIC CHLORIDE, ANHYDROUS
Fire Fighting Procedures:
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Annex F
WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING
APPARATUS. COOL EXTERIOR OF STORAGE TANKS.
Unusual Fire or Explosion Hazard:
MAY RELEASE CHLORINE GAS OR HYDROGEN CHLORIDE GAS AT HIGH TEMPERATURES AS
MATERIAL DECOMPOSES. CAUTION: THIS MATERIAL HEATS ON CONTACT WITH WATER.
Extinguishing Media:
USE CARBON DIOXIDE, OR DRY CHEMICAL.
Flash Point: Flash Point Text: NONE
Autoignition Temperature:
Autoignition Temperature Text: N/R
Lower Limit(s): N/R
Upper Limit(s): N/R
Section 6 - Accidental Release Measures
FERRIC CHLORIDE, ANHYDROUS
Spill Release Procedures:
WEAR PROTECTIVE EQUIPMENT AND VENTILATE AREA AS REQUIRED. SWEEP OR SCOOP UP AND
REMOVE. FLUSH AREA WITH WATER.
Section 7 - Handling and Storage
FERRIC CHLORIDE, ANHYDROUS
Handling and Storage Precautions:
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
FERRIC CHLORIDE, ANHYDROUS
Repiratory Protection:
USE NIOSH/MSHA APPROVED, FULL FACE RESPIRATOR WITH DUST FILTER. CONSULT RESPIRATOR
MANUFACTURER TO DETERMINE APPROPRIATE EQUIPMENT.
Ventilation:
MECHANICAL (GENERAL) VENTILATION IS USUALLY ADEQUATE.
Protective Gloves:
IMPERVIOUS RUBBER GLOVES
Eye Protection: SAFETY GLASSES WITH SIDE SHIELDS
Other Protective Equipment: SAFETY SHOWER AND EYE BATH.
Work Hygenic Practices: WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING.
LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Health & Safety Information: NONE
Section 9 - Physical & Chemical Properties
FERRIC CHLORIDE, ANHYDROUS
HCC: C1
NRC/State License Number: N/R
Net Property Weight for Ammo: N/R
Boiling Point: Boiling Point Text: 581F,305C
Melting/Freezing Point: Melting/Freezing Text: UNKNOWN
Decomposition Point: Decomposition Text: UNKNOWN
Vapor Pressure: NEGLIGIBLE Vapor Density: N/A
Percent Volatile Organic Content:
168 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Specific Gravity: 2.8 -2.9
Volatile Organic Content Pounds per Gallon:
pH: N/K
Volatile Organic Content Grams per Liter:
Viscosity: N/P
Evaporation Weight and Reference: N/A
Solubility in Water: APPRECIABLE
Appearance and Odor: GREENISH BLACK GRANULAR SOLID
Percent Volatiles by Volume: N/A
Corrosion Rate: UNKNOWN
Section 10 - Stability & Reactivity Data
FERRIC CHLORIDE, ANHYDROUS
Stability Indicator: YES
Materials to Avoid:
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:
AVOID HIGH TEMPERATURES.
Hazardous Decomposition Products:
CAN RELEASE CHLORINE GAS AT ELEVATED TEMPERATURES ABOVE 553F. CAN RELEASE HYDROGEN
CHLORIDE GAS ON CONTACT WITH WATER.
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
NONE SPECIFIED BY MANUFACTURER.
Section 11 - Toxicological Information
FERRIC CHLORIDE, ANHYDROUS
Toxicological Information:
N/P
Section 12 - Ecological Information
FERRIC CHLORIDE, ANHYDROUS
Ecological Information:
N/P
Section 13 - Disposal Considerations
FERRIC CHLORIDE, ANHYDROUS
Waste Disposal Methods:
DISPOSE OF SPILLED, NEUTRALIZED, OR WASTE PRODUCT CONTAMINATED SOIL AND OTHER
CONTAMINATED MATERIALS IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL
REGULATIONS.
Section 14 - MSDS Transport Information
FERRIC CHLORIDE, ANHYDROUS
Transport Information:
N/P
Section 15 - Regulatory Information
FERRIC CHLORIDE, ANHYDROUS
SARA Title III Information:
N/P
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Annex F
Federal Regulatory Information:
N/P
State Regulatory Information:
N/P
Section 16 - Other Information
FERRIC CHLORIDE, ANHYDROUS
Other Information:
N/P
HMIS Transportation Information
Product Identification: FERRIC CHLORIDE, ANHYDROUS
Transporation ID Number: 82163
Responsible Party CAGE: 64713
Date MSDS Prepared: 10/11/1993
Date MSDS Reviewed: 05/17/1996
MFN: 05/17/1996
Submitter: D DG
Status Code: C
Container Information
Unit of Issue: DR
Container Quantity: L
Type of Container: DRUM
Net Unit Weight: 135 LB
Article without MSDS: N
Technical Entry NOS Shipping Number:
Radioactivity:
Form:
Net Explosive Weight:
Coast Guard Ammunition Code:
Magnetism: N/P
AF MMAC Code:
DOD Exemption Number:
Limited Quantity Indicator:
Multiple Kit Number: 0
Kit Indicator: N
Kit Part Indicator: N
Review Indicator: Y
Additional Data:
Department of Transportation Information
170 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
DOT Proper Shipping Name: FERRIC CHLORIDE, ANHYDROUS
DOT PSN Code: GEO
Symbols:
DOT PSN Modifier:
Hazard Class: 8
UN ID Number: UN1773
DOT Packaging Group: III
Label: CORROSIVE
Special Provision(s):
Packaging Exception:
Non Bulk Packaging: 213
Bulk Packaging: 240
Maximimum Quanity in Passenger Area: 25 KG
Maximimum Quanity in Cargo Area: 100 KG
Stow in Vessel Requirements: A
Requirements Water/Sp/Other:
IMO Detail Information
IMO Proper Shipping Name: FERRIC CHLORIDE, ANHYDROUS
IMO PSN Code: HEC
IMO PSN Modifier:
IMDG Page Number: 8173
UN Number: 1773
UN Hazard Class: 8
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: 8-06
Medical First Aid Guide Number: 700
IATA Detail Information
IATA Proper Shipping Name: FERRIC CHLORIDE, ANHYDROUS
IATA PSN Code: LUN
IATA PSN Modifier:
IATA UN Id Number: 1773
IATA UN Class: 8
Subsidiary Risk Class:
UN Packaging Group: III
IATA Label: CORROSIVE
Packaging Note for Passengers: 822
Maximum Quantity for Passengers: 25KG
Packaging Note for Cargo: 823
Maximum Quantity for Cargo: 100KG
Exceptions:
AFI Detail Information
AFI Proper Shipping Name: FERRIC CHLORIDE, ANHYDROUS
AFI Symbols:
AFI PSN Code: LUN
AFI PSN Modifier:
AFI UN Id Number: UN1773
AFI Hazard Class: 8
AFI Packing Group: III
AFI Label:
Special Provisions: P5
Back Pack Reference: A12.4
HAZCOM Label Information
Product Identification: FERRIC CHLORIDE, ANHYDROUS
CAGE: 64713
Assigned Individual: N
Company Name: POLY RESEARCH CORPORATION
171
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Annex F
Company PO Box:
Company Street Address1: 125 CORPORATE DRIVE
Company Street Address2: HOLTSVILLE, NY 11742-2007 US
Health Emergency Telephone: 800-424-9300
Label Required Indicator: Y
Date Label Reviewed: 07/12/1994
Status Code: C
Manufacturer’s Label Number: NONE
Date of Label: 07/12/1994
Year Procured: N/K
Organization Code: F
Chronic Hazard Indicator: N/P
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: YES
Signal Word: CAUTION
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Section 1 - Product and Company Identification
GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
Product Identification: GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
Date of MSDS: 11/01/1995 Technical Review Date: 10/19/2000
FSC: NIIN: EMPTY
Submitter: N EN
Status Code: A
MFN: 01
Article: N
Kit Part: N
Manufacturer’s Information
Manufacturer’s Name: SIGMA CHEMICAL COMPANY
Post Office Box: 14508
Manufacturer’s Address1:
Manufacturer’s Address2: SAINT LOUIS, MO 63178
Manufacturer’s Country: US
General Information Telephone: 800-325-3010
Emergency Telephone: (314) 771-5765
Emergency Telephone: (314) 771-5765
Proprietary: N
Reviewed: Y
Published: Y
CAGE: 21076
Contractor Information
Contractor’s Name: SIGMA CHEMICAL COMPANY
Contractor’s Address1: 3050 SPRUCE ST
Contractor’s Address2: ST LOUIS, MO 63178
Contractor’s Telephone: 314-771-5765
Contractor’s CAGE: 21076
172 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Section 2 - Compositon/Information on Ingredients
GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
Ingredient Name: GOLD CHLORIDE SOLUTION
Ingredient CAS Number: Ingredient CAS Code: X
RTECS Number: RTECS Code: X
=WT: =WT Code:
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text: N/P
% Enviromental Weight:
Other REC Limits: N/P
OSHA PEL: N/P OSHA PEL Code: M
OSHA STEL: N/P OSHA STEL Code: M
ACGIH TLV: N/P ACGIH TLV Code: M
ACGIH STEL: N/P ACGIH STEL Code: M
EPA Reporting Quantity:
DOT Reporting Quantity:
Ozone Depleting Chemical:
Section 3 - Hazards Identification, Including Emergency Overview
GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
None Listed
Section 4 - First Aid Measures
GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
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Annex F
None Listed
Section 5 - Fire Fighting Measures
GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
Fire Fighting Procedures:
WEAR (NIOSH APPROVED - FP N) SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE
CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire or Explosion Hazard:
N/P
Extinguishing Media:
NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Flash Point: Flash Point Text: N/P
Autoignition Temperature:
Autoignition Temperature Text: N/P
Lower Limit(s):
Upper Limit(s):
Section 6 - Accidental Release Measures
GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
None Listed
Section 7 - Handling and Storage
GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
None Listed
Section 8 - Exposure Controls & Personal Protection
GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
Repiratory Protection:
WEAR APPROPRIATE NIOSH-APPROVED RESPIRATOR.
Ventilation:
MECHANICAL EXHAUST IS REQUIRED.
Protective Gloves:
CHEMICAL-RESISTANT GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL SAFETY GOGGLES (FP N).
Other Protective Equipment: SAFET SHOWER AND EYEBATH (MEETING ANSI DESIGN CRITERIA - FP N).
WEAR PROTECTIVE CLOTHING.
Work Hygenic Practices: WASH THOROUGHLY AFTER HANDLING.
Supplemental Health & Safety Information: PHYSICAL AND CHEMICAL PROPERTIES (CONT):
SOLUABILITY: ETHER - SOLUABLE, ETHANOL - SOLUABLE.
Section 9 - Physical & Chemical Properties
GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
HCC:
NRC/State License Number:
Net Property Weight for Ammo:
Boiling Point: Boiling Point Text: N/P
Melting/Freezing Point: Melting/Freezing Text: N/P
Decomposition Point: Decomposition Text: N/P
Vapor Pressure: N/P Vapor Density: N/P
Percent Volatile Organic Content:
Specific Gravity: N/P
174 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Volatile Organic Content Pounds per Gallon:
pH: N/P
Volatile Organic Content Grams per Liter:
Viscosity: N/P
Evaporation Weight and Reference: N/P
Solubility in Water: SOLUBLE
Appearance and Odor: LIQUID. ODOR: NONE SPECIFIED BY MANUFACTURER (FP N).
Percent Volatiles by Volume: N/P
Corrosion Rate: N/P
Section 10 - Stability & Reactivity Data
GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
Stability Indicator: YES
Materials to Avoid:
REDUCING AGENTS.
Stability Condition to Avoid:
PROTECT FROM LIGHT.
Hazardous Decomposition Products:
DECOMPOSES ON HEATING TO CHLORINE GAS, HYDROGEN CHLORIDE AND METALLIC GOLD.
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
N/P
Section 11 - Toxicological Information
GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
Toxicological Information:
TO THE BEST OF THE MANUFACTURER’S KNOWLEDGE, THE CHEMICAL, PHYSICAL AND
TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
Section 12 - Ecological Information
GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
Ecological Information:
DATA NOT YET AVAILABLE.
Section 13 - Disposal Considerations
GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
None Listed
Section 14 - MSDS Transport Information
GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
Transport Information:
CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
Section 15 - Regulatory Information
GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
SARA Title III Information:
N/P
Federal Regulatory Information:
EUROPEAN INFORMATION. CAUTION: SUBSTANCE NOT YET FULLY TESTED. IRRITANT. R 36/37/38
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. S 26 IN CASE OF CONTACT WITH EYES, RINSE
175
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Annex F
IMMEDIATELY WITH PLENTY O F WATER AND SEEK MEDICAL ADVICE. S36 WEAR SUITABLE
PROTECTIVE CLOTHING.
State Regulatory Information:
N/P
Section 16 - Other Information
GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
Other Information:
FAX: USA/CANADA 1-800-325-5052; OUTSIDE USA/CANADA 314-771-5757. TELEX: 910-761-0593 OR 434475
ANSWERBACK “SIG OK COLLECT�. TELEPHONE # OUTSIDE USA/CANADA CALL COLLECT 314-771-5757.
HAZCOM Label Information
Product Identification: GOLD CHLORIDE SOLUTION, HT100-1, HT100-4
CAGE: 21076
Assigned Individual: N
Company Name: SIGMA CHEMICAL COMPANY
Company PO Box:
Company Street Address1: 3050 SPRUCE ST
Company Street Address2: ST LOUIS, MO 63178 US
Health Emergency Telephone: (314) 771-5765
Label Required Indicator: Y
Date Label Reviewed: 10/19/2000
Status Code: A
Manufacturer’s Label Number:
Date of Label:
Year Procured: N/K
Organization Code: F
Chronic Hazard Indicator: Y
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: YES
Signal Word: WARNING
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Section 1 - Product and Company Identification
H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
Product Identification: H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
Date of MSDS: 07/01/1997 Technical Review Date: 01/27/1999
FSC: NIIN: EMPTY
Submitter: F BT
Status Code: A
MFN: 01
Article: N
Kit Part: N
Manufacturer’s Information
Manufacturer’s Name: SIGMA CHEMICAL COMPANY
Post Office Box: 14508
Manufacturer’s Address1: 3050 SPRUCE ST
Manufacturer’s Address2: ST. LOUIS, MO 63178
Manufacturer’s Country: US
176 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
General Information Telephone:
Emergency Telephone: 314-771-5765
Emergency Telephone: 314-771-5765
Proprietary: N
Reviewed: Y
Published: Y
CAGE: 21076
Contractor Information
Contractor’s Name: ALDRICH CHEMICAL CO INC
Post Office Box: 355
Contractor’s Address1: 1001 WEST ST PAUL AVE
Contractor’s Address2: MILWAUKEE, WI 53233
Contractor’s Telephone: 414-273-3850
Contractor’s CAGE: 60928
Contractor Information
Contractor’s Name: FLUKA CHEMICAL CORP
Contractor’s Address1: 1001 WEST ST PAUL
Contractor’s Address2: MILWAUKEE, WI 53233
Contractor’s Telephone: 414-273-3850
Contractor’s CAGE: 63181
Contractor Information
Contractor’s Name: SIGMA CHEMICAL COMPANY
Contractor’s Address1: 3050 SPRUCE ST
Contractor’s Address2: ST LOUIS, MO 63178
Contractor’s Telephone: 314-771-5765
Contractor’s CAGE: 21076
Section 2 - Compositon/Information on Ingredients
H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
Ingredient Name: HYDROXYAMINE HYDROCHLORIDE
Ingredient CAS Number: 5470-11-1 Ingredient CAS Code: T
RTECS Number: NC3675000 RTECS Code: T
=WT: =WT Code:
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
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Annex F
% High Volume: % High Volume Code:
% Text: N/P
% Enviromental Weight:
Other REC Limits: N/P
OSHA PEL: N/P OSHA PEL Code:
OSHA STEL: N/P OSHA STEL Code:
ACGIH TLV: N/P ACGIH TLV Code:
ACGIH STEL: N/P ACGIH STEL Code:
EPA Reporting Quantity:
DOT Reporting Quantity:
Ozone Depleting Chemical: N
Section 3 - Hazards Identification, Including Emergency Overview
H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
None Listed
Section 4 - First Aid Measures
H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
None Listed
Section 5 - Fire Fighting Measures
H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
Fire Fighting Procedures:
WEAR SELF CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING TO PREVENT CONTACT
W/SKIN & EYES.
Unusual Fire or Explosion Hazard:
MAY EXPLODE WHEN HEATED. EMITS TOXIC FUMES UNDER FIRE CONDITIONS. CONTAINER
EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS.THIS MATERIAL MAY EXPODE IF HEATED > 239F.
Extinguishing Media:
CO2, DRY CHEMICAL POWDER/APPROPRIATE FOAM.
Flash Point: Flash Point Text: N/P
Autoignition Temperature:
Autoignition Temperature Text: N/P
Lower Limit(s):
Upper Limit(s):
Section 6 - Accidental Release Measures
H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
None Listed
Section 7 - Handling and Storage
H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
178 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
None Listed
Section 8 - Exposure Controls & Personal Protection
H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
Repiratory Protection:
WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:
USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:
CHEMICAL RESISTANT
Eye Protection: SAFETY GOGGLES, FACESHIELD 8-INCH MINIMUM
Other Protective Equipment: PROTECTIVE CLOTHING, SAFETY SHOWER, EYE BATH,
Work Hygenic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH
THOROUGHLY AFTER HANDLING. DISCARD CONTAMINATED SHOES.
