MATERIAL SAFETY DATA SHEET
Page:1/8
Product Name: MT TONER 401[] MSDS No.: PPC-041
Date Printed: 25-Aug-98 Date Prepared: 13-Dec-96
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: MT TONER 401[] [],denoted with an alphabet.
used for: EP3050, EP4050
Supplier Identification:
Minolta Corporation
101 Williams Drive, Ramsey, New Jersey 07446, U.S.A.
Telephone: 201-825-4000
Emergency Telephone No.
Contact your regional poison control center.
2. COMPOSITION / INFORMATION ON INGREDIENTS
Substance [ ] Preparation [ X ]
Hazardous Ingredients:
Chemical Name: Carbon black WT%: 5-10 %
CAS No.: 1333-86-4 EEC-No.: 215-609-9
OSHA Z-Tables(USA): 3.5mg/m3 ACGIH-TLV(USA): 3.5mg/m3
NTP(USA): Not listed IARC Monographs: Group 2B
Symbol(EC): Not listed R-Phrase(EC): Not listed
DFG-MAK(EC): Not listed Worksafe-TWA(Austl): 3mg/m3
Major Ingredients:
[Generic Name] [CAS No.] [WT%]
Styrene acrylate copolymer +++ >80 %
Carbon black 1333-86-4 5-10 %
Organic pigment +++ 1- 5 %
Polyolefin wax +++ 1- 5 %
Ferrite +++ 1- 5 %
+++: Supplier鈥檚 confidential information
MATERIAL SAFETY DATA SHEET
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Product Name: MT TONER 401[] MSDS No.: PPC-041
Date Printed: 25-Aug-98 Date Prepared: 13-Dec-96
3. HAZARDS IDENTIFICATION
Most Important Hazards and Effects of the Products
For Human Health: This toner is not classified as a human carcinogen.
No symptoms expected with intended use.
For the Environment: No data are available on the adverse effects of this
product on the environment.
For Others: None
Specific Hazards: Dust explosion (like most finely divided organic
powders)
4. FIRST-AID MEASURES
Symptoms of Overexposure: No symptoms expected with intended use.
Routes of Entry: Eye contact, inhalation, ingestion
Information
Inhalation: If symptoms are experienced, remove source of contamination
or move victim to fresh air and obtain medical advice.
Skin Contact: Flush with gently flowing water (preferably lukewarm) and
soap for 15 minutes or until particle is removed. If irritation does
occur, obtain medical advice.
Eye Contact: Do not allow victim to rub eye(s). Flush with gently flowing
water (preferably lukewarm) for 15 minutes or until particle is
removed. Have victim look right and left, and, then up and down. If
irritation does occur, obtain medical attention. DO NOT attempt to
manually remove anything stuck to the eye(s).
Ingestion: If irritation or discomfort occurs, obtain medical
attention immediately.
Note to Physician: None
Further Information: None
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: CO2, water spray, foam and dry chemical
Extinguishing Media to Avoid: Full water jet
Special Firefighting Procedures: None
Fire and Explosion Hazards: If dispersed in air, like most finely divided
organic powders, may form an explosive mixture.
Protection of Firefighters: Use self-contained breathing apparatus
(SCBA).
MATERIAL SAFETY DATA SHEET
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Product Name: MT TONER 401[] MSDS No.: PPC-041
Date Printed: 25-Aug-98 Date Prepared: 13-Dec-96
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions: None
Environmental Precautions: None
Methods for Cleaning Up: Wipe off with paper or cloth.
DO NOT use vacuum cleaner when a large amount is released. It, like most
finely divided organic powders, may create a dust explosion.
Further Information: None
7. HANDLING AND STORAGE
Handling
Technical Measures: None
Precautions: None
Safe Handling Advice: Try not to disperse the particles.
Storage
Technical Measures: None
Storage Conditions: Keep container closed.
Store in a cool and dry place.
Incompatible Products: None
Packing Materials : Bottles or Cartridge designated by Minolta.
Further Information: None
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Measures
Ventilation: None required with intended use.
Control Parameters(As total dust)
OSHA-PEL(USA): 15mg/m3 ACGIH-TLV(USA): 10mg/m3
DFG-MAK(EC): 6mg/m3 Worksafe-TWA(Austl.): 10mg/m3
Personal Protective Equipment
Respiratory protection: None required when used as intended in Minolta
equipment.
