**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 619-21-6 |Benzoic acid, 3-formyl- | 98 | 210-585-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Lachrymator
(substance which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears).
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. May cause burning
sensation, coughing, wheezing, laryngitis, shortness of breath,
headache, nausea, and vomiting. Causes corrosive action on the mucous
membranes.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. During a fire, irritating and
highly toxic gases may be generated by thermal decomposition or
combustion. Vapors may be heavier than air. They can spread along
the ground and collect in low or confined areas. Containers may
explode when heated. Combustible material; may burn but does not
ignite readily. Water hydrolyzes material liberating acidic gas which
in contact with metal surfaces can generate flammable and/or
explosive hydrogen gas.
Extinguishing Media:
DO NOT USE WATER! In case of fire, use carbon dioxide, dry chemical
powder or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Cover with sand, dry lime or soda ash and place in a closed
container for disposal. Provide ventilation. Do not get water inside
containers. Cover with plastic sheet to prevent spreading.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Keep container
tightly closed. Do not get on skin or in eyes. Do not ingest or
inhale. Discard contaminated shoes.
Storage:
Keep away from water. Keep containers tightly closed. Store in a
cool, dry area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 619-21-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: light yellow to tan
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 175 -183 deg C @ 30-35 mm Hg
Freezing/Melting Point: 42-47 deg C
Autoignition Temperature: Not applicable.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble.
Specific Gravity/Density: Not available.
Molecular Formula: C7H6ClN02
Molecular Weight: 171.59
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable, however, may violently decompose at temperatures above
125C.
Conditions to Avoid:
Incompatible materials, moisture, temperatures above 125C.
Incompatibilities with Other Materials:
Oxidizing agents, bases, alcohols, amines, steel, moisture.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide,
chloride fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 619-21-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Benzoic acid, 3-formyl- -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 619-21-6: No information available.
Canada
CAS# 619-21-6 is listed on Canada's NDSL List.
CAS# 619-21-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 619-21-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/15/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
O-Benzylbenzyl Alcohol, 97%
| 1586-00-1 |
|
M-Hydroxybenzylhydrazine Dihydrochloride, 98%
| 81012-99-9 |
|
trans-Cinnamaldehyde, p.a.
| 104-55-2 |
|
Zinc fluoride, 99%
| 7783-49-5 |
|
Deuterium Chloride, 20 wt.% Solution in D2O, 100.0 Atom % D
| 7698-05-7 |
|
Acetyl bromide, 98%
| 506-96-7 |
|
Amberlyst ?? A-21 ion-exchange resin
| 9049-93-8 |
|
5,5-Dimethyl-1,3-cyclohexanedione, 99%
| 126-81-8 |
|
2,2-Dichlorooctanal, 85%
| 50735-74-5 |
|
Butyl butyrate, 98%
| 109-21-7 |
|
4-(3-(Trifluoromethyl)phenyl)-4-Piperidinol. 97%
| 2249-28-7 |
|
Fullerene C-70
| 115383-22-7 |
|
4-tert-Butylcalix (4) Arene, 99% (TLC)
| 60705-62-6 |
|
O-Methoxybenzylamine, 98%
| 6850-57-3 |
|
3-Bromo-1-propanol, 92% (GC)
| 627-18-9 |
|
2-Methyl-2-pentanol, 99%
| 590-36-3 |
|
Tartrazine
| 1934-21-0 |
|
Cyclohexylamine Hydrochloride, 99%
| 4998-76-9 |
|
Cyclohexylphenylacetic Acid, 99%
| 3894-09-5 |
|
Oxazolo[4,5-b]pyridin-2(3h)thione
| 53052-06-5 |
|
3-Nitrobenzyl chloride, 99% (titr.)
| 619-21-6 |
|
Coumarin 153, Laser Grade
| 53518-18-6 |
|
Pentene (Techn)
| 25377-72-4 |
|
Antimony(V)-Pentachloride, Anhydrous, 99%
| 7647-18-9 |
|
4-Biphenylcarboxylic acid 99%
| 92-92-2 |
|
Anhydrotetracycline Hydrochloride,"can be used as Secondary
| 13803-65-1 |
|
Tetraethylene Glycol Dimethyl Ether, 99%
| 143-24-8 |
|
1,1-Dimethyl-4-Phenylpiperazinium Iodide, 99%
| 54-77-3 |
|
3-Ethoxymethacrolein, Tech., 95%
| 42588-57-8 |
|
2,6-Diethylaniline, P.A.
| 579-66-8 |
|
3,5-Dimethylanisole, 99%
| 874-63-5 |
|
2-Decalone, Mixture of Cis and Trans, Tech.
| 4832-17-1 |
|
4-Imidazoleacetic Acid Hydrochloride, 99%
| 3251-69-2 |
|
Tris Ortho Xenyl Phosphite, 95%
| 2752-19-4 |
|
Carbobenzyloxyglycine, 98.5%
| 1138-80-3 |
|
(2r,3s)-1-carboxy-4-phenyl-2,3-dihydroxycyclohexa-4,6-diene,potassium
| |
|
4-(2-Aminoethyl)benzene sulfonamide, 99%
| 35303-76-5 |
|
p-Tolylhydrazine hydrochloride, 98%
| 637-60-5 |
|
3-Cyanopyridine, 98%
| 100-54-9 |
|
Tetrahydro-4H-pyran-4-one, 99%
| 29943-42-8 |
|
Potassium cyclohexanebutyrate, 16.6-18.8% potassium
| 62638-03-3 |
|
5-Cyanoindole, 99%
| 15861-24-2 |
|
Purpurin
| 81-54-9 |
|
Phosphorus(III) iodide, 99+%
| 13455-01-1 |
|
1-Methylindole, 98+%
| 603-76-9 |
|
2,2-Dichloroacetamide, 93%
| 683-72-7 |
|
1-Ethylpiperazine, 98+%
| 5308-25-8 |
|
Tris(hydroxymethyl)aminomethane hemisulfate, 99%
| 6992-38-7 |
|
1-Chlorohexadecane, Ca. 97%(GC)
| 4860-03-1 |
|
3-Methyl-2-pentanol, 99%
| 565-60-6 |
|
|