Supplemental Health & Safety Information: TOXIC. HARMFUL: DANGER OF SERIOUS DAMAGE TO
HEALTH BY PROLONGED EXPOSURE IF SWALLOWED. AVOID RELEASE TO THE ENVIRONMENT.
Section 9 - Physical & Chemical Properties
H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
HCC:
NRC/State License Number:
Net Property Weight for Ammo:
Boiling Point: Boiling Point Text: N/P
Melting/Freezing Point: =159.C, 318.2F Melting/Freezing Text:
Decomposition Point: Decomposition Text: N/P
Vapor Pressure: N/P Vapor Density: N/P
Percent Volatile Organic Content:
Specific Gravity: 1.670
Volatile Organic Content Pounds per Gallon:
pH: N/P
Volatile Organic Content Grams per Liter:
Viscosity: N/P
Evaporation Weight and Reference: N/P
Solubility in Water: N/P
Appearance and Odor: WHITE CRYSTALLINE POWDER
Percent Volatiles by Volume: N/P
Corrosion Rate: N/P
Section 10 - Stability & Reactivity Data
H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
Stability Indicator: YES
Materials to Avoid:
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:
HEAT, OPEN FLAME, FIRE & OTHER IGNITION SOURCES, AIR/MOISTURE
Hazardous Decomposition Products:
NITROGEN OXIDES, HYDROGEN CHLORIDE GAS
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
N/P
Section 11 - Toxicological Information
H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
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Annex F
Toxicological Information:
LABORATORY EXPERIMENTS HAVE SHOWN MUTAGENIC EFFECTS. TO THE BEST OF OUR
KNOWLEDGE THE TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
Section 12 - Ecological Information
H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
Ecological Information:
DATA NOT YET AVAILABLE.
Section 13 - Disposal Considerations
H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
None Listed
Section 14 - MSDS Transport Information
H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
Transport Information:
CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
Section 15 - Regulatory Information
H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
SARA Title III Information:
N/P
Federal Regulatory Information:
N/P
State Regulatory Information:
EUROPEAN INFORMATION TOXIC. R22 HARMFUL IF SWALLOWED. R36/38 IRRITATING TO EYES & SKIN.
R43 MAY CAUSE SENSITIZATION BY SKIN CONTACT. R48/22 HARMFUL: DANGER OF SERIOUS DAMAGE
TO HEALTH BY PROLONGED EXP OSURE IF SWALLOWED. R50 VERY TOXIC TO AQUATIC ORGANISMS.
S22 DON’T BREATHE DUST. S24 AVOID CONTACT W/SKIN. S37 WEAR SUITABLE GLOVES. S61 AVOID
RELEASE TO THE ENVIRONMENT.
Section 16 - Other Information
H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
Other Information:
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE ALL
INCLUSIVE & SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH, FLUKA SHALL NOT BE HELD
LIABLE FOR ANY DAMAGE RESULTING FROM H ANDLING/FROM CONTACT W/THE ABOVE PRODUCT.
SEE REVERSE SIDE OF INVOICE/PACKING SLIP FOR ADDITIONAL TERMS & CONDITIONS OF SALE.
COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC., FLUKA CHEMI E AG. LICENSE
GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.
HAZCOM Label Information
Product Identification: H2391 HYDROXYLAMINE HYDROCHLORIDE ACS REAGENT
CAGE: 21076
Assigned Individual: N
Company Name: SIGMA CHEMICAL COMPANY
Company PO Box:
Company Street Address1: 3050 SPRUCE ST
Company Street Address2: ST LOUIS, MO 63178 US
Health Emergency Telephone: 314-771-5765
Label Required Indicator: Y
Date Label Reviewed: 01/27/1999
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Annex F
Status Code: A
Manufacturer’s Label Number:
Date of Label:
Year Procured: N/K
Organization Code: G
Chronic Hazard Indicator: N/P
Eye Protection Indicator: N/P
Skin Protection Indicator: N/P
Respiratory Protection Indicator: N/P
Signal Word: N/P
Health Hazard:
Contact Hazard:
Fire Hazard:
Reactivity Hazard:
Section 1 - Product and Company Identification
MAGNESIUM SULFATE, 5691
Product Identification: MAGNESIUM SULFATE, 5691
Date of MSDS: 12/08/1996 Technical Review Date: 03/09/2000
FSC: NIIN: EMPTY
Submitter: N EN
Status Code: A
MFN: 01
Article: N
Kit Part: N
Manufacturer’s Information
Manufacturer’s Name: MALLINCKRODT BAKER INC
Manufacturer’s Address1: 222 RED SCHOOL LANE
Manufacturer’s Address2: PHILLIPSBURG, NJ 08865
Manufacturer’s Country: US
General Information Telephone: 800-582-2537
Emergency Telephone: 908-859-2151
Other Number for MSDS Information: M0234
Emergency Telephone: 908-859-2151
Chemtec Telephone: (800)424-9300
Proprietary: N
Reviewed: Y
Published: Y
CAGE: 70829
Contractor Information
Contractor’s Name: MALLINCKRODT BAKER, INC. (FORMERLY J.T. BAKER INC)
Contractor’s Address1: 222 RED SCHOOL LANE
Contractor’s Address2: PHILLIPSBURG, NJ 08865-2219
Contractor’s Telephone: 800-582-2537
Contractor’s CAGE: 70829
Section 2 - Compositon/Information on Ingredients
MAGNESIUM SULFATE, 5691
Ingredient Name: MAGNESIUM SULFATE; (MAGNESIUM SULFATE ANHYDROUS)
Ingredient CAS Number: 7487-88-9 Ingredient CAS Code: T
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Annex F
RTECS Number: OM4500000 RTECS Code: T
=WT: =WT Code:
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: 99. % Low WT Code: M
% High WT: 100. % High WT Code: M
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text:
% Enviromental Weight:
Other REC Limits: N/P
OSHA PEL: N/P OSHA PEL Code:
OSHA STEL: N/P OSHA STEL Code:
ACGIH TLV: N/P ACGIH TLV Code:
ACGIH STEL: N/P ACGIH STEL Code:
EPA Reporting Quantity:
DOT Reporting Quantity:
Ozone Depleting Chemical: N
Section 3 - Hazards Identification, Including Emergency Overview
MAGNESIUM SULFATE, 5691
Health Hazards Acute & Chronic: INHALATION: DUST MAY BE SLIGHTLY IRRITATING. SORE THROAT OR
COUGHING MAY OCCUR. INGESTION: SINCE MAGNESIUM SALTS ARE SLOWLY ABSORBED,
ABDOMINAL PAIN, VOMITING AND DIARRHEA MAY BE THE ONLY SYMPTOMS. HO WEVER, IF
ELIMINATION IS BLOCKED BY BOWEL BLOCKAGE OR OTHER REASONS, CNS DEPRESSION, LACK OF
REFLEXES, HYPOCALCEMIA (DEFICIENCY OF CALCIUM IN THE BLOOD) MAY OCCUR. SKIN CONTACT:
NO ADVERSE EFFECTS EXP ECTED BUT MAY CAUSE MINOR SKIN IRRITATION. EYE CONTACT: NO
ADVERSE EFFECTS EXPECTED BUT DUST MAY CAUSE MECHANICAL IRRITATION. CHRONIC
EXPOSURE: NO INFORMATION FOUND.
Signs & Symptoms of Overexposure:
SEE HEALTH HAZARDS.
182 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Medical Conditions Aggravated by Exposure:
NO INFORMATION FOUND.
LD50 LC50 Mixture: N/P
Route of Entry Indicators:
Inhalation: YES
Skin: YES
Ingestion: YES
Carcenogenicity Indicators
NTP: NO
IARC: NO
OSHA: NO
Carcinogenicity Explanation: N/P
Section 4 - First Aid Measures
MAGNESIUM SULFATE, 5691
First Aid:
INHAL: REMOVE TO FRESH AIR. GET MED ATTN FOR ANY BREATHING DIFFICULTY. INGEST: GIVE
SEVERAL GLASSES OF WATER TO DRINK TO DILUTE. IF LARGE AMOUNTS WERE SWALLOWED, GET
MED ADVICE. SKIN CONTACT: REMOVE A NY CONTAM CLTHG. WASH SKIN W/SOAP & WATER FOR AT
LEAST 15 MINUTES. GET MED ATTN IF IRRITATION DEVELOPS OR PERSISTS. EYE CONTACT: WASH
THOROUGHLY W/RUNNING WATER FOR AT LEAST 15 MINUTES. GET MED ADVICE IF IRRITATION
DEVELOPS. NOTE TO MD: IV ADMINISTRATION OF CALCIUM GLUCONATE WILL PARTIALLY REVERSE
EFFECTS OF ACUTE MAGNESIIUM TOXICITY. VENTRICULAR SUPPORT W/CALCIUM CHLORIDE
INFUSION & MANNITOL FORC ED DIURESIS HAS ALSO BEEN SUCCESSFUL.
Section 5 - Fire Fighting Measures
MAGNESIUM SULFATE, 5691
Fire Fighting Procedures:
USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N).
Unusual Fire or Explosion Hazard:
NOT CONSIDERED TO BE A FIRE HAZARD. NOT CONSIDERED TO BE AN EXPLOSION HAZARD.
Extinguishing Media:
USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE.
Flash Point: Flash Point Text: N/P
Autoignition Temperature:
Autoignition Temperature Text: N/P
Lower Limit(s):
Upper Limit(s):
Section 6 - Accidental Release Measures
MAGNESIUM SULFATE, 5691
Spill Release Procedures:
VENTILATE AREA OF LEAK OR SPILL. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT AS
SPECIFIED IN EXPOSURE CONTROLS/PERSONAL PROTECTION. SPILLS: SWEEP UP AND CONTAINERIZE
FOR RECLAMATION OR DISPOSAL. VA CUUMING OR WET SWEEPING MAY BE USED TO AVOID DUST
DISPERSAL.
Section 7 - Handling and Storage
MAGNESIUM SULFATE, 5691
Handling and Storage Precautions:
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Annex F
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
MAGNESIUM SULFATE, 5691
Repiratory Protection:
PERSONAL RESPS (NIOSH APPRVD): FOR CNDTNS OF USE WHERE EXPOSURE TO DUST OR MIST IS
APPARENT, A HALF-FACE DUST/MIST RESP MAY BE WORN. FOR EMERGENCIES OR INSTANCES WHERE
THE EXPOSURE LEVELS ARE NOT KNOW N, USE A FULL-FACE POSITIVE-PRESSURE, AIR-SUPPLIED
RESPIRATOR. WARNING: AIR-PURIFYING RESPS DO NOT PROTECT WORKERS IN OXYGEN-DEFICIENT
ATMOSPHERES.
Ventilation:
A SYSTEM OF LOCAL &/OR GENERAL EXHAUST IS RECOM TO KEEP EMPLOYEE EXPOSURES AS LOW
AS POSS. LOCAL EXHAUST VENT IS GENERALLY PREFERRED BECAUSE IT CAN (SUPDAT)
Protective Gloves:
IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N).
WEAR CLEAN BODY-COVERING CLOTHING.
Work Hygenic Practices: N/P
Supplemental Health & Safety Information: VENT: CONTROL EMISSIONS OF CONTAMINANT AT ITS
SOURCE, PREVENTING DISPERION OF IT INTO THE GENERAL WORK AREA. PLEASE REFER TO ACGIH
DOCUMENT, INDUSTRIAL VENTILATION, A MANUAL OF RECOMMENDED PRACTICES, MOST RECENT
EDITION, FOR DETAILS. AIRBORNE EXPOSURE LIMITS: NONE ESTABLISHED.
Section 9 - Physical & Chemical Properties
MAGNESIUM SULFATE, 5691
HCC:
NRC/State License Number:
Net Property Weight for Ammo:
Boiling Point: Boiling Point Text: NOT APPLICABLE
Melting/Freezing Point: =1124.C, ######F Melting/Freezing Text: DECOMPOSES (TOX INFO)
Decomposition Point: =1124.C, 2055.2F Decomposition Text:
Vapor Pressure: NO INFO FOUND Vapor Density: N/K
Percent Volatile Organic Content:
Specific Gravity: 1.67
Volatile Organic Content Pounds per Gallon:
pH: TOX INFO
Volatile Organic Content Grams per Liter:
Viscosity: N/P
Evaporation Weight and Reference: NO INFO FOUND
Solubility in Water: VERY SOLUBLE
Appearance and Odor: TRANSPARENT CRYSTALS, OR WHITE POWDER; ODORLESS.
Percent Volatiles by Volume: N/P
Corrosion Rate: N/P
Section 10 - Stability & Reactivity Data
MAGNESIUM SULFATE, 5691
Stability Indicator: YES
Materials to Avoid:
ETHOXY ETHYL ALCOHOLS, ARSENATES, PHOSPHATES, TARTRATES, LEAD, BARIUM, STRONTIUM,
AND CALCIUM.
184 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Stability Condition to Avoid:
STABLE UNDER ORDINARY CONDITIONS OF USE AND STORAGE. LOSES SOME MOISTURE ON
EXPOSURE TO DRY AIR AT ROOM TEMPERATURE. CONDITIONS TO AVOID: HEAT, MOISTURE,
INCOMPATIBLES.
Hazardous Decomposition Products:
OXIDES OF SULFUR AND THE CONTAINED METAL.
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
N/P
Section 11 - Toxicological Information
MAGNESIUM SULFATE, 5691
Toxicological Information:
NO LD50/LC50 INFORMATION FOUND RELATING TO NORMAL ROUTES OF OCCUPATIONAL EXPOSURE.
INVESTIGATED AS A MUTAGEN, REPRODUCTIVE EFFECTOR. CANCER LISTS - MAGNESIUM SULFATE
ANHYDROUS (7487-88-9): NTP CARCIN - KNOWN: NO; ANTICIPATED: NO; IARC CATEGORY: NONE.
PHYSICAL DATA: MELTING POINT: 1124C(2055F) DECOMPOSES. LOSES ALL WATERS OF HYDRATION @
250C(482F). PH: AQUEOUS SOLUTION IS NEUTRAL OR SLIGHTLY ACID.
Section 12 - Ecological Information
MAGNESIUM SULFATE, 5691
Ecological Information:
ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL TOXICITY: NO INFORMATION
FOUND.
Section 13 - Disposal Considerations
MAGNESIUM SULFATE, 5691
Waste Disposal Methods:
WHATEVER CANNOT BE SAVED FOR RECOVERY OR RECYCLING SHOULD BE MANAGED IN
APPROPRIATE & APPROVED WASTE DISPOSAL FACILITY. PROCESSING, USE OR CONTAMINATION OF
THIS PROD MAY CHANGE THE WASTE MANAGEMENT OP TIONS. STATE & LOCAL DISPOSAL REGS
MAY DIFFER FROM FED DISPOSAL REGS. DISPOSE OF CNTNR & UNUSED CONT ENTS I/A/W FEDERAL,
STATE & LOCAL REQS.
Section 14 - MSDS Transport Information
MAGNESIUM SULFATE, 5691
Transport Information:
NOT REGULATED.
Section 15 - Regulatory Information
MAGNESIUM SULFATE, 5691
SARA Title III Information:
MAGNESIUM SULFATE ANHYRDOUS (487-88-9) - FEDERAL, STATE & LOCAL REGULATIONS - PART 1 -
SARA 302: RQ-NO; TPQ-NO. SARA 313: LIST-NO; CHEMICAL CATG-NO. SARA 311/312: ACUTE-YES;
CHRONIC-NO; FIRE-NO; PRESS URE-NO; REACTIVITY-NO. (PURE / SOLID).
Federal Regulatory Information:
MAGNESIUM SULFATE ANHYDROUS (7487-88-9): CHEMICAL INVENTORY STATUS - PART 1 - TSCA-YES;
EC-YES; JAPAN-YES; AUSTRALIA-YES. CHEMICAL INVENTORY STATUS - PART 2 - KOREA-YES; DSL-
YES; NDSL-NO; PHIL-YES. FE DERAL, STATE & INTERNATIONAL REGULATIONS - PART 2 - CERCLA-NO;
RCRA 261.33-NO; TSCA 8(D)-NO. CHEMICAL WEAPONS CONVENTION: NO. TSCA 12(B): NO. CDTA: NO.
AUSTRALIAN HAZCHEM CODE: NO INFO FOUND. POISON S CHEDULE: NO INFO FOUND. WHMIS: THIS
185
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Annex F
MSDS HAS BEEN PREPARED ACCORDING TO THE HAZARD CRITERIA OF THE C ONTROLLED
PRODUCTS REGULATIONS (CPR) & MSDS CONTAINS ALL INFO REQUIRED BY CPR.
State Regulatory Information:
N/P
Section 16 - Other Information
MAGNESIUM SULFATE, 5691
Other Information:
NFPA RATINGS: HLTH 1; FLAMMABILITY 0; REACTIVITY 0. LABEL HAZARD WARNING: CAUTION! MAY
BE HARMFUL IF SWALLOWED. LABEL PRECS: KEEP CNTNR CLOSED. WASH THOROUGHLY AFTER
HANDLING. LABEL FIRE AID: IF SWALL OWED, GIVE SEVERAL GLASSES OF WATER TO DRINK TO
DILUTE. IF LARGE AMOUNTS WERE SWALLOWED, GET MEDICAL ADVICE. PRODUCT USE: LAB
REAGENT. REVISION INFO: NEW 16 SECTION MSDS FORMATL, ALL SECTIONS HAVE BEE N REVISED. JT
BAKER SAF-T-DATA RATINGS: HEALTH RATING: 1-SLIGHT; FLAMMABILITY RATING: 0-NONE;
REACTIVITY RATING: 0-NONE. CONTACT RATING: 1-SLIGHT. LAB PROT EQUIP: GOGGLES; LAB COAT.
