CONSUMER MATERIAL SAFETY DATA SHEET
NAME OF PRODUCT: Loctite Super Glue Goof Proof Greenwing
MSDS DATE: 04/19/06
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Loctite Super Glue Goof Proof Greenwing
PRODUCT CODES: 01-06983
SUPPLIER: Henkel Consumer Adhesives.
ADDRESS: 32150 Just Imagine Drive
Avon, Ohio 44011
EMERGENCY PHONE: (440) 937-7000
CHEMICAL FAMILY: Cyanoacrylates
PRODUCT USE: Consumer Product; Super Glue
PREPARED BY: Regulatory Affairs
MSDS PREPARATION DATE: 04/19/2006
SECTION 1 NOTES: Household Super Glue
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT: % CAS NO. OSHA PEL ACGIH TLV
Ethyl cyanoacrylate 60-100 7085-85-0 None 0.2ppm TWA
SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: BONDS SKIN IN SECONDS
MAY CAUSE EYE AND RESPIRATORY IRRITATION
COMBUSTIBLE LIQUID AND VAPOR
ROUTES OF ENTRY: oral, dermal, inhalation
POTENTIAL HEALTH EFFECTS
EYES: Irritating to the eyes. Causes excessive tearing. Eyelids may
bond.
SKIN: Bonds skin in seconds. May cause skin irritation.
Cyanoacrylates have been reported to cause allergic reaction
but due to rapid polymerization at the skin surface, an allergic
reaction is rare. Cyanoacrylates generate heat on solidification.
In rare circumstances, a large drop will burn the skin. Cured
adhesive does not present a health hazard even if bonded to the
skin.
INGESTION: Not expected to be harmful by ingestion. Rapidly polymerizes
(solidifies) and bonds in mouth. It is almost impossible to
swallow.
INHALATION: Exposure to vapors above established exposure limit results in
respiratory irritation which may lead to difficulty in breathing
and tightness in the chest.
SECTION 4: FIRST AID MEASURES
EYES: Immediately flush with plenty of water for at least 15 minutes. Get medical attention. If eyelids
are bonded closed, release eyelashes with warm water by covering with a wet pad. Do not force eye
open. Cyanoacrylate will bond to eye protein and will cause a lachrymatory effect, which will help to
debond the adhesive. Keep eye covered until debonding is complete, usually within 1-3 days.
Medical attention should be sought in case solid particles of polymerized cyanoacrylate trapped
behind the eyelid cause abrasive damage.
SKIN: Do not pull bonded skin apart. Soak in warm soapy water. Gently peel apart using a blunt
instrument. If skin is burned due to the rapid generation of heat by a large drop, seek medical
attention. If lips are bonded, apply warm water to the lips and encourage wetting and pressure from
saliva in mouth. Peel or roll lips apart. Do not pull lips apart with direct opposing force.
INGESTION: Ensure breathing passages are not obstructed. The product will polymerize rapidly and
bond to the mouth making it almost impossible to swallow. Saliva will separate any solidified
product in several hours. Prevent the patient from swallowing by separating mass.
INHALATION: Remove to fresh air. If discomfort persists seek medical attention.
SECTION 5: FIRE-FIGHTING MEASURES
NFPA HAZARD CLASSIFICATION
HEALTH: FLAMMABILITY: REACTIVITY: <2,2,1>
EXTINGUISHING MEDIA: Foam, CO2, Dry chemical (B-C)
FLAMMABLE LIMITS IN AIR: Not determined
FLASHPOINT: 80C-93.4C (176F-200F)
UNUSUAL FIRE AND EXPLOSION HAZARDS: None
SPECIAL FIREFIGHTING PROCEDURES: Firefighters should wear positive pressure self-contained
breathing apparatus (SCBA).
HAZARDOUS DECOMPOSITION PRODUCTS: Trace amount of toxic or irritating fumes may be
released and the use of breathing apparatus is recommended.
