**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 103-82-2 |Phenylacetic acid | 100 | 203-148-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Use with adequate ventilation. Avoid breathing dust.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from strong bases.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 103-82-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: white
Odor: floral-like - Concentrated solution smells bad.
pH: Not available.
Vapor Pressure: 0.0038 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 265.5 deg C
Freezing/Melting Point: 76.5 deg C
Autoignition Temperature: Not available.
Flash Point: > 100 deg C (> 212.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: 1.0809
Molecular Formula: C8H8O2
Molecular Weight: 136.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 103-82-2: AJ2430000
LD50/LC50:
CAS# 103-82-2: Draize test, rabbit, eye: 100 mg/24H Moderate; Oral,
mouse: LD50 = 2250 mg/kg; Oral, rat: LD50 = 2250 mg/kg; Skin,
rabbit: LD50 = >5 gm/kg.
Carcinogenicity:
Phenylacetic acid -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 22 Do not breathe dust.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 103-82-2: 1
Canada
CAS# 103-82-2 is listed on Canada's DSL List.
CAS# 103-82-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 103-82-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/23/1998 Revision #4 Date: 2/17/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tellurium, Reagent (Powder), >99% (Titr.)
| 13494-80-9 |
|
Pamoic acid, 98+% (hplc)
| 130-85-8 |
|
Isopilocarpine nitrate
| 5984-94-1 |
|
4-Ethylcyclohexanone, 97%
| 5441-51-0 |
|
Pentane
| 109-66-0 |
|
Pepsin
| 9001-75-6 |
|
2-Methyl-3-Furanethiol, ca.90%, Balance Oxidized Compound
| 28588-74-1 |
|
Perchloric acid, 50-72%
| 7601-90-3 |
|
4-Amino-2,6-Dibromophenol, 99% (TLC)
| 609-21-2 |
|
Calcon, pract.
| 2538-85-4 |
|
4-Nitrophenyl phosphate di(cyclohexylamine) salt
| 52483-84-8 |
|
1-Aminopyrene, 97%
| 1606-67-3 |
|
Periodic Acid
| 10450-60-9 |
|
Tribenzylamine, 99+%
| 620-40-6 |
|
Diethyl chlorothiophosphate, 97%
| 2524-04-1 |
|
Petrolatum, White
| 8009-03-8 |
|
Petroleum Ether
| 71-43-2 |
|
N-Amylamine , 99%
| 110-58-7 |
|
4-Formylcinnamic acid, 98%, predominantly trans
| 23359-08-2 |
|
Cresyl Violet perchlorate, laser grade, 99%
| 41830-80-2 |
|
1-Octyne, 99%
| 629-05-0 |
|
Phenol, Crystallized
| 108-95-2 |
|
Phenol Liquid
| 108-95-2 |
|
Dodecylphenol, mixture of isomers
| 104-43-8 |
|
Phenolphthalein
| 77-09-8 |
|
N-Methyl Pyrrolecarboxylate, 95%, Remainder Mainly Pyrrole
| 4277-63-8 |
|
2,6-Diphenylpyridine, 97+%
| 3558-69-8 |
|
n-(Phenylseleno)-phthalimide, 98%
| 71098-88-9 |
|
Ethyl 3-(2,2-dichlorovinyl)-2,2-dimethyl-1
| 59609-49-3 |
|
Phenylacetic acid
| 103-82-2 |
|
Phenylthiotrimethylsilane, 97%
| 4551-15-9 |
|
Tetrakis(2-Hydroxyethyl)Ammonium Bromide, 99% (Titr.)
| 4328-04-5 |
|
n-Hexane-d14, 99.5+ atom % D
| 110-54-3 |
|
Calycanthine
| 595-05-1 |
|
2,2-Dichloropentanoic acid, 92%
| 18240-68-1 |
|
2-Chloro-5-Nitropyridine, 99%
| 4548-45-2 |
|
3,6-Endoxo-1,2,3,6-tetrahydrophthalic anhydride, 98%
| 5426-09-5 |
|
Linolenoyl Chloride (Pract)
| 59044-29-0 |
|
2-Amino-2-Thiazoline, 98%
| 1779-81-3 |
|
7-Trifluoromethyl-4-Quinolinethiol, Tech.
| 322-97-4 |
|
4-Piperidinoacetophenone, 97%
| 10342-85-5 |
|
4-Chloro-2,6-diaminopyrimidine, 98%
| 156-83-2 |
|
4-Heptylphenol, 98% (Titr.)
| 1987-50-4 |
|
Tetracosanol 99+%
| 506-51-4 |
|
4-Maleimido-Tempo,Free Radical
| 15178-63-9 |
|
2-Chloroethyl ethyl sulfide, 95%
| 693-07-2 |
|
Titanium (II) Hydride, 98%
| 7704-98-5 |
|
Phenyl Salicylate
| 118-55-8 |
|
Rhodanine, 99%
| 141-84-4 |
|
3,4-Dichlorophenyl Isocyanate, 99+% (GC)
| 102-36-3 |
|
|