STORAGE COLOR CODE : ORANGE (GENERAL STORAGE).
HAZCOM Label Information
Product Identification: MAGNESIUM SULFATE, 5691
CAGE: 70829
Assigned Individual: N
Company Name: MALLINCKRODT BAKER, INC. (FORMERLY J.T. BAKER INC)
Company PO Box:
Company Street Address1: 222 RED SCHOOL LANE
Company Street Address2: PHILLIPSBURG, NJ 08865-2219 US
Health Emergency Telephone: 908-859-2151
Label Required Indicator: Y
Date Label Reviewed: 03/10/2000
Status Code: A
Manufacturer’s Label Number:
Date of Label:
Year Procured: N/K
Organization Code: F
Chronic Hazard Indicator: N
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: YES
Signal Word: CAUTION
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Section 1 - Product and Company Identification
METHYLENE CHLORIDE
Product Identification: METHYLENE CHLORIDE
Date of MSDS: 01/01/1985 Technical Review Date: 12/26/1984
FSC: 6810 NIIN: 00-616-9188
Submitter: D DG
Status Code: C
MFN: 01
Article: N
Kit Part: N
186 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Manufacturer’s Information
Manufacturer’s Name: YANCY MINERALS INCORPORATED
Manufacturer’s Address1:
Manufacturer’s Address2: N/P, NK 00000
Manufacturer’s Country: NK
General Information Telephone:
Emergency Telephone: (203)624-8067
Emergency Telephone: (203)624-8067
MSDS Preparer’s Name: N/P
Proprietary: N
Reviewed: Y
Published: Y
CAGE: 95652
Special Project Code: N
Item Description
Item Name: DICHLOROMETHANE,TECHNICAL
Item Manager: S9G
Specification Number: MIL-D-6998
Type/Grade/Class: NONE
Unit of Issue: DR Quantitative Expression: 00000000055GL
Unit of Issue Quantity: 1
Type of Container: DRUM
Contractor Information
Contractor’s Name: YANCY MINERALS INCORPORATED
Contractor’s Address1: UNKNOWN
Contractor’s Address2: UNKNOWN, NK 00000
Contractor’s Telephone: UNKNOWN
Contractor’s CAGE: 95652
Section 2 - Compositon/Information on Ingredients
METHYLENE CHLORIDE
Ingredient Name: METHYLENE CHLORIDE (SARA III)
Ingredient CAS Number: 75-09-2 Ingredient CAS Code: M
RTECS Number: PA8050000 RTECS Code: M
=WT: =WT Code:
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
% High WT: % High WT Code:
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Annex F
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text: 100
% Enviromental Weight:
Other REC Limits: N/P
OSHA PEL: 500 PPM/C,1000; Z2 OSHA PEL Code: M
OSHA STEL: OSHA STEL Code:
ACGIH TLV: 50 PPM, A2; 9192 ACGIH TLV Code: M
ACGIH STEL: N/P ACGIH STEL Code:
EPA Reporting Quantity: 1000 LBS
DOT Reporting Quantity: 1000 LBS
Ozone Depleting Chemical: N
Section 3 - Hazards Identification, Including Emergency Overview
METHYLENE CHLORIDE
Health Hazards Acute & Chronic: N/P
Signs & Symptoms of Overexposure:
LIGHT HEADEDNESS,MENTAL CONFUSTION,NAUSEA,HEADACHE.TINGLING OR CREEPING SKIN
FEELING ON INHALATION.
Medical Conditions Aggravated by Exposure:
N/P
LD50 LC50 Mixture: N/P
Route of Entry Indicators:
Inhalation: N/P
Skin: N/P
Ingestion: N/P
Carcenogenicity Indicators
NTP: N/P
IARC: N/P
OSHA: N/P
Carcinogenicity Explanation: N/P
Section 4 - First Aid Measures
METHYLENE CHLORIDE
First Aid:
REMOVE TO FRESH AIR,IF UNCONSCIOUS,USE ARTIFICIAL RESPIRATION & CALL A PHYSICIAN,KEEP
WARM & COMFORTABLE. FOR EYE CONTACT.WASH WITH WATER FOR 15 MIN. IN CASE OF SKIN
CONTACT, WASH WITH SOAP & WATER
Section 5 - Fire Fighting Measures
188 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
METHYLENE CHLORIDE
Fire Fighting Procedures:
WEAR SELF-CNTD BRTHG,APP H*20 SPRAY TO COOL CONTR.
Unusual Fire or Explosion Hazard:
MAY DECOMPOSE & GIVE PHOSGENE GAS.
Extinguishing Media:
CO*2, FOAM, DRY CHEM & H*2O FOG.
Flash Point: Flash Point Text: NON-FLAMMABLE
Autoignition Temperature:
Autoignition Temperature Text: N/A
Lower Limit(s): 15.5
Upper Limit(s): 66.0
Section 6 - Accidental Release Measures
METHYLENE CHLORIDE
Spill Release Procedures:
ALLOW MATERIAL TO VAPORIZE.KEEP UNPROTECTED EMPLOYEES AWAY.REMOVE IGNITION
SOURCES.CLOSE VALVE IF PERTINENT & WITHOUT RISK.
Section 7 - Handling and Storage
METHYLENE CHLORIDE
Handling and Storage Precautions:
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
METHYLENE CHLORIDE
Repiratory Protection:
SELF-CONTAINEE BREATHING APPARATUS;POSITIVE PRESSUR HOSE MASKS
Ventilation:
PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN
Protective Gloves:
IMPERVIOUS
Eye Protection: GOGGLES/FACE SHIELD
Other Protective Equipment: EYE WASH STATION. APRONS. SPECIAL IMPERVIOUS CLOTHING.
Work Hygenic Practices: N/P
Supplemental Health & Safety Information: MSDS NOT DATED & SIGNED
Section 9 - Physical & Chemical Properties
METHYLENE CHLORIDE
HCC: T4
NRC/State License Number:
Net Property Weight for Ammo:
Boiling Point: Boiling Point Text: 104F
Melting/Freezing Point: Melting/Freezing Text: N/A
Decomposition Point: Decomposition Text: N/A
Vapor Pressure: 350 Vapor Density: 2.93
Percent Volatile Organic Content:
Specific Gravity: 1.326
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Annex F
Volatile Organic Content Pounds per Gallon:
pH: N/P
Volatile Organic Content Grams per Liter:
Viscosity: N/P
Evaporation Weight and Reference: 1.8
Solubility in Water: MODERATE
Appearance and Odor: CLEAR,COLORLESS LIQUID WITH PLEASANT,AROMATIC ODOR
Percent Volatiles by Volume: 100
Corrosion Rate: N/P
Section 10 - Stability & Reactivity Data
METHYLENE CHLORIDE
Stability Indicator: YES
Materials to Avoid:
ALUMINUM,POTASSIUM,SODIUM
Stability Condition to Avoid:
EXCESSIVE HEAT,AUTOIGNITION TEMPERATURE 1180-1220F
Hazardous Decomposition Products:
PHOSGENE GAS
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
HIGH TEMPERATURE
Section 11 - Toxicological Information
METHYLENE CHLORIDE
Toxicological Information:
N/P
Section 12 - Ecological Information
METHYLENE CHLORIDE
Ecological Information:
N/P
Section 13 - Disposal Considerations
METHYLENE CHLORIDE
Waste Disposal Methods:
RESIDUE MAY BE POURED ON SAND,EARTH OR ASHES AT A SAFE DISTANCE FROM OCCUPIED AREAS
& ALLOWED TO EVAPORATE INTO THE ATMOSPHERE,ACCORDLY IN CONSULTATION WITH
LOCAL,STATE & FEDERAL AUTHORITIES.
Section 14 - MSDS Transport Information
METHYLENE CHLORIDE
Transport Information:
N/P
Section 15 - Regulatory Information
METHYLENE CHLORIDE
SARA Title III Information:
N/P
Federal Regulatory Information:
N/P
190 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
State Regulatory Information:
N/P
Section 16 - Other Information
METHYLENE CHLORIDE
Other Information:
N/P
HMIS Transportation Information
Product Identification: METHYLENE CHLORIDE
Transporation ID Number: 79915
Responsible Party CAGE: 95652
Date MSDS Prepared: 01/01/1985
Date MSDS Reviewed: 12/26/1984
MFN: 12/26/1984
Submitter: D DG
Status Code: C
Container Information
Unit of Issue: DR
Container Quantity: 1
Type of Container: DRUM
Net Unit Weight:
Article without MSDS: N
Technical Entry NOS Shipping Number:
Radioactivity:
Form:
Net Explosive Weight:
Coast Guard Ammunition Code:
Magnetism: N/P
AF MMAC Code:
DOD Exemption Number:
Limited Quantity Indicator:
Multiple Kit Number: 0
Kit Indicator: N
Kit Part Indicator: N
Review Indicator: Y
Additional Data:
HANDLE WITH CARE AVOID INHALATION OF VAPORS & SKIN OR EYE CONTACT.PROVIDE ADEQUATE
VENTILATION. TARG ET ORGANS:SKIN,CVS,EYES & CNS.
Department of Transportation Information
DOT Proper Shipping Name: DICHLOROMETHANE
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Annex F
DOT PSN Code: EUP
Symbols:
DOT PSN Modifier:
Hazard Class: 6.1
UN ID Number: UN1593
DOT Packaging Group: III
Label: KEEP AWAY FROM FOOD
Special Provision(s): N36,T13
Packaging Exception: 153
Non Bulk Packaging: 203
Bulk Packaging: 241
Maximimum Quanity in Passenger Area: 60 L
Maximimum Quanity in Cargo Area: 220 L
Stow in Vessel Requirements: A
Requirements Water/Sp/Other:
IMO Detail Information
IMO Proper Shipping Name: DICHLOROMETHANE
IMO PSN Code: FLF
IMO PSN Modifier:
IMDG Page Number: 6127
UN Number: 1593
UN Hazard Class: 6.1
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: 6.1-02
Medical First Aid Guide Number: 340
IATA Detail Information
IATA Proper Shipping Name: DICHLOROMETHANE
IATA PSN Code: IYW
IATA PSN Modifier:
IATA UN Id Number: 1593
IATA UN Class: 6.1
Subsidiary Risk Class:
UN Packaging Group: III
IATA Label: TOXIC
Packaging Note for Passengers: 605
Maximum Quantity for Passengers: 60L
Packaging Note for Cargo: 612
Maximum Quantity for Cargo: 220L
Exceptions:
AFI Detail Information
AFI Proper Shipping Name: DICHLOROMETHANE
AFI Symbols:
AFI PSN Code: IYW
AFI PSN Modifier:
AFI UN Id Number: UN1593
AFI Hazard Class: 6.1
AFI Packing Group: III
AFI Label:
Special Provisions: P5, N36
Back Pack Reference: A10.5
HAZCOM Label Information
Product Identification: METHYLENE CHLORIDE
CAGE: 95652
Assigned Individual: N
Company Name: YANCY MINERALS INCORPORATED
Company PO Box:
192 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Company Street Address1: UNKNOWN
Company Street Address2: UNKNOWN, NK 00000 NK
Health Emergency Telephone: 203-624-8067
Label Required Indicator: Y
Date Label Reviewed: 09/12/1990
Status Code: C
Manufacturer’s Label Number: N/R
Date of Label: 09/12/1990
Year Procured: N/K
Organization Code: F
Chronic Hazard Indicator: Y
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: YES
Signal Word: WARNING
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Section 1 - Product and Company Identification
NICKEL CHLORIDE
Product Identification: NICKEL CHLORIDE
Date of MSDS: 06/23/1999 Technical Review Date: 12/01/2000
FSC: 6810 NIIN: 00-726-9306
Submitter: D DG
Status Code: C
MFN: 01
Article: N
Kit Part: N
Manufacturer’s Information
Manufacturer’s Name: SPECTRUM CHEMICAL MFG. CORP.
Manufacturer’s Address1: 14422 SOUTH SAN PEDRO STREET
Manufacturer’s Address2: GARDENA, CA 90248-2027
Manufacturer’s Country: US
General Information Telephone: 310-516-8000
Emergency Telephone: 310-516-8000
Other Number for MSDS Information: CODE: N3250/ CATAGLO NO: N1050,N1051
Emergency Telephone: 310-516-8000
MSDS Preparer’s Name: G. A. BINAS
Chemtec Telephone: (800)424-9300
Proprietary: N
Reviewed: Y
Published: Y
CAGE: 63415
Item Description
Item Name: NICKEL CHLORIDE,HEXAHYDRATE,TECHNICAL
Item Manager:
Specification Number: NK
Type/Grade/Class: NK
Unit of Issue: BG Quantitative Expression: 00000000100LB
Unit of Issue Quantity: 1
Type of Container:
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Annex F
Contractor Information
Contractor’s Name: COMPTECH CORP
Contractor’s Address1: 15944 DERWOOD RD
Contractor’s Address2: ROCKVILLE, MD 20855
Contractor’s Telephone: 800-284-5279; 301-519-3401
Contract Number: SP0-450-01-M-322
Contractor’s CAGE: 0BR38
Contractor Information
Contractor’s Name: INDUSTRIAL CHEMICAL COMMODITIES INC
Contractor’s Address1: 15944 DERWOOD RD
Contractor’s Address2: ROCKVILLE, MD 20855
Contractor’s Telephone: 800-284-5279
Contract Number: SP0450-00-M-SH27
Contractor’s CAGE: 1ELU0
Contractor Information
Contractor’s Name: SPECTRUM CHEMICAL MFG. CORP.
Contractor’s Address1: 14422 SOUTH SAN PEDRO STREET
Contractor’s Address2: GARDENA, CA 90248-2027
Contractor’s Telephone: 310-516-8000
Contractor’s CAGE: 63415
Section 2 - Compositon/Information on Ingredients
NICKEL CHLORIDE
Ingredient Name: NICKEL(II) CHLORIDE HEXAHYDRATE
Ingredient CAS Number: 7791-20-0 Ingredient CAS Code: M
RTECS Number: QR6480000 RTECS Code: T
=WT: 100. =WT Code: M
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text:
% Enviromental Weight:
194 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Other REC Limits: 0.1 MG/M3 TWA
OSHA PEL: N/P OSHA PEL Code:
OSHA STEL: N/P OSHA STEL Code:
ACGIH TLV: N/P ACGIH TLV Code:
ACGIH STEL: N/P ACGIH STEL Code:
EPA Reporting Quantity:
DOT Reporting Quantity:
Ozone Depleting Chemical: N
Section 3 - Hazards Identification, Including Emergency Overview
NICKEL CHLORIDE
Health Hazards Acute & Chronic: ACUTE: VERY HAZARDOUS IN CASE OF SKIN CONTACT (IRRITANT,
SENSITIZER), EYE CONTACT (IRRITANT), INHALATION. SEVERE OVEREXPOSURE CAN RESULT IN
DEATH. CHRONIC:TOXIC TO KIDNEYS, LUNGS, NERVOUS SYSTEM & MUC OUS MEMBRANES. TARGET
ORGANS: KIDNEYS, LUNGS, NERVOUS SYSTEM AND MUCOUS MAMBRANES.
Signs & Symptoms of Overexposure:
IRRITATION OF EYES, SKIN AND RESPIRATORY SYSTEM. INFLAMMATION OF EYES IS
CHARACTERIZED BY REDNESS, WATERING AND ITCHING. SKIN: ITCHING, SCALING, REDDENING, OR
OCCASIONALLY BLISTERING.
Medical Conditions Aggravated by Exposure:
NONE PROVIDED BY MFR.
LD50 LC50 Mixture: ACUTE ORAL RAT: LD50< 157 MG/KG
Route of Entry Indicators:
Inhalation: N/P
Skin: N/P
Ingestion: N/P
Carcenogenicity Indicators
NTP: YES
IARC: YES
OSHA: YES
Carcinogenicity Explanation: CLASSFIED AS A1(CONFIRMED HUMAN CARCINOGEN) BY ACGIH, 1
(PROVEN FOR HUMAN) BY IARC, AND PROVEN BY OSHA. CALSSIFIED 2 (REASONABLEY
ANTICIPATED) BY NTP.
Section 4 - First Aid Measures
NICKEL CHLORIDE
First Aid:
EYE:REMOVE ANY CONTACT LENSES. IMMEDIATELY FLUSH EYES WITH RUNNING WATER FOR AT
LEAST 15 MINS KEEPING EYELIDS OPEN. DO NOT USE AN EYE OINTMENT. SEEK MEDICAL HELP. SKIN:
WASH IMMEDIATELY WITH SOAP & W ATER. CLEAN FOLDS, CREVICES, CREASES & GROIN. COVER
THE IRRITATED SKIN WITH AN EMOLLENT. IF IRRITATION PERSISTS, SEEK MEDICAL HELP.
INHALTION: REMOVE TO FRESH AIR. GET MEDICAL HELP. INGESTION: DO NOT INDUCE VOMITING. IF
NOT BREATHING, GIVE MOUTH TO MOUTH RESUSCITATION, GET MEDICAL HELP.
