Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROTEUS OD110 4X5L BOT ELL 1/7
Version 1 / EU Revision Date: 07.08.2006
102000008150 Print Date: 07.02.2007
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product information
Trade name PROTEUS OD110 4X5L BOT ELL
Product code (UVP) 06002463
Usage insecticide
Company Bayer CropScience AG
Alfred-Nobel-Stra脽e 50
40789 Monheim
Germany
Telephone +49(0)2173-38-3373
Telefax +49(0)2173-38-7394
Responsible Department Material and Transport Safety Management
+49(0)2173-38-3409/4566
Emergency telephone number +49(0)2133-51-4233 (Sicherheitszentrale Dormagen, Bayer AG)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Oil dispersion (OD)
Thiacloprid 100 g/l, Deltamethrin 10 g/l
Hazardous components
Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%]
EINECS-No.
Thiaclopride 111988-49-9 Xn R20/22, R40, 10,40
R52/53
Deltamethrin 52918-63-5 T, N R23/25, 1,00
258-256-6 R50/53
Alkylaryl sulfonate 247-557-8 Xi R38, R41 11,30
2-Ethylhexanol propylene 64366-70-7 Xn R20, R52/53 23,00
ethyleneglycol ether
3. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Harmful if swallowed.
Irritating to eyes and skin.
Limited evidence of a carcinogenic effect.
May cause sensitization by skin contact.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. FIRST AID MEASURES
General advice
Move out of dangerous area. Remove contaminated clothing immediately and dispose of safely.
Place and transport victim in stable position (lying sideways).
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROTEUS OD110 4X5L BOT ELL 2/7
Version 1 / EU Revision Date: 07.08.2006
102000008150 Print Date: 07.02.2007
Inhalation
Keep patient warm and at rest. Move to fresh air. Call a physician or poison control center
immediately.
Skin contact
Wash off immediately with soap and plenty of water. If symptoms persist, call a physician.
Eye contact
In the case of contact with eyes, rinse immediately with plenty of water and seek medical
advice. Call a physician or poison control center immediately.
Ingestion
Do NOT induce vomiting. Call a physician or poison control center immediately. Rinse mouth.
Notes to Physician
Treatment
Elementary aid, decontamination and symptomatic treatment.
Gastric lavage, then charcoal (carbo medicalis) and sodium sulfate.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
water spray
carbon dioxide (CO2)
foam
sand
Specific hazards during fire fighting
In the event of fire the following can be released:
hydrogen chloride (HCl)
hydrogen cyanide (hydrocyanic acid)
carbon monoxide (CO)
sulphur dioxide (SO2)
nitrous gases (NOx)
Special protective equipment for fire-fighters
In the event of fire and/or explosion do not breathe fumes.
Use breathing apparatus.
Further information
Contain the spread of the fire-fighting media.
Do not allow run-off from fire fighting to enter drains or water courses.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Avoid contact with spilled product or contaminated surfaces.
Wear personal protective equipment. Unprotected persons must be kept away.
Environmental Precautions
Do not discharge into the drains/surface water/groundwater.
Methods for Cleaning Up
Take up with absorbent material (e.g. sand, diatomaceous earth or a proprietary absorbent
material).
Clean contaminated floors and objects thoroughly, observing environmental regulations.
Keep in suitable, closed containers for disposal.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROTEUS OD110 4X5L BOT ELL 3/7
Version 1 / EU Revision Date: 07.08.2006
102000008150 Print Date: 07.02.2007
Additional Advice
Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.
7. HANDLING AND STORAGE
Handling
Advice on safe handling
Use only in area provided with appropriate exhaust ventilation.
Storage
Requirements for storage areas and containers
Store in a place accessible by authorized persons only.
Keep containers tightly closed in a cool, well-ventilated place.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Suitable materials
HDPE (high density polyethylene)
Coextruded containers with an internal barrier layer made of ethylene vinyl alcohol copolymer
(EVOH)
Coextruded containers with an internal barrier layer made of polyamide (PA).
Black mild steel sheet with interior coating
Deformation through oxygen consumption possible.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protective equipment
Respiratory Protection If product is handled while not enclosed, and if contact may occur:
Full mask
Multi-range filter ABEK/P2
Hand Protection Chemical resistant nitrile rubber gloves
Hygiene measures
Avoid contact with skin, eyes and clothing.
Keep working clothes separately.
Wash hands immediately after work, if necessary take a shower.
Remove soiled and/or soaked clothing immediately and clean thoroughly before using again.
Garments that cannot be cleaned must be destroyed (burnt).
