**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7647-18-9 |Antimony(V)-Pentachloride | 99 | 231-601-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34 37
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns. Irritating to respiratory
system.Corrosive.Water-reactive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns. May cause perforation of the
digestive tract.
Inhalation:
Harmful if inhaled. May cause severe irritation of the respiratory
tract with sore throat, coughing, shortness of breath and delayed
lung edema.
Chronic:
May cause reproductive and fetal effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases may
be generated by thermal decomposition or combustion. Use water spray
to keep fire-exposed containers cool. Vapors may be heavier than
air. They can spread along the ground and collect in low or confined
areas.
Extinguishing Media:
Do NOT use water directly on fire. Substance is noncombustible; use
agent most appropriate to extinguish surrounding fire. Do NOT get
water inside containers. Cool containers with flooding quantities of
water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Do not get water inside containers. Use water spray to
reduce vapors or divert vapor cloud drift.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Do not get in eyes, on skin, or on clothing.
Keep container tightly closed. Do not ingest or inhale. Do not allow
contact with water. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket. Corrosives area. Water free area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 7647-18-9:
United Kingdom, WEL - TWA: (listed as antimony compounds): 0.5 mg
TWA (except stibine, as Sb)
United Kingdom, WEL - STEL: (listed as antimony compounds): 1.5 m
STEL (except stibine, as Sb)
United States OSHA: 0.5 mg/m3 TWA (listed under Antimony).0.5 mg
TWA (as Sb) (listed under Antimony compounds).
Belgium - TWA: (listed as antimony compounds): 0.5 mg/m3 VLE (as
France - VME: (listed as antimony compounds): 0.5 mg/m3 VME (as S
Germany: (listed as antimony compounds): 0.5 mg/m3 VME (as Sb)
Japan: (listed as antimony compounds): 0.1 mg/m3 OEL (except stib
as Sb)
Malaysia: (listed as antimony compounds): 0.5 mg/m3 TWA (as Sb)
Netherlands: (listed as antimony compounds): 0.5 mg/m3 MAC (as Sb
Russia: 0.3 mg/m3 TWA
Russia: (listed as antimony): 0.2 mg/m3 STEL
Spain: (listed as antimony compounds): 0.5 mg/m3 VLA-ED (except
antimony hydride, as Sb)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to yellow
Odor: Offensive odor.
pH: Not available.
Vapor Pressure: 1 mm Hg @ 20 C
Viscosity: Not available.
Boiling Point: 140 deg C (decomposes)
Freezing/Melting Point: 2.8 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 77 C
Solubility in water: Reacts with water.
Specific Gravity/Density: 2.3
Molecular Formula: Cl5Sb
Molecular Weight: 298.975
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, contact with water, temperatures above 50C
(122F), exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents and moist air or water.
Hazardous Decomposition Products:
Hydrogen chloride, irritating and toxic fumes and gases,
antimony/antimony oxides, chlorine.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7647-18-9: CC5075000
LD50/LC50:
CAS# 7647-18-9: Inhalation, mouse: LC50 = 620 mg/m3; Inhalation,
rat: LC50 = 720 mg/m3/2H; Oral, rat: LD50 = 1115 mg/kg.
Carcinogenicity:
Antimony(V)-Pentachloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ANTIMONY PENTACHLORIDE, LIQUID
Hazard Class: 8
UN Number: 1730
Packing Group: II
IMO
Shipping Name: ANTIMONY PENTACHLORIDE, LIQUID
Hazard Class: 8
UN Number: 1730
Packing Group: II
RID/ADR
Shipping Name: ANTIMONY PENTACHLORIDE, LIQUID
Hazard Class: 8
UN Number: 1730
Packing group: II
USA RQ: CAS# 7647-18-9: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
R 37 Irritating to respiratory system.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7647-18-9: No information available.
Canada
CAS# 7647-18-9 is listed on Canada's DSL List.