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Annex F
Section 5 - Fire Fighting Measures
NICKEL CHLORIDE
Fire Fighting Procedures:
NOT AVAILABLE
Unusual Fire or Explosion Hazard:
NOT AVAILABLE
Extinguishing Media:
NOT APPLICABLE
Flash Point: Flash Point Text: NOT APPLICABLE
Autoignition Temperature:
Autoignition Temperature Text: NOT AP
Lower Limit(s): NOT APPLICAB
Upper Limit(s): NOT APPLICAB
Section 6 - Accidental Release Measures
NICKEL CHLORIDE
Spill Release Procedures:
SM: USE APPROPRIATE TOOLS TO PUT THE SPILLED SOLID IN A CONVENIENT WASTE DISPOSAL
CONTAINER. LG: USE A SHOVEL TO PUT THE MAIERIAL INTO A CONVENIENT WAST DISPOSAL
CONTAINER. BE CAREFUL THAT THE PRODUCT IS NOT PRESENT AT A CONCENTRATION LEVEL
ABOVE TLV. CHECK TLV ON THE MSDS & WITH LOCAL AUTHORITIES.
Section 7 - Handling and Storage
NICKEL CHLORIDE
Handling and Storage Precautions:
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
NICKEL CHLORIDE
Repiratory Protection:
DUST RESPIRATOR. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR OR EQUIVALENT. A SELF
CONTAINED BREATHING APPARATUS SHOULD BE USED TO AVOID INHALATION OF THE PRODUCT.
Ventilation:
USE PORCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS
TO KEEP AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
Protective Gloves:
NONE PROVIDED BY MFR.
Eye Protection: SPLASH GOGGLES
Other Protective Equipment: LAB COAT, FULL SUIT, BOOTS, GLOVES
Work Hygenic Practices: NONE PROVIDED BY MFR.
Supplemental Health & Safety Information: NONE PROVIDED BY MFR.
Section 9 - Physical & Chemical Properties
NICKEL CHLORIDE
HCC: T4
NRC/State License Number:
Net Property Weight for Ammo:
Boiling Point: Boiling Point Text: NOT AVAILABLE
196 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Melting/Freezing Point: Melting/Freezing Text: SUBLIMES
Decomposition Point: Decomposition Text: NONE PROVIDED BY MFR.
Vapor Pressure: NOT APPLICABLE Vapor Density: NOT AVAILA
Percent Volatile Organic Content:
Specific Gravity: 3.6 (WATER=1)
Volatile Organic Content Pounds per Gallon:
pH: NOT AVAILABLE
Volatile Organic Content Grams per Liter:
Viscosity: NOT AVAILABLE
Evaporation Weight and Reference: NONE PROVIDED BY MFR.
Solubility in Water: SOLUBLE IN COLD WATER
Appearance and Odor: SOLID (DELIQUESCENT CRYSTALS SOLID), GREEN COLOR, NO ODOR INFO
AVAILABLE
Percent Volatiles by Volume: NONE PROVIDE
Corrosion Rate: NONE PROVIDED BY MFR
Section 10 - Stability & Reactivity Data
NICKEL CHLORIDE
Stability Indicator: YES
Materials to Avoid:
NOT AVAILABLE
Stability Condition to Avoid:
NOT AVAILABLE
Hazardous Decomposition Products:
NONE PROVIDED BY MFR.
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
NONE PROVIDED BY MFR.
Section 11 - Toxicological Information
NICKEL CHLORIDE
Toxicological Information:
ACUTE ORAL TOXICITY LD50 (RAT) = 157 MG/KG
Section 12 - Ecological Information
NICKEL CHLORIDE
Ecological Information:
ECOTOXICITY: NO INFORMATION AVAILABLE. PRODUCTS OF BIODEGRADATION: POSSIBLY
HAZARDOUS SHORT TERM DEGRADATION PRODUCTS ARE NOT LIKELY. HOWEVER, LONG TERM
DEGRADATION PRODUCTS MAY ARISE. TOXICITY OF THE BIODEGRADATION PRODUCTS: THE
PRODUCTS OF DEGRADATION ARE AS TOXIC AS THE ORIGINAL PRODUCT.
Section 13 - Disposal Considerations
NICKEL CHLORIDE
Waste Disposal Methods:
RECYCLE TO PROCESS, IF POSSIBLE. CONSULT YOUR LOCAL OR REGIONAL AUTHORITIES.
Section 14 - MSDS Transport Information
NICKEL CHLORIDE
Transport Information:
PSN: TOXIC SOLID, INORGANIC, N.O.S. (NICKEL CHLORIDE), 6.1, UN3288, III.
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Annex F
Section 15 - Regulatory Information
NICKEL CHLORIDE
SARA Title III Information:
SARA 313 TOXIC CHEMICAL NOTIFICATION AND RELEASE REPORTING: NICKEL CHLORIDE. CERCLA
HAZARDOUS SUBSTANCE: NICKEL CHLORIDE.
Federal Regulatory Information:
LISTED ON TSCA INVENTORY: NICKEL CHLORIDE.
State Regulatory Information:
CALIFORNIA PROP 65: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE CANCER, BIRTH DEFECTS, OR OTHER REPRODUCTIVE HARM. (CA HEALTH & SAFETY CODE
SEC 25249.6): NICKEL CHLORIDE . PENNSYLVANIA RTK AND MASSACHUSETTE RTK ; NICKEL
CHLORIDE.
Section 16 - Other Information
NICKEL CHLORIDE
Other Information:
N/P
HMIS Transportation Information
Product Identification: NICKEL CHLORIDE
Transporation ID Number: 154598
Responsible Party CAGE: 63415
Date MSDS Prepared: 06/23/1999
Date MSDS Reviewed: 09/01/2000
MFN: 09/01/2000
Submitter: D DG
Status Code: A
Container Information
Unit of Issue: BG
Container Quantity: 1
Type of Container:
Net Unit Weight: 100 LBS
Article without MSDS: N
Technical Entry NOS Shipping Number:
Radioactivity:
Form:
Net Explosive Weight: N/A
Coast Guard Ammunition Code:
Magnetism: N/A
AF MMAC Code:
DOD Exemption Number: N/A
Limited Quantity Indicator: N
Multiple Kit Number: 0
Kit Indicator: N
198 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Kit Part Indicator: N
Review Indicator: N
Additional Data:
PSN PER MSDS.
Department of Transportation Information
DOT Proper Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.
DOT PSN Code: QLW
Symbols: G
DOT PSN Modifier:
Hazard Class: 6.1
UN ID Number: UN3288
DOT Packaging Group: III
Label: KEEP AWAY FROM FOOD
Special Provision(s):
Packaging Exception: 153
Non Bulk Packaging: 213
Bulk Packaging: 240
Maximimum Quanity in Passenger Area: 100 KG
Maximimum Quanity in Cargo Area: 200 KG
Stow in Vessel Requirements: A
Requirements Water/Sp/Other:
IMO Detail Information
IMO Proper Shipping Name: TOXIC SOLID, INORGANIC, N.O.S. o
IMO PSN Code: OTQ
IMO PSN Modifier:
IMDG Page Number: 6270-6
UN Number: 3288
UN Hazard Class: 6.1
IMO Packaging Group: I/II/III
Subsidiary Risk Label: -
EMS Number: 6.1-04
Medical First Aid Guide Number: T
IATA Detail Information
IATA Proper Shipping Name: TOXIC SOLID, INORGANIC, N.O.S. *
IATA PSN Code: YJF
IATA PSN Modifier:
IATA UN Id Number: 3288
IATA UN Class: 6.1
Subsidiary Risk Class:
UN Packaging Group: III
IATA Label: TOXIC
Packaging Note for Passengers: 619
Maximum Quantity for Passengers: 100KG
Packaging Note for Cargo: 619
Maximum Quantity for Cargo: 200KG
Exceptions:
AFI Detail Information
AFI Proper Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.
AFI Symbols: *
AFI PSN Code: YHR
AFI PSN Modifier:
AFI UN Id Number: UN3288
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Annex F
AFI Hazard Class: 6.1
AFI Packing Group: III
AFI Label:
Special Provisions: P5
Back Pack Reference: A10.6
HAZCOM Label Information
Product Identification: NICKEL CHLORIDE
CAGE: 63415
Assigned Individual: N
Company Name: SPECTRUM CHEMICAL MFG. CORP.
Company PO Box:
Company Street Address1: 14422 SOUTH SAN PEDRO STREET
Company Street Address2: GARDENA, CA 90248-2027 US
Health Emergency Telephone: 310-516-8000
Label Required Indicator: Y
Date Label Reviewed: 09/01/2000
Status Code: A
Manufacturer’s Label Number:
Date of Label:
Year Procured: 2000
Organization Code: F
Chronic Hazard Indicator: Y
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: YES
Signal Word: DANGER
Health Hazard: Severe
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Section 1 - Product and Company Identification
POTASSIUM HYDROXIDE, 5%
Product Identification: POTASSIUM HYDROXIDE, 5%
Date of MSDS: 01/02/1998 Technical Review Date: 01/14/2000
FSC: NIIN: EMPTY
Submitter: D DG
Status Code: A
MFN: 01
Article: N
Kit Part: N
Manufacturer’s Information
Manufacturer’s Name: CAROLINA BIOLOGICAL SUPPLY
Manufacturer’s Address1: 2700 YORK RD
Manufacturer’s Address2: BURLINGTON, NC 27215-3387
Manufacturer’s Country: US
General Information Telephone: 800-227-1150/800-424-9300
Emergency Telephone: 800-227-1150
Emergency Telephone: 800-227-1150
Chemtec Telephone: (800)424-9300
Proprietary: N
Reviewed: Y
Published: Y
CAGE: 59896
200 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Contractor Information
Contractor’s Name: CAROLINA BIOLOGICAL SUPPLY CO
Contractor’s Address1: 2700 YORK RD
Contractor’s Address2: BURLINGTON, NC 27215-3387
Contractor’s Telephone: 800-227-1150/910-584-0381
Contract Number: MDA414-98-A-0118-0127
Contractor’s CAGE: 59896
Section 2 - Compositon/Information on Ingredients
POTASSIUM HYDROXIDE, 5%
Ingredient Name: POTASSIUM HYDROXIDE
Ingredient CAS Number: 1310-58-3 Ingredient CAS Code: T
RTECS Number: TT2100000 RTECS Code: T
=WT: 2. =WT Code: M
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text:
% Enviromental Weight:
Other REC Limits: N/P
OSHA PEL: N/P OSHA PEL Code:
OSHA STEL: N/P OSHA STEL Code:
ACGIH TLV: NOT ESTABLISHED ACGIH TLV Code: T
ACGIH STEL: C2 MG/M3 ACGIH STEL Code: T
EPA Reporting Quantity: 1000 LBS
DOT Reporting Quantity: 1000 LBS
Ozone Depleting Chemical: N
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Annex F
Section 3 - Hazards Identification, Including Emergency Overview
POTASSIUM HYDROXIDE, 5%
Health Hazards Acute & Chronic: TARGET ORGANS: ABDOMINAL PAIN. EYES-MAY CAUSE IRRITATION.
SKIN-MAY CAUSE IRRITATION. INGESTION-MAY CAUSE GASTROINTESTINAL DISCOMFORT.
INHALATION-MAY CAUSE IRRITATION TO RESPIRATORY TRACT.
Signs & Symptoms of Overexposure:
N/P
Medical Conditions Aggravated by Exposure:
N/A
LD50 LC50 Mixture: ORAL LD50(RAT): 365 MG (KOH) KG
Route of Entry Indicators:
Inhalation: YES
Skin: YES
Ingestion: YES
Carcenogenicity Indicators
NTP: N/P
IARC: N/P
OSHA: N/P
Carcinogenicity Explanation: N/P
Section 4 - First Aid Measures
POTASSIUM HYDROXIDE, 5%
First Aid:
EYES-FLUSH WITH WATER FOR 15 MINS, RAISING & LOWERING EYELIDS OCCASIONALLY. GET
MEDICAL AID IF IRRITATION PERSISTS. SKIN-THOROUGHLY WASH EXPOSED AREA FOR 15 MIN.
REMOVE CONTAMINATED CLOTHES. LAUNDER C ONTAMINATED CLOTHING BEFORE REUSE. GET
MEDICAL AID IF IRRITATION PERSISTS. INGESTION-IF SWALLOWED, IF CONSCIOUS, GIVE PLENTY OF
WATER. IMMEDIATELY CALL A PHYSICIAN OR POISON CONTROL CENTER. NEVER GIVE ANYTHING
BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION-REMOVE TO FRESH AIR. GIVE OXYGEN IF
BREATHING IS DIFFICULT; GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. KEEP
PERSON WARM, QUIET, & GET MEDICAL AID.
Section 5 - Fire Fighting Measures
POTASSIUM HYDROXIDE, 5%
Fire Fighting Procedures:
FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL FIRE FIGHTER’S
PROTECTIVE GEAR.
Unusual Fire or Explosion Hazard:
N/A
Extinguishing Media:
USE DRY CHEMICAL, CARBON DIOXIDE OR APPROPIATE FOAM.
Flash Point: Flash Point Text: N/P
Autoignition Temperature:
Autoignition Temperature Text: N/P
Lower Limit(s):
Upper Limit(s):
Section 6 - Accidental Release Measures
POTASSIUM HYDROXIDE, 5%
202 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Spill Release Procedures:
VENTILATE SPILL AREA. ELIMINATE ALL SOURCES OF IGNITION. REMOVE ALL NON0-ESSENTIAL
PERSONNEL FROM AREA. CLEAN-UP PERSONNEL SHOULD WEAR PROPER PERSONAL PROTECTIVE
GEAR. ABSORB MATERIAL WITH SUITABLE AB SORBANT AND CONTAINERIZE FOR DISPOSAL.
Section 7 - Handling and Storage
POTASSIUM HYDROXIDE, 5%
Handling and Storage Precautions:
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
POTASSIUM HYDROXIDE, 5%
Repiratory Protection:
A NIOSH/MSHA CHEMICAL CARTRIDGE RESPIRATOR SHOULD BE WORN IF PEL OR TLV IS EXCEEDED.
Ventilation:
LOCAL EXHAUST: YES. MECHANICAL (GENERAL): YES.
Protective Gloves:
RUBBER, NEOPRENE, PVC OR EQUIVALENT.
Eye Protection: SPLASH PROOF CHEMICAL SAFETY GOGGLES SHOULD BE WORN.
Other Protective Equipment: LAB COAT, EYE WASH, AND SAFETY SHOWER.
Work Hygenic Practices: N/P
Supplemental Health & Safety Information: N/P
Section 9 - Physical & Chemical Properties
POTASSIUM HYDROXIDE, 5%
HCC: B1
NRC/State License Number:
Net Property Weight for Ammo:
Boiling Point: =100.C, 212.F Boiling Point Text:
Melting/Freezing Point: =0.C, 32.F Melting/Freezing Text:
Decomposition Point: Decomposition Text: N/P
Vapor Pressure: N/P Vapor Density: N/P
Percent Volatile Organic Content:
Specific Gravity: N/P
Volatile Organic Content Pounds per Gallon:
pH: N/P
Volatile Organic Content Grams per Liter:
Viscosity: N/P
Evaporation Weight and Reference: N/P
Solubility in Water: MISCIBLE WITH WATER
Appearance and Odor: ODORLESS.
Percent Volatiles by Volume: N/P
Corrosion Rate: N/P
Section 10 - Stability & Reactivity Data
POTASSIUM HYDROXIDE, 5%
Stability Indicator: YES
Materials to Avoid:
MATERIAL DOES NOT POLYMERIZE, ACIDS.
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Annex F
Stability Condition to Avoid:
N/A
Hazardous Decomposition Products:
POTASSIUM OXIDE AT VERY HIGH TEMPERATURES.
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
WILL NOT OCCUR.
Section 11 - Toxicological Information
POTASSIUM HYDROXIDE, 5%
Toxicological Information:
SKIN-RABBIT 50 MG/24H SEVERE. MUTATION DATA REFERENCE CITED.
Section 12 - Ecological Information
POTASSIUM HYDROXIDE, 5%
Ecological Information:
NONE
Section 13 - Disposal Considerations
POTASSIUM HYDROXIDE, 5%
Waste Disposal Methods:
DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS.
ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE.
Section 14 - MSDS Transport Information
POTASSIUM HYDROXIDE, 5%
Transport Information:
POTASSIUM HYDROXIDE SOLUTION., 8, UN1814, II, CORROSIVE.
Section 15 - Regulatory Information
POTASSIUM HYDROXIDE, 5%
SARA Title III Information:
HAZARD CATEGORY FOR SARA SECTION 311/312 REPORTING: ACUTE.
Federal Regulatory Information:
ON TSCA INVENTORY. CERCLA SECTION 103: YES RQ 1000 LBS.
