**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 536-75-4 |4-Ethylpyridine | 98 | 208-646-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 10 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Causes burns.Stench.Corrosive.
Potential Health Effects
Eye:
Causes eye irritation and possible burns. May cause chemical
conjunctivitis and corneal damage.
Skin:
Causes skin irritation and possible burns. May cause cyanosis of the
extremities. May cause skin rash (in milder cases), and cold and
clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. Ingestion of large amounts may cause CNS depression. May
cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. Vapors may cause dizziness or suffocation. May
cause systemic effects. May cause burning sensation in the chest.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Water may be
ineffective. Material is lighter than water and a fire may be spread
by the use of water. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They
can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Use agent most appropriate to
extinguish fire. Do NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Do not get in eyes,
on skin, or on clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Do not ingest or
inhale. Discard contaminated shoes. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 536-75-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear very slight yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 168 deg C @ 760.00 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 47 deg C ( 116.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 0.9420 g/cm3
Molecular Formula: C7H9N
Molecular Weight: 107.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 536-75-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Ethylpyridine -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 34 Causes burns.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 536-75-4: 2
Canada
CAS# 536-75-4 is listed on Canada's DSL List.
CAS# 536-75-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 536-75-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Lanthanum(iii)chloride hydrated,64.5-70% LaCl3
| 20211-76-1 |
|
2-Fluorobenzyl bromide, 98%
| 446-48-0 |
|
4-Ethylpyridine, 98%
| 536-75-4 |
|
EEDQ, 99+%
| 16357-59-8 |
|
Oxalic acid, anhydrous
| 144-62-7 |
|
Lithium acetate dihydrate, 98%
| 546-89-4 |
|
2-Bromopropane, 99%
| 75-26-3 |
|
Calcium Turnings, 99.5%
| 7440-70-2 |
|
Tungsten(vi)chloride, 99.9+%
| 13283-01-7 |
|
Fluorescein Diacetate, 99% (UV-VIS)
| 596-09-8 |
|
Brucine
| 357-57-3 |
|
1-Heptanesulfonic acid sodium salt pre- mixed concentrate (low uv)
| 0-00-0 |
|
(R)-(+)-2-Bromopropionic acid, 99% (>85% e.e.)
| 598-72-1 |
|
Phenoxy-2-Propanone, 99%
| 621-87-4 |
|
2,5-Diphenylfuran
| 955-83-9 |
|
5-Methoxyindole-3-acetic acid, 99%
| 3471-31-6 |
|
2-Nitrobenzaldehyde Tosylhydrazone, 99%
| 58809-90-8 |
|
4-(4-Dimethylaminophenylazo)Benzoic Acid Sodium Salt, 98% (UV-VIS)
| 845-46-5 |
|
2-Furaldehyde diethyl acetal, 98%
| 13529-27-6 |
|
New methylene Blue N, 85% (titr.)
| 1934-16-3 |
|
Chromium(II) chloride, 90%
| 10049-05-5 |
|
3-Methyl-2(3H)-benzoxazolethione, 97%
| 13673-63-7 |
|
l-(-)-Allose, 99%
| 7635-11-2 |
|
1-Ethyl-1,4-Dihydro-5H-Tetrazol-5-One 98+%
| 69048-98-2 |
|
Benzohydroxamic acid, 99%
| 495-18-1 |
|
3-(2,3,4-TRIMETHOXYPHENYL)PROPIONIC ACID, 98+%
| 33130-04-0 |
|
2-N-decylaminoethanethiol, 95%
| 5891-06-5 |
|
DL-1,2-Hexanediol, 98+%
| 6920-22-5 |
|
Jenner stain, high purity biological stain
| 62851-42-7 |
|
(4-Bromophenyl)cyclopropylmethanone
| 6952-89-2 |
|
5-Nitro-m-xylene, 99+%
| 99-12-7 |
|
8-Chlorotheophylline, 99%(Titr.)
| 85-18-7 |
|
Cadmium sulfide, 99.999%, -325 Mesh
| 1306-23-6 |
|
Zincon, monosodium salt monohydrate, 80%
| 0-00-0 |
|
2-Chlorobenzyl Chloride, 98+%
| 611-19-8 |
|
Methyl 3-hydroxyisoxazole-5-carboxylate, 99%
| 10068-07-2 |
|
(2S)-2-Boc-Amino-3-Phenylsulfonyl-1-(2-Tetrahydropyranyloxy)Propane,
| 0-01-1 |
|
Propylamine, 99+%
| 107-10-8 |
|
2-Naphthyl Sulfate, Potassium Salt, Hydrate ,99%
| 21409-32-5 |
|
M-Hydroxyphenylacetic Acid, 99+%
| 621-37-4 |
|
Methacrylamide, 98%
| 79-39-0 |
|
1,2,3,4-Dibenzanthracene, 97%
| 215-58-7 |
|
3-Methyl-5-Methoxycarbonyl-4-Piperidone Hydrochloride, 99%
| 0-00-0 |
|
Benzyltributylammonium chloride, 98+%
| 23616-79-7 |
|
N-Acetyl-S-benzyl-L-cysteine methyl ester
| 77549-14-5 |
|
4-Octyloxybenzaldehyde, 98%
| 24083-13-4 |
|
Xylenol blue, indicator grade
| 125-31-5 |
|
1,9-Nonanediol, 99%
| 3937-56-2 |
|
4-(P-Chlorobenzoyl)-Pyridine, 99%
| 14548-48-2 |
|
4-Chlorophenyl Sulfoxide, 97%
| 3085-42-5 |
|
|