**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 12007-01-1 |Nickel boride | ca 100 | 234-494-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22 40 42/43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Limited evidence of a carcinogenic effect. May cause sensitization
by inhalation and skin contact.Harmful.Moisture sensitive.Cancer
suspect agent.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin. May
cause severe irritation and possible burns. May cause dermatitis.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. May cause allergic respiratory
reaction.
Chronic:
Prolonged or repeated skin contact may cause sensitization
dermatitis and possible destruction and/or ulceration. May cause
respiratory tract cancer.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
In case of fire, use carbon dioxide, dry chemical powder or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Do not get in eyes, on
skin, or on clothing. Do not ingest or inhale. Use only in a chemical
fume hood. Do not breathe dust.
Storage:
Store in a tightly closed container. Keep under a nitrogen blanket.
Store in a cool, dry, well-ventilated area away from incompatible
substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 12007-01-1:
United States OSHA: 1 mg/m3 TWA (as Ni) (listed under Nickel sol
compounds).
Belgium - TWA: (listed as nickel soluble compounds): 0.1 mg/m3 VL
(as Ni)
Malaysia: (listed as nickel soluble compounds): 0.1 mg/m3 TWA
(inhalable fraction, as Ni)
Netherlands: (listed as nickel soluble compounds): 0.1 mg/m3 MAC
Ni)
Spain: (listed as nickel soluble compounds): 0.1 mg/m3 VLA-ED (as
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: silver-gray
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: May decompose.
Specific Gravity/Density:
Molecular Formula: Ni2B
Molecular Weight: 128.19
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, exposure to moist air or
water.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of boron, borane, nickel oxide, nickel.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 12007-01-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Nickel boride -
California: carcinogen, initial date 5/7/04 (listed as Nickel compound
NTP: Known carcinogen (listed as Nickel compounds).
IARC: Group 1 carcinogen (listed as Nickel compounds).
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3288
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3288
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3288
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 40 Limited evidence of a carcinogenic effect.
R 42/43 May cause sensitization by inhalation and
skin contact.
Safety Phrases:
S 22 Do not breathe dust.
S 24 Avoid contact with skin.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 12007-01-1: No information available.
Canada
CAS# 12007-01-1 is listed on Canada's NDSL List.
CAS# 12007-01-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 12007-01-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/24/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Ethyl-3-hydroxypiperidine, 98+%
| 13444-24-1 |
|
Betaine hydrochloride, 99%
| 590-46-5 |
|
Diethyl Malonate, 99+%
| 105-53-3 |
|
P-Fluorocinnamic Acid, 99%
| 459-32-5 |
|
Methanol
| 67-56-1 |
|
BOC-L-Serine, Tech., Hydrate, 93%
| 3262-72-4 |
|
Methyl Benzoate
| 93-58-3 |
|
4,4'-Methylenenbis(n,n-dimethylaniline), 99+% (titr.)
| 101-61-1 |
|
2-Ethyl thiophenol, 98%
| 4500-58-7 |
|
Methyl 3-aminobenzoate, 98%
| 4518-10-9 |
|
Triethyl Phosphate, 99%
| 78-40-0 |
|
Ethylene glycol monomethyl ether
| 109-86-4 |
|
Desyl Chloride, 98+%
| 447-31-4 |
|
Methyl Cellulose
| 9004-67-5 |
|
2,4-Dimethylphenol, 99% (GC)
| 105-67-9 |
|
Dimethyl phosphite (Pract), 98% (Titr.)
| 67-56-1 |
|
5-Bromo-2-Fluorobenzylamine Hydrochloride 99%
| 99725-13-0 |
|
1,1,1-Trichloroethane
| 71-55-6 |
|
Ethyl Propenyl Ether
| 928-55-2 |
|
Cellulose n,n-diethylaminoethyl ether
| 9013-34-7 |
|
3,4-Dichlorophenylacetonitrile, 98%
| 3218-49-3 |
|
n-Propyl ether, 99+%
| 111-43-3 |
|
Nickel Boride
| 12007-01-1 |
|
5-Bromo-2-Fluorocinnamic Acid, 98% (GC)
| 0-00-1 |
|
L-Carnitine, 99+%
| 541-15-1 |
|
5'-O-Dimethoxytrityl-N-Isobutyryl-Deoxyguanosine
| 68892-41-1 |
|
Methyl ethyl ketone
| 78-93-3 |
|
3-Cyclopentylpropionic acid, 98%
| 140-77-2 |
|
4-(2-Thienyl)butyric Acid , 98%
| 4653-11-6 |
|
1-Bromo-2-Naphthol, 98%
| 573-97-7 |
|
5-Amino-1H-Tetrazole
| 4418-61-5 |
|
5-Bromonicotinic Acid, 98%
| 20826-04-4 |
|
Cyclohexylphenylacetonitrile, 98%
| 3893-23-0 |
|
2-(Trimethylsilyl)ethoxymethyl Chloride, Stabilized, Tech., 90%
| 76513-69-4 |
|
P-Acetotoluidide
| 103-89-9 |
|
2,2,5,5-Tetramethyl-3-Pyrrolin-1-Oxyl- 3-Carboxylic Acid, 99% (Titr.)
| 2154-67-8 |
|
Dichloromethane
| 75-09-2 |
|
Methylene Iodide
| 75-11-6 |
|
N,N-Dimethyl-4,4'-Azodianiline
| 539-17-3 |
|
5-Tert-Butyl-1,3-Benzenedicarboxylic Acid 98%
| 2359-09-3 |
|
N-Acetyl-2-Phenylethylamine, 98%
| 877-95-2 |
|
Octyl aldehyde, 99%
| 124-13-0 |
|
Trimethyl 1,3,5-Benzenetricarboxylate 99% (TLC)
| 2672-58-4 |
|
Indophenol acetate
| 7761-80-0 |
|
3-Methylmercaptoaniline, 97%
| 1783-81-9 |
|
2-Methylbenzyl Alcohol, 98%
| 89-95-2 |
|
Triphenylphosphine Dibromide, ca.33% Bromine
| 1034-39-5 |
|
Tryptophol, 97%
| 526-55-6 |
|
2'-Hydroxy-4'-Methoxyacetophenone, 99%
| 552-41-0 |
|
alpha-Phenyl-2-toluic acid, 97%
| 612-35-1 |
|
|