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CAS

75-66-1

File Name: ilo_org---icsc0019.asp
2-METHYL-2-PROPANETHIOL                                                                                                           0019
April 2004
tert-Butyl mercaptan
CAS No: 75-66-1
(CH3)3CSH / C4H10S
RTECS No: TZ7660000
Molecular mass: 90.2
UN No: 2347


TYPES OF
ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING
HAZARD/
EXPOSURE

Highly flammable. NO open flames, NO sparks, and Foam, carbon dioxide, powder.
FIRE
NO smoking.

Vapour/air mixtures are explosive. Closed system, ventilation, In case of fire: keep drums, etc.,
EXPLOSION
explosion-proof electrical equipment cool by spraying with water.
and lighting. Do NOT use
compressed air for filling,
discharging, or handling.


EXPOSURE

Cough. Dizziness. Headache. Ventilation, local exhaust, or Fresh air, rest. Refer for medical
Inhalation
Nausea. Drowsiness. breathing protection. attention.

Protective gloves. Remove contaminated clothes.
Skin
Rinse and then wash skin with water
and soap.

Redness. Safety goggles, or eye protection in First rinse with plenty of water for
Eyes
combination with breathing several minutes (remove contact
protection. lenses if easily possible), then take
to a doctor.

Nausea. Vomiting. Do not eat, drink, or smoke during Rinse mouth.
Ingestion
work.


SPILLAGE DISPOSAL PACKAGING & LABELLING

Evacuate danger area! Remove all ignition sources. UN Hazard Class: 3
Collect leaking and spilled liquid in sealable UN Pack Group: II
containers as far as possible. Absorb remaining
liquid in sand or inert absorbent and remove to safe
place. Do NOT wash away into sewer. Carefully
collect remainder, then remove to safe place.
Personal protection: filter respirator for organic
gases and vapours.


EMERGENCY RESPONSE STORAGE

Transport Emergency Card: TEC (R)-30GFI-I+II Fireproof. Separated from strong oxidants, strong bases, strong acids,
metals, strong reducing agents.




IPCS Prepared in the context of cooperation between the International
Programme on Chemical Safety and the European Commission 漏
International IPCS 2004
Programme on
Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK.
0019 2-METHYL-2-PROPANETHIOL


IMPORTANT DATA
Physical State; Appearance Routes of exposure
COLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR. The substance can be absorbed into the body by inhalation.

Physical dangers Inhalation risk
The vapour is heavier than air and may travel along the ground; A harmful contamination of the air can be reached rather quickly
distant ignition possible. on evaporation of this substance at 20/C.

Chemical dangers Effects of short-term exposure
The substance decomposes on burning producing toxic gases The substance is irritating to the eyes and the respiratory tract.
including sulfur oxides. Reacts with strong acids, strong bases, Exposure at high levels may result in lowering of consciousness.
metals, strong oxidants, strong reducing agents to produce
sulfur oxides.

Occupational exposure limits
TLV not established.
MAK not established.


PHYSICAL PROPERTIES
Boiling point: 64/C Relative vapour density (air = 1): 3.1
Melting point: 0/C Relative density of the vapour/air-mixture at 20/C (air = 1): 1.4
Relative density (water = 1): 0.80 Flash point: -26/C c.c.
Vapour pressure, kPa at 20/C: 19.0


ENVIRONMENTAL DATA



NOTES
Auto-ignition temperature is unknown in literature.
Explosive limits are unknown in literature, although the substance is combustible and has a flash point < 61/C.
Health effects of exposure to the substance have not been investigated adequately.


ADDITIONAL INFORMATION




Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible
LEGAL NOTICE

漏IPCS 2004

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