State Regulatory Information:
N/P
Section 16 - Other Information
POTASSIUM HYDROXIDE, 5%
Other Information:
******P/N 74-6614********
HMIS Transportation Information
Product Identification: POTASSIUM HYDROXIDE, 5%
Transporation ID Number: 151052
Responsible Party CAGE: 59896
Date MSDS Prepared: 01/02/1998
Date MSDS Reviewed: 01/14/2000
MFN: 01/14/2000
Submitter: D DG
Status Code: A
204 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Container Information
Unit of Issue: NK
Container Quantity: NK
Type of Container:
Net Unit Weight:
Article without MSDS: N
Technical Entry NOS Shipping Number:
Radioactivity:
Form:
Net Explosive Weight:
Coast Guard Ammunition Code:
Magnetism:
AF MMAC Code:
DOD Exemption Number: N/A
Limited Quantity Indicator: N
Multiple Kit Number: 0
Kit Indicator: N
Kit Part Indicator: N
Review Indicator: Y
Additional Data:
Department of Transportation Information
DOT Proper Shipping Name: POTASSIUM HYDROXIDE, SOLUTION
DOT PSN Code: LZO
Symbols:
DOT PSN Modifier:
Hazard Class: 8
UN ID Number: UN1814
DOT Packaging Group: II
Label: CORROSIVE
Special Provision(s): B2,T8
Packaging Exception: 154
Non Bulk Packaging: 202
Bulk Packaging: 242
Maximimum Quanity in Passenger Area: 1 L
Maximimum Quanity in Cargo Area: 30 L
Stow in Vessel Requirements: A
Requirements Water/Sp/Other:
IMO Detail Information
IMO Proper Shipping Name: POTASSIUM HYDROXIDE, SOLUTION
IMO PSN Code: MDV
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Annex F
IMO PSN Modifier:
IMDG Page Number: 8214
UN Number: 1814
UN Hazard Class: 8
IMO Packaging Group: II/III
Subsidiary Risk Label: -
EMS Number: 8-06
Medical First Aid Guide Number: 705
IATA Detail Information
IATA Proper Shipping Name: POTASSIUM HYDROXIDE SOLUTION
IATA PSN Code: UPY
IATA PSN Modifier:
IATA UN Id Number: 1814
IATA UN Class: 8
Subsidiary Risk Class:
UN Packaging Group: II
IATA Label: CORROSIVE
Packaging Note for Passengers: 809
Maximum Quantity for Passengers: 1L
Packaging Note for Cargo: 813
Maximum Quantity for Cargo: 30L
Exceptions: A3
AFI Detail Information
AFI Proper Shipping Name: POTASSIUM HYDROXIDE SOLUTION
AFI Symbols:
AFI PSN Code: UPY
AFI PSN Modifier:
AFI UN Id Number: UN1814
AFI Hazard Class: 8
AFI Packing Group: II
AFI Label:
Special Provisions: P5
Back Pack Reference: A12.3
HAZCOM Label Information
Product Identification: POTASSIUM HYDROXIDE, 5%
CAGE: 59896
Assigned Individual: N
Company Name: CAROLINA BIOLOGICAL SUPPLY CO
Company PO Box:
Company Street Address1: 2700 YORK RD
Company Street Address2: BURLINGTON, NC 27215-3387 US
Health Emergency Telephone: 800-227-1150
Label Required Indicator: Y
Date Label Reviewed: 01/14/2000
Status Code: A
Manufacturer’s Label Number:
Date of Label:
Year Procured: N/K
Organization Code: F
Chronic Hazard Indicator: Y
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: YES
Signal Word: WARNING
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: Slight
206 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Section 1 - Product and Company Identification
P6142 POTASSIUM PERMANGANATE
Product Identification: P6142 POTASSIUM PERMANGANATE
Date of MSDS: 09/29/1989 Technical Review Date: 07/19/1990
FSC: 6505 NIIN: 00-935-6568
Submitter: D DG
Status Code: C
MFN: 01
Article: N
Kit Part: N
Manufacturer’s Information
Manufacturer’s Name: SIGMA CHEMICAL COMPANY
Post Office Box: 14508
Manufacturer’s Address1:
Manufacturer’s Address2: ST. LOUIS, MO 63178
Manufacturer’s Country: NK
General Information Telephone: 800-325-8070
Emergency Telephone: 314-771-5765
Emergency Telephone: 314-771-5765
MSDS Preparer’s Name: N/P
Proprietary: N
Reviewed: Y
Published: Y
CAGE: 21076
Special Project Code: N
Item Description
Item Name:
Item Manager: S9M
Specification Number: O-C-275D
Type/Grade/Class: NK
Unit of Issue: BT
Unit of Issue Quantity: B
Type of Container: BOTTLE
Contractor Information
Contractor’s Name: SIGMA CHEMICAL COMPANY
Contractor’s Address1: 3050 SPRUCE ST
Contractor’s Address2: ST LOUIS, MO 63178
Contractor’s Telephone: 314-771-5765
Contractor’s CAGE: 21076
Section 2 - Compositon/Information on Ingredients
P6142 POTASSIUM PERMANGANATE
Ingredient Name: POTASSIUM PERMANGANATE (SARA III)
Ingredient CAS Number: 7722-64-7 Ingredient CAS Code: M
RTECS Number: SD6475000 RTECS Code: M
=WT: =WT Code:
=Volume: =Volume Code:
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>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text: 100
% Enviromental Weight:
Other REC Limits: NOT ESTABLISHED
OSHA PEL: 5 MG MN/M3;CEILING OSHA PEL Code: M
OSHA STEL: OSHA STEL Code:
ACGIH TLV: 5 MG MN/M3; 9192 ACGIH TLV Code: M
ACGIH STEL: N/P ACGIH STEL Code:
EPA Reporting Quantity: 100 LBS
DOT Reporting Quantity: 100 LBS
Ozone Depleting Chemical: N
Section 3 - Hazards Identification, Including Emergency Overview
P6142 POTASSIUM PERMANGANATE
Health Hazards Acute & Chronic: HARMFUL IF SWALLOWED,INHALED,OR ABSORBED THROUGH
SKIN.MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT,EYES AND SKIN.OVEREXPOSURE CAN RESULT IN ANEMIA,SW ELLING OF THE
THROAT WITH THE POSSIBILITY OF SUFFOCATION AND KIDNEY DAMAGE.INHALATION MAY BE
FATAL.
Signs & Symptoms of Overexposure:
SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING, WHEEZING,
LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND VOMITING.
Medical Conditions Aggravated by Exposure:
PERSONS WITH A HISTORY OF SKIN AND RESPIRATORY DISORDERS MAY BE AT INCREASED RISK
FROM EXPOSURE.
LD50 LC50 Mixture: LD50 (ORAL RAT) IS 1090 MG/KG
Route of Entry Indicators:
Inhalation: YES
208 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Skin: YES
Ingestion: YES
Carcenogenicity Indicators
NTP: NO
IARC: NO
OSHA: NO
Carcinogenicity Explanation: THIS PRODUCT IS NOT LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN.
Section 4 - First Aid Measures
P6142 POTASSIUM PERMANGANATE
First Aid:
EYES:IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
SKIN:IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES. INHALATION:REMOVE TO FRES H AIR.IF NOT BREATHING GIVE ARTICIAL
RESPIRATION.IF BREATHING IS DIFFICULT,GIVE OXYGEN.SEE DOCTOR.
Section 5 - Fire Fighting Measures
P6142 POTASSIUM PERMANGANATE
Fire Fighting Procedures:
FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN
FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire or Explosion Hazard:
FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS.
CONTACT WITH OTHER MATERIALS MAY CAUSE FIRE.
Extinguishing Media:
WATER SPRAY.
Flash Point: Flash Point Text: N/R
Autoignition Temperature:
Autoignition Temperature Text: N/R
Lower Limit(s): N/R
Upper Limit(s): N/R
Section 6 - Accidental Release Measures
P6142 POTASSIUM PERMANGANATE
Spill Release Procedures:
EVACUATE AREA.SHUT OFF IGNITION SOURCES.VENTILATE.WEAR SCBA,RUBBER BOOTS AND HEAVY
RUBBER GLOVES.COVER WITH DRY-LIME,SAND OR SODA ASH.PLACE IN COVERED CONTAINERS
USING NON-SPARKING TOOLS AND TRANSPORT OUTDOORS.WASH AREA WITH LARGE AMOUNTS OF
WATER.
Section 7 - Handling and Storage
P6142 POTASSIUM PERMANGANATE
Handling and Storage Precautions:
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
P6142 POTASSIUM PERMANGANATE
Repiratory Protection:
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Annex F
USE NIOSH/MSHA APPROVED RESPIRATOR AS PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/
WARNINGS AND NIOSH-RESPIRATOR SELECTION.
Ventilation:
USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:
RUBBER
Eye Protection: CHEMICAL SAFETY GOGGLES
Other Protective Equipment: SAFETY SHOWER AND EYE BATH. OTHER EQUIPMENT AS REQUIRED TO
MINIMIZE EXPOSURE FROM PROLONGED OR REPEATED CONTACT.
Work Hygenic Practices: WASH THROUGHLY AFTER HANDLING AND BEFORE EATING.LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE.DISCARD CONTAMINATED SHOES.
Supplemental Health & Safety Information: SEE CASE HISTORY 90200A FOR MORE INFORMATION ON
WASTE DISPOSAL PROCEDURES AND ON INCOMPATIBLE MATERIALS THAT MAY RESULT IN IGNITION,
INCREASED SENSITIVITY TO HEAT OR FRICTION, VIOLENT REACTIONS, OR EX PLOSIONS.-THIS
PRODUCT CAUSES EFFECTS ON MALE FERTILITY.-
Section 9 - Physical & Chemical Properties
P6142 POTASSIUM PERMANGANATE
HCC: D1
NRC/State License Number:
Net Property Weight for Ammo:
Boiling Point: Boiling Point Text: N/R
Melting/Freezing Point: Melting/Freezing Text: UNKNOWN
Decomposition Point: Decomposition Text: UNKNOWN
Vapor Pressure: N/R Vapor Density: N/R
Percent Volatile Organic Content:
Specific Gravity: 2.703
Volatile Organic Content Pounds per Gallon:
pH: N/R
Volatile Organic Content Grams per Liter:
Viscosity: N/P
Evaporation Weight and Reference: N/R
Solubility in Water: COMPLETE
Appearance and Odor: BLACK OR DEEP PURPLE CRYSTALS
Percent Volatiles by Volume: N/R
Corrosion Rate: UNKNOWN
Section 10 - Stability & Reactivity Data
P6142 POTASSIUM PERMANGANATE
Stability Indicator: YES
Materials to Avoid:
STRONG REDUCING AGENTS,FINELY POWDERED
METALS,PEROXIDES,ALUMINUM,ZINC,LEAD,COPPER,AND THEIR ALLOYS.
Stability Condition to Avoid:
HIGH TEMPERATURES, OPEN FLAMES.
Hazardous Decomposition Products:
NATURE OF DECOMPOSITION PRODUCTS NOT KNOWN.
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
NOT APPLICABLE
Section 11 - Toxicological Information
P6142 POTASSIUM PERMANGANATE
Toxicological Information:
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N/P
Section 12 - Ecological Information
P6142 POTASSIUM PERMANGANATE
Ecological Information:
N/P
Section 13 - Disposal Considerations
P6142 POTASSIUM PERMANGANATE
Waste Disposal Methods:
CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER. A SPECIAL PRECIPITATION PROCEDURE MUST BE
FOLLOWED PRIOR TO DISPOSAL. FOLLOW MANUFACTURER’S INSTRUCTIONS. DISPOSE OF IN
ACCORDANCE WITH ALL APPLICABLE FEDERAL , STATE AND LOCAL LAWS AND REGULATIONS.
Section 14 - MSDS Transport Information
P6142 POTASSIUM PERMANGANATE
Transport Information:
N/P
Section 15 - Regulatory Information
P6142 POTASSIUM PERMANGANATE
SARA Title III Information:
N/P
Federal Regulatory Information:
N/P
State Regulatory Information:
N/P
Section 16 - Other Information
P6142 POTASSIUM PERMANGANATE
Other Information:
N/P
HMIS Transportation Information
Product Identification: P6142 POTASSIUM PERMANGANATE
Transporation ID Number: 93340
Responsible Party CAGE: 21076
Date MSDS Prepared: 09/29/1989
Date MSDS Reviewed: 07/19/1990
MFN: 07/19/1990
Submitter: D DG
Status Code: C
Container Information
Unit of Issue: BT
Container Quantity: B
Type of Container: BOTTLE
Net Unit Weight: 0.3 GM
Article without MSDS: N
Technical Entry NOS Shipping Number:
Radioactivity:
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Annex F
Form:
Net Explosive Weight:
Coast Guard Ammunition Code:
Magnetism: N/P
AF MMAC Code:
DOD Exemption Number:
Limited Quantity Indicator:
Multiple Kit Number: 0
Kit Indicator: N
Kit Part Indicator: N
Review Indicator: Y
Additional Data:
Department of Transportation Information
DOT Proper Shipping Name: POTASSIUM PERMANGANATE
DOT PSN Code: MAU
Symbols:
DOT PSN Modifier:
Hazard Class: 5.1
UN ID Number: UN1490
DOT Packaging Group: II
Label: OXIDIZER
Special Provision(s): B12
Packaging Exception: 152
Non Bulk Packaging: 212
Bulk Packaging: 240
Maximimum Quanity in Passenger Area: 5 KG
Maximimum Quanity in Cargo Area: 25 KG
Stow in Vessel Requirements: D
Requirements Water/Sp/Other: 56,58,69,106,107
IMO Detail Information
IMO Proper Shipping Name: POTASSIUM PERMANGANATE
IMO PSN Code: MFN
IMO PSN Modifier:
IMDG Page Number: 5173
UN Number: 1490
UN Hazard Class: 5.1
IMO Packaging Group: II
Subsidiary Risk Label: -
EMS Number: 5.1-06
Medical First Aid Guide Number: 715
IATA Detail Information
IATA Proper Shipping Name: POTASSIUM PERMANGANATE
IATA PSN Code: URW
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Annex F
IATA PSN Modifier:
IATA UN Id Number: 1490
IATA UN Class: 5.1
Subsidiary Risk Class:
UN Packaging Group: II
IATA Label: OXIDIZER
Packaging Note for Passengers: 508
Maximum Quantity for Passengers: 5KG
Packaging Note for Cargo: 511
Maximum Quantity for Cargo: 25KG
Exceptions:
AFI Detail Information
AFI Proper Shipping Name: POTASSIUM PERMANGANATE
AFI Symbols:
AFI PSN Code: URW
AFI PSN Modifier:
AFI UN Id Number: UN1490
AFI Hazard Class: 5.1
AFI Packing Group: II
AFI Label:
Special Provisions: P5
Back Pack Reference: A9.8
HAZCOM Label Information
Product Identification: P6142 POTASSIUM PERMANGANATE
CAGE: 21076
Assigned Individual: N
Company Name: SIGMA CHEMICAL COMPANY
Company PO Box:
Company Street Address1: 3050 SPRUCE ST
Company Street Address2: ST LOUIS, MO 63178 US
Health Emergency Telephone: 314-771-5765
Label Required Indicator: Y
Date Label Reviewed: 07/18/1990
Status Code: C
Manufacturer’s Label Number: NONE
Date of Label: 07/18/1990
Year Procured: N/K
Organization Code: F
Chronic Hazard Indicator: Y
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: YES
Signal Word: DANGER
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: Severe
Section 1 - Product and Company Identification
RESORCINOL, 3366
Product Identification: RESORCINOL, 3366
Date of MSDS: 03/09/1992 Technical Review Date: 09/29/1995
FSC: 6810 NIIN: LIIN: 00N046932
Submitter: N EN
Status Code: C
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Annex F
MFN: 01
Article: N
Kit Part: N
Manufacturer’s Information
Manufacturer’s Name: J T BAKER INC
Manufacturer’s Address1: 222 RED SCHOOL LANE
Manufacturer’s Address2: PHILLIPSBURG, NJ 08865
Manufacturer’s Country: US
General Information Telephone: 800-582-2537
Emergency Telephone: 800-424-8802;800-424-9300(CHEMTREC)
Emergency Telephone: 800-424-8802;800-424-9300(CHEMTREC)
MSDS Preparer’s Name: N/P
Proprietary: N
Reviewed: N
Published: Y
CAGE: DO803
Special Project Code: N
Contractor Information
Contractor’s Name: J T BAKER INC
Post Office Box: N/K
Contractor’s Address1: 222 RED SCHOOL LANE
Contractor’s Address2: PHILLIPSBURG, NJ 08865
Contractor’s Telephone: 1-800-582-2537
Contractor’s CAGE: DO803
Contractor Information
Contractor’s Name: MALLINCKRODT BAKER, INC. (FORMERLY J.T. BAKER INC)
Contractor’s Address1: 222 RED SCHOOL LANE
Contractor’s Address2: PHILLIPSBURG, NJ 08865-2219
Contractor’s Telephone: 800-582-2537
Contractor’s CAGE: 70829
Section 2 - Compositon/Information on Ingredients
RESORCINOL, 3366
Ingredient Name: RESORCINOL
Ingredient CAS Number: 108-46-3 Ingredient CAS Code: M
RTECS Number: VG9625000 RTECS Code: M
=WT: =WT Code:
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
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Annex F
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text: 90-100
% Enviromental Weight:
Other REC Limits: N/K
OSHA PEL: 10 PPM;20 STEL OSHA PEL Code: M
OSHA STEL: OSHA STEL Code:
ACGIH TLV: 10 PPM;20 STEL ACGIH TLV Code: M
ACGIH STEL: N/P ACGIH STEL Code:
EPA Reporting Quantity: 5000 LBS
DOT Reporting Quantity: 5000 LBS
Ozone Depleting Chemical: N
Section 3 - Hazards Identification, Including Emergency Overview
RESORCINOL, 3366
Health Hazards Acute & Chronic: ACUTE: INHAL: HEADACHE, COUGHING, DIZZINESS, DIFFICULT
BREATHING. SKIN/EYE/SKIN ABSORP: NONE IDENTIFIED. INGEST: NONE IDENTIFIED. CHRONIC: NONE
IDENTIFIED.
Signs & Symptoms of Overexposure:
SEE HEALTH HAZARDS.
Medical Conditions Aggravated by Exposure:
NONE INDICATED.
