**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 10049-16-8 |Vanadium (IV) Fluoride | ca 100 | 233-171-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Causes
burns.Hygroscopic (absorbs moisture from the air).Corrosive.The
toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. The toxicological properties of this
substance have not been fully investigated.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological
properties of this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid. Do NOT allow victim to rub eyes or keep eyes
closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid. Get medical aid immediately. Flush skin with plenty
of water for at least 15 minutes while removing contaminated clothing
and shoes. Immediately flush skin with plenty of water for at least
15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. Never give anything by mouth to an
unconscious person. Get medical aid. Do NOT induce vomiting. If
conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or
water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Do NOT get water
inside containers. Use water spray, dry chemical, carbon dioxide, or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid contact with eyes, skin, and clothing. Do not
breathe dust, vapor, mist, or gas. Keep container tightly closed.
Avoid ingestion and inhalation. Use with adequate ventilation. Do not
allow contact with water. Discard contaminated shoes. Keep from
contact with moist air and steam.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 10049-16-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: yellow to green
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Decomposes
Freezing/Melting Point: 325 deg C dec
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 325 deg C
Solubility in water:
Specific Gravity/Density: 2.975
Molecular Formula: VF4
Molecular Weight: 126.9351
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, moisture, excess heat,
exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, vanadium oxide (VOx) gases,
fluorine.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 10049-16-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Vanadium (IV) Fluoride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: VANADIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3285
Packing Group: III
IMO
Shipping Name: VANADIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3285
Packing Group: III
RID/ADR
Shipping Name: VANADIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3285
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 34 Causes burns.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 10049-16-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 10049-16-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10049-16-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/08/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Dimethyl Bromomalonate, Tech., 90%
| 868-26-8 |
|
(2-Iodoethyl)benzene, 97%
| 17376-04-4 |
|
2-Bromo-2-methylpropionic acid, 98%
| 2052-01-9 |
|
1-Bromo-2-Ethylbutane
| 3814-34-4 |
|
1-Amino-1-cyclopropanecarboxylic acid
| 22059-21-8 |
|
l-2-Aminoadipic acid, 98%
| 1118-90-7 |
|
l-Leucinamide hydrochloride, 99%
| 10466-61-2 |
|
N-(2-Chlorobenzyloxycarbonyloxy)-Succinimide, 98%
| 65853-65-8 |
|
Ethylpyrazine, 98%
| 13925-00-3 |
|
Sodium Metavanadate, 96%
| 13718-26-8 |
|
4-(Trifluoromethyl)Benzoyl Chloride, 97%
| 329-15-7 |
|
2,3,4,5,6-Pentafluorphenylacetic Acid, 99%
| 653-21-4 |
|
(alpha,alpha,alpha-Trifluoro-o-tolyl)acetic acid, 98%
| 3038-48-0 |
|
3-Fluoro-4-Nitrophenol, 99%
| 394-41-2 |
|
4-Fluorophenyl Methyl Sulfone, 99%
| 455-15-2 |
|
3-Chloro-4-Fluoronitrobenzene, 98%
| 350-30-1 |
|
2,5-Difluorobenzoic Acid, 98%
| 2991-28-8 |
|
6-Bromo-1-hexene, 98%
| 2695-47-8 |
|
n-Butylbenzylamine, 98%
| 2403-22-7 |
|
4-Hexylbiphenyl, 99%
| 59662-31-6 |
|
TRIFLUOROMETHYL IODIDE, 99%
| 2314-97-8 |
|
Fluorotribromomethane, 99+%
| 353-54-8 |
|
2,6-Difluoropyridine, 99%
| 1513-65-1 |
|
4,5-Dimethylthiazole, 97%
| 3581-91-7 |
|
Vanadium (IV) Fluoride
| 10049-16-8 |
|
3,5-Difluorophenol, 99%
| 2713-34-0 |
|
Hexafluoroglutaric Acid, 97%
| 376-73-8 |
|
3-Methylthiophene, 99+%
| 616-44-4 |
|
(Phenylsulfonyl)acetonitrile, 98%
| 7605-28-9 |
|
Busulfan, 98%
| 55-98-1 |
|
2,3-Dimethylbenzoic Acid, 98%
| 603-79-2 |
|
1-Tridecanol, 97%
| 112-70-9 |
|
3-Bromostyrene, 97%
| 2039-86-3 |
|
Tetrafluorophthalic acid, 98%
| 652-03-9 |
|
2-Acetyl-5-chlorothiophene, 99%
| 6310-09-4 |
|
4-Fluoro-Alpha-Methylbenzyl Alcohol, 99%
| 403-41-8 |
|
Hydantoin, 99%
| 461-72-3 |
|
3-Methyl-2-thiophenecarboxylic acid, 98%
| 23806-24-8 |
|
Methyl Vinyl Sulfone, 98%
| 3680-02-2 |
|
Dimethylaminosulfur Trifluoride
| 3880-03-3 |
|
3-Phenylglutaric acid
| 4165-96-2 |
|
1-(Trifluoromethyl)ethenyl Acetate, 99%
| 2247-91-8 |
|
4-Butoxybenzoic Acid, 98%
| 1498-96-0 |
|
4-Dodecyloxybenzoic acid, 98%
| 2312-15-4 |
|
N,N'-Bis(Salicylidene)ethylenediamine, 98%
| 94-93-9 |
|
4-Methyl-1,3-dioxane, 99%
| 1120-97-4 |
|
n-Methylsuccinimide, 99%
| 1121-07-9 |
|
4-Nonyloxybenzoic Acid, 97%
| 15872-43-2 |
|
4-Octyloxybenzoic Acid, 98%
| 2493-84-7 |
|
N,N'-Terephthalylidene-Bis(4-Butylaniline) , 99%
| 29743-21-3 |
|
|