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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/16/2006 Reviewed on 05/16/2006
1 Identification of substance
Product details
Trade name: 104
Application of the substance / the preparation: Thinner, Diluent
Manufacturer/Supplier:
Kester Tel.(847) 297-1600
515 E. Touhy Ave. Fax.(847) 390-9338
Des Plaines, IL 60018
Information department:
MSDS Coordinator Tel. (847) 699-5755
Emergency information:
CHEMTREC 24-Hour Emergency Telephone Number: (800)424-9300
CHEMTREC 24-Hour Emergency Telephone Number (Outside of the U.S. and Canada): (703)527-3887
2 Composition/Data on components
Chemical characterization
Description: Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
78-92-2 sec-butanol 50-100%
3 Hazards identification
WHMIS Hazard Symbols
:=
Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Has a narcotizing effect.
Flammable.
Irritating to eyes and respiratory system.
Vapours may cause drowsiness and dizziness.
NFPA ratings (scale 0 - 4)
Health = 1
3 Fire = 3
1 0 Reactivity = 0
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Material Safety Data Sheet
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Printing date 05/16/2006 Reviewed on 05/16/2006
Trade name: 104
(Contd. of page 1)
HMIS-ratings (scale 0 - 4)
HEALTH 1 Health = 1
Fire = 3
FIRE 3
Reactivity = 0
REACTIVITY 0
4 First aid measures
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing: Seek immediate medical advice.
5 Fire fighting measures
Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
For safety reasons unsuitable extinguishing agents: Water with full jet
Special hazards caused by the material, its products of combustion or resulting gases:
In case of fire, the following can be released:
Carbon monoxide (CO)
Carbon dioxide (CO2)
Aliphatic aldehydes
Protective equipment: Wear self-contained respiratory protective device.
6 Accidental release measures
Person-related safety precautions: Ensure adequate ventilation
Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
Measures for cleaning/collecting:
Absorb with clay, dry sand, or other inert material. Do not use combustible materials such as sawdust. Place in a
chemical waste container.
7 Handling and storage
Handling:
Information for safe handling:
Store in cool, dry place in tightly closed receptacles.
Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Storage:
Requirements to be met by storerooms and receptacles: Store in a cool location.
Information about storage in one common storage facility: Store away from oxidizing agents.
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Material Safety Data Sheet
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Printing date 05/16/2006 Reviewed on 05/16/2006
Trade name: 104
(Contd. of page 2)
Further information about storage conditions: Keep receptacle tightly sealed.
8 Exposure controls and personal protection
Additional information about design of technical systems: No further data; see item 7.
Components with limit values that require monitoring at the workplace:
78-92-2 sec-butanol
PEL 450 mg/m鲁, 150 ppm
REL Short-term value: 455 mg/m鲁, 150 ppm
Long-term value: 305 mg/m鲁, 100 ppm
TLV 300 mg/m鲁, 100 ppm
Additional information:
PEL = Permissible Exposure Limit (OSHA)
REL= Recommended Exposure Limit (NIOSH)
TLV= Threshold Limit Value (ACGIH)
OSHA= Occupational Safety and Health Administration
ACGIH= American Conference of Governmental Industrial Hygienists
NIOSH= National Institute for Occupational Safety and Health
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
When ventilation is not sufficient to remove fumes from the breathing zone, a safety approved respirator or self-
contained breathing apparatus should be worn.
Protection of hands:
S Protective gloves
Material of gloves:
Nitrile rubber, NBR
Natural rubber, NR
Penetration time of glove material:
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Safety glasses
R Tightly sealed goggles
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Material Safety Data Sheet
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Trade name: 104
(Contd. of page 3)
9 Physical and chemical properties
General Information
Form: Liquid
Color: Amber colored
Odor: Alcohol-like
Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 100掳C (212掳F)
Flash point: 23掳C (73掳F)
Ignition temperature: 390.0掳C (734掳F)
Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are
possible.
Explosion limits:
Lower: 2.5 Vol %
Upper: 15.0 Vol %
Vapor pressure at 20掳C (68掳F): 40 hPa (30 mm Hg)
Density at 20掳C (68掳F): 0.806 g/cm鲁
Solubility in / Miscibility with
Water at 20掳C (68掳F): 75 %
10 Stability and reactivity
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Materials to be avoided: Strong acids, strong oxidizers.
Dangerous reactions No dangerous reactions known.
Dangerous products of decomposition:
When heated to soldering temperatures, solvents will be evaporated and organic matierial may release aliphatic
aldehydes and acids.
Carbon monoxide and carbon dioxide
11 Toxicological information
Acute toxicity:
LD/LC50 values that are relevant for classification:
78-92-2 sec-butanol
Oral LD50 6480 mg/kg (rat)
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
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Material Safety Data Sheet
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Trade name: 104
(Contd. of page 4)
through inhalation:
Fumes during use may irritate mucous membranes and respiratory system. High concentrations can cause
headache, dizziness, narcosis, and nausea.
through ingestion: May cause gastrointestinal irritation.
Sensitization: No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
12 Ecological information
General notes: Do not allow product to reach ground water, water course or sewage system.
13 Disposal considerations
Product:
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
14 Transport information
DOT regulations:
Hazard class: 3
Identification number: UN1120
Packing group: III
Proper shipping name (technical name): BUTANOLS, mixture
Label 3
Land transport ADR/RID (cross-border):
ADR/RID class: 3 Flammable liquids
Danger code (Kemler): 30
UN-Number: 1120
Packaging group: III
Description of goods: 1120 BUTANOLS, mixture
Maritime transport IMDG:
IMDG Class: 3
UN Number: 1120
Label 3
Packaging group: III
Marine pollutant: No
Propper shipping name: BUTANOLS, mixture
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: 3
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Trade name: 104
(Contd. of page 5)
UN/ID Number: 1120
Label 3
Packaging group: III
Propper shipping name: BUTANOLS, mixture
15 Regulations
USA The following information relates to product regulation specific to the USA.
SARA (Superfund Amendments and Reauthorization Act)
Section 355 (extremely hazardous substances):
None of the ingredient is listed.
Section 313 (Specific toxic chemical listings):
78-92-2 sec-butanol
TSCA (Toxic Substances Control Act):
All ingredients are listed.
California Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity:
None of the ingredients is listed.
Carcinogenicity categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
CANADA: The following information relates to product regulation specific to Canada.
Workplace Hazardous Materials Identification (WHMIS):
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulation (CPR) and the MSDS contains all of the information required by the CPR.
WHMIS Classification:
B2
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Material Safety Data Sheet
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D2A
EUROPEAN UNION
The following information relates to product regulation specific to the directives of the European Union.
Risk phrases:
Flammable.
Irritating to eyes and respiratory system.
Vapours may cause drowsiness and dizziness.
Safety phrases:
Keep out of the reach of children.
Keep container tightly closed and in a well-ventilated place.
If swallowed, seek medical advice immediately and show this container or label.
Dispose of this material and its container to hazardous or special waste collection point.
16 Other information
The information contained herein is based on data considered accurate and is offered solely for information,
consideration and investigation. Kester extends no warranties, makes no representations and assumes no
responsibilty as to the accuracy, completeness or suitability of this data for any purchaser's use. The data on this
Material Safety Data Sheet relates only to this product and does not relate to use with any other material or in any
process. All chemical products should be used only by, or under the direction of, technically qualified personnel
who are aware of the hazards involved and the necessity for reasonable care in handling. Hazard communication
regulations require that employees must be trained on how to use a Material Safety Data Sheet as a source for
hazard information.
Department issuing MSDS: Product Safety
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