SECTION 6: ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE MEASURES: Ventilate area. Prevent product from entering the drains.
Do not use cloth for mopping up. Flood with water to complete polymerization and scrape off the
floor. Cured materials can be disposed of as non-hazardous wastes.
SECTION 7: HANDLING AND STORAGE
HANDLING AND STORAGE: Avoid contact with eyes, skin and clothing. Avoid breathing
vapor and mist. Wash thoroughly after handling. Avoid contact with fabric or paper goods.
Contact with these materials may cause rapid polymerization which can generate smoke
and strong irritating vapors and cause thermal burns.
See label on product for use directions.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Use positive downdraft exhaust ventilation if general
ventilation is insufficient to maintain vapor concentration
below established exposure limits.
RESPIRATORY PROTECTION: Use NIOSH approved respirator if there is potential to
exceed exposure limits..
EYE PROTECTION: Chemical splash goggles or safety glasses with side
shields.
SKIN PROTECTION: Use nitrile gloves and aprons as necessary to prevent
contact. Do not use PVC, nylon or cotton.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Clear/Pale yellow Liquid.
ODOR: Sharp, irritating.
PHYSICAL STATE: Liquid
pH AS SUPPLIED: Not applicable.
SPECIFIC GRAVITY (H2O = 1): 1.075
SOLUBILITY IN WATER: Polymerizes in presence of water.
EVAPORATION RATE: Not available
BOILING POINT: > 149C (300F)
VAPOR PRESSURE: <0.2mm Hg
% VOC <20g/L (California SCAQMD Method 316B (estimated))
SECTION 10: STABILITY AND REACTIVITY
STABILITY: Stable under recommended storage conditions.
CONDITIONS TO AVOID: Spontaneous polymerization.
HAZARDOUS POLYMERIZATION: Rapid exothermic polymerization will occur in the presence of
water, amines, alkalis and alcohols.
INCOMPATIBILITY: Water, amines, alkalis and alcohols.
SECTION 11: TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION: Acute oral LD50 >5000mg/kg, rat (estimated). LD50 >2000mg/kg,
rabbit (estimated).
See also Section 3 Hazard Identifications.
SECTION 11 NOTES: Contact Regulatory Affairs if further information is required.
SECTION 12: ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION: No data available.
SECTION 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose in accordance with federal, state or local regulations.
SECTION 14: TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION
PROPER SHIPPING NAME: Combustible liquids N.O.S (Cyanoacrylate ester)
HAZARD CLASS: 3
UN NUMBER: NA 1993
PACKING GROUP: III
EXCEPTIONS: (Not more than 450L) Unrestricted
MARINE POLLUTANT: None
NOTE: This product classifies as a Consumer Commodity ORM-D due to its size and intended use.
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA)
PROPER SHIPPING NAME: Aviation regulated liquids N.O.S (Cyanoacrylate ester)
HAZARD CLASS: 9
UN NUMBER: UN3334
PACKING GROUP: III
EXCEPTIONS: (Not more than 500ml). Unrestricted.
WATER TRANSPORATION (IMO/IMDG)
PROPER SHIPPING NAME: Unrestricted.
SECTION 15: REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS
This product has been labeled according to the Federal Hazardous Substances Act and the
associated Consumer Product Safety Regulations.
SECTION 16: OTHER INFORMATION
OTHER INFORMATION: Information provided in this MSDS is intended to provide supplementary
information for consumer uses of this product. This product is not intended for industrial uses.
PREPARATION INFORMATION: Prepared by Regulatory Affairs
DISCLAIMER: The information appearing herein is furnished without express or implied warranty
and is based upon tests and data believed to be accurate to the best knowledge of Henkel Consumer
Adhesives Inc. It is the user鈥檚 responsibility to ensure that the product is handled safely and that
the instructions for use are properly communicated and followed. Henkel Consumer Adhesives Inc.
assumes no legal responsibility or liability for any use not in accordance with the use described in
this MSDS or in the product labeling.
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