CAS# 7647-18-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7647-18-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/12/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
O-Benzylbenzyl Alcohol, 97%
| 1586-00-1 |
|
M-Hydroxybenzylhydrazine Dihydrochloride, 98%
| 81012-99-9 |
|
trans-Cinnamaldehyde, p.a.
| 104-55-2 |
|
Zinc fluoride, 99%
| 7783-49-5 |
|
Deuterium Chloride, 20 wt.% Solution in D2O, 100.0 Atom % D
| 7698-05-7 |
|
Acetyl bromide, 98%
| 506-96-7 |
|
Amberlyst ?? A-21 ion-exchange resin
| 9049-93-8 |
|
5,5-Dimethyl-1,3-cyclohexanedione, 99%
| 126-81-8 |
|
2,2-Dichlorooctanal, 85%
| 50735-74-5 |
|
Butyl butyrate, 98%
| 109-21-7 |
|
4-(3-(Trifluoromethyl)phenyl)-4-Piperidinol. 97%
| 2249-28-7 |
|
Fullerene C-70
| 115383-22-7 |
|
4-tert-Butylcalix (4) Arene, 99% (TLC)
| 60705-62-6 |
|
O-Methoxybenzylamine, 98%
| 6850-57-3 |
|
3-Bromo-1-propanol, 92% (GC)
| 627-18-9 |
|
2-Methyl-2-pentanol, 99%
| 590-36-3 |
|
Tartrazine
| 1934-21-0 |
|
Cyclohexylamine Hydrochloride, 99%
| 4998-76-9 |
|
Cyclohexylphenylacetic Acid, 99%
| 3894-09-5 |
|
Oxazolo[4,5-b]pyridin-2(3h)thione
| 53052-06-5 |
|
3-Nitrobenzyl chloride, 99% (titr.)
| 619-21-6 |
|
Coumarin 153, Laser Grade
| 53518-18-6 |
|
Pentene (Techn)
| 25377-72-4 |
|
Antimony(V)-Pentachloride, Anhydrous, 99%
| 7647-18-9 |
|
4-Biphenylcarboxylic acid 99%
| 92-92-2 |
|
Anhydrotetracycline Hydrochloride,"can be used as Secondary
| 13803-65-1 |
|
Tetraethylene Glycol Dimethyl Ether, 99%
| 143-24-8 |
|
1,1-Dimethyl-4-Phenylpiperazinium Iodide, 99%
| 54-77-3 |
|
3-Ethoxymethacrolein, Tech., 95%
| 42588-57-8 |
|
2,6-Diethylaniline, P.A.
| 579-66-8 |
|
3,5-Dimethylanisole, 99%
| 874-63-5 |
|
2-Decalone, Mixture of Cis and Trans, Tech.
| 4832-17-1 |
|
4-Imidazoleacetic Acid Hydrochloride, 99%
| 3251-69-2 |
|
Tris Ortho Xenyl Phosphite, 95%
| 2752-19-4 |
|
Carbobenzyloxyglycine, 98.5%
| 1138-80-3 |
|
(2r,3s)-1-carboxy-4-phenyl-2,3-dihydroxycyclohexa-4,6-diene,potassium
| |
|
4-(2-Aminoethyl)benzene sulfonamide, 99%
| 35303-76-5 |
|
p-Tolylhydrazine hydrochloride, 98%
| 637-60-5 |
|
3-Cyanopyridine, 98%
| 100-54-9 |
|
Tetrahydro-4H-pyran-4-one, 99%
| 29943-42-8 |
|
Potassium cyclohexanebutyrate, 16.6-18.8% potassium
| 62638-03-3 |
|
5-Cyanoindole, 99%
| 15861-24-2 |
|
Purpurin
| 81-54-9 |
|
Phosphorus(III) iodide, 99+%
| 13455-01-1 |
|
1-Methylindole, 98+%
| 603-76-9 |
|
2,2-Dichloroacetamide, 93%
| 683-72-7 |
|
1-Ethylpiperazine, 98+%
| 5308-25-8 |
|
Tris(hydroxymethyl)aminomethane hemisulfate, 99%
| 6992-38-7 |
|
1-Chlorohexadecane, Ca. 97%(GC)
| 4860-03-1 |
|
3-Methyl-2-pentanol, 99%
| 565-60-6 |
|
|