**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 554-00-7 |2,4-Dichloroaniline | 98 | 209-057-8 |
|----------------|--------------------------------------|----------|-----------|
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T N
Risk Phrases: 23/24/25 33 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Danger
of cumulative effects. Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause methemoglobinemia, cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood),
convulsions, and death. Methemoglobinemia is characterized by
dizziness, drowsiness, headache, shortness of breath, cyanosis
(bluish discoloration of skin due to deficient oxygenation of the
blood), rapid heart rate and chocolate-brown colored blood. May be
harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May cause methemoglobinemia,
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), convulsions, tachycardia, dyspnea (labored
breathing), and death. Methemoglobinemia is characterized by
dizziness, drowsiness, headache, shortness of breath, cyanosis
(bluish discoloration of skin due to deficient oxygenation of the
blood), rapid heart rate and chocolate-brown blood.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Approach fire from upwind to avoid hazardous vapors and toxic
decomposition products.
Extinguishing Media:
Water or foam may cause frothing. Use water spray, dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Avoid ingestion and
inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 554-00-7:
CAS# 27134-27-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: light gray to light brown
Odor: characteristic odor
pH: Not available.
Vapor Pressure: 0.02 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 242 deg C @ 760 mm Hg
Freezing/Melting Point: 59-63 deg C
Autoignition Temperature: Not available.
Flash Point: > 100 deg C (> 212.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >300 deg C
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C6H5Cl2N
Molecular Weight: 162.02
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, confined spaces.
Incompatibilities with Other Materials:
Oxidizing agents, acids, acid chlorides, acid anhydrides.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide,
aniline.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 554-00-7: BX2600000
CAS# 27134-27-6 unlisted.
LD50/LC50:
CAS# 554-00-7: Oral, mouse: LD50 = 400 mg/kg; Oral, rat: LD50 = 1600
mg/kg.
CAS# 27134-27-6.
Carcinogenicity:
2,4-Dichloroaniline -
Not listed by ACGIH, IARC, or NTP.
Dichloroaniline -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DICHLOROANILINES, SOLID
Hazard Class: 6.1
UN Number: 1590
Packing Group: II
IMO
Shipping Name: DICHLOROANILINES, SOLID
Hazard Class: 6.1
UN Number: 1590
Packing Group: II
RID/ADR
Shipping Name: DICHLOROANILINES
Hazard Class: 6.1
UN Number: 1590
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 33 Danger of cumulative effects.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 554-00-7: 3
CAS# 27134-27-6: No information available.
Canada
CAS# 554-00-7 is listed on Canada's DSL List.
CAS# 554-00-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 27134-27-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 554-00-7 is listed on the TSCA inventory.
CAS# 27134-27-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 1/30/1998 Revision #2 Date: 5/09/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,7-Naphthalenedisulfonic acid disodium salt, 95+% (uv-vis)
| 1655-35-2 |
|
1-(O-Tolyl)Piperazine Dihydro-Chloride, 98% (Titr.)
| 70849-60-4 |
|
3-Amino-1,2-propanediol, 98%
| 616-30-8 |
|
1-Bromo-2,6-difluorobenzene
| 64248-56-2 |
|
2,4-Dichloroaniline, 98%
| 554-00-7 |
|
5-Hexen-2-one, 98%
| 109-49-9 |
|
5-FLUORESCEIN ISOTHIOCYANATE (CERT)
| 3326-32-7 |
|
Coumarin 4, Laser Grade
| 90-33-5 |
|
2-Chloro-5-Methylphenol, 99%
| 615-74-7 |
|
3-Methyl-2-thiophenecarboxaldehyde, tech.
| 5834-16-2 |
|
Cesium Hydroxide, 99.5%, Monohydrate, may contain various amounts of
| 35103-79-8 |
|
Ethyl sulfone, 99+%
| 597-35-3 |
|
Diglycolic Anhydride, 97%
| 4480-83-5 |
|
Methyl Trifluoromethanesulfonate, 96+% (GC )
| 333-27-7 |
|
Carbohydrazide, 97% (Titr.)
| 497-18-7 |
|
4-Hydroxy-3-Nitrophenylacetic Acid, 99%
| 10463-20-4 |
|
3-(5-Fluoro-2,4-dinitroanilino)-PROXYL, free radical, 98%
| 73784-45-9 |
|
4,5-Dihydro-6-Methyl-3(2H)-Pyridazinone Hydrate, 98%
| 0-00-1 |
|
Bes (N,N-Bis-(2-Hydroxyethyl)-2- Aminoethanesulfonic Acid), 99+%
| 10191-18-1 |
|
1,5-bis(methylamino)-3-oxapentane, 98%
| |
|
Ursodeoxycholic acid, 99%
| 128-13-2 |
|
4'-Chloropropiophenone, 97%
| 6285-05-8 |
|
N-[3-(Trimethoxysilyl)propyl]ethylenediamine, 97%
| 1760-24-3 |
|
Mordant brown 6
| 6247-28-5 |
|
2,4-Dichlorobenzaldehyde, 98%
| 874-42-0 |
|
2,3-Dichloro-1-propanol
| 616-23-9 |
|
N-Acryloxysuccinimide, 99% (Titr.)
| 38862-24-7 |
|
Pyrazine, 99+%
| 290-37-9 |
|
Phenylacetaldehyde (50% wt in isopropyl alcohol)
| 67-63-0 |
|
Glyoxylic acid, 50% in water
| 298-12-4 |
|
Neutron activation standard, long irradiation i
| |
|
1,2,4-Triacetoxybenzene, 97%
| 613-03-6 |
|
3,5-Di-Tert.-Butyl-4-Hydroxybenzaldehyde, 97%
| 1620-98-0 |
|
N-Ethylmorpholine, 99%
| 100-74-3 |
|
BOC-L-Threonine, 98%
| 2592-18-9 |
|
3-Chlorotoluene, 97%
| 108-41-8 |
|
Benzoyl cyanide 98%
| 613-90-1 |
|
2-(3-Chloropropyl)-2-(4-fluorophenyl)-1,3 -dioxolane, 97%
| 3308-94-9 |
|
Propiophenone, 99%
| 93-55-0 |
|
2,5-Dichlorobenzoic acid, 97%
| 50-79-3 |
|
Cyclononanone, 95%
| 3350-30-9 |
|
Cis-2-Hydroxymethyl-1-Cyclohexylamine, Hydrochloride, 99%
| 5691-37-2 |
|
Methyl Viologen hydrate
| 1910-42-5 |
|
Sesamol, 98%
| 533-31-3 |
|
Ethylmalonic acid, 97%
| 601-75-2 |
|
4-Hydroxybenzoic acid hydrazide 98%
| 5351-23-5 |
|
4-Hydroxyisophthalic Acid, 98%
| 636-46-4 |
|
Phenylselenyl iodide, 99+%
| 81926-79-6 |
|
2-Methylcyclopentanone, 99%
| 1120-72-5 |
|
3-Methyl-3-methoxybutanol, 99%
| 56539-66-3 |
|
|