**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 100-74-3 |N-Ethylmorpholine | 99 | 202-885-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 10 20/22 36
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation and if swallowed. Irritating to
eyes.
Potential Health Effects
Eye:
May cause chemical conjunctivitis and corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Ingestion of large amounts may cause CNS depression.
Inhalation:
Aspiration may lead to pulmonary edema. Vapors may cause dizziness
or suffocation. May cause burning sensation in the chest.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Immediately flush
eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Remove
contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately. Do NOT induce
vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls
of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Use agent most appropriate to
extinguish fire. Do NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. A vapor suppressing foam
may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous.
Keep away from heat, sparks and flame. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits. Use process
enclosure, local exhaust ventilation, or other engineering controls
to control airborne levels. Use adequate general or local
explosion-proof ventilation to keep airborne levels to acceptable
levels.
Exposure Limits
CAS# 100-74-3:
United Kingdom, WEL - TWA: 5 ppm TWA; 24 mg/m3 TWA
United Kingdom, WEL - STEL: 20 ppm STEL; 96 mg/m3 STEL
United States OSHA: 20 ppm TWA; 94 mg/m3 TWA
Belgium - TWA: 5 ppm VLE; 24 mg/m3 VLE
France - VME: 5 ppm VME; 23 mg/m3 VME
Germany: 23 mg/m3 TWA
Germany: Skin absorber
Malaysia: 5 ppm TWA; 24 mg/m3 TWA
Netherlands: 5 ppm MAC; 23 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 5 ppm VLA-ED; 24 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear chemical splash goggles. Wear safety glasses and
chemical goggles if splashing is possible.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure. Wear appropriate protective
gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Wear a NIOSH/MSHA
or European Standard EN 149 approved full-facepiece
airline respirator in the positive pressure mode with
emergency escape provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 8.1 hPa @ 20 C
Viscosity: Not available.
Boiling Point: 139 deg C @ 760.00mmHg
Freezing/Melting Point: -63 deg C
Autoignition Temperature: Not available.
Flash Point: 27 deg C ( 80.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible with water
Specific Gravity/Density: .9050g/cm3
Molecular Formula: C6H13NO
Molecular Weight: 115.17
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 100-74-3: QE4025000
LD50/LC50:
CAS# 100-74-3: Inhalation, mouse: LC50 = 18000 mg/m3/2H; Oral,
mouse: LD50 = 1200 mg/kg; Oral, rat: LD50 = 1780 mg/kg.
Carcinogenicity:
N-Ethylmorpholine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20/22 Harmful by inhalation and if swallowed.
R 36 Irritating to eyes.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 100-74-3: 1
Canada
CAS# 100-74-3 is listed on Canada's DSL List.
CAS# 100-74-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 100-74-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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Methyl Trifluoromethanesulfonate, 96+% (GC )
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| 10463-20-4 |
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| 0-00-1 |
|
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| 10191-18-1 |
|
1,5-bis(methylamino)-3-oxapentane, 98%
| |
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Ursodeoxycholic acid, 99%
| 128-13-2 |
|
4'-Chloropropiophenone, 97%
| 6285-05-8 |
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| 1760-24-3 |
|
Mordant brown 6
| 6247-28-5 |
|
2,4-Dichlorobenzaldehyde, 98%
| 874-42-0 |
|
2,3-Dichloro-1-propanol
| 616-23-9 |
|
N-Acryloxysuccinimide, 99% (Titr.)
| 38862-24-7 |
|
Pyrazine, 99+%
| 290-37-9 |
|
Phenylacetaldehyde (50% wt in isopropyl alcohol)
| 67-63-0 |
|
Glyoxylic acid, 50% in water
| 298-12-4 |
|
Neutron activation standard, long irradiation i
| |
|
1,2,4-Triacetoxybenzene, 97%
| 613-03-6 |
|
3,5-Di-Tert.-Butyl-4-Hydroxybenzaldehyde, 97%
| 1620-98-0 |
|
N-Ethylmorpholine, 99%
| 100-74-3 |
|
BOC-L-Threonine, 98%
| 2592-18-9 |
|
3-Chlorotoluene, 97%
| 108-41-8 |
|
Benzoyl cyanide 98%
| 613-90-1 |
|
2-(3-Chloropropyl)-2-(4-fluorophenyl)-1,3 -dioxolane, 97%
| 3308-94-9 |
|
Propiophenone, 99%
| 93-55-0 |
|
2,5-Dichlorobenzoic acid, 97%
| 50-79-3 |
|
Cyclononanone, 95%
| 3350-30-9 |
|
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| 5691-37-2 |
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| 1910-42-5 |
|
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| 533-31-3 |
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| 601-75-2 |
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4-Hydroxybenzoic acid hydrazide 98%
| 5351-23-5 |
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4-Hydroxyisophthalic Acid, 98%
| 636-46-4 |
|
Phenylselenyl iodide, 99+%
| 81926-79-6 |
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2-Methylcyclopentanone, 99%
| 1120-72-5 |
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| 56539-66-3 |
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