**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 616-44-4 |3-Methylthiophene | >99 | 210-482-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F
Risk Phrases: 11 20/22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation and if swallowed. Irritating
to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause digestive tract disturbances. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. Inhalation of vapors may cause
drowsiness and dizziness.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Remove
contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Use water spray to keep
fire-exposed containers cool. Containers may explode in the heat of
a fire. Flammable liquid and vapor. May be ignited by heat, sparks,
and flame.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Do NOT use straight streams of water. For small fires,
use dry chemical, carbon dioxide, water spray or regular foam. For
large fires, use water spray, fog or regular foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors. Water spray may
reduce vapor but may not prevent ignition in closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames. Use only with adequate ventilation.
Keep away from heat, sparks and flame. Avoid breathing vapor or mist.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 616-44-4:
Russia: 20 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: pale yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 42 mm Hg
Viscosity: Not available.
Boiling Point: 115-117 deg C
Freezing/Melting Point: -69 deg C
Autoignition Temperature: Not available.
Flash Point: 11 deg C ( 51.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: immiscible
Specific Gravity/Density: 1.0160g/cm3
Molecular Formula: C5H6S
Molecular Weight: 98.16
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen sulfide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 616-44-4: XM9800000
LD50/LC50:
CAS# 616-44-4: Inhalation, mouse: LC50 = 18 gm/m3/2H; Oral, mouse:
LD50 = 1800 mg/kg.
Carcinogenicity:
3-Methylthiophene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 20/22 Harmful by inhalation and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
S 36 Wear suitable protective clothing.
S 50A Do not mix with acids.
WGK (Water Danger/Protection)
CAS# 616-44-4: No information available.
Canada
CAS# 616-44-4 is listed on Canada's DSL List.
CAS# 616-44-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 616-44-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/03/1998 Revision #3 Date: 8/06/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Dimethyl Bromomalonate, Tech., 90%
| 868-26-8 |
|
(2-Iodoethyl)benzene, 97%
| 17376-04-4 |
|
2-Bromo-2-methylpropionic acid, 98%
| 2052-01-9 |
|
1-Bromo-2-Ethylbutane
| 3814-34-4 |
|
1-Amino-1-cyclopropanecarboxylic acid
| 22059-21-8 |
|
l-2-Aminoadipic acid, 98%
| 1118-90-7 |
|
l-Leucinamide hydrochloride, 99%
| 10466-61-2 |
|
N-(2-Chlorobenzyloxycarbonyloxy)-Succinimide, 98%
| 65853-65-8 |
|
Ethylpyrazine, 98%
| 13925-00-3 |
|
Sodium Metavanadate, 96%
| 13718-26-8 |
|
4-(Trifluoromethyl)Benzoyl Chloride, 97%
| 329-15-7 |
|
2,3,4,5,6-Pentafluorphenylacetic Acid, 99%
| 653-21-4 |
|
(alpha,alpha,alpha-Trifluoro-o-tolyl)acetic acid, 98%
| 3038-48-0 |
|
3-Fluoro-4-Nitrophenol, 99%
| 394-41-2 |
|
4-Fluorophenyl Methyl Sulfone, 99%
| 455-15-2 |
|
3-Chloro-4-Fluoronitrobenzene, 98%
| 350-30-1 |
|
2,5-Difluorobenzoic Acid, 98%
| 2991-28-8 |
|
6-Bromo-1-hexene, 98%
| 2695-47-8 |
|
n-Butylbenzylamine, 98%
| 2403-22-7 |
|
4-Hexylbiphenyl, 99%
| 59662-31-6 |
|
TRIFLUOROMETHYL IODIDE, 99%
| 2314-97-8 |
|
Fluorotribromomethane, 99+%
| 353-54-8 |
|
2,6-Difluoropyridine, 99%
| 1513-65-1 |
|
4,5-Dimethylthiazole, 97%
| 3581-91-7 |
|
Vanadium (IV) Fluoride
| 10049-16-8 |
|
3,5-Difluorophenol, 99%
| 2713-34-0 |
|
Hexafluoroglutaric Acid, 97%
| 376-73-8 |
|
3-Methylthiophene, 99+%
| 616-44-4 |
|
(Phenylsulfonyl)acetonitrile, 98%
| 7605-28-9 |
|
Busulfan, 98%
| 55-98-1 |
|
2,3-Dimethylbenzoic Acid, 98%
| 603-79-2 |
|
1-Tridecanol, 97%
| 112-70-9 |
|
3-Bromostyrene, 97%
| 2039-86-3 |
|
Tetrafluorophthalic acid, 98%
| 652-03-9 |
|
2-Acetyl-5-chlorothiophene, 99%
| 6310-09-4 |
|
4-Fluoro-Alpha-Methylbenzyl Alcohol, 99%
| 403-41-8 |
|
Hydantoin, 99%
| 461-72-3 |
|
3-Methyl-2-thiophenecarboxylic acid, 98%
| 23806-24-8 |
|
Methyl Vinyl Sulfone, 98%
| 3680-02-2 |
|
Dimethylaminosulfur Trifluoride
| 3880-03-3 |
|
3-Phenylglutaric acid
| 4165-96-2 |
|
1-(Trifluoromethyl)ethenyl Acetate, 99%
| 2247-91-8 |
|
4-Butoxybenzoic Acid, 98%
| 1498-96-0 |
|
4-Dodecyloxybenzoic acid, 98%
| 2312-15-4 |
|
N,N'-Bis(Salicylidene)ethylenediamine, 98%
| 94-93-9 |
|
4-Methyl-1,3-dioxane, 99%
| 1120-97-4 |
|
n-Methylsuccinimide, 99%
| 1121-07-9 |
|
4-Nonyloxybenzoic Acid, 97%
| 15872-43-2 |
|
4-Octyloxybenzoic Acid, 98%
| 2493-84-7 |
|
N,N'-Terephthalylidene-Bis(4-Butylaniline) , 99%
| 29743-21-3 |
|
|