LD50 LC50 Mixture: LD50(ORAL,RAT)301 MG/KG
Route of Entry Indicators:
Inhalation: YES
Skin: NO
Ingestion: NO
Carcenogenicity Indicators
NTP: NO
IARC: NO
OSHA: NO
Carcinogenicity Explanation: NOT RELEVANT
Section 4 - First Aid Measures
RESORCINOL, 3366
First Aid:
INGEST: CALL A PHYS. IF SWALLOWED, IF CONSCIOUS, IMMED INDUCE VOMIT. INHAL: REMOVE TO
FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. SKIN: IMMED FLUSH
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Annex F
W/PLENTY OF WATER FOR @ LST 15 MIN. EYE: IMMED FLUSH WITH PLENTY OF WATER FOR AT LEAST
15 MINUTES.
Section 5 - Fire Fighting Measures
RESORCINOL, 3366
Fire Fighting Procedures:
NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP (FP N). MOVE CONTRS FROM FIRE AREA IF IT CAN BE
DONE W/OUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTRS COOL.
Unusual Fire or Explosion Hazard:
NONE IDENTIFIED.
Extinguishing Media:
USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE. (WATER MAY BE INEFFECTIVE).
Flash Point: Flash Point Text: NOT APPLICABLE
Autoignition Temperature:
Autoignition Temperature Text: N/A
Lower Limit(s): N/A
Upper Limit(s): N/A
Section 6 - Accidental Release Measures
RESORCINOL, 3366
Spill Release Procedures:
WEAR NIOSH/MSHA APPRVD SCBA AND FULL PROT EQUIP. SHUT OFF IGNIT SOURCES; NO FLARES,
SMOKING, OR FLAMES IN AREA. W/ CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY
CONTAINER & COVER; REMOVE FROM AREA. FLUSH SPILL AREA W/WATER.
Section 7 - Handling and Storage
RESORCINOL, 3366
Handling and Storage Precautions:
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
RESORCINOL, 3366
Repiratory Protection:
RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT
CONCENTRATIONS ABOVE 10 PPM, A NIOSH/MSHA APPROVED SCBA IS ADVISED.
Ventilation:
USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS.
Protective Gloves:
RUBBER GLOVES.
Eye Protection: SAFETY GOGGLES.
Other Protective Equipment: UNIFORM. LAB COAT.
Work Hygenic Practices: WASH THOROUGHLY AFTER HANDLING.
Supplemental Health & Safety Information: NONE SPECIFIED BY MANUFACTURER.
Section 9 - Physical & Chemical Properties
RESORCINOL, 3366
HCC: N1
NRC/State License Number:
216 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Net Property Weight for Ammo:
Boiling Point: Boiling Point Text: 537F,281C
Melting/Freezing Point: Melting/Freezing Text: 232F,111C
Decomposition Point: Decomposition Text: N/K
Vapor Pressure: N/A Vapor Density: 3.8
Percent Volatile Organic Content:
Specific Gravity: 1.27(H2O=1)
Volatile Organic Content Pounds per Gallon:
pH: N/A
Volatile Organic Content Grams per Liter:
Viscosity: N/P
Evaporation Weight and Reference: NOT APPLICABLE
Solubility in Water: COMPLETE(100%)
Appearance and Odor: WHITE CRYSTALS OR POWDER
Percent Volatiles by Volume: N/A
Corrosion Rate: N/K
Section 10 - Stability & Reactivity Data
RESORCINOL, 3366
Stability Indicator: YES
Materials to Avoid:
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:
HEAT, FLAME, SOURCES OF IGNITION.
Hazardous Decomposition Products:
NONE IDENTIFIED.
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
NOT RELEVANT
Section 11 - Toxicological Information
RESORCINOL, 3366
Toxicological Information:
N/P
Section 12 - Ecological Information
RESORCINOL, 3366
Ecological Information:
N/P
Section 13 - Disposal Considerations
RESORCINOL, 3366
Waste Disposal Methods:
DISPOSE I/A/W ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS.
Section 14 - MSDS Transport Information
RESORCINOL, 3366
Transport Information:
N/P
Section 15 - Regulatory Information
RESORCINOL, 3366
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Annex F
SARA Title III Information:
N/P
Federal Regulatory Information:
N/P
State Regulatory Information:
N/P
Section 16 - Other Information
RESORCINOL, 3366
Other Information:
N/P
HAZCOM Label Information
Product Identification: RESORCINOL, 3366
CAGE: DO803
Assigned Individual: Y
Company Name: J T BAKER INC
Company PO Box: N/K
Company Street Address1: 222 RED SCHOOL LANE
Company Street Address2: PHILLIPSBURG, NJ 08865 US
Health Emergency Telephone: 800-424-8802;800-424-9300(CHEMTREC)
Label Required Indicator: Y
Date Label Reviewed: 12/30/1993
Status Code: C
Manufacturer’s Label Number:
Date of Label: 12/30/1993
Year Procured: N/K
Organization Code: G
Chronic Hazard Indicator: N
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: YES
Signal Word: CAUTION
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Section 1 - Product and Company Identification
SILVER CHROMATE, 99%, 22789-7
Product Identification: SILVER CHROMATE, 99%, 22789-7
Date of MSDS: 05/29/1990 Technical Review Date: 03/28/1991
FSC: 6810 NIIN: LIIN: 00N014624
Submitter: N EN
Status Code: C
MFN: 01
Article: N
Kit Part: N
Manufacturer’s Information
Manufacturer’s Name: ALDRICH CHEMICAL CO
Post Office Box: 355
Manufacturer’s Address1:
Manufacturer’s Address2: MILWAUKEE, WI 53201
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Annex F
Manufacturer’s Country: US
General Information Telephone: 414-273-3850
Emergency Telephone: N/P
Emergency Telephone: N/P
MSDS Preparer’s Name: N/P
Proprietary: N
Reviewed: N
Published: Y
CAGE: 60928
Special Project Code: N
Contractor Information
Contractor’s Name: ALDRICH CHEMICAL CO INC
Post Office Box: 355
Contractor’s Address1: 1001 WEST ST PAUL AVE
Contractor’s Address2: MILWAUKEE, WI 53233
Contractor’s Telephone: 414-273-3850
Contractor’s CAGE: 60928
Section 2 - Compositon/Information on Ingredients
SILVER CHROMATE, 99%, 22789-7
Ingredient Name: SILVER CHROMATE, 99%
Ingredient CAS Number: 7784-01-2 Ingredient CAS Code: M
RTECS Number: RTECS Code: X
=WT: =WT Code:
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text: 99
% Enviromental Weight:
Other REC Limits: N/K
OSHA PEL: NOT APPLICABLE OSHA PEL Code: M
OSHA STEL: OSHA STEL Code:
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Annex F
ACGIH TLV: NOT APPLICABLE ACGIH TLV Code: M
ACGIH STEL: N/P ACGIH STEL Code:
EPA Reporting Quantity:
DOT Reporting Quantity:
Ozone Depleting Chemical: N
Section 3 - Hazards Identification, Including Emergency Overview
SILVER CHROMATE, 99%, 22789-7
Health Hazards Acute & Chronic: ACUTE: HARMFUL IF INGEST, INHAL, OR ABSORBED THRU SKIN.
CAUSES EYE & SKIN IRRITS. MATL IS IRRIT TO MUC MEMBS & UPPER RESP TRACT. MAY CAUSE
ARGYRIA (SLATE-GRAY OR BLUISH DISCOLORATION OF SKIN & DEEP TI SSUES DUE TO DEPOSIT OF
INSOLUBLE ALBUMINATE OF SILVER). CHRONIC:CARCINOGEN. MAY ALTER GENETIC MATL. (SEE
SUPP DATA)
Signs & Symptoms of Overexposure:
NONE SPECIFIED BY MANUFACTURER.
Medical Conditions Aggravated by Exposure:
NONE SPECIFIED BY MANUFACTURER.
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route of Entry Indicators:
Inhalation: YES
Skin: YES
Ingestion: YES
Carcenogenicity Indicators
NTP: NO
IARC: YES
OSHA: NO
Carcinogenicity Explanation: IARC GROUP 1
Section 4 - First Aid Measures
SILVER CHROMATE, 99%, 22789-7
First Aid:
EYES:FLUSH W/COPIOUS AMTS OF H*2O FOR AT LEAST 15 MIN. GET MD. SKIN:FLUSH W/COPIOUS
AMTS OF H*2O FOR AT LEAST 15 MIN WHILE REMOVING CONTAM CLTHNG & SHOES. DISCARD
CONTAM CLTHNG & SHOES. GET MD. INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE
O*2/ARTF RESP). GET MD. INGEST:CALL MD IMMEDIATELY (FP N).
Section 5 - Fire Fighting Measures
SILVER CHROMATE, 99%, 22789-7
Fire Fighting Procedures:
WEAR NIOSH/MSHA APPROVED SCBA & PROTECTIVE CLOTHING TO PREVENT CONTACT W/SKIN &
EYES. OXIDIZER.
Unusual Fire or Explosion Hazard:
EMITS TOXIC FUMES UNDER FIRE CONDITIONS. CONTACT W/OTHER MATLS MAY CAUSE FIRE.
Extinguishing Media:
NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Flash Point: Flash Point Text: NONE
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Annex F
Autoignition Temperature:
Autoignition Temperature Text: N/A
Lower Limit(s): N/K
Upper Limit(s): N/K
Section 6 - Accidental Release Measures
SILVER CHROMATE, 99%, 22789-7
Spill Release Procedures:
EVACUATE AREA. WEAR NIOSH/MSHA APPROVED SCBA, RUB BOOTS & HVY RUB GLOVES. WEAR
DISPOSABLE COVERALLS & DISCARD AFTER USE. SWEEP UP, PLACE IN BAG & HOLD FOR WASTE
DISPOSAL. AVOID RAISING DUST. VENT AREA & WASH SPILL SITE AFT MATL PICKUP IS COMPLETE.
Section 7 - Handling and Storage
SILVER CHROMATE, 99%, 22789-7
Handling and Storage Precautions:
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
SILVER CHROMATE, 99%, 22789-7
Repiratory Protection:
WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:
USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:
CHEMICAL-RESISTANT GLOVES.
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: PROTECTIVE CLOTHING. SAFETY SHOWER & EYE BATH.
Work Hygenic Practices: WASH THOROUGHLY AFTER USE & BEFORE EATING, DRINKING, SMOKING, OR
USING SANITARY FACILITIES (FP N).
Supplemental Health & Safety Information: HLTH HAZ:TARGET ORGAN(S):LUNGS & KIDNEYS.
Section 9 - Physical & Chemical Properties
SILVER CHROMATE, 99%, 22789-7
HCC: N1
NRC/State License Number:
Net Property Weight for Ammo:
Boiling Point: Boiling Point Text: N/K
Melting/Freezing Point: Melting/Freezing Text: N/K
Decomposition Point: Decomposition Text: N/K
Vapor Pressure: N/K Vapor Density: N/K
Percent Volatile Organic Content:
Specific Gravity: 5.625
Volatile Organic Content Pounds per Gallon:
pH: N/K
Volatile Organic Content Grams per Liter:
Viscosity: N/P
Evaporation Weight and Reference: N/K
Solubility in Water: N/K
Appearance and Odor: BLACK POWDER
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Annex F
Percent Volatiles by Volume: N/K
Corrosion Rate: N/K
Section 10 - Stability & Reactivity Data
SILVER CHROMATE, 99%, 22789-7
Stability Indicator: N/P
Materials to Avoid:
STRONG REDUCING AGENTS. ALCOHOLS. STRONG ACIDS.
Stability Condition to Avoid:
MAY DECOMPOSE ON EXPOSURE TO LIGHT.
Hazardous Decomposition Products:
NONE SPECIFIED BY MANUFACTURER.
Hazardous Polymerization Indicator: N/P
Conditions to Avoid Polymerization:
NONE SPECIFIED BY MANUFACTURER.
Section 11 - Toxicological Information
SILVER CHROMATE, 99%, 22789-7
Toxicological Information:
N/P
Section 12 - Ecological Information
SILVER CHROMATE, 99%, 22789-7
Ecological Information:
N/P
Section 13 - Disposal Considerations
SILVER CHROMATE, 99%, 22789-7
Waste Disposal Methods:
CATALYSTS & EXPENSIVE METALS SHOULD BE RECOVERED FOR REUSE OR RECYCLING. OBSERVE
ALL FEDERAL, STATE, AND LOCAL LAWS.
Section 14 - MSDS Transport Information
SILVER CHROMATE, 99%, 22789-7
Transport Information:
N/P
Section 15 - Regulatory Information
SILVER CHROMATE, 99%, 22789-7
SARA Title III Information:
N/P
Federal Regulatory Information:
N/P
State Regulatory Information:
N/P
Section 16 - Other Information
SILVER CHROMATE, 99%, 22789-7
Other Information:
N/P
222 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
HMIS Transportation Information
Product Identification: SILVER CHROMATE, 99%, 22789-7
Transporation ID Number: 19853
Responsible Party CAGE: 60928
Date MSDS Prepared: 05/29/1990
Date MSDS Reviewed: 08/09/1991
MFN: 08/09/1991
Submitter: N TN
Status Code: C
Container Information
Unit of Issue: NK
Container Quantity: NK
Type of Container:
Net Unit Weight:
Article without MSDS: N
Technical Entry NOS Shipping Number:
Radioactivity:
Form:
Net Explosive Weight:
Coast Guard Ammunition Code:
Magnetism: N/P
AF MMAC Code:
DOD Exemption Number:
Limited Quantity Indicator:
Multiple Kit Number: 0
Kit Indicator: N
Kit Part Indicator: N
Review Indicator: Y
Additional Data:
Department of Transportation Information
DOT Proper Shipping Name: TEAR GAS SUBSTANCES, SOLID, N.O.S.
DOT PSN Code: NWS
Symbols: G
DOT PSN Modifier:
Hazard Class: 6.1
UN ID Number: UN1693
DOT Packaging Group: II
Label: POISON
Special Provision(s):
Packaging Exception:
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Annex F
Non Bulk Packaging: 212
Bulk Packaging: NONE
Maximimum Quanity in Passenger Area: FORBIDDEN
Maximimum Quanity in Cargo Area: 25 KG
Stow in Vessel Requirements: D
Requirements Water/Sp/Other: 40
IMO Detail Information
IMO Proper Shipping Name: TEAR GAS SUBSTANCE, SOLID, N.O.S. o
IMO PSN Code: OII
IMO PSN Modifier:
IMDG Page Number: 6262
UN Number: 1693
UN Hazard Class: 6.1
IMO Packaging Group: I/II
Subsidiary Risk Label: -
EMS Number: 6.1-03
Medical First Aid Guide Number: 740
IATA Detail Information
IATA Proper Shipping Name: TEAR GAS SUBSTANCE, SOLID, N.O.S. *
IATA PSN Code: XNK
IATA PSN Modifier:
IATA UN Id Number: 1693
IATA UN Class: 6.1
Subsidiary Risk Class:
UN Packaging Group: II
IATA Label: TOXIC
Packaging Note for Passengers: FORB
Maximum Quantity for Passengers: FORB
Packaging Note for Cargo: 615
Maximum Quantity for Cargo: 25 KG
Exceptions: A36
AFI Detail Information
AFI Proper Shipping Name: TEAR GAS SUBSTANCES, SOLID, N.O.S.
AFI Symbols: *
AFI PSN Code: XNK
AFI PSN Modifier:
AFI UN Id Number: UN1693
AFI Hazard Class: 6.1
AFI Packing Group: II
AFI Label:
Special Provisions: P5
Back Pack Reference: A10.6
HAZCOM Label Information
Product Identification: SILVER CHROMATE, 99%, 22789-7
CAGE: 60928
Assigned Individual: N
Company Name: ALDRICH CHEMICAL CO INC
Company PO Box: 355
Company Street Address1: 1001 WEST ST PAUL AVE
Company Street Address2: MILWAUKEE, WI 53233 US
Health Emergency Telephone:
Label Required Indicator: Y
Date Label Reviewed: 06/07/1991
Status Code: C
Manufacturer’s Label Number:
Date of Label: 06/07/1991
Year Procured: N/K
224 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Organization Code: G
Chronic Hazard Indicator: Y
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: YES
Signal Word: WARNING
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Section 1 - Product and Company Identification
SODIUM FLUORIDE
Product Identification: SODIUM FLUORIDE
Date of MSDS: 09/11/1996 Technical Review Date: 05/01/1998
FSC: 6810 NIIN: 00-871-0551
Submitter: D DG
Status Code: C
MFN: 01
Article: N
Kit Part: N
Manufacturer’s Information
Manufacturer’s Name: ANACHEMIA CANADA INC
Manufacturer’s Address1: 500 2ND AVE
Manufacturer’s Address2: VILLE ST. PIERRE QUE CAN H8R 1M3, NK 00000
Manufacturer’s Country: CN
General Information Telephone: 514-489-5711
Emergency Telephone: 514-489-5711
Emergency Telephone: 514-489-5711
MSDS Preparer’s Name: UNKNOWN
Proprietary: N
Reviewed: Y
Published: Y
CAGE: 36842
Special Project Code: N
Item Description
Item Name: SODIUM FLUORIDE,ACS
Item Manager:
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue:
Unit of Issue Quantity:
Type of Container: DRUM
Contractor Information
Contractor’s Name: ANACHEMIA CANADA
Contractor’s Address1: 255 NORMAN H8R 1A3
Contractor’s Address2: VILLE ST. PIERRE (MONTREAL), PQ 00000
Contractor’s Telephone: 514-489-5711;518-297-4444
Contractor’s CAGE: 36842
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Annex F
Contractor Information
Contractor’s Name: CHEM SCIENTIFIC INC
Contractor’s Address1: 1250 WASHINGTON ST
Contractor’s Address2: NORWOOD, MA 02062
Contractor’s Telephone: 781-440-0900
Contractor’s CAGE: 0X801
Section 2 - Compositon/Information on Ingredients
SODIUM FLUORIDE
Ingredient Name: SODIUM FLUORIDE (CERCLA)
Ingredient CAS Number: 7681-49-4 Ingredient CAS Code: M
RTECS Number: WB0350000 RTECS Code: M
=WT: =WT Code:
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text: 60- 100
% Enviromental Weight:
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 2.5 PPM (F) OSHA PEL Code: M
OSHA STEL: OSHA STEL Code:
ACGIH TLV: 2.5 MG (F/)M3; 9596 ACGIH TLV Code: M
ACGIH STEL: N/P ACGIH STEL Code:
EPA Reporting Quantity: 1000 LBS
DOT Reporting Quantity: 1000 LBS
Ozone Depleting Chemical: N
226 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Section 3 - Hazards Identification, Including Emergency Overview
SODIUM FLUORIDE
Health Hazards Acute & Chronic: TARGET ORGANS:HEART, LIVER, CNS, KIDNEYS, EYES, SKIN. ACUTE-
TOXIC. CAUSES EYE BURNS. CAUSES SEVERE SKIN IRRITATION/BURNS. MAY BE FATAL IF INHALED/
INGESTED/ABSORBED THROUGH SKIN. EXTREMELY DESTRUCTIVE TO MUCOUS MEMBRANES. VERY
TOXIC BY INGESTION. CHRONIC- FLUOROSIS, FRAGILE BONES, ANEMIA, TOOTH & KIDNEY DAMAGE.
