**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 101-61-1 |4,4'-Methylenebis(N,N-dimethylaniline)| 99+ | 202-959-2 |
| | | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 40
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Limited evidence of a carcinogenic
effect.Cancer suspect agent.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause skin irritation. Absorption into the body may cause
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood).
Ingestion:
May cause irritation of the digestive tract. May cause liver and
kidney damage. Methemoglobinemia is characterized by dizziness,
drowsiness, headache, shortness of breath, cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood),
rapid heart rate and chocolate-brown colored blood. Overexposure may
cause methemoglobinemia.
Inhalation:
May cause respiratory tract irritation. May cause liver and kidney
damage. Methemoglobinemia is characterized by dizziness, drowsiness,
headache, shortness of breath, cyanosis (bluish discoloration of
skin due to deficient oxygenation of the blood), rapid heart rate and
chocolate-brown blood. Inhalation of aniline causes anoxia due to the
formation of methemoglobin.
Chronic:
No information found. May cause liver and kidney damage. May cause
methemoglobinemia, which is characterized by chocolate-brown colored
blood, headache, weakness, dizziness, breath shortness, cyanosis
(bluish skin due to deficient oxygenation of blood), rapid heart
rate, unconsciousness and possible death.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene
Blue depending on the methemoglobin concentration in the blood.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid
generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 101-61-1:
Germany: 0.1 ppm TWA (inhalable fraction)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Plates
Color: Yellow
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 340 deg C
Freezing/Melting Point: 90 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: subl w/o decmp
Solubility in water: Insoluble.
Specific Gravity/Density: Not available.
Molecular Formula: C17H22N2
Molecular Weight: 254.38
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen, ammonia.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 101-61-1: BY5250000
LD50/LC50:
CAS# 101-61-1: Oral, mouse: LD50 = 3160 mg/kg.
Carcinogenicity:
4,4'-Methylenebis(N,N-dimethylaniline) -
California: carcinogen, initial date 10/1/89
NTP: Suspect carcinogen
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 101-61-1: No information available.
Canada
CAS# 101-61-1 is listed on Canada's DSL List.
CAS# 101-61-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 101-61-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/24/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Ethyl-3-hydroxypiperidine, 98+%
| 13444-24-1 |
|
Betaine hydrochloride, 99%
| 590-46-5 |
|
Diethyl Malonate, 99+%
| 105-53-3 |
|
P-Fluorocinnamic Acid, 99%
| 459-32-5 |
|
Methanol
| 67-56-1 |
|
BOC-L-Serine, Tech., Hydrate, 93%
| 3262-72-4 |
|
Methyl Benzoate
| 93-58-3 |
|
4,4'-Methylenenbis(n,n-dimethylaniline), 99+% (titr.)
| 101-61-1 |
|
2-Ethyl thiophenol, 98%
| 4500-58-7 |
|
Methyl 3-aminobenzoate, 98%
| 4518-10-9 |
|
Triethyl Phosphate, 99%
| 78-40-0 |
|
Ethylene glycol monomethyl ether
| 109-86-4 |
|
Desyl Chloride, 98+%
| 447-31-4 |
|
Methyl Cellulose
| 9004-67-5 |
|
2,4-Dimethylphenol, 99% (GC)
| 105-67-9 |
|
Dimethyl phosphite (Pract), 98% (Titr.)
| 67-56-1 |
|
5-Bromo-2-Fluorobenzylamine Hydrochloride 99%
| 99725-13-0 |
|
1,1,1-Trichloroethane
| 71-55-6 |
|
Ethyl Propenyl Ether
| 928-55-2 |
|
Cellulose n,n-diethylaminoethyl ether
| 9013-34-7 |
|
3,4-Dichlorophenylacetonitrile, 98%
| 3218-49-3 |
|
n-Propyl ether, 99+%
| 111-43-3 |
|
Nickel Boride
| 12007-01-1 |
|
5-Bromo-2-Fluorocinnamic Acid, 98% (GC)
| 0-00-1 |
|
L-Carnitine, 99+%
| 541-15-1 |
|
5'-O-Dimethoxytrityl-N-Isobutyryl-Deoxyguanosine
| 68892-41-1 |
|
Methyl ethyl ketone
| 78-93-3 |
|
3-Cyclopentylpropionic acid, 98%
| 140-77-2 |
|
4-(2-Thienyl)butyric Acid , 98%
| 4653-11-6 |
|
1-Bromo-2-Naphthol, 98%
| 573-97-7 |
|
5-Amino-1H-Tetrazole
| 4418-61-5 |
|
5-Bromonicotinic Acid, 98%
| 20826-04-4 |
|
Cyclohexylphenylacetonitrile, 98%
| 3893-23-0 |
|
2-(Trimethylsilyl)ethoxymethyl Chloride, Stabilized, Tech., 90%
| 76513-69-4 |
|
P-Acetotoluidide
| 103-89-9 |
|
2,2,5,5-Tetramethyl-3-Pyrrolin-1-Oxyl- 3-Carboxylic Acid, 99% (Titr.)
| 2154-67-8 |
|
Dichloromethane
| 75-09-2 |
|
Methylene Iodide
| 75-11-6 |
|
N,N-Dimethyl-4,4'-Azodianiline
| 539-17-3 |
|
5-Tert-Butyl-1,3-Benzenedicarboxylic Acid 98%
| 2359-09-3 |
|
N-Acetyl-2-Phenylethylamine, 98%
| 877-95-2 |
|
Octyl aldehyde, 99%
| 124-13-0 |
|
Trimethyl 1,3,5-Benzenetricarboxylate 99% (TLC)
| 2672-58-4 |
|
Indophenol acetate
| 7761-80-0 |
|
3-Methylmercaptoaniline, 97%
| 1783-81-9 |
|
2-Methylbenzyl Alcohol, 98%
| 89-95-2 |
|
Triphenylphosphine Dibromide, ca.33% Bromine
| 1034-39-5 |
|
Tryptophol, 97%
| 526-55-6 |
|
2'-Hydroxy-4'-Methoxyacetophenone, 99%
| 552-41-0 |
|
alpha-Phenyl-2-toluic acid, 97%
| 612-35-1 |
|
|