**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 78-40-0 |TRIETHYL PHOSPHATE | 99% | 201-114-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed. May inhibit cholinesterase activity, thereby producing
nervous system effects.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic exposure to organic solvents has been associated with
various neurotoxic effects including permanent brain and nervous
system damage. Chronic ingestion may cause neurological symptoms.
Adverse reproductive effects have been reported in animals.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Wash clothing
before reuse. Flush skin with plenty of soap and water.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Containers may explode when heated.
Extinguishing Media:
Water or foam may cause frothing. Use water spray, dry chemical,
carbon dioxide, or chemical foam. Use agent most appropriate to
extinguish fire. Cool containers with flooding quantities of water
until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with
adequate ventilation. Avoid contact with eyes, skin, and clothing.
Avoid ingestion and inhalation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 78-40-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Ester-like
pH: Not available.
Vapor Pressure: 1 mm Hg @ 20 deg C
Viscosity: mPas 20 deg C
Boiling Point: 215 deg C @ 760.00mm Hg
Freezing/Melting Point: -56 deg C
Autoignition Temperature: 480 deg C ( 896.00 deg F)
Flash Point: 130 deg C ( 266.00 deg F)
Explosion Limits, lower: 1.20 vol %
Explosion Limits, upper: 10.00 vol %
Decomposition Temperature:
Solubility in water: soluble in most other organic solvents
Specific Gravity/Density: 1.0720g/cm3
Molecular Formula: C6H15O4P
Molecular Weight: 182.16
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong bases.
Hazardous Decomposition Products:
Carbon monoxide, oxides of phosphorus, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 78-40-0: TC7900000
LD50/LC50:
CAS# 78-40-0: Dermal, guinea pig: LD50 = >20 mL/kg; Draize test,
rabbit, eye: 100 mg Moderate; Oral, mouse: LD50 = 1180 mg/kg; Oral,
rat: LD50 = 1165 mg/kg.
Carcinogenicity:
TRIETHYL PHOSPHATE -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND
EXPOSURE DATA."
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 25 Avoid contact with eyes.
WGK (Water Danger/Protection)
CAS# 78-40-0: 1
Canada
CAS# 78-40-0 is listed on Canada's DSL List.
CAS# 78-40-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 78-40-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/05/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Ethyl-3-hydroxypiperidine, 98+%
| 13444-24-1 |
|
Betaine hydrochloride, 99%
| 590-46-5 |
|
Diethyl Malonate, 99+%
| 105-53-3 |
|
P-Fluorocinnamic Acid, 99%
| 459-32-5 |
|
Methanol
| 67-56-1 |
|
BOC-L-Serine, Tech., Hydrate, 93%
| 3262-72-4 |
|
Methyl Benzoate
| 93-58-3 |
|
4,4'-Methylenenbis(n,n-dimethylaniline), 99+% (titr.)
| 101-61-1 |
|
2-Ethyl thiophenol, 98%
| 4500-58-7 |
|
Methyl 3-aminobenzoate, 98%
| 4518-10-9 |
|
Triethyl Phosphate, 99%
| 78-40-0 |
|
Ethylene glycol monomethyl ether
| 109-86-4 |
|
Desyl Chloride, 98+%
| 447-31-4 |
|
Methyl Cellulose
| 9004-67-5 |
|
2,4-Dimethylphenol, 99% (GC)
| 105-67-9 |
|
Dimethyl phosphite (Pract), 98% (Titr.)
| 67-56-1 |
|
5-Bromo-2-Fluorobenzylamine Hydrochloride 99%
| 99725-13-0 |
|
1,1,1-Trichloroethane
| 71-55-6 |
|
Ethyl Propenyl Ether
| 928-55-2 |
|
Cellulose n,n-diethylaminoethyl ether
| 9013-34-7 |
|
3,4-Dichlorophenylacetonitrile, 98%
| 3218-49-3 |
|
n-Propyl ether, 99+%
| 111-43-3 |
|
Nickel Boride
| 12007-01-1 |
|
5-Bromo-2-Fluorocinnamic Acid, 98% (GC)
| 0-00-1 |
|
L-Carnitine, 99+%
| 541-15-1 |
|
5'-O-Dimethoxytrityl-N-Isobutyryl-Deoxyguanosine
| 68892-41-1 |
|
Methyl ethyl ketone
| 78-93-3 |
|
3-Cyclopentylpropionic acid, 98%
| 140-77-2 |
|
4-(2-Thienyl)butyric Acid , 98%
| 4653-11-6 |
|
1-Bromo-2-Naphthol, 98%
| 573-97-7 |
|
5-Amino-1H-Tetrazole
| 4418-61-5 |
|
5-Bromonicotinic Acid, 98%
| 20826-04-4 |
|
Cyclohexylphenylacetonitrile, 98%
| 3893-23-0 |
|
2-(Trimethylsilyl)ethoxymethyl Chloride, Stabilized, Tech., 90%
| 76513-69-4 |
|
P-Acetotoluidide
| 103-89-9 |
|
2,2,5,5-Tetramethyl-3-Pyrrolin-1-Oxyl- 3-Carboxylic Acid, 99% (Titr.)
| 2154-67-8 |
|
Dichloromethane
| 75-09-2 |
|
Methylene Iodide
| 75-11-6 |
|
N,N-Dimethyl-4,4'-Azodianiline
| 539-17-3 |
|
5-Tert-Butyl-1,3-Benzenedicarboxylic Acid 98%
| 2359-09-3 |
|
N-Acetyl-2-Phenylethylamine, 98%
| 877-95-2 |
|
Octyl aldehyde, 99%
| 124-13-0 |
|
Trimethyl 1,3,5-Benzenetricarboxylate 99% (TLC)
| 2672-58-4 |
|
Indophenol acetate
| 7761-80-0 |
|
3-Methylmercaptoaniline, 97%
| 1783-81-9 |
|
2-Methylbenzyl Alcohol, 98%
| 89-95-2 |
|
Triphenylphosphine Dibromide, ca.33% Bromine
| 1034-39-5 |
|
Tryptophol, 97%
| 526-55-6 |
|
2'-Hydroxy-4'-Methoxyacetophenone, 99%
| 552-41-0 |
|
alpha-Phenyl-2-toluic acid, 97%
| 612-35-1 |
|
|