Signs & Symptoms of Overexposure:
BURNS, SEVERE IRRITATION, PAIN, TEARING, NAUSEA, VOMITING, DIARRHEA, WEIGHT LOSS,
WEAKNESS, STIFFNESS OF JOINTS, LOSS OF APPETITE, LOSS OF VISION, FEVER, DEATH
Medical Conditions Aggravated by Exposure:
PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS OR IMPAIRED CNS, KIDNEY OR
RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.
LD50 LC50 Mixture: LD50 (ORAL, RAT) 57 MG/KG
Route of Entry Indicators:
Inhalation: YES
Skin: YES
Ingestion: YES
Carcenogenicity Indicators
NTP: NO
IARC: NO
OSHA: NO
Carcinogenicity Explanation: NONE
Section 4 - First Aid Measures
SODIUM FLUORIDE
First Aid:
SEEK IMMEDIATE MEDICAL ATTENTION. EYE/SKIN:IMMEDIATELY FLUSH WITH WATER FOR 15
MINUTES. HOLD EYELIDS OPEN. INHALED:MOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED.
ORAL:IF CONSCIOUS, WASH OUT MOUTH WI TH WATER. DRINK SEVERAL GLASSES OF WATER &
INDUCE VOMITING. NEVER GIVE FLUID OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS
CONVULSIONS.
Section 5 - Fire Fighting Measures
SODIUM FLUORIDE
Fire Fighting Procedures:
WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS. MAY FORM TOXIC/CORROSIVE GASES.
Unusual Fire or Explosion Hazard:
FORMS HAZARDOUS DECOMPOSITION PRODUCTS. CONTAINER MAY RUPTURE.
Extinguishing Media:
WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER
SPRAY TO COOL FIRE EXPOSED CONTAINERS.
Flash Point: Flash Point Text: NONE
Autoignition Temperature:
Autoignition Temperature Text: N/R
Lower Limit(s): NOT RELEVANT
Upper Limit(s): NOT RELEVANT
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Annex F
Section 6 - Accidental Release Measures
SODIUM FLUORIDE
Spill Release Procedures:
WEAR SUITABLE PROTECTIVE CLOTHING. AVOID MAKING DUST. RECOVER FOR REUSE IF NOT
CONTAMINATED. SWEEP UP AND PLACE IN A SUITABLE CONTAINER FOR DISPOSAL. WASH SPILL SITE
WELL WITH WATER AFTER PICK UP IS C OMPLETE.
Section 7 - Handling and Storage
SODIUM FLUORIDE
Handling and Storage Precautions:
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
SODIUM FLUORIDE
Repiratory Protection:
NONE SHOULD BE NEEDED IN NORMAL LABORATORY HANDLING. IF DUSTY CONDITIONS PREVAIL,
WORK IN A FUME HOOD OR WEAR A NIOSH-APPROVED DUST RESPIRATOR OR DUST MASK. IN
EMERGENCY, WEAR NIOSH-APPROVED SELF-CONT AINED BREATHING APPARATUS.
Ventilation:
USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS.
Protective Gloves:
RUBBER, NEOPRENE, PVC
Eye Protection: SAFETY GOGGLES/CHEMICAL SAFETY GLASSES
Other Protective Equipment: EYE WASH STATION, SAFETY SHOWER, PROTECTIVE CLOTHING AND/OR
UNIFORM
Work Hygenic Practices: OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED
PROCEDURES. WASH AFTER HANDLING AND BEFORE EATING OR DRINKING.
Supplemental Health & Safety Information: N/P
Section 9 - Physical & Chemical Properties
SODIUM FLUORIDE
HCC: T4
NRC/State License Number: NOT RELEVANT
Net Property Weight for Ammo: N/R
Boiling Point: Boiling Point Text: 3092F,1700C
Melting/Freezing Point: Melting/Freezing Text: 1819F,993C
Decomposition Point: Decomposition Text: UNKNOWN
Vapor Pressure: N/R Vapor Density: N/R
Percent Volatile Organic Content:
Specific Gravity: 2.58 - 2.78
Volatile Organic Content Pounds per Gallon:
pH: N/K
Volatile Organic Content Grams per Liter:
Viscosity: NOT RELEVANT
Evaporation Weight and Reference: NOT RELEVANT
Solubility in Water: 4% @ 15C/59F
Appearance and Odor: WHITE CRYSTALS OR POWDER - ODORLESS
Percent Volatiles by Volume: N/R
Corrosion Rate: N/R
228 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Section 10 - Stability & Reactivity Data
SODIUM FLUORIDE
Stability Indicator: YES
Materials to Avoid:
ACIDS, ALKALIS, GLASS, OXIDIZING AGENTS, ALUMINUM
Stability Condition to Avoid:
EXCESSIVE HEAT
Hazardous Decomposition Products:
MAY FORM HYDROGEN FLUORIDE, FLUORINE AND SODIUM OXIDE.
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
NOT RELEVANT
Section 11 - Toxicological Information
SODIUM FLUORIDE
Toxicological Information:
N/P
Section 12 - Ecological Information
SODIUM FLUORIDE
Ecological Information:
N/P
Section 13 - Disposal Considerations
SODIUM FLUORIDE
Waste Disposal Methods:
DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. REPORTABLE
QUANTITY (RQ): 1000 POUNDS. CAN BE DANGEROUS IF ALLOWED TO ENTER DRINKING WATER
INTAKES. DO NOT CONTAMIANTE LAKES, STREAM S, PONDS OR RIVERS.
Section 14 - MSDS Transport Information
SODIUM FLUORIDE
Transport Information:
N/P
Section 15 - Regulatory Information
SODIUM FLUORIDE
SARA Title III Information:
N/P
Federal Regulatory Information:
N/P
State Regulatory Information:
N/P
Section 16 - Other Information
SODIUM FLUORIDE
Other Information:
N/P
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Annex F
HMIS Transportation Information
Product Identification: SODIUM FLUORIDE
Transporation ID Number: 89420
Responsible Party CAGE: 36842
Date MSDS Prepared: 09/11/1996
Date MSDS Reviewed: 05/01/1998
MFN: 05/01/1998
Submitter: D DG
Status Code: C
Container Information
Unit of Issue:
Container Quantity:
Type of Container: DRUM
Net Unit Weight: 25 LBS
Article without MSDS: N
Technical Entry NOS Shipping Number:
Radioactivity: NOT RELEVANT
Form:
Net Explosive Weight: N/R
Coast Guard Ammunition Code: N/R
Magnetism: N/P
AF MMAC Code:
DOD Exemption Number: NOT RELEVANT
Limited Quantity Indicator:
Multiple Kit Number: 0
Kit Indicator: N
Kit Part Indicator: N
Review Indicator: Y
Additional Data:
Department of Transportation Information
DOT Proper Shipping Name: SODIUM FLUORIDE
DOT PSN Code: NFI
Symbols:
DOT PSN Modifier:
Hazard Class: 6.1
UN ID Number: UN1690
DOT Packaging Group: III
Label: KEEP AWAY FROM FOOD
Special Provision(s): T8
Packaging Exception: 153
230 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Non Bulk Packaging: 213
Bulk Packaging: 240
Maximimum Quanity in Passenger Area: 100 KG
Maximimum Quanity in Cargo Area: 200 KG
Stow in Vessel Requirements: A
Requirements Water/Sp/Other: 26
IMO Detail Information
IMO Proper Shipping Name: SODIUM FLUORIDE, SOLID
IMO PSN Code: NRR
IMO PSN Modifier:
IMDG Page Number: 6258
UN Number: 1690
UN Hazard Class: 6.1
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: 6.1-04
Medical First Aid Guide Number: 750
IATA Detail Information
IATA Proper Shipping Name: SODIUM FLUORIDE
IATA PSN Code: WQB
IATA PSN Modifier:
IATA UN Id Number: 1690
IATA UN Class: 6.1
Subsidiary Risk Class:
UN Packaging Group: III
IATA Label: TOXIC
Packaging Note for Passengers: 619
Maximum Quantity for Passengers: 100KG
Packaging Note for Cargo: 619
Maximum Quantity for Cargo: 200KG
Exceptions:
AFI Detail Information
AFI Proper Shipping Name: SODIUM FLUORIDE
AFI Symbols:
AFI PSN Code: WQB
AFI PSN Modifier:
AFI UN Id Number: UN1690
AFI Hazard Class: 6.1
AFI Packing Group: III
AFI Label:
Special Provisions: P5
Back Pack Reference: A10.6
HAZCOM Label Information
Product Identification: SODIUM FLUORIDE
CAGE: 36842
Assigned Individual: N
Company Name: ANACHEMIA CANADA
Company PO Box:
Company Street Address1: 255 NORMAN H8R 1A3
Company Street Address2: VILLE ST. PIERRE (MONTREAL), PQ 00000 CN
Health Emergency Telephone: 514-489-5711
Label Required Indicator: Y
Date Label Reviewed: 05/01/1998
Status Code: C
Manufacturer’s Label Number: UNKNOWN
Date of Label: 05/01/1998
Year Procured: N/K
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Annex F
Organization Code: F
Chronic Hazard Indicator: N/P
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: N/P
Signal Word: WARNING
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Section 1 - Product and Company Identification
61B25042 SODIUM HYDROXIDE 15%
Product Identification: 61B25042 SODIUM HYDROXIDE 15%
Date of MSDS: 02/19/1987 Technical Review Date: 08/17/1993
FSC: 6630 NIIN: 00-831-5932
Submitter: F BT
Status Code: C
MFN: 07
Article: N
Kit Part: Y
Manufacturer’s Information
Manufacturer’s Name: VERSATILE MACHINING INC
Post Office Box: N/K
Manufacturer’s Address1: 7450 TOWER ST
Manufacturer’s Address2: FORT WORTH, TX 76118-6424
Manufacturer’s Country: US
General Information Telephone: N/K
Emergency Telephone: N/K
Emergency Telephone: N/K
MSDS Preparer’s Name: N/P
Proprietary: N
Reviewed: Y
Published: Y
CAGE: 6S522
Special Project Code: N
Item Description
Item Name: KIT,IDENTIFICATION
Item Manager: FLZ
Specification Number: NK
Type/Grade/Class: NK
Unit of Issue: EA
Unit of Issue Quantity: 1
Type of Container:
Preparer Information
Preparer’s Name: VERSATILE MACHINING INC
Preparer’s Address1: 7450 TOWER ST
Preparer’s Address2: FORT WORTH, TX 76118-6424
Preparer’s CAGE: 6S522
Assigned Individual: N
232 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Contractor Information
Contractor’s Name: ANDERSON LABORATORIES INC
Contractor’s Address1: 5901 FITZHUGH AVE
Contractor’s Address2: FORT WORTH, TX 76119
Contractor’s Telephone: 817-547-4474
Contractor’s CAGE: 0E6L4
Contractor Information
Contractor’s Name: VERSATILE MACHINING INC
Contractor’s Address1: 7450 TOWER ST
Contractor’s Address2: FORT WORTH, TX 76118-6424
Contractor’s Telephone: N/K
Contractor’s CAGE: 6S522
Section 2 - Compositon/Information on Ingredients
61B25042 SODIUM HYDROXIDE 15%
Ingredient Name: SODIUM HYDROXIDE, CAUSTIC SODA, LYE
Ingredient CAS Number: 1310-73-2 Ingredient CAS Code: M
RTECS Number: WB4900000 RTECS Code: M
=WT: =WT Code:
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text: 10
% Enviromental Weight:
Other REC Limits: 2MG/M3 CEILING NIOSH
OSHA PEL: 2 MG/M3 OSHA PEL Code: M
OSHA STEL: OSHA STEL Code:
ACGIH TLV: C 2 MG/M3; 9293 ACGIH TLV Code: M
ACGIH STEL: N/P ACGIH STEL Code:
233
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Annex F
EPA Reporting Quantity: 1000 LBS
DOT Reporting Quantity: 1000 LBS
Ozone Depleting Chemical: N
Ingredient Name: WATER
Ingredient CAS Number: 7732-18-5 Ingredient CAS Code: M
RTECS Number: ZC0110000 RTECS Code: M
=WT: =WT Code:
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text: 90
% Enviromental Weight:
Other REC Limits: N/K
OSHA PEL: N/K OSHA PEL Code: M
OSHA STEL: OSHA STEL Code:
ACGIH TLV: N/K ACGIH TLV Code: M
ACGIH STEL: N/P ACGIH STEL Code:
EPA Reporting Quantity:
DOT Reporting Quantity:
Ozone Depleting Chemical: N
Section 3 - Hazards Identification, Including Emergency Overview
61B25042 SODIUM HYDROXIDE 15%
234 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Health Hazards Acute & Chronic: CAUSES SEVERE BURNS TO SKIN & EYES.
Signs & Symptoms of Overexposure:
SKIN/EYES: BURNS.
Medical Conditions Aggravated by Exposure:
N/K
LD50 LC50 Mixture: N/K
Route of Entry Indicators:
Inhalation: NO
Skin: YES
Ingestion: YES
Carcenogenicity Indicators
NTP: NO
IARC: NO
OSHA: NO
Carcinogenicity Explanation: NONE
Section 4 - First Aid Measures
61B25042 SODIUM HYDROXIDE 15%
First Aid:
EYES: WASH IMMEDIATELY W/WATER UNDER LOW PRESSURE FROM AN EYE-WASH FOUNTAIN, FOR A
MINIMUM OF 15 MINS. DON’T ATTEMPT TO NEUTRALIZE THE CAUSTIC W/CHEMICALS. SKIN: WASH
W/PLENTY OF WATER FOR AT LEAST 15 MINS. INGESTION: GIVE PLENTY OF WATER OR (PREFERABLY)
MILK. DON’T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES.
Section 5 - Fire Fighting Measures
61B25042 SODIUM HYDROXIDE 50%
Fire Fighting Procedures:
N/K
Unusual Fire or Explosion Hazard:
CONTACT W/ALUMINUM, TIN OR ZINC WILL PRODUCE HYDROGEN GAS WHICH IS A FIRE &
EXPLOSIVE HAZARD.
Extinguishing Media:
N/K
Flash Point: Flash Point Text: N/R
Autoignition Temperature:
Autoignition Temperature Text: N/A
Lower Limit(s): N/R
Upper Limit(s): N/R
Section 6 - Accidental Release Measures
61B25042 SODIUM HYDROXIDE 50%
Spill Release Procedures:
ABSORB ON SAND OR VERMICULITE & PLACE IN CLOSED CONTAINER FOR DISPOSAL.
Section 7 - Handling and Storage
61B25042 SODIUM HYDROXIDE 15%
Handling and Storage Precautions:
235
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Annex F
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
61B25042 SODIUM HYDROXIDE 15%
Repiratory Protection:
N/K
Ventilation:
N/K
Protective Gloves:
REQUIRED
Eye Protection: GOGGLES
Other Protective Equipment: APRONS
Work Hygenic Practices: N/K
Supplemental Health & Safety Information: N/K
Section 9 - Physical & Chemical Properties
61B25042 SODIUM HYDROXIDE 15%
HCC:
NRC/State License Number:
Net Property Weight for Ammo:
Boiling Point: Boiling Point Text: N/K
Melting/Freezing Point: Melting/Freezing Text: N/K
Decomposition Point: Decomposition Text: N/K
Vapor Pressure: N/K Vapor Density: N/K
Percent Volatile Organic Content:
Specific Gravity: N/K
Volatile Organic Content Pounds per Gallon:
pH: N/K
Volatile Organic Content Grams per Liter:
Viscosity: N/P
Evaporation Weight and Reference: N/K
Solubility in Water: N/K
Appearance and Odor: ODORLESS & COLORLESS LIQUIDS.
Percent Volatiles by Volume: N/K
Corrosion Rate: N/K
Section 10 - Stability & Reactivity Data
61B25042 SODIUM HYDROXIDE 50%
Stability Indicator: YES
Materials to Avoid:
STRONG ACIDS, ALUMINUM, TIN, ZINC.