Hand Protection: None required when used as intended in Minolta equipment.
Eye protection: None required when used as intended in Minolta equipment.
Skin Protection: None required when used as intended in Minolta equipment.
Other: For use other than normal customer-operating procedures
(such as in bulk toner processing facilities), goggles and
respirators may be required.
Hygiene Measures: Wash hands after handling.
Further Information: None
MATERIAL SAFETY DATA SHEET
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Product Name: MT TONER 401[] MSDS No.: PPC-041
Date Printed: 25-Aug-98 Date Prepared: 13-Dec-96
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical State: Solid Form: Powder Color: Black
Odor: Faint odor
Particle Size(碌m): 10 - 20
Boiling Point: Not applicable
Melting Point(掳C): No data available
Softening Point(掳C): 120 - 125 *
Flash Point: Not applicable
pH: Not applicable
Explosion Properties: No data available
Density(g/cm鲁): 1.15 * (bulk density: 0.42 *)
Solubility in water: Negligible
Flammability: No data available
Oxidizing Properties: No data available
Ignition Temperature(掳C): approx.450 *
Vapor Pressure: Not applicable
Partition Coefficient, n-octagonal/Water: Not applicable
Thermal decomposition: >280 degrees *
(*= Based on data for other Minolta Products with similar ingredients)
10. STABILITY AND REACTIVITY
Stability: Stable [ X ] Unstable [ ]
Hazardous Reactions: Dust explosion, like most finely divided organic
powders.
Conditions to avoid: Electronic discharge, throwing into fire.
Materials to Avoid: Oxidizing materials.
Hazardous Decomposition Products: CO, CO2
Further Information: None
11. TOXICOLOGICAL INFORMATION
Health Effects from Exposure: No symptoms expected with intended use.
Toxicological Data
Acute Toxicity:
Inhalation, LC50(g/m鲁/4h): >1.79 (Rats) *
(This was the highest attainable concentration.)
Ingestion(oral), LD50(g/kg): >5.0 (Rats) *
Dermal, LD50(g/kg): No data available
Eye irritation: Mild conjunctival irritation (Rabbits) *
Skin irritation: Not an irritant (Rabbits) *
Skin sensitizer: No signs(Guinea-Pig) *
Mutagenicity: Negative (AMES test)
MATERIAL SAFETY DATA SHEET
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Product Name: MT TONER 401[] MSDS No.: PPC-041
Date Printed: 25-Aug-98 Date Prepared: 13-Dec-96
Local Effects: see Chronic Toxicity or Long term Toxicity
Chronic Toxicity or Long Term Toxicity:
Prolonged inhalation of excessive dust may cause lung damage. It is
attributed to 鈥渓ung overloading鈥?, a generic response to excessive
amounts of any dust retained in the lungs for a prolonged interval.
Use of this product, as intended, does not result in inhalation of
excessive dust.
In a study in rats by chronic inhalation exposure to a typical toner,
a mild to moderate degree of lung fibrosis was observed in 92% of rats
in the high concentration(16mg/m鲁) exposure group, and a minimal to
mild degree of fibrosis was noted in 22% of the animals in the
middle(4mg/m鲁) exposure group. But no pulmonary change was reported
in the lowest(1mg/m鲁) exposure group, the most relevant level to
potential human exposures.
Carcinogenicity
IARC Monographs: Not listed
NTP(USA): Not listed
OSHA Regulated(USA): Not listed
In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen
(possible human carcinogen). This evaluation is given to Carbon Black
for which there is inadequate human evidence, but sufficient animal
evidence. The latter is based upon the development of lung tumors in
rats receiving chronic inhalation exposures to free carbon black at
levels that induce particle overload of the lung.
Studies performed in animal models other than rats have not demonstrated
an association between carbon black and lung tumors. Moreover, a two-year
cancer bioassay using a typical toner preparation containing carbon
black demonstrated no association between toner exposure and tumor
development in rats.
(*= Based on data for other Minolta Products with similar ingredients)
12. ECOLOGICAL INFORMATION
Mobility: No data are available on the adverse effects of this material on
the environment.
Persistence/Degradability: No data are available on the adverse effects of
this material on the environment.
