**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 6108-17-4 |Lithium acetate dihydrate | 98 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN
Risk Phrases: 22 36 38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes. Irritating to skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic exposure to lithium salts may cause drowsiness, visual
abnormalities, weakness, ringing in the ears, and muscle tremors.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal. Avoid generating dusty conditions.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 546-89-4:
CAS# 6108-17-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: Not available.
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 58 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 21.5 g/100ml ethanol
Specific Gravity/Density:
Molecular Formula: C2H3O2Li.2H2O
Molecular Weight: 102.02
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizers, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, oxides of lithium.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 546-89-4: AI5450000
CAS# 6108-17-4 unlisted.
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
Acetic acid, lithium salt -
Not listed by ACGIH, IARC, or NTP.
Lithium acetate dihydrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36 Irritating to eyes.
R 38 Irritating to skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 546-89-4: 1
CAS# 6108-17-4: No information available.
Canada
CAS# 546-89-4 is listed on Canada's DSL List.
CAS# 546-89-4 is not listed on Canada's Ingredient Disclosure List.
CAS# 6108-17-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 546-89-4 is listed on the TSCA inventory.
CAS# 6108-17-4 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 8/24/1997 Revision #3 Date: 10/30/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Lanthanum(iii)chloride hydrated,64.5-70% LaCl3
| 20211-76-1 |
|
2-Fluorobenzyl bromide, 98%
| 446-48-0 |
|
4-Ethylpyridine, 98%
| 536-75-4 |
|
EEDQ, 99+%
| 16357-59-8 |
|
Oxalic acid, anhydrous
| 144-62-7 |
|
Lithium acetate dihydrate, 98%
| 546-89-4 |
|
2-Bromopropane, 99%
| 75-26-3 |
|
Calcium Turnings, 99.5%
| 7440-70-2 |
|
Tungsten(vi)chloride, 99.9+%
| 13283-01-7 |
|
Fluorescein Diacetate, 99% (UV-VIS)
| 596-09-8 |
|
Brucine
| 357-57-3 |
|
1-Heptanesulfonic acid sodium salt pre- mixed concentrate (low uv)
| 0-00-0 |
|
(R)-(+)-2-Bromopropionic acid, 99% (>85% e.e.)
| 598-72-1 |
|
Phenoxy-2-Propanone, 99%
| 621-87-4 |
|
2,5-Diphenylfuran
| 955-83-9 |
|
5-Methoxyindole-3-acetic acid, 99%
| 3471-31-6 |
|
2-Nitrobenzaldehyde Tosylhydrazone, 99%
| 58809-90-8 |
|
4-(4-Dimethylaminophenylazo)Benzoic Acid Sodium Salt, 98% (UV-VIS)
| 845-46-5 |
|
2-Furaldehyde diethyl acetal, 98%
| 13529-27-6 |
|
New methylene Blue N, 85% (titr.)
| 1934-16-3 |
|
Chromium(II) chloride, 90%
| 10049-05-5 |
|
3-Methyl-2(3H)-benzoxazolethione, 97%
| 13673-63-7 |
|
l-(-)-Allose, 99%
| 7635-11-2 |
|
1-Ethyl-1,4-Dihydro-5H-Tetrazol-5-One 98+%
| 69048-98-2 |
|
Benzohydroxamic acid, 99%
| 495-18-1 |
|
3-(2,3,4-TRIMETHOXYPHENYL)PROPIONIC ACID, 98+%
| 33130-04-0 |
|
2-N-decylaminoethanethiol, 95%
| 5891-06-5 |
|
DL-1,2-Hexanediol, 98+%
| 6920-22-5 |
|
Jenner stain, high purity biological stain
| 62851-42-7 |
|
(4-Bromophenyl)cyclopropylmethanone
| 6952-89-2 |
|
5-Nitro-m-xylene, 99+%
| 99-12-7 |
|
8-Chlorotheophylline, 99%(Titr.)
| 85-18-7 |
|
Cadmium sulfide, 99.999%, -325 Mesh
| 1306-23-6 |
|
Zincon, monosodium salt monohydrate, 80%
| 0-00-0 |
|
2-Chlorobenzyl Chloride, 98+%
| 611-19-8 |
|
Methyl 3-hydroxyisoxazole-5-carboxylate, 99%
| 10068-07-2 |
|
(2S)-2-Boc-Amino-3-Phenylsulfonyl-1-(2-Tetrahydropyranyloxy)Propane,
| 0-01-1 |
|
Propylamine, 99+%
| 107-10-8 |
|
2-Naphthyl Sulfate, Potassium Salt, Hydrate ,99%
| 21409-32-5 |
|
M-Hydroxyphenylacetic Acid, 99+%
| 621-37-4 |
|
Methacrylamide, 98%
| 79-39-0 |
|
1,2,3,4-Dibenzanthracene, 97%
| 215-58-7 |
|
3-Methyl-5-Methoxycarbonyl-4-Piperidone Hydrochloride, 99%
| 0-00-0 |
|
Benzyltributylammonium chloride, 98+%
| 23616-79-7 |
|
N-Acetyl-S-benzyl-L-cysteine methyl ester
| 77549-14-5 |
|
4-Octyloxybenzaldehyde, 98%
| 24083-13-4 |
|
Xylenol blue, indicator grade
| 125-31-5 |
|
1,9-Nonanediol, 99%
| 3937-56-2 |
|
4-(P-Chlorobenzoyl)-Pyridine, 99%
| 14548-48-2 |
|
4-Chlorophenyl Sulfoxide, 97%
| 3085-42-5 |
|
|