**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3880-03-3 |Dimethylaminosulfur Trifluoride | ca 100 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 11 14 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Reacts violently with water. Causes burns.Highly
flammable.Water-reactive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Vapors may cause
dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Water Reactive. Material will react with
water and may release a flammable and/or toxic gas. Use water spray
to keep fire-exposed containers cool. Water may be ineffective.
Material is lighter than water and a fire may be spread by the use of
water. Flammable liquid and vapor. Reacts violently with water.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. May ignite or explode on contact
with steam or moist air. Will be easily ignited by heat, sparks or
flame. Containers may explode if exposed to fire.
Extinguishing Media:
Use dry sand or earth to smother fire. If water is the only media
available, use in flooding amounts. Use dry chemical to fight fire.
DO NOT USE WATER! Contact professional fire-fighters immediately.
Cool containers with flooding quantities of water until well after
fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal. Remove all sources of ignition. Use a spark-proof tool.
Provide ventilation. Do not expose spill to water.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not allow water to get into the container because of violent
reaction. Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Do not breathe dust,
vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Keep away from heat, sparks and flame. Use with
adequate ventilation. Do not allow contact with water. Discard
contaminated shoes. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames. Keep from contact with moist air and steam.
Storage:
Keep away from heat and flame. Keep away from sources of ignition.
Store in a tightly closed container. Store in a dry area. Keep away
from water. Flammables-area. Keep refrigerated. (Store below
4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate ventilation to keep airborne
concentrations low.
Exposure Limits
CAS# 3880-03-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: almost colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 117.5 deg C @ 760.00mm Hg
Freezing/Melting Point: -78.7 deg C
Autoignition Temperature: Not available.
Flash Point: 10 deg C ( 50.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts
Specific Gravity/Density: 1.3640g/cm3
Molecular Formula: C2H6F3NS
Molecular Weight: 133.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Combines vigorously or explosively with water.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, exposure to
moist air or water.
Incompatibilities with Other Materials:
Strong acids, strong bases, strong oxidizing agents, strong reducing
agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon
dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3880-03-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Dimethylaminosulfur Trifluoride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 3 (8)
UN Number: 2924
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3.2 (8)
UN Number: 2924
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3 (8)
UN Number: 2924
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 14 Reacts violently with water.
R 34 Causes burns.
Safety Phrases:
S 8 Keep container dry.
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 3880-03-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 3880-03-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3880-03-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/02/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Dimethyl Bromomalonate, Tech., 90%
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(2-Iodoethyl)benzene, 97%
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2-Bromo-2-methylpropionic acid, 98%
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1-Bromo-2-Ethylbutane
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|
1-Amino-1-cyclopropanecarboxylic acid
| 22059-21-8 |
|
l-2-Aminoadipic acid, 98%
| 1118-90-7 |
|
l-Leucinamide hydrochloride, 99%
| 10466-61-2 |
|
N-(2-Chlorobenzyloxycarbonyloxy)-Succinimide, 98%
| 65853-65-8 |
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Ethylpyrazine, 98%
| 13925-00-3 |
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Sodium Metavanadate, 96%
| 13718-26-8 |
|
4-(Trifluoromethyl)Benzoyl Chloride, 97%
| 329-15-7 |
|
2,3,4,5,6-Pentafluorphenylacetic Acid, 99%
| 653-21-4 |
|
(alpha,alpha,alpha-Trifluoro-o-tolyl)acetic acid, 98%
| 3038-48-0 |
|
3-Fluoro-4-Nitrophenol, 99%
| 394-41-2 |
|
4-Fluorophenyl Methyl Sulfone, 99%
| 455-15-2 |
|
3-Chloro-4-Fluoronitrobenzene, 98%
| 350-30-1 |
|
2,5-Difluorobenzoic Acid, 98%
| 2991-28-8 |
|
6-Bromo-1-hexene, 98%
| 2695-47-8 |
|
n-Butylbenzylamine, 98%
| 2403-22-7 |
|
4-Hexylbiphenyl, 99%
| 59662-31-6 |
|
TRIFLUOROMETHYL IODIDE, 99%
| 2314-97-8 |
|
Fluorotribromomethane, 99+%
| 353-54-8 |
|
2,6-Difluoropyridine, 99%
| 1513-65-1 |
|
4,5-Dimethylthiazole, 97%
| 3581-91-7 |
|
Vanadium (IV) Fluoride
| 10049-16-8 |
|
3,5-Difluorophenol, 99%
| 2713-34-0 |
|
Hexafluoroglutaric Acid, 97%
| 376-73-8 |
|
3-Methylthiophene, 99+%
| 616-44-4 |
|
(Phenylsulfonyl)acetonitrile, 98%
| 7605-28-9 |
|
Busulfan, 98%
| 55-98-1 |
|
2,3-Dimethylbenzoic Acid, 98%
| 603-79-2 |
|
1-Tridecanol, 97%
| 112-70-9 |
|
3-Bromostyrene, 97%
| 2039-86-3 |
|
Tetrafluorophthalic acid, 98%
| 652-03-9 |
|
2-Acetyl-5-chlorothiophene, 99%
| 6310-09-4 |
|
4-Fluoro-Alpha-Methylbenzyl Alcohol, 99%
| 403-41-8 |
|
Hydantoin, 99%
| 461-72-3 |
|
3-Methyl-2-thiophenecarboxylic acid, 98%
| 23806-24-8 |
|
Methyl Vinyl Sulfone, 98%
| 3680-02-2 |
|
Dimethylaminosulfur Trifluoride
| 3880-03-3 |
|
3-Phenylglutaric acid
| 4165-96-2 |
|
1-(Trifluoromethyl)ethenyl Acetate, 99%
| 2247-91-8 |
|
4-Butoxybenzoic Acid, 98%
| 1498-96-0 |
|
4-Dodecyloxybenzoic acid, 98%
| 2312-15-4 |
|
N,N'-Bis(Salicylidene)ethylenediamine, 98%
| 94-93-9 |
|
4-Methyl-1,3-dioxane, 99%
| 1120-97-4 |
|
n-Methylsuccinimide, 99%
| 1121-07-9 |
|
4-Nonyloxybenzoic Acid, 97%
| 15872-43-2 |
|
4-Octyloxybenzoic Acid, 98%
| 2493-84-7 |
|
N,N'-Terephthalylidene-Bis(4-Butylaniline) , 99%
| 29743-21-3 |
|
|