Stability Condition to Avoid:
N/K
Hazardous Decomposition Products:
N/K
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
N/K
Section 11 - Toxicological Information
61B25042 SODIUM HYDROXIDE 15%
Toxicological Information:
236 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
N/P
Section 12 - Ecological Information
61B25042 SODIUM HYDROXIDE 15%
Ecological Information:
N/P
Section 13 - Disposal Considerations
61B25042 SODIUM HYDROXIDE 15%
Waste Disposal Methods:
DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
Section 14 - MSDS Transport Information
61B25042 SODIUM HYDROXIDE 15%
Transport Information:
N/P
Section 15 - Regulatory Information
61B25042 SODIUM HYDROXIDE 15%
SARA Title III Information:
N/P
Federal Regulatory Information:
N/P
State Regulatory Information:
N/P
Section 16 - Other Information
61B25042 SODIUM HYDROXIDE 15%
Other Information:
N/P
HMIS Transportation Information
Product Identification: 61B25042 SODIUM HYDROXIDE 15%
Transporation ID Number: 87660
Responsible Party CAGE: 6S522
Date MSDS Prepared: 02/19/1987
Date MSDS Reviewed: 05/12/1995
MFN: 05/12/1995
Submitter: F KT
Status Code: C
Container Information
Unit of Issue: EA
Container Quantity: 1
Type of Container:
Net Unit Weight: 8 OZ
Article without MSDS: N
Technical Entry NOS Shipping Number:
Radioactivity:
Form:
237
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Annex F
Net Explosive Weight:
Coast Guard Ammunition Code:
Magnetism: N/P
AF MMAC Code:
DOD Exemption Number:
Limited Quantity Indicator:
Multiple Kit Number: 0
Kit Indicator: N
Kit Part Indicator: Y
Review Indicator: Y
Additional Data:
Department of Transportation Information
DOT Proper Shipping Name: SODIUM HYDROXIDE SOLUTION
DOT PSN Code: NGY
Symbols:
DOT PSN Modifier:
Hazard Class: 8
UN ID Number: UN1824
DOT Packaging Group: II
Label: CORROSIVE
Special Provision(s): B2,N34,T8
Packaging Exception: 154
Non Bulk Packaging: 202
Bulk Packaging: 242
Maximimum Quanity in Passenger Area: 1 L
Maximimum Quanity in Cargo Area: 30 L
Stow in Vessel Requirements: A
Requirements Water/Sp/Other:
IMO Detail Information
IMO Proper Shipping Name: SODIUM HYDROXIDE, SOLUTION
IMO PSN Code: NTB
IMO PSN Modifier:
IMDG Page Number: 8226
UN Number: 1824
UN Hazard Class: 8
IMO Packaging Group: II/III
Subsidiary Risk Label: -
EMS Number: 8-06
Medical First Aid Guide Number: 705
IATA Detail Information
IATA Proper Shipping Name: SODIUM HYDROXIDE SOLUTION
IATA PSN Code: WST
IATA PSN Modifier:
IATA UN Id Number: 1824
238 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
IATA UN Class: 8
Subsidiary Risk Class:
UN Packaging Group: II
IATA Label: CORROSIVE
Packaging Note for Passengers: 809
Maximum Quantity for Passengers: 1L
Packaging Note for Cargo: 813
Maximum Quantity for Cargo: 30L
Exceptions: A3
AFI Detail Information
AFI Proper Shipping Name: SODIUM HYDROXIDE, SOLUTION
AFI Symbols:
AFI PSN Code: WST
AFI PSN Modifier:
AFI UN Id Number: UN1824
AFI Hazard Class: 8
AFI Packing Group: II
AFI Label:
Special Provisions: P5, N34
Back Pack Reference: A12.3
HAZCOM Label Information
Product Identification: 61B25042 SODIUM HYDROXIDE 15%
CAGE: 6S522
Assigned Individual: N
Company Name: VERSATILE MACHINING INC
Company PO Box:
Company Street Address1: 7450 TOWER ST
Company Street Address2: FORT WORTH, TX 76118-6424 US
Health Emergency Telephone: N/K
Label Required Indicator: Y
Date Label Reviewed: 08/17/1993
Status Code: C
Manufacturer’s Label Number: N/R
Date of Label: 08/17/1993
Year Procured: N/K
Organization Code: F
Chronic Hazard Indicator: N
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: N/P
Signal Word: DANGER
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: Slight
Section 1 - Product and Company Identification
SODIUM NITRITE
Product Identification: SODIUM NITRITE
Date of MSDS: 12/04/1989 Technical Review Date: 01/22/1991
FSC: 6810 NIIN: 00-143-7000
Submitter: N EN
Status Code: C
239
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Annex F
MFN: 01
Article: N
Kit Part: N
Manufacturer’s Information
Manufacturer’s Name: MALLINCKRODT INC
Post Office Box: M
Manufacturer’s Address1: PARIS BYPASS
Manufacturer’s Address2: PARIS, KY 40361
Manufacturer’s Country: US
General Information Telephone: 606-987-7000
Emergency Telephone: 314-982-5000
Emergency Telephone: 314-982-5000
MSDS Preparer’s Name: N/P
Proprietary: N
Reviewed: N
Published: Y
CAGE: 62910
Special Project Code: N
Item Description
Item Name: SODIUM NITRITE,ACS
Item Manager:
Specification Number: NK
Type/Grade/Class: NK
Unit of Issue: BT
Unit of Issue Quantity: 1
Type of Container:
Contractor Information
Contractor’s Name: MALLINCKRODT SPECIALTY CHEMICALS CO
Contractor’s Address1: 222 RED SCHOOL LANE
Contractor’s Address2: PHILLIPSBURG, NJ 08865
Contractor’s Telephone: 908-859-2151
Contractor’s CAGE: 62910
Section 2 - Compositon/Information on Ingredients
SODIUM NITRITE
Ingredient Name: SODIUM NITRITE (SARA III)
Ingredient CAS Number: 7632-00-0 Ingredient CAS Code: M
RTECS Number: RA1225000 RTECS Code: M
=WT: =WT Code:
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
240 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text: N/K
% Enviromental Weight:
Other REC Limits: N/K
OSHA PEL: NOT ESTABLISHED OSHA PEL Code: M
OSHA STEL: OSHA STEL Code:
ACGIH TLV: NOT ESTABLISHED ACGIH TLV Code: M
ACGIH STEL: N/P ACGIH STEL Code:
EPA Reporting Quantity: 100 LBS
DOT Reporting Quantity: 100 LBS
Ozone Depleting Chemical: N
Section 3 - Hazards Identification, Including Emergency Overview
SODIUM NITRITE
Health Hazards Acute & Chronic: INHAL: MAY CAUSE IRRIT TO RESP TRACT & SYSTEMIC POIS W/
SYMPTOMS PARALLELING INGEST. INGEST: MAY CAUSE HDCH, FLUSHING OF SKIN, VOMIT, COLIC &
DIARR, MUSCULAR WEAK, DIZZ, COLLAPSE, FALL IN BLOOD PRESS, CYANOSIS, CONVULSIONS,
COMA, RESP PARALYSIS, & DEATH DUE TO CIRCULATORY COLLAPSE. EST LETHAL DOSE (SEE EFTS OF
OVEREXP)
Signs & Symptoms of Overexposure:
HLTH HAZ: 1-2 GRAMS. SKIN: MAY CAUSE IRRIT, REDNESS & PAIN. MAY BE ABSORBED THROUGH
SKIN CAUSING SYSTEMIC POIS; SYMPTOMS MAY PARALLEL INGEST. EYES: MAY CAUSE IRRIT,
REDNESS & PAIN. CHRONIC: RPTD EXPOS URE THROUGH ANY ROUTE MAY CAUSE SYMPTOMS
SIMILAR TO ACUTE TOXICITY.
Medical Conditions Aggravated by Exposure:
NO INFORMATION FOUND.
LD50 LC50 Mixture: LD50:(ORAL)85 MG/KG(RAT)
Route of Entry Indicators:
Inhalation: YES
Skin: YES
Ingestion: NO
Carcenogenicity Indicators
NTP: NO
IARC: NO
OSHA: NO
Carcinogenicity Explanation: NOT APPLICABLE
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Annex F
Section 4 - First Aid Measures
SODIUM NITRITE
First Aid:
INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG GIVE ARTF RESP. IF BRTHG DFCLT GIVE OXYGEN.
CALL MD. INGEST: INDUCE VOMIT IMMED BY GIVING 2 GLASSES WATER & STICK FINGER DOWN
THROAT. NEVER GIVE ANYTHING BY MO UTH TO AN UNCON PERSON. CALL MD IMMED. SKIN:
IMMED FLUSH WITH WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAM CLTHG/SHOES. CALL
MD. EYES: WASH WITH WATER FOR AT LEAST 15 MIN, LIFT LIDS OCCAS. GET MD.
Section 5 - Fire Fighting Measures
SODIUM NITRITE
Fire Fighting Procedures:
PROD IS NONCOMBUST BUT IS STRONG OXIDIZER. ITS HEAT OF RX W/REDUCING AGENTS/
COMBUSTIBLES MAY CAUSE IGNIT. WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT(SEE SUPP DATA)
Unusual Fire or Explosion Hazard:
CONT W/OXIDIZABLE SUBSTANCES MAY CAUSE EXTREMELY VIOLENT COMBUST. MAY EXPLODE
WHEN HEATED TO 537C/ON SEV IMPACT/ON CONT WITH CYANIDES, AMMONIUM (SEE SUPP DATA)
Extinguishing Media:
WATER/WATER SPRAY IN EARLY STAGES. MAY USE FOAM. AVOID USING MULTI-PURP DRY CHEM FIRE
EXTING WHERE CONT W/PROD MAY OCCUR
Flash Point: Flash Point Text: N/K
Autoignition Temperature:
Autoignition Temperature Text: N/A
Lower Limit(s): N/K
Upper Limit(s): N/K
Section 6 - Accidental Release Measures
SODIUM NITRITE
Spill Release Procedures:
VENT AREA OF LEAK OR SPILL. PROTECT CLEAN-UP PERSONNEL FROM DUST WITH NIOSH/MSHA
APPROVED RESPIRATOR & PROTECTIVE CLOTHING. PICK UP & PLACE IN SUITABLE CNTNR FOR
RECLAMATION OR DISPOSAL IN A METHOD TH AT DOES NOT GENERATE DUST.
Section 7 - Handling and Storage
SODIUM NITRITE
Handling and Storage Precautions:
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
SODIUM NITRITE
Repiratory Protection:
NIOSH/MSHA APPROVED SUPPLIED AIR, FULL FACEPIECE RESPIRATOR, AIR-LINED HOOD, OR SCBA.
Ventilation:
LOCAL EXHAUST RECOMMENDED TO PREVENT DISPERSION OF CONTAMINANT INTO WORKROOM
AIR.
Protective Gloves:
IMPERVIOUS GLOVES
242 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Eye Protection: CHEM WORK GOGGLES/FACESHLD OPTNL (FP N)
Other Protective Equipment: IMPERVIOUS PROTECTIVE CLOTHING INCLUDING BOOTS, LAB COAT,
APRON OR COVERALLS TO PREVENT SKIN CONTACT.
Work Hygenic Practices: DO NOT WEAR CONT LENSES WHILE WORKING W/MATL. MAINTAIN EYE WASH
FOUNTAIN & QUICK-DRENCH FAC. WASH THORO AFTER HANDLING.
Supplemental Health & Safety Information: FIRE FIGHT PROC: EQUIP IN PRESS DEMAND/OTHER POS
PRESS MODE. EXPLO HAZ: SALTS, CELLULOSE, LI, K + NH*3, SODIUM THIOSULFATE. MATLS TO AVOID:
SALTS, BUTADIENE, PHTHALIC ACID, PHTHALIC ANHYDRIDE, REDUCAN TS, SODIUM AMIDE, SODIUM
DISULPHITE, SODIUM THIOCYANATE, UREA, WOOD ORG MATTER. DECOMP PRODS MAY LEAVE
CAUSTIC RESIDUE.
Section 9 - Physical & Chemical Properties
SODIUM NITRITE
HCC: D2
NRC/State License Number:
Net Property Weight for Ammo:
Boiling Point: Boiling Point Text: DECOMP>320C
Melting/Freezing Point: Melting/Freezing Text: 520F,271C
Decomposition Point: Decomposition Text: >608F,>320C
Vapor Pressure: N/K Vapor Density: N/K
Percent Volatile Organic Content:
Specific Gravity: N/K
Volatile Organic Content Pounds per Gallon:
pH: N/K
Volatile Organic Content Grams per Liter:
Viscosity: N/P
Evaporation Weight and Reference: N/K
Solubility in Water: 85.2G/100G H*2O
Appearance and Odor: WHITE OR YELLOWISH-WHITE CRYSTALLINE GRANULES, ODORLESS.
Percent Volatiles by Volume: N/K
Corrosion Rate: N/K
Section 10 - Stability & Reactivity Data
SODIUM NITRITE
Stability Indicator: YES
Materials to Avoid:
AMMONIUM SALTS, CELLULOSE, CYANIDES, LITHIUM, POTASSIUM PLUS AMMONIA, SODIUM
THIOSULFATE, AMINOGUANIDE (SEE SUPP DATA)
Stability Condition to Avoid:
NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:
OXIDES OF NITROGEN
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
NOT APPLICABLE
Section 11 - Toxicological Information
SODIUM NITRITE
Toxicological Information:
N/P
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Annex F
Section 12 - Ecological Information
SODIUM NITRITE
Ecological Information:
N/P
Section 13 - Disposal Considerations
SODIUM NITRITE
Waste Disposal Methods:
DISPOSE WHAT CANNOT BE RECLAIMED IN A RCRA APPROVED HAZARDOUS WASTE FACILITY I/A/W
LOCAL, STATE AND FEDERAL REGULATIONS.
Section 14 - MSDS Transport Information
SODIUM NITRITE
Transport Information:
N/P
Section 15 - Regulatory Information
SODIUM NITRITE
SARA Title III Information:
N/P
Federal Regulatory Information:
N/P
State Regulatory Information:
N/P
Section 16 - Other Information
SODIUM NITRITE
Other Information:
N/P
HMIS Transportation Information
Product Identification: SODIUM NITRITE
Transporation ID Number: 50407
Responsible Party CAGE: 62910
Date MSDS Prepared: 12/04/1989
Date MSDS Reviewed: 04/05/1991
MFN: 04/05/1991
Submitter: N TN
Status Code: C
Container Information
Unit of Issue: BT
Container Quantity: 1
Type of Container:
Net Unit Weight:
Article without MSDS: N
Technical Entry NOS Shipping Number:
Radioactivity:
Form:
244 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
Annex F
Net Explosive Weight:
Coast Guard Ammunition Code:
Magnetism: N/P
AF MMAC Code:
DOD Exemption Number:
Limited Quantity Indicator:
Multiple Kit Number: 0
Kit Indicator: N
Kit Part Indicator: N
Review Indicator: Y
Additional Data:
Department of Transportation Information
DOT Proper Shipping Name: SODIUM NITRITE
DOT PSN Code: NIB
Symbols:
DOT PSN Modifier:
Hazard Class: 5.1
UN ID Number: UN1500
DOT Packaging Group: III
Label: OXIDIZER
Special Provision(s): A1,A29
Packaging Exception: 152
Non Bulk Packaging: 213
Bulk Packaging: 240
Maximimum Quanity in Passenger Area: 25 KG
Maximimum Quanity in Cargo Area: 100 KG
Stow in Vessel Requirements: A
Requirements Water/Sp/Other: 56,58
IMO Detail Information
IMO Proper Shipping Name: SODIUM NITRITE
IMO PSN Code: NVF
IMO PSN Modifier:
IMDG Page Number: 5181
UN Number: 1500
UN Hazard Class: 5.1
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: 5.1-06
Medical First Aid Guide Number: 235
IATA Detail Information
IATA Proper Shipping Name: SODIUM NITRITE
IATA PSN Code: WUM
IATA PSN Modifier:
IATA UN Id Number: 1500
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Annex F
IATA UN Class: 5.1
Subsidiary Risk Class: 6.1
UN Packaging Group: III
IATA Label: OXIDIZER & TOXIC
Packaging Note for Passengers: 516
Maximum Quantity for Passengers: 25KG
Packaging Note for Cargo: 518
Maximum Quantity for Cargo: 100KG
Exceptions:
AFI Detail Information
AFI Proper Shipping Name: SODIUM NITRITE
AFI Symbols:
AFI PSN Code: WUM
AFI PSN Modifier:
AFI UN Id Number: UN1500
AFI Hazard Class: 5.1
AFI Packing Group: III
AFI Label:
Special Provisions: P5, A1, A29
Back Pack Reference: A9.8
HAZCOM Label Information
Product Identification: SODIUM NITRITE
CAGE: 62910
Assigned Individual: N
Company Name: MALLINCKRODT SPECIALTY CHEMICALS CO
Company PO Box:
Company Street Address1: 222 RED SCHOOL LANE
Company Street Address2: PHILLIPSBURG, NJ 08865 US
Health Emergency Telephone: 314-982-5000
Label Required Indicator: Y
Date Label Reviewed: 03/25/1991
Status Code: C
Manufacturer’s Label Number:
Date of Label: 03/25/1991
Year Procured: N/K
Organization Code: F
Chronic Hazard Indicator: N
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: YES
Signal Word: WARNING
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
246 ©2003 HazTech Systems, Inc. PO Box 929 Mariposa, CA. 95338 (800)5ID-KITS Fax (209) 966-8089 www.hazcat.com
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