Bioaccumulation: No data are available on the adverse effects of this material
on the environment.
MATERIAL SAFETY DATA SHEET
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Product Name: MT TONER 401[] MSDS No.: PPC-041
Date Printed: 25-Aug-98 Date Prepared: 13-Dec-96
Ecotoxicity
Behavior in Sewage Works: No data are available on the adverse effects
of this material on the environment.
Aquatic Toxicity: No data are available on the adverse effects of this
material on the environment.
Ecological Data(EC)
Csb Value(EC): No data are available on the adverse effects of this material
on the environment.
AOX-Remark(EC): No data are available on the adverse effects of this
material on the environment.
BsB5 Value(EC): No data are available on the adverse effects of this
material on the environment.
Significant Components(EC): Not applicable
13. DISPOSAL CONSIDERATION
Appropriate Methods of Disposal
Preparation(community provisions):
Waste may be disposed or incinerated under conditions which meet all
federal, state and local environmental regulations.
Contaminated Packaging:
Waste may be disposed or incinerated under conditions which meet all
federal, state and local environmental regulations.
14. TRANSPORT INFORMATION
Special Precautions: None
Information on Code and Classifications According to
International Regulations
UN Classification: None
Land
RID(EC): None
ADR(EC): None
DOT(USA): None
Inland Waterways
ADNR(Rhine R.): None
Sea
IMDG: None
Air
ICAO-TI: None
IATA-DGR: None
MATERIAL SAFETY DATA SHEET
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Product Name: MT TONER 401[] MSDS No.: PPC-041
Date Printed: 25-Aug-98 Date Prepared: 13-Dec-96
15. REGULATORY INFORMATION
US Information
Information on the label: Not required
TSCA(Toxic Substances Control Act):
All chemical substances in this product comply with all applicable rules
or order under TSCA.
SARA(Superfund Amendments and Reauthorization Act) Title III
302 Extreme Hazardous Substance: None
311/312 Hazard Categories: None
313 Reportable Ingredients: None
California Proposition 65:
This product contains no chemical substances subject to California
Proposition 65.
EU Information
Information on the label (88/379/EEC and 67/548/EEC):
Symbol & Indication: Not required
R-Phrase: Not required
S-Phrase: Not required
76/769/EEC:
All chemical substances in this product comply with all applicable rules
or order under 76/769/EEC.
16. OTHER INFORMATION
NFPA Hazard Rating: The National Fire Protection Agency(USA):
Health: 1 Flammability: 1 Reactivity: 0
HMIS Rating: The National Paint and Coating Association(USA):
Health: 1 Flammability: 1 Reactivity: 0
Recommended Uses:
Toner for Photocopier EP3050, EP4050
Restrictions:
Information on this data sheet represents our current data and the best
opinion as to the proper use in handling of this product under normal
conditions specified in our User鈥榮 Manual. However, neither Minolta
Co.,Ltd. nor any of its subsidiaries assumes any liability whatsoever
for the accuracy or completeness of the information contained herein.
All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we do not guarantee that
these are the only hazards which exist.
MATERIAL SAFETY DATA SHEET
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Product Name: MT TONER 401[] MSDS No.: PPC-041
Date Printed: 25-Aug-98 Date Prepared: 13-Dec-96
Literature References:
ANSI Z400.1-1993
TRGS 220: Sicherheitsdatenblatt f眉r gef盲hrliche Stoffe und Zubereitungen
ISO 11014-1
Commission Directive 91/155/EEC
The Material Safety Data sheet: A Practical Guide to First Aid:
Canadian Centre for Occupational Health and Safety鈥榮 publication
HMIS IMPLEMENTATION MANUAL: National Paint & Coatings association
IARC(1996): IARC monographs on the Evaluation of the Carcinogenic Risk
of Chemicals to Humans, Vol. 65, Printing Process and Printing
Inks, Carbon Black and Some Nitro Compounds, Lyon, pp.149-261
H.Muhle, B.Bellmann, O.Creutzenberg, C.Dasenbrock, H.Ernst, R.Kilpper,
J.C.MacKenzie, P.Morrow, U.Mohr, S.Takenaka, and R.Mermelstein(1991)
Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats.
Fundamental and Applied Toxicology 17, pp.280-299.
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