**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 10049-05-5 |Chromium(II) chloride | 90 | 233-163-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and
skin.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
May cause respiratory tract irritation. May cause ulceration and
perforation of the nasal septum if inhaled in excessive quantities.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Substance
is noncombustible. Powerful reducing agent.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 10049-05-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: green gray
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 824 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density: 2.900
Molecular Formula: Cl2Cr
Molecular Weight: 122.90
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. However, may decompose if exposed to moist air or water.
Reported to have exploded when in a sealed container. This was most
likely due to pressure of hydrogen by reduction of water.
Conditions to Avoid:
Incompatible materials, moisture, strong oxidants.
Incompatibilities with Other Materials:
Active metals, oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 10049-05-5: GB5250000
LD50/LC50:
CAS# 10049-05-5: Oral, rat: LD50 = 1870 mg/kg.
Carcinogenicity:
Chromium(II) chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 10049-05-5: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 22 Do not breathe dust.
S 24 Avoid contact with skin.
S 24/25 Avoid contact with skin and eyes.
S 37 Wear suitable gloves.
WGK (Water Danger/Protection)
CAS# 10049-05-5: No information available.
Canada
CAS# 10049-05-5 is listed on Canada's NDSL List.
CAS# 10049-05-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10049-05-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/09/1998 Revision #5 Date: 6/23/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Lanthanum(iii)chloride hydrated,64.5-70% LaCl3
| 20211-76-1 |
|
2-Fluorobenzyl bromide, 98%
| 446-48-0 |
|
4-Ethylpyridine, 98%
| 536-75-4 |
|
EEDQ, 99+%
| 16357-59-8 |
|
Oxalic acid, anhydrous
| 144-62-7 |
|
Lithium acetate dihydrate, 98%
| 546-89-4 |
|
2-Bromopropane, 99%
| 75-26-3 |
|
Calcium Turnings, 99.5%
| 7440-70-2 |
|
Tungsten(vi)chloride, 99.9+%
| 13283-01-7 |
|
Fluorescein Diacetate, 99% (UV-VIS)
| 596-09-8 |
|
Brucine
| 357-57-3 |
|
1-Heptanesulfonic acid sodium salt pre- mixed concentrate (low uv)
| 0-00-0 |
|
(R)-(+)-2-Bromopropionic acid, 99% (>85% e.e.)
| 598-72-1 |
|
Phenoxy-2-Propanone, 99%
| 621-87-4 |
|
2,5-Diphenylfuran
| 955-83-9 |
|
5-Methoxyindole-3-acetic acid, 99%
| 3471-31-6 |
|
2-Nitrobenzaldehyde Tosylhydrazone, 99%
| 58809-90-8 |
|
4-(4-Dimethylaminophenylazo)Benzoic Acid Sodium Salt, 98% (UV-VIS)
| 845-46-5 |
|
2-Furaldehyde diethyl acetal, 98%
| 13529-27-6 |
|
New methylene Blue N, 85% (titr.)
| 1934-16-3 |
|
Chromium(II) chloride, 90%
| 10049-05-5 |
|
3-Methyl-2(3H)-benzoxazolethione, 97%
| 13673-63-7 |
|
l-(-)-Allose, 99%
| 7635-11-2 |
|
1-Ethyl-1,4-Dihydro-5H-Tetrazol-5-One 98+%
| 69048-98-2 |
|
Benzohydroxamic acid, 99%
| 495-18-1 |
|
3-(2,3,4-TRIMETHOXYPHENYL)PROPIONIC ACID, 98+%
| 33130-04-0 |
|
2-N-decylaminoethanethiol, 95%
| 5891-06-5 |
|
DL-1,2-Hexanediol, 98+%
| 6920-22-5 |
|
Jenner stain, high purity biological stain
| 62851-42-7 |
|
(4-Bromophenyl)cyclopropylmethanone
| 6952-89-2 |
|
5-Nitro-m-xylene, 99+%
| 99-12-7 |
|
8-Chlorotheophylline, 99%(Titr.)
| 85-18-7 |
|
Cadmium sulfide, 99.999%, -325 Mesh
| 1306-23-6 |
|
Zincon, monosodium salt monohydrate, 80%
| 0-00-0 |
|
2-Chlorobenzyl Chloride, 98+%
| 611-19-8 |
|
Methyl 3-hydroxyisoxazole-5-carboxylate, 99%
| 10068-07-2 |
|
(2S)-2-Boc-Amino-3-Phenylsulfonyl-1-(2-Tetrahydropyranyloxy)Propane,
| 0-01-1 |
|
Propylamine, 99+%
| 107-10-8 |
|
2-Naphthyl Sulfate, Potassium Salt, Hydrate ,99%
| 21409-32-5 |
|
M-Hydroxyphenylacetic Acid, 99+%
| 621-37-4 |
|
Methacrylamide, 98%
| 79-39-0 |
|
1,2,3,4-Dibenzanthracene, 97%
| 215-58-7 |
|
3-Methyl-5-Methoxycarbonyl-4-Piperidone Hydrochloride, 99%
| 0-00-0 |
|
Benzyltributylammonium chloride, 98+%
| 23616-79-7 |
|
N-Acetyl-S-benzyl-L-cysteine methyl ester
| 77549-14-5 |
|
4-Octyloxybenzaldehyde, 98%
| 24083-13-4 |
|
Xylenol blue, indicator grade
| 125-31-5 |
|
1,9-Nonanediol, 99%
| 3937-56-2 |
|
4-(P-Chlorobenzoyl)-Pyridine, 99%
| 14548-48-2 |
|
4-Chlorophenyl Sulfoxide, 97%
| 3085-42-5 |
|
|