**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3680-02-2 |Methyl Vinyl Sulfone | 98% | 222-958-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+
Risk Phrases: 22 27 41
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Very toxic in contact with skin. Risk of
serious damage to eyes.Highly toxic.
Potential Health Effects
Eye:
May cause eye irritation and possible damage.
Skin:
Causes mild skin irritation. May be fatal if absorbed through the
skin.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. Vapors may cause dizziness
or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Containers may explode when heated.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Cool containers with flooding quantities of water until well after
fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Do not
breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Do not get on skin or in eyes. Use only in a chemical fume
hood. Discard contaminated shoes.
Storage:
Store in a tightly closed container. Store in a dry area. Keep
refrigerated. (Store below 4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 3680-02-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 115 - 117 deg C @ 19.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.2120g/cm3
Molecular Formula: C3H6O2S
Molecular Weight: 106.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3680-02-2: WR6825000
LD50/LC50:
CAS# 3680-02-2: Draize test, rabbit, eye: 5 mg/24H Severe; Draize
test, rabbit, skin: 500 mg/24H Mild; Oral, rat: LD50 = 570 mg/kg;
Skin, rabbit: LD50 = 32 uL/kg.
Carcinogenicity:
Methyl Vinyl Sulfone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: I
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: I
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 22 Harmful if swallowed.
R 27 Very toxic in contact with skin.
R 41 Risk of serious damage to eyes.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 3680-02-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 3680-02-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3680-02-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/03/1999 Revision #2 Date: 12/03/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Dimethyl Bromomalonate, Tech., 90%
| 868-26-8 |
|
(2-Iodoethyl)benzene, 97%
| 17376-04-4 |
|
2-Bromo-2-methylpropionic acid, 98%
| 2052-01-9 |
|
1-Bromo-2-Ethylbutane
| 3814-34-4 |
|
1-Amino-1-cyclopropanecarboxylic acid
| 22059-21-8 |
|
l-2-Aminoadipic acid, 98%
| 1118-90-7 |
|
l-Leucinamide hydrochloride, 99%
| 10466-61-2 |
|
N-(2-Chlorobenzyloxycarbonyloxy)-Succinimide, 98%
| 65853-65-8 |
|
Ethylpyrazine, 98%
| 13925-00-3 |
|
Sodium Metavanadate, 96%
| 13718-26-8 |
|
4-(Trifluoromethyl)Benzoyl Chloride, 97%
| 329-15-7 |
|
2,3,4,5,6-Pentafluorphenylacetic Acid, 99%
| 653-21-4 |
|
(alpha,alpha,alpha-Trifluoro-o-tolyl)acetic acid, 98%
| 3038-48-0 |
|
3-Fluoro-4-Nitrophenol, 99%
| 394-41-2 |
|
4-Fluorophenyl Methyl Sulfone, 99%
| 455-15-2 |
|
3-Chloro-4-Fluoronitrobenzene, 98%
| 350-30-1 |
|
2,5-Difluorobenzoic Acid, 98%
| 2991-28-8 |
|
6-Bromo-1-hexene, 98%
| 2695-47-8 |
|
n-Butylbenzylamine, 98%
| 2403-22-7 |
|
4-Hexylbiphenyl, 99%
| 59662-31-6 |
|
TRIFLUOROMETHYL IODIDE, 99%
| 2314-97-8 |
|
Fluorotribromomethane, 99+%
| 353-54-8 |
|
2,6-Difluoropyridine, 99%
| 1513-65-1 |
|
4,5-Dimethylthiazole, 97%
| 3581-91-7 |
|
Vanadium (IV) Fluoride
| 10049-16-8 |
|
3,5-Difluorophenol, 99%
| 2713-34-0 |
|
Hexafluoroglutaric Acid, 97%
| 376-73-8 |
|
3-Methylthiophene, 99+%
| 616-44-4 |
|
(Phenylsulfonyl)acetonitrile, 98%
| 7605-28-9 |
|
Busulfan, 98%
| 55-98-1 |
|
2,3-Dimethylbenzoic Acid, 98%
| 603-79-2 |
|
1-Tridecanol, 97%
| 112-70-9 |
|
3-Bromostyrene, 97%
| 2039-86-3 |
|
Tetrafluorophthalic acid, 98%
| 652-03-9 |
|
2-Acetyl-5-chlorothiophene, 99%
| 6310-09-4 |
|
4-Fluoro-Alpha-Methylbenzyl Alcohol, 99%
| 403-41-8 |
|
Hydantoin, 99%
| 461-72-3 |
|
3-Methyl-2-thiophenecarboxylic acid, 98%
| 23806-24-8 |
|
Methyl Vinyl Sulfone, 98%
| 3680-02-2 |
|
Dimethylaminosulfur Trifluoride
| 3880-03-3 |
|
3-Phenylglutaric acid
| 4165-96-2 |
|
1-(Trifluoromethyl)ethenyl Acetate, 99%
| 2247-91-8 |
|
4-Butoxybenzoic Acid, 98%
| 1498-96-0 |
|
4-Dodecyloxybenzoic acid, 98%
| 2312-15-4 |
|
N,N'-Bis(Salicylidene)ethylenediamine, 98%
| 94-93-9 |
|
4-Methyl-1,3-dioxane, 99%
| 1120-97-4 |
|
n-Methylsuccinimide, 99%
| 1121-07-9 |
|
4-Nonyloxybenzoic Acid, 97%
| 15872-43-2 |
|
4-Octyloxybenzoic Acid, 98%
| 2493-84-7 |
|
N,N'-Terephthalylidene-Bis(4-Butylaniline) , 99%
| 29743-21-3 |
|
|