**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1306-23-6 |Cadmium sulfide | 99.999 | 215-147-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 22 40 53 48/23/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Limited evidence of a carcinogenic effect. May
cause long-term adverse effects in the aquatic environment. Toxic :
danger of serious damage to health by prolonged exposure through
inhalation and if swallowed.Cancer suspect agent.
Potential Health Effects
Eye:
Causes eye irritation. Causes redness and pain. May cause
chemical conjunctivitis.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause kidney damage. Ingestion may result in a
decomposition to hydrogen sulfide in the stomach with systemic
poisoning. May cause worsening of asthma in asthmatics. Individuals
sensitive to sulfides may experience stomach upset, chest tightness
or wheezing.
Inhalation:
Inhalation of fumes may cause metal fume fever, which is
characterized by flu-like symptoms with metallic taste, fever,
chills, cough, weakness, chest pain, muscle pain and increased white
blood cell count. May cause lung damage. Olfactory fatigue may occur.
May cause salivation, nausea, vomiting, abdominal pain, fever, and
labored breathing. Can produce delayed pulmonary edema.
Chronic:
Cadmium and compounds may cause lung, liver and kidney damage and
lung and prostate cancer in humans. May cause lung damage. Chronic
exposure may cause blood effects. May cause kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Contact with metals may evolve flammable hydrogen gas.
Containers may explode when heated. Non-combustible, substance
itself does not burn but may decompose upon heating to produce
corrosive and/or toxic fumes.
Extinguishing Media:
Do NOT get water inside containers. For small fires, use dry
chemical, carbon dioxide, or water spray. For large fires, use dry
chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after
fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Minimize dust generation and accumulation.
Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Do not store in metal containers. Keep containers
tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 1306-23-6:
United Kingdom, WEL - TWA: 0.03 mg/m3 TWA (respirable dust, as Cd
United Kingdom, WEL - STEL: 0.09 mg/m3 STEL (respirable dust, as
United States OSHA: 2.5 ??g/m3 Action Level (as Cd); 5 ??g/m3 PEL (
Cd. Do not eat, drink or chew t obacco or gum or apply cosmetics
regulated areas. Carcinogen: dust can cause lung and kidney
disease. See 29 CFR 1910.1027) (listed under Cadmium compounds).
Belgium - TWA: (listed as cadmium compounds): 0.002 mg/m3 VLE
(respirable particulates, as Cd); 0.01 mg/m3 VLE (inhalable part
France - VME: (listed as cadmium compounds): 0.05 mg/m3 VME (as C
Germany: (listed as cadmium compounds): 0.05 mg/m3 VME (as Cd)
Japan: (listed as cadmium compounds): 0.05 mg/m3 OEL (as Cd)
Malaysia: (listed as cadmium compounds): 0.01 mg/m3 TWA (as Cd);
0.002 mg/m3 TWA (respirable fraction, as Cd)
Netherlands: (listed as cadmium inorganic compounds): 0.005 mg/m3
(as Cd)
Russia: (listed as cadmium compounds): 0.05 mg/m3 TWA (as Cd)
Russia: (listed as cadmium compounds): 0.01 mg/m3 STEL (as Cd)
Spain: 0.01 mg/m3 VLA-ED (inhalable fraction, as Cd); 0.002 mg/m3
VLA-ED (respirable fr
Personal Protective Equipment
Eyes:
Wear safety glasses and chemical goggles if splashing
is possible.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: brown to orange
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: > 999 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 0.13 mg/100g (18 c)
Specific Gravity/Density: 4.8200 g/cm3
Molecular Formula: CdS
Molecular Weight: 144.46
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Acids - strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of sulfur, hydrogen sulfide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1306-23-6: EV3150000
LD50/LC50:
CAS# 1306-23-6: Oral, mouse: LD50 = 1166 mg/kg; Oral, rat: LD50 =
7080 mg/kg.
Carcinogenicity:
Cadmium sulfide -
California: carcinogen, initial date 10/1/87 (listed as Cadmium compou
NTP: Known carcinogen (listed as Cadmium compounds).
IARC: Group 1 carcinogen (listed as Cadmium compounds).
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CADMIUM COMPOUND
Hazard Class: 6.1
UN Number: 2570
Packing Group: III
IMO
Shipping Name: CADMIUM COMPOUND
Hazard Class: 6.1
UN Number: 2570
Packing Group: III
RID/ADR
Shipping Name: CADMIUM COMPOUND
Hazard Class: 6.1
UN Number: 2570
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 22 Harmful if swallowed.
R 40 Limited evidence of a carcinogenic effect.
R 48/23/25 Toxic : danger of serious damage to
health by prolonged exposure through inhalation and if
swallowed.
R 53 May cause long-term adverse effects in the
aquatic environment.
Safety Phrases:
S 22 Do not breathe dust.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 1306-23-6: 1
Canada
CAS# 1306-23-6 is listed on Canada's DSL List.
CAS# 1306-23-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1306-23-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 7/15/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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| 621-87-4 |
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| 955-83-9 |
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| 845-46-5 |
|
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| 13529-27-6 |
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| 1934-16-3 |
|
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| 10049-05-5 |
|
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| 13673-63-7 |
|
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| 7635-11-2 |
|
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| 69048-98-2 |
|
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| 495-18-1 |
|
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| 33130-04-0 |
|
2-N-decylaminoethanethiol, 95%
| 5891-06-5 |
|
DL-1,2-Hexanediol, 98+%
| 6920-22-5 |
|
Jenner stain, high purity biological stain
| 62851-42-7 |
|
(4-Bromophenyl)cyclopropylmethanone
| 6952-89-2 |
|
5-Nitro-m-xylene, 99+%
| 99-12-7 |
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8-Chlorotheophylline, 99%(Titr.)
| 85-18-7 |
|
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| 1306-23-6 |
|
Zincon, monosodium salt monohydrate, 80%
| 0-00-0 |
|
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| 611-19-8 |
|
Methyl 3-hydroxyisoxazole-5-carboxylate, 99%
| 10068-07-2 |
|
(2S)-2-Boc-Amino-3-Phenylsulfonyl-1-(2-Tetrahydropyranyloxy)Propane,
| 0-01-1 |
|
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| 107-10-8 |
|
2-Naphthyl Sulfate, Potassium Salt, Hydrate ,99%
| 21409-32-5 |
|
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| 621-37-4 |
|
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| 79-39-0 |
|
1,2,3,4-Dibenzanthracene, 97%
| 215-58-7 |
|
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| 0-00-0 |
|
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| 23616-79-7 |
|
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| 77549-14-5 |
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| 125-31-5 |
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| 3937-56-2 |
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| 14548-48-2 |
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