**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7783-49-5 |Zinc fluoride | 99 | 232-001-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
May cause severe irritation and possible burns.
Ingestion:
Exposure to fluoride compounds can result in systemic toxic effects
on the heart, liver, and kidneys. It may also deplete calcium
levels in the body leading to hypocalcemia and death. The oral human
LDLo for the fluoride ion (CAS= 16984-48-8) is 50 mg/kg. Acute
fluoride intoxication produces nausea, vomiting, abdominal pain,
diarrhea and tetany, often resulting in death from cardiovascular
collapse.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract.
Chronic:
Chronic inhalation and ingestion may cause chronic fluoride
poisoning (fluorosis) characterized by weight loss, weakness,
anemia, brittle bones, and stiff joints.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious
and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Do not get
on skin or in eyes. Do not ingest or inhale.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Personal Protective Equipment
Eyes:
Wear safety glasses and chemical goggles if splashing
is possible.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: none reported
pH: acidic in water
Vapor Pressure: 1 mm Hg @ 970 deg C
Viscosity: Not available.
Boiling Point: 1500 deg C @ 760 mm Hg
Freezing/Melting Point: 872 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: slightly soluble
Specific Gravity/Density: 4.9500 g/cm3
Molecular Formula: F2Zn
Molecular Weight: 103.38
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Bases.
Hazardous Decomposition Products:
Hydrogen fluoride gas, zinc oxides.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7783-49-5: ZH3500000
LD50/LC50:
Not available.
Frog LDLo subcutaneous: 280 mg/kg.
fluoride ion)
Carcinogenicity:
Zinc fluoride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ:CAS# 7783-49-5: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 7783-49-5: No information available.
United Kingdom Occupational Exposure Limits
CAS# 7783-49-5: OES-United Kingdom, TWA (listed as ** undefined
**): 2.5 mg/m3 TWA (inorganic, as F)
United Kingdom Maximum Exposure Limits
Canada
CAS# 7783-49-5 is listed on Canada's DSL List.
CAS# 7783-49-5 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 7783-49-5: OEL-AUSTRALIA:TWA 2.5 mg(F)/m3
OEL-BELGIUM:TWA 2.5 mg(F)/m3
OEL-CZECHOSLOVAKIA:TWA 1 mg(F)/m3;STEL 5 mg(F)/m3
OEL-DENMARK:TWA 2.5 mg(F)/m3
OEL-FINLAND:TWA 2.5 mg(F)/m3
OEL-FRANCE:TWA 2.5 mg(F)/m3
OEL-GERMANY:TWA 2.5 mg(F)/m3
OEL-HUNGARY:TWA 1 mg(F)/m3;STEL 2 mg(F)/m3
OEL-THE NETHERLANDS:TWA 2.5 mg(F)/m3
OEL-THE PHILIPPINES:TWA 2.5 mg(F)/m3
OEL-POLAND:TWA 1 mg(F)/m3
OEL-RUSSIA:TWA 0.2 ppm;STEL 1 ppm
OEL-SWEDEN:TWA 2 mg(F)/m3
OEL-SWITZERLAND:TWA 1.8 ppm (1.5 mg(F)/m3);STEL 9.0 ppm
OEL-THAILAND:TWA 2.5 mg(F)/m3
OEL-TURKEY:TWA 2.5 mg(F)/m3
OEL-UNITED KINGDOM:TWA 2.5 mg(F)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 7783-49-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #3 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
O-Benzylbenzyl Alcohol, 97%
| 1586-00-1 |
|
M-Hydroxybenzylhydrazine Dihydrochloride, 98%
| 81012-99-9 |
|
trans-Cinnamaldehyde, p.a.
| 104-55-2 |
|
Zinc fluoride, 99%
| 7783-49-5 |
|
Deuterium Chloride, 20 wt.% Solution in D2O, 100.0 Atom % D
| 7698-05-7 |
|
Acetyl bromide, 98%
| 506-96-7 |
|
Amberlyst ?? A-21 ion-exchange resin
| 9049-93-8 |
|
5,5-Dimethyl-1,3-cyclohexanedione, 99%
| 126-81-8 |
|
2,2-Dichlorooctanal, 85%
| 50735-74-5 |
|
Butyl butyrate, 98%
| 109-21-7 |
|
4-(3-(Trifluoromethyl)phenyl)-4-Piperidinol. 97%
| 2249-28-7 |
|
Fullerene C-70
| 115383-22-7 |
|
4-tert-Butylcalix (4) Arene, 99% (TLC)
| 60705-62-6 |
|
O-Methoxybenzylamine, 98%
| 6850-57-3 |
|
3-Bromo-1-propanol, 92% (GC)
| 627-18-9 |
|
2-Methyl-2-pentanol, 99%
| 590-36-3 |
|
Tartrazine
| 1934-21-0 |
|
Cyclohexylamine Hydrochloride, 99%
| 4998-76-9 |
|
Cyclohexylphenylacetic Acid, 99%
| 3894-09-5 |
|
Oxazolo[4,5-b]pyridin-2(3h)thione
| 53052-06-5 |
|
3-Nitrobenzyl chloride, 99% (titr.)
| 619-21-6 |
|
Coumarin 153, Laser Grade
| 53518-18-6 |
|
Pentene (Techn)
| 25377-72-4 |
|
Antimony(V)-Pentachloride, Anhydrous, 99%
| 7647-18-9 |
|
4-Biphenylcarboxylic acid 99%
| 92-92-2 |
|
Anhydrotetracycline Hydrochloride,"can be used as Secondary
| 13803-65-1 |
|
Tetraethylene Glycol Dimethyl Ether, 99%
| 143-24-8 |
|
1,1-Dimethyl-4-Phenylpiperazinium Iodide, 99%
| 54-77-3 |
|
3-Ethoxymethacrolein, Tech., 95%
| 42588-57-8 |
|
2,6-Diethylaniline, P.A.
| 579-66-8 |
|
3,5-Dimethylanisole, 99%
| 874-63-5 |
|
2-Decalone, Mixture of Cis and Trans, Tech.
| 4832-17-1 |
|
4-Imidazoleacetic Acid Hydrochloride, 99%
| 3251-69-2 |
|
Tris Ortho Xenyl Phosphite, 95%
| 2752-19-4 |
|
Carbobenzyloxyglycine, 98.5%
| 1138-80-3 |
|
(2r,3s)-1-carboxy-4-phenyl-2,3-dihydroxycyclohexa-4,6-diene,potassium
| |
|
4-(2-Aminoethyl)benzene sulfonamide, 99%
| 35303-76-5 |
|
p-Tolylhydrazine hydrochloride, 98%
| 637-60-5 |
|
3-Cyanopyridine, 98%
| 100-54-9 |
|
Tetrahydro-4H-pyran-4-one, 99%
| 29943-42-8 |
|
Potassium cyclohexanebutyrate, 16.6-18.8% potassium
| 62638-03-3 |
|
5-Cyanoindole, 99%
| 15861-24-2 |
|
Purpurin
| 81-54-9 |
|
Phosphorus(III) iodide, 99+%
| 13455-01-1 |
|
1-Methylindole, 98+%
| 603-76-9 |
|
2,2-Dichloroacetamide, 93%
| 683-72-7 |
|
1-Ethylpiperazine, 98+%
| 5308-25-8 |
|
Tris(hydroxymethyl)aminomethane hemisulfate, 99%
| 6992-38-7 |
|
1-Chlorohexadecane, Ca. 97%(GC)
| 4860-03-1 |
|
3-Methyl-2-pentanol, 99%
| 565-60-6 |
|
|