**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 613-90-1 |Benzoyl cyanide | 98 | 210-359-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.Moisture
sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema. Inhalation at high concentrations may cause CNS depression and
asphixiation. Harmful if inhaled.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode
when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use extinguishing
media most appropriate for the surrounding fire. Do NOT get water
inside containers. Use water spray, dry chemical, carbon dioxide, or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Avoid
generating dusty conditions. Remove all sources of ignition. Use a
spark-proof tool. Provide ventilation. Do not get water inside
containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Do not
get in eyes, on skin, or on clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame. Do
not ingest or inhale. Do not allow contact with water. Use only in a
chemical fume hood. Discard contaminated shoes. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames. Keep from contact with moist air and
steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 613-90-1:
United States OSHA: 5 mg/m3 TWA (listed under Cyanide anion).
Germany: (listed as cyanide anion): Skin absorber
Netherlands: (listed as cyanide anion): 5 mg/m3 MAC (as CN)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 206 deg C @ 760.00 mmHg
Freezing/Melting Point: 29-32 deg C
Autoignition Temperature: Not applicable.
Flash Point: 84 deg C ( 183.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density:
Molecular Formula: C8H5NO
Molecular Weight: 131.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Moisture sensitive.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong acids, strong
bases, moisture.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 613-90-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Benzoyl cyanide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 3.29-6.28 mg/L; 5,15,30
min; Microtox test at 15 C
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 613-90-1: 3
Canada
CAS# 613-90-1 is listed on Canada's NDSL List.
CAS# 613-90-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 613-90-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/03/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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3-Amino-1,2-propanediol, 98%
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1-Bromo-2,6-difluorobenzene
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2,4-Dichloroaniline, 98%
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5-Hexen-2-one, 98%
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5-FLUORESCEIN ISOTHIOCYANATE (CERT)
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Coumarin 4, Laser Grade
| 90-33-5 |
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2-Chloro-5-Methylphenol, 99%
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3-Methyl-2-thiophenecarboxaldehyde, tech.
| 5834-16-2 |
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Cesium Hydroxide, 99.5%, Monohydrate, may contain various amounts of
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Ethyl sulfone, 99+%
| 597-35-3 |
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Diglycolic Anhydride, 97%
| 4480-83-5 |
|
Methyl Trifluoromethanesulfonate, 96+% (GC )
| 333-27-7 |
|
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| 497-18-7 |
|
4-Hydroxy-3-Nitrophenylacetic Acid, 99%
| 10463-20-4 |
|
3-(5-Fluoro-2,4-dinitroanilino)-PROXYL, free radical, 98%
| 73784-45-9 |
|
4,5-Dihydro-6-Methyl-3(2H)-Pyridazinone Hydrate, 98%
| 0-00-1 |
|
Bes (N,N-Bis-(2-Hydroxyethyl)-2- Aminoethanesulfonic Acid), 99+%
| 10191-18-1 |
|
1,5-bis(methylamino)-3-oxapentane, 98%
| |
|
Ursodeoxycholic acid, 99%
| 128-13-2 |
|
4'-Chloropropiophenone, 97%
| 6285-05-8 |
|
N-[3-(Trimethoxysilyl)propyl]ethylenediamine, 97%
| 1760-24-3 |
|
Mordant brown 6
| 6247-28-5 |
|
2,4-Dichlorobenzaldehyde, 98%
| 874-42-0 |
|
2,3-Dichloro-1-propanol
| 616-23-9 |
|
N-Acryloxysuccinimide, 99% (Titr.)
| 38862-24-7 |
|
Pyrazine, 99+%
| 290-37-9 |
|
Phenylacetaldehyde (50% wt in isopropyl alcohol)
| 67-63-0 |
|
Glyoxylic acid, 50% in water
| 298-12-4 |
|
Neutron activation standard, long irradiation i
| |
|
1,2,4-Triacetoxybenzene, 97%
| 613-03-6 |
|
3,5-Di-Tert.-Butyl-4-Hydroxybenzaldehyde, 97%
| 1620-98-0 |
|
N-Ethylmorpholine, 99%
| 100-74-3 |
|
BOC-L-Threonine, 98%
| 2592-18-9 |
|
3-Chlorotoluene, 97%
| 108-41-8 |
|
Benzoyl cyanide 98%
| 613-90-1 |
|
2-(3-Chloropropyl)-2-(4-fluorophenyl)-1,3 -dioxolane, 97%
| 3308-94-9 |
|
Propiophenone, 99%
| 93-55-0 |
|
2,5-Dichlorobenzoic acid, 97%
| 50-79-3 |
|
Cyclononanone, 95%
| 3350-30-9 |
|
Cis-2-Hydroxymethyl-1-Cyclohexylamine, Hydrochloride, 99%
| 5691-37-2 |
|
Methyl Viologen hydrate
| 1910-42-5 |
|
Sesamol, 98%
| 533-31-3 |
|
Ethylmalonic acid, 97%
| 601-75-2 |
|
4-Hydroxybenzoic acid hydrazide 98%
| 5351-23-5 |
|
4-Hydroxyisophthalic Acid, 98%
| 636-46-4 |
|
Phenylselenyl iodide, 99+%
| 81926-79-6 |
|
2-Methylcyclopentanone, 99%
| 1120-72-5 |
|
3-Methyl-3-methoxybutanol, 99%
| 56539-66-3 |
|
|