**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 298-12-4 |Glyoxylic acid | 50 | 206-058-5 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 50 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 34 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns. May cause sensitization by skin contact.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Effects may be delayed. Repeated or prolonged exposure may cause
allergic reactions in sensitive individuals.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Reacts with most metals
in the presence of moisture, liberating extremely flammable hydrogen
gas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Do not get in eyes, on skin, or on clothing. Keep
container tightly closed. Discard contaminated shoes. Use only with
adequate ventilation. Do not breathe vapor or mist.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Corrosives area. Keep away from strong bases.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 298-12-4:
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: pale-yellow
Odor: obnoxious odor
pH: acidic
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 111 deg C
Freezing/Melting Point: -93 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.3000 g/cm3
Molecular Formula: C2H2O3
Molecular Weight: 74.04
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Metals, strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 298-12-4: MD4550000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Glyoxylic acid -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 298-12-4: No information available.
CAS# 7732-18-5: No information available.
Canada
CAS# 298-12-4 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 298-12-4 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 298-12-4 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 7/08/1999 Revision #2 Date: 9/04/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,7-Naphthalenedisulfonic acid disodium salt, 95+% (uv-vis)
| 1655-35-2 |
|
1-(O-Tolyl)Piperazine Dihydro-Chloride, 98% (Titr.)
| 70849-60-4 |
|
3-Amino-1,2-propanediol, 98%
| 616-30-8 |
|
1-Bromo-2,6-difluorobenzene
| 64248-56-2 |
|
2,4-Dichloroaniline, 98%
| 554-00-7 |
|
5-Hexen-2-one, 98%
| 109-49-9 |
|
5-FLUORESCEIN ISOTHIOCYANATE (CERT)
| 3326-32-7 |
|
Coumarin 4, Laser Grade
| 90-33-5 |
|
2-Chloro-5-Methylphenol, 99%
| 615-74-7 |
|
3-Methyl-2-thiophenecarboxaldehyde, tech.
| 5834-16-2 |
|
Cesium Hydroxide, 99.5%, Monohydrate, may contain various amounts of
| 35103-79-8 |
|
Ethyl sulfone, 99+%
| 597-35-3 |
|
Diglycolic Anhydride, 97%
| 4480-83-5 |
|
Methyl Trifluoromethanesulfonate, 96+% (GC )
| 333-27-7 |
|
Carbohydrazide, 97% (Titr.)
| 497-18-7 |
|
4-Hydroxy-3-Nitrophenylacetic Acid, 99%
| 10463-20-4 |
|
3-(5-Fluoro-2,4-dinitroanilino)-PROXYL, free radical, 98%
| 73784-45-9 |
|
4,5-Dihydro-6-Methyl-3(2H)-Pyridazinone Hydrate, 98%
| 0-00-1 |
|
Bes (N,N-Bis-(2-Hydroxyethyl)-2- Aminoethanesulfonic Acid), 99+%
| 10191-18-1 |
|
1,5-bis(methylamino)-3-oxapentane, 98%
| |
|
Ursodeoxycholic acid, 99%
| 128-13-2 |
|
4'-Chloropropiophenone, 97%
| 6285-05-8 |
|
N-[3-(Trimethoxysilyl)propyl]ethylenediamine, 97%
| 1760-24-3 |
|
Mordant brown 6
| 6247-28-5 |
|
2,4-Dichlorobenzaldehyde, 98%
| 874-42-0 |
|
2,3-Dichloro-1-propanol
| 616-23-9 |
|
N-Acryloxysuccinimide, 99% (Titr.)
| 38862-24-7 |
|
Pyrazine, 99+%
| 290-37-9 |
|
Phenylacetaldehyde (50% wt in isopropyl alcohol)
| 67-63-0 |
|
Glyoxylic acid, 50% in water
| 298-12-4 |
|
Neutron activation standard, long irradiation i
| |
|
1,2,4-Triacetoxybenzene, 97%
| 613-03-6 |
|
3,5-Di-Tert.-Butyl-4-Hydroxybenzaldehyde, 97%
| 1620-98-0 |
|
N-Ethylmorpholine, 99%
| 100-74-3 |
|
BOC-L-Threonine, 98%
| 2592-18-9 |
|
3-Chlorotoluene, 97%
| 108-41-8 |
|
Benzoyl cyanide 98%
| 613-90-1 |
|
2-(3-Chloropropyl)-2-(4-fluorophenyl)-1,3 -dioxolane, 97%
| 3308-94-9 |
|
Propiophenone, 99%
| 93-55-0 |
|
2,5-Dichlorobenzoic acid, 97%
| 50-79-3 |
|
Cyclononanone, 95%
| 3350-30-9 |
|
Cis-2-Hydroxymethyl-1-Cyclohexylamine, Hydrochloride, 99%
| 5691-37-2 |
|
Methyl Viologen hydrate
| 1910-42-5 |
|
Sesamol, 98%
| 533-31-3 |
|
Ethylmalonic acid, 97%
| 601-75-2 |
|
4-Hydroxybenzoic acid hydrazide 98%
| 5351-23-5 |
|
4-Hydroxyisophthalic Acid, 98%
| 636-46-4 |
|
Phenylselenyl iodide, 99+%
| 81926-79-6 |
|
2-Methylcyclopentanone, 99%
| 1120-72-5 |
|
3-Methyl-3-methoxybutanol, 99%
| 56539-66-3 |
|
|