**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 75-26-3 |2-Bromopropane | 99 | 200-855-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T F
Risk Phrases: 11 48/20 60 66
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful : danger of serious damage to health by
prolonged exposure through inhalation. May impair fertility.
Repeated exposure may cause skin dryness or cracking.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Repeated or prolonged exposure may cause
drying and cracking of the skin.
Ingestion:
May cause central nervous system depression, kidney damage, and
liver damage. Symptoms may include: headache, excitement, fatigue,
nausea, vomiting, stupor, and coma. The toxicological properties of
this substance have not been fully investigated.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those
of acute inhalation and ingestion. Adverse reproductive effects have
been reported in humans.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Flammable liquid and vapor.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation. Approach spill from upwind.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Do not breathe vapor. Use only with adequate ventilation.
Keep away from heat, sparks and flame.
Storage:
Keep away from heat, sparks, and flame. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use explosion-proof ventilation equipment. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 75-26-3:
Japan: 1 ppm OEL; 5 mg/m3 OEL
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 224 mbar @ 20 C
Viscosity: Not available.
Boiling Point: 59 deg C @ 760 mm Hg
Freezing/Melting Point: -89 deg C
Autoignition Temperature: Not available.
Flash Point: 1 deg C ( 33.80 deg F)
Explosion Limits, lower: 4.60 vol %
Explosion Limits, upper: .00 vol %
Decomposition Temperature:
Solubility in water: 0.3g/100ml
Specific Gravity/Density: 1.3100g/cm3
Molecular Formula: C3H7Br
Molecular Weight: 122.99
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-26-3: TX4111000
LD50/LC50:
CAS# 75-26-3: Inhalation, mouse: LC50 = 31171 ppm/4H; Inhalation,
mouse: LC50 = 36000 mg/m3.
Carcinogenicity:
2-Bromopropane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BROMOPROPANES
Hazard Class: 3
UN Number: 2344
Packing Group: II
IMO
Shipping Name: BROMOPROPANES
Hazard Class: 3.2
UN Number: 2344
Packing Group: II
RID/ADR
Shipping Name: BROMOPROPANES
Hazard Class: 3
UN Number: 2344
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
R 48/20 Harmful : danger of serious damage to health
by prolonged exposure through inhalation.
R 60 May impair fertility.
R 66 Repeated exposure may cause skin dryness or
cracking.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 16 Keep away from sources of ignition - No
smoking.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 75-26-3: No information available.
Canada
CAS# 75-26-3 is listed on Canada's DSL List.
CAS# 75-26-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-26-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #3 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Lanthanum(iii)chloride hydrated,64.5-70% LaCl3
| 20211-76-1 |
|
2-Fluorobenzyl bromide, 98%
| 446-48-0 |
|
4-Ethylpyridine, 98%
| 536-75-4 |
|
EEDQ, 99+%
| 16357-59-8 |
|
Oxalic acid, anhydrous
| 144-62-7 |
|
Lithium acetate dihydrate, 98%
| 546-89-4 |
|
2-Bromopropane, 99%
| 75-26-3 |
|
Calcium Turnings, 99.5%
| 7440-70-2 |
|
Tungsten(vi)chloride, 99.9+%
| 13283-01-7 |
|
Fluorescein Diacetate, 99% (UV-VIS)
| 596-09-8 |
|
Brucine
| 357-57-3 |
|
1-Heptanesulfonic acid sodium salt pre- mixed concentrate (low uv)
| 0-00-0 |
|
(R)-(+)-2-Bromopropionic acid, 99% (>85% e.e.)
| 598-72-1 |
|
Phenoxy-2-Propanone, 99%
| 621-87-4 |
|
2,5-Diphenylfuran
| 955-83-9 |
|
5-Methoxyindole-3-acetic acid, 99%
| 3471-31-6 |
|
2-Nitrobenzaldehyde Tosylhydrazone, 99%
| 58809-90-8 |
|
4-(4-Dimethylaminophenylazo)Benzoic Acid Sodium Salt, 98% (UV-VIS)
| 845-46-5 |
|
2-Furaldehyde diethyl acetal, 98%
| 13529-27-6 |
|
New methylene Blue N, 85% (titr.)
| 1934-16-3 |
|
Chromium(II) chloride, 90%
| 10049-05-5 |
|
3-Methyl-2(3H)-benzoxazolethione, 97%
| 13673-63-7 |
|
l-(-)-Allose, 99%
| 7635-11-2 |
|
1-Ethyl-1,4-Dihydro-5H-Tetrazol-5-One 98+%
| 69048-98-2 |
|
Benzohydroxamic acid, 99%
| 495-18-1 |
|
3-(2,3,4-TRIMETHOXYPHENYL)PROPIONIC ACID, 98+%
| 33130-04-0 |
|
2-N-decylaminoethanethiol, 95%
| 5891-06-5 |
|
DL-1,2-Hexanediol, 98+%
| 6920-22-5 |
|
Jenner stain, high purity biological stain
| 62851-42-7 |
|
(4-Bromophenyl)cyclopropylmethanone
| 6952-89-2 |
|
5-Nitro-m-xylene, 99+%
| 99-12-7 |
|
8-Chlorotheophylline, 99%(Titr.)
| 85-18-7 |
|
Cadmium sulfide, 99.999%, -325 Mesh
| 1306-23-6 |
|
Zincon, monosodium salt monohydrate, 80%
| 0-00-0 |
|
2-Chlorobenzyl Chloride, 98+%
| 611-19-8 |
|
Methyl 3-hydroxyisoxazole-5-carboxylate, 99%
| 10068-07-2 |
|
(2S)-2-Boc-Amino-3-Phenylsulfonyl-1-(2-Tetrahydropyranyloxy)Propane,
| 0-01-1 |
|
Propylamine, 99+%
| 107-10-8 |
|
2-Naphthyl Sulfate, Potassium Salt, Hydrate ,99%
| 21409-32-5 |
|
M-Hydroxyphenylacetic Acid, 99+%
| 621-37-4 |
|
Methacrylamide, 98%
| 79-39-0 |
|
1,2,3,4-Dibenzanthracene, 97%
| 215-58-7 |
|
3-Methyl-5-Methoxycarbonyl-4-Piperidone Hydrochloride, 99%
| 0-00-0 |
|
Benzyltributylammonium chloride, 98+%
| 23616-79-7 |
|
N-Acetyl-S-benzyl-L-cysteine methyl ester
| 77549-14-5 |
|
4-Octyloxybenzaldehyde, 98%
| 24083-13-4 |
|
Xylenol blue, indicator grade
| 125-31-5 |
|
1,9-Nonanediol, 99%
| 3937-56-2 |
|
4-(P-Chlorobenzoyl)-Pyridine, 99%
| 14548-48-2 |
|
4-Chlorophenyl Sulfoxide, 97%
| 3085-42-5 |
|
|