**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 75-11-6 |Methane, diiodo- | 100 | 200-841-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Light sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause liver and kidney damage. May cause central
nervous system depression, characterized by excitement, followed by
headache, dizziness, drowsiness, and nausea. Advanced stages may
cause collapse, unconsciousness, coma and possible death due to
respiratory failure.
Inhalation:
Causes respiratory tract irritation. May cause effects similar to
those described for ingestion. Can produce delayed pulmonary edema.
Chronic:
Chronic exposure can lead to iodism characterized by salivation,
nasal discharge, sneezing, conjunctivitis, fever, laryngitis,
bronchitis, stomatitis, and skin rashes. Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode in
the heat of a fire. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. Use agent most
appropriate to extinguish fire. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Neutralize spill with sodium bicarbonate. Remove all sources of
ignition. Absorb spill using an absorbent, non-combustible material
such as earth, sand, or vermiculite. Do not use combustible
materials such as sawdust. Carefully scoop up and place into
appropriate disposal container. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not get on skin
or in eyes. Do not ingest or inhale. Store protected from light.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store in
opaque, air-tight containers.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 75-11-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear impervious gloves.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: yellow amber
Odor: odorless
pH: Not available.
Vapor Pressure: 0.68 mm Hg @ 20C
Viscosity: 2.80 cP 20 C
Boiling Point: 181 deg C
Freezing/Melting Point: 6 deg C
Autoignition Temperature: Not available.
Flash Point: > 230 deg F (> 110.00 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 181 C
Solubility in water: Insoluble in water.
Specific Gravity/Density: 3.325 @ 20C.
Molecular Formula: CH2I2
Molecular Weight: 267.823
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, light, metals, excess heat.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen iodide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-11-6: PA8575000
LD50/LC50:
Not available.
Carcinogenicity:
Methane, diiodo- -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, NOS
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, NOS
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, NOS
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately
with...
WGK (Water Danger/Protection)
CAS# 75-11-6: 2
Canada
CAS# 75-11-6 is listed on Canada's DSL List.
CAS# 75-11-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-11-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/10/1998 Revision #4 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Ethyl-3-hydroxypiperidine, 98+%
| 13444-24-1 |
|
Betaine hydrochloride, 99%
| 590-46-5 |
|
Diethyl Malonate, 99+%
| 105-53-3 |
|
P-Fluorocinnamic Acid, 99%
| 459-32-5 |
|
Methanol
| 67-56-1 |
|
BOC-L-Serine, Tech., Hydrate, 93%
| 3262-72-4 |
|
Methyl Benzoate
| 93-58-3 |
|
4,4'-Methylenenbis(n,n-dimethylaniline), 99+% (titr.)
| 101-61-1 |
|
2-Ethyl thiophenol, 98%
| 4500-58-7 |
|
Methyl 3-aminobenzoate, 98%
| 4518-10-9 |
|
Triethyl Phosphate, 99%
| 78-40-0 |
|
Ethylene glycol monomethyl ether
| 109-86-4 |
|
Desyl Chloride, 98+%
| 447-31-4 |
|
Methyl Cellulose
| 9004-67-5 |
|
2,4-Dimethylphenol, 99% (GC)
| 105-67-9 |
|
Dimethyl phosphite (Pract), 98% (Titr.)
| 67-56-1 |
|
5-Bromo-2-Fluorobenzylamine Hydrochloride 99%
| 99725-13-0 |
|
1,1,1-Trichloroethane
| 71-55-6 |
|
Ethyl Propenyl Ether
| 928-55-2 |
|
Cellulose n,n-diethylaminoethyl ether
| 9013-34-7 |
|
3,4-Dichlorophenylacetonitrile, 98%
| 3218-49-3 |
|
n-Propyl ether, 99+%
| 111-43-3 |
|
Nickel Boride
| 12007-01-1 |
|
5-Bromo-2-Fluorocinnamic Acid, 98% (GC)
| 0-00-1 |
|
L-Carnitine, 99+%
| 541-15-1 |
|
5'-O-Dimethoxytrityl-N-Isobutyryl-Deoxyguanosine
| 68892-41-1 |
|
Methyl ethyl ketone
| 78-93-3 |
|
3-Cyclopentylpropionic acid, 98%
| 140-77-2 |
|
4-(2-Thienyl)butyric Acid , 98%
| 4653-11-6 |
|
1-Bromo-2-Naphthol, 98%
| 573-97-7 |
|
5-Amino-1H-Tetrazole
| 4418-61-5 |
|
5-Bromonicotinic Acid, 98%
| 20826-04-4 |
|
Cyclohexylphenylacetonitrile, 98%
| 3893-23-0 |
|
2-(Trimethylsilyl)ethoxymethyl Chloride, Stabilized, Tech., 90%
| 76513-69-4 |
|
P-Acetotoluidide
| 103-89-9 |
|
2,2,5,5-Tetramethyl-3-Pyrrolin-1-Oxyl- 3-Carboxylic Acid, 99% (Titr.)
| 2154-67-8 |
|
Dichloromethane
| 75-09-2 |
|
Methylene Iodide
| 75-11-6 |
|
N,N-Dimethyl-4,4'-Azodianiline
| 539-17-3 |
|
5-Tert-Butyl-1,3-Benzenedicarboxylic Acid 98%
| 2359-09-3 |
|
N-Acetyl-2-Phenylethylamine, 98%
| 877-95-2 |
|
Octyl aldehyde, 99%
| 124-13-0 |
|
Trimethyl 1,3,5-Benzenetricarboxylate 99% (TLC)
| 2672-58-4 |
|
Indophenol acetate
| 7761-80-0 |
|
3-Methylmercaptoaniline, 97%
| 1783-81-9 |
|
2-Methylbenzyl Alcohol, 98%
| 89-95-2 |
|
Triphenylphosphine Dibromide, ca.33% Bromine
| 1034-39-5 |
|
Tryptophol, 97%
| 526-55-6 |
|
2'-Hydroxy-4'-Methoxyacetophenone, 99%
| 552-41-0 |
|
alpha-Phenyl-2-toluic acid, 97%
| 612-35-1 |
|
|