Protective measures
If product is handled while not enclosed, and if contact may occur:
complete suit protecting against chemicals
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form liquid, suspension
Colour white
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROTEUS OD110 4X5L BOT ELL 4/7
Version 1 / EU Revision Date: 07.08.2006
102000008150 Print Date: 07.02.2007
Odour weak, characteristic
Safety data
pH 5 - 8 at 1 % (20 掳C)
Flash point 103 掳C
92/69/EEC, A.9 / EPA OPPTS 830.6315
Ignition temperature 405 掳C
Density ca. 1,000 g/cm鲁 at 20 掳C
Water solubility miscible
Surface tension 21,5 mN/m
Determined in the undiluted form.
Explosivity Not explosive
92/69/EEC, A.14 / OECD 113
10. STABILITY AND REACTIVITY
Hazardous Reactions No hazardous reactions when stored and handled according to
prescribed instructions.
Stable under recommended storage conditions.
11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity LD50 (rat) > 300 - < 2.000 mg/kg
Acute Inhalation Toxicity LC50 (rat) > 4,793 mg/l
Exposure time: 4 h
Determined in the form of a respirable aerosol.
Highest attainable concentration.
Acute Dermal Toxicity LD50 (rat) > 4.000 mg/kg
Skin Irritation Irritating to skin. (rabbit)
Eye Irritation Irritating to eyes. (rabbit)
Sensitization sensitizing (guinea pig)
OECD Test Guideline 406, Magnusson & Kligman test
12. ECOLOGICAL INFORMATION
Ecotoxicity effects
Toxicity to Fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 0,386 mg/l
Exposure time: 96 h
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROTEUS OD110 4X5L BOT ELL 5/7
Version 1 / EU Revision Date: 07.08.2006
102000008150 Print Date: 07.02.2007
Toxicity to daphnia EC50 (Water flea (Daphnia magna)) 0,0427 mg/l
Exposure time: 48 h
Toxicity to algae EC50 (Pseudokirchneriella subcapitata) > 100 mg/l
Growth rate Exposure time: 72 h
The value mentioned relates to the active ingredient thiaclopride.
Toxicity to algae EC50 (Pseudokirchneriella subcapitata) 9,1 mg/l
Growth rate Exposure time: 72 h
The value mentioned relates to the active ingredient deltamethrin.
13. DISPOSAL CONSIDERATIONS
Product
In accordance with current regulations may be taken to waste disposal site or incineration plant,
after consultation with site operator and/or with the responsible authority.
Waste key for the unused product
020108 agrochemical waste containing dangerous substances
14. TRANSPORT INFORMATION
ADR/RID/ADNR
3082
UN-No
Labels 9
Packaging group III
Hazard no. 90
Description of the goods UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
(DELTAMETHRIN)
IMDG
3082
UN-No
Class 9
Packaging group III
EmS F-A , S-F
Marine pollutant Marine pollutant
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(DELTAMETHRIN )
IATA
3082
UN-No
Class 9
Packaging group III
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(DELTAMETHRIN )
15. REGULATORY INFORMATION
Classification and labelling in accordance with the EC Directive on dangerous preparations
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROTEUS OD110 4X5L BOT ELL 6/7
Version 1 / EU Revision Date: 07.08.2006
102000008150 Print Date: 07.02.2007
1999/45/EC as amended.
Classification:
Labelling according to EC Directives
Hazardous components which must be listed on the label:
鈥? Thiaclopride
鈥? Deltamethrin
Symbol(s)
Xn Harmful
N Dangerous for the environment
R-phrase(s)
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.
R40 Limited evidence of a carcinogenic effect.
R43 May cause sensitization by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S24 Avoid contact with skin.
S35 This material and its container must be disposed of in a safe way.
S36/37 Wear suitable protective clothing and gloves.
S57 Use appropriate container to avoid environmental contamination.
Exceptional labelling
To avoid risks to man and the environment, comply with the instructions for use.
Further information
WHO-classification: II (Moderately hazardous)
16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 2:
R20 Harmful by inhalation.
R20/22 Harmful by inhalation and if swallowed.
R23/25 Toxic by inhalation and if swallowed.
R38 Irritating to skin.
R40 Limited evidence of a carcinogenic effect.
R41 Risk of serious damage to eyes.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
The information given in this Data Sheet has been included in accordance with the guidelines
established by EC Directive 1991/155/EC as amended. This data sheet complements the user's
instructions, but does not replace them. The information it contains is based on the knowledge
available about the product concerned at the time it was compiled. Users are further reminded of the
possible risks of using a product for purposes other than those for which it was intended. The
required information complies with current EEC legislation. Addressees are requested to observe
any additional national requirements.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROTEUS OD110 4X5L BOT ELL 7/7
Version 1 / EU Revision Date: 07.08.2006
102000008150 Print Date: 07.02.2007
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