**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 100-54-9 |3-Cyanopyridine | 98.0 | 202-863-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
Causes severe eye irritation.
Skin:
Causes severe skin irritation. Effects may be delayed.
Ingestion:
Causes gastrointestinal tract irritation. Effects may be delayed.
May be harmful if swallowed.
Inhalation:
Effects may be delayed. Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. If breathing has ceased
apply artificial respiration using oxygen and a suitable mechanical
device such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Use with adequate ventilation. Minimize dust generation and
accumulation. Do not get in eyes, on skin, or on clothing. Keep
container tightly closed. Do not ingest or inhale.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 100-54-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: Off-White Crystalline Solid
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 201 deg C @ 760.00mmHg
Freezing/Melting Point: 50.00 - 52.00 deg C
Autoignition Temperature: Not available.
Flash Point: 84 deg C ( 183.20 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: 140 g/l (20 c)
Specific Gravity/Density:
Molecular Formula: C6H4N2
Molecular Weight: 104.11
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat, reducing agents, oxidizers.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 100-54-9: QT3030000
LD50/LC50:
CAS# 100-54-9: Oral, rat: LD50 = 1185 mg/kg.
Skin, rabbit: LDLo = 4000
Carcinogenicity:
3-Cyanopyridine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 100-54-9: 1
Canada
CAS# 100-54-9 is listed on Canada's NDSL List.
CAS# 100-54-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 100-54-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/05/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
O-Benzylbenzyl Alcohol, 97%
| 1586-00-1 |
|
M-Hydroxybenzylhydrazine Dihydrochloride, 98%
| 81012-99-9 |
|
trans-Cinnamaldehyde, p.a.
| 104-55-2 |
|
Zinc fluoride, 99%
| 7783-49-5 |
|
Deuterium Chloride, 20 wt.% Solution in D2O, 100.0 Atom % D
| 7698-05-7 |
|
Acetyl bromide, 98%
| 506-96-7 |
|
Amberlyst ?? A-21 ion-exchange resin
| 9049-93-8 |
|
5,5-Dimethyl-1,3-cyclohexanedione, 99%
| 126-81-8 |
|
2,2-Dichlorooctanal, 85%
| 50735-74-5 |
|
Butyl butyrate, 98%
| 109-21-7 |
|
4-(3-(Trifluoromethyl)phenyl)-4-Piperidinol. 97%
| 2249-28-7 |
|
Fullerene C-70
| 115383-22-7 |
|
4-tert-Butylcalix (4) Arene, 99% (TLC)
| 60705-62-6 |
|
O-Methoxybenzylamine, 98%
| 6850-57-3 |
|
3-Bromo-1-propanol, 92% (GC)
| 627-18-9 |
|
2-Methyl-2-pentanol, 99%
| 590-36-3 |
|
Tartrazine
| 1934-21-0 |
|
Cyclohexylamine Hydrochloride, 99%
| 4998-76-9 |
|
Cyclohexylphenylacetic Acid, 99%
| 3894-09-5 |
|
Oxazolo[4,5-b]pyridin-2(3h)thione
| 53052-06-5 |
|
3-Nitrobenzyl chloride, 99% (titr.)
| 619-21-6 |
|
Coumarin 153, Laser Grade
| 53518-18-6 |
|
Pentene (Techn)
| 25377-72-4 |
|
Antimony(V)-Pentachloride, Anhydrous, 99%
| 7647-18-9 |
|
4-Biphenylcarboxylic acid 99%
| 92-92-2 |
|
Anhydrotetracycline Hydrochloride,"can be used as Secondary
| 13803-65-1 |
|
Tetraethylene Glycol Dimethyl Ether, 99%
| 143-24-8 |
|
1,1-Dimethyl-4-Phenylpiperazinium Iodide, 99%
| 54-77-3 |
|
3-Ethoxymethacrolein, Tech., 95%
| 42588-57-8 |
|
2,6-Diethylaniline, P.A.
| 579-66-8 |
|
3,5-Dimethylanisole, 99%
| 874-63-5 |
|
2-Decalone, Mixture of Cis and Trans, Tech.
| 4832-17-1 |
|
4-Imidazoleacetic Acid Hydrochloride, 99%
| 3251-69-2 |
|
Tris Ortho Xenyl Phosphite, 95%
| 2752-19-4 |
|
Carbobenzyloxyglycine, 98.5%
| 1138-80-3 |
|
(2r,3s)-1-carboxy-4-phenyl-2,3-dihydroxycyclohexa-4,6-diene,potassium
| |
|
4-(2-Aminoethyl)benzene sulfonamide, 99%
| 35303-76-5 |
|
p-Tolylhydrazine hydrochloride, 98%
| 637-60-5 |
|
3-Cyanopyridine, 98%
| 100-54-9 |
|
Tetrahydro-4H-pyran-4-one, 99%
| 29943-42-8 |
|
Potassium cyclohexanebutyrate, 16.6-18.8% potassium
| 62638-03-3 |
|
5-Cyanoindole, 99%
| 15861-24-2 |
|
Purpurin
| 81-54-9 |
|
Phosphorus(III) iodide, 99+%
| 13455-01-1 |
|
1-Methylindole, 98+%
| 603-76-9 |
|
2,2-Dichloroacetamide, 93%
| 683-72-7 |
|
1-Ethylpiperazine, 98+%
| 5308-25-8 |
|
Tris(hydroxymethyl)aminomethane hemisulfate, 99%
| 6992-38-7 |
|
1-Chlorohexadecane, Ca. 97%(GC)
| 4860-03-1 |
|
3-Methyl-2-pentanol, 99%
| 565-60-6 |
|
|