**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1120-97-4 |4-Methyl-1,3-dioxane | 99 | 214-323-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 10 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to eyes, respiratory system and skin.The
toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
Causes eye irritation. Vapors cause eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
The toxicological properties of this material have not been fully
investigated.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated. May be
harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. May be harmful if
inhaled.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes. Get medical aid. Wash
clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Water may be
ineffective. Material is lighter than water and a fire may be spread
by the use of water. Containers may explode in the heat of a fire.
Flammable liquid and vapor. May form explosive peroxides. Vapors may
be heavier than air. They can spread along the ground and collect in
low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames. Use
only with adequate ventilation.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Storage under a nitrogen blanket has been
recommended.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1120-97-4:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 114 deg C @ 760 mm Hg
Freezing/Melting Point: -45 - -44 deg C
Autoignition Temperature: Not available.
Flash Point: 22 deg C ( 71.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9760g/cm3
Molecular Formula: C5H10O2
Molecular Weight: 102.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
On long term storage, substances with similar functional groups form
explosive peroxides. May form peroxides in the absence of inhibitors.
Peroxide formation may occur in containers that have been opened and
remain in storage.
Conditions to Avoid:
Ignition sources, excess heat, exposure to flame.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1120-97-4: JH2200000
LD50/LC50:
CAS# 1120-97-4: Inhalation, mouse: LC50 = 47 gm/m3/2H.
Carcinogenicity:
4-Methyl-1,3-dioxane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 1120-97-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1120-97-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1120-97-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/15/1999 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Dimethyl Bromomalonate, Tech., 90%
| 868-26-8 |
|
(2-Iodoethyl)benzene, 97%
| 17376-04-4 |
|
2-Bromo-2-methylpropionic acid, 98%
| 2052-01-9 |
|
1-Bromo-2-Ethylbutane
| 3814-34-4 |
|
1-Amino-1-cyclopropanecarboxylic acid
| 22059-21-8 |
|
l-2-Aminoadipic acid, 98%
| 1118-90-7 |
|
l-Leucinamide hydrochloride, 99%
| 10466-61-2 |
|
N-(2-Chlorobenzyloxycarbonyloxy)-Succinimide, 98%
| 65853-65-8 |
|
Ethylpyrazine, 98%
| 13925-00-3 |
|
Sodium Metavanadate, 96%
| 13718-26-8 |
|
4-(Trifluoromethyl)Benzoyl Chloride, 97%
| 329-15-7 |
|
2,3,4,5,6-Pentafluorphenylacetic Acid, 99%
| 653-21-4 |
|
(alpha,alpha,alpha-Trifluoro-o-tolyl)acetic acid, 98%
| 3038-48-0 |
|
3-Fluoro-4-Nitrophenol, 99%
| 394-41-2 |
|
4-Fluorophenyl Methyl Sulfone, 99%
| 455-15-2 |
|
3-Chloro-4-Fluoronitrobenzene, 98%
| 350-30-1 |
|
2,5-Difluorobenzoic Acid, 98%
| 2991-28-8 |
|
6-Bromo-1-hexene, 98%
| 2695-47-8 |
|
n-Butylbenzylamine, 98%
| 2403-22-7 |
|
4-Hexylbiphenyl, 99%
| 59662-31-6 |
|
TRIFLUOROMETHYL IODIDE, 99%
| 2314-97-8 |
|
Fluorotribromomethane, 99+%
| 353-54-8 |
|
2,6-Difluoropyridine, 99%
| 1513-65-1 |
|
4,5-Dimethylthiazole, 97%
| 3581-91-7 |
|
Vanadium (IV) Fluoride
| 10049-16-8 |
|
3,5-Difluorophenol, 99%
| 2713-34-0 |
|
Hexafluoroglutaric Acid, 97%
| 376-73-8 |
|
3-Methylthiophene, 99+%
| 616-44-4 |
|
(Phenylsulfonyl)acetonitrile, 98%
| 7605-28-9 |
|
Busulfan, 98%
| 55-98-1 |
|
2,3-Dimethylbenzoic Acid, 98%
| 603-79-2 |
|
1-Tridecanol, 97%
| 112-70-9 |
|
3-Bromostyrene, 97%
| 2039-86-3 |
|
Tetrafluorophthalic acid, 98%
| 652-03-9 |
|
2-Acetyl-5-chlorothiophene, 99%
| 6310-09-4 |
|
4-Fluoro-Alpha-Methylbenzyl Alcohol, 99%
| 403-41-8 |
|
Hydantoin, 99%
| 461-72-3 |
|
3-Methyl-2-thiophenecarboxylic acid, 98%
| 23806-24-8 |
|
Methyl Vinyl Sulfone, 98%
| 3680-02-2 |
|
Dimethylaminosulfur Trifluoride
| 3880-03-3 |
|
3-Phenylglutaric acid
| 4165-96-2 |
|
1-(Trifluoromethyl)ethenyl Acetate, 99%
| 2247-91-8 |
|
4-Butoxybenzoic Acid, 98%
| 1498-96-0 |
|
4-Dodecyloxybenzoic acid, 98%
| 2312-15-4 |
|
N,N'-Bis(Salicylidene)ethylenediamine, 98%
| 94-93-9 |
|
4-Methyl-1,3-dioxane, 99%
| 1120-97-4 |
|
n-Methylsuccinimide, 99%
| 1121-07-9 |
|
4-Nonyloxybenzoic Acid, 97%
| 15872-43-2 |
|
4-Octyloxybenzoic Acid, 98%
| 2493-84-7 |
|
N,N'-Terephthalylidene-Bis(4-Butylaniline) , 99%
| 29743-21-3 |
|
|