**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 110-58-7 |N-Amylamine | 99 | 203-780-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F
Risk Phrases: 11 21/22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.Highly flammable.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. Vapors may cause dizziness or
suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Will burn if involved in a fire.
Use water spray to keep fire-exposed containers cool. Water may be
ineffective. Material is lighter than water and a fire may be spread
by the use of water. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They
can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Avoid contact with skin and eyes. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Wash clothing before reuse. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area. Keep containers tightly
closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 110-58-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear very slight yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 121 hPa @ 47 C
Viscosity: Not available.
Boiling Point: 104 deg C @ 760.00mm Hg
Freezing/Melting Point: -50 deg C
Autoignition Temperature: 305 deg C ( 581.00 deg F)
Flash Point: 4 deg C ( 39.20 deg F)
Explosion Limits, lower: 2.20 vol %
Explosion Limits, upper: 22.00 vol %
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density: .7520g/cm3
Molecular Formula: C5H13N
Molecular Weight: 87.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 110-58-7: SC0300000
LD50/LC50:
Not available.
Carcinogenicity:
N-Amylamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: AMYLAMINE
Hazard Class: 3 (8)
UN Number: 1106
Packing Group: II
IMO
Shipping Name: AMYLAMINES
Hazard Class: 3.2 (8)
UN Number: 1106
Packing Group: II
RID/ADR
Shipping Name: AMYLAMINES
Hazard Class: 3
UN Number: 1106
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 21/22 Harmful in contact with skin and if
swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 33 Take precautionary measures against static
discharges.
S 50A Do not mix with acids.
WGK (Water Danger/Protection)
CAS# 110-58-7: 1
Canada
CAS# 110-58-7 is listed on Canada's DSL List.
CAS# 110-58-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 110-58-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/27/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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ALL MSDS PAGES IN THIS GROUP
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| 5984-94-1 |
4-Ethylcyclohexanone, 97%
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Pentane
| 109-66-0 |
Pepsin
| 9001-75-6 |
2-Methyl-3-Furanethiol, ca.90%, Balance Oxidized Compound
| 28588-74-1 |
Perchloric acid, 50-72%
| 7601-90-3 |
4-Amino-2,6-Dibromophenol, 99% (TLC)
| 609-21-2 |
Calcon, pract.
| 2538-85-4 |
4-Nitrophenyl phosphate di(cyclohexylamine) salt
| 52483-84-8 |
1-Aminopyrene, 97%
| 1606-67-3 |
Periodic Acid
| 10450-60-9 |
Tribenzylamine, 99+%
| 620-40-6 |
Diethyl chlorothiophosphate, 97%
| 2524-04-1 |
Petrolatum, White
| 8009-03-8 |
Petroleum Ether
| 71-43-2 |
N-Amylamine , 99%
| 110-58-7 |
4-Formylcinnamic acid, 98%, predominantly trans
| 23359-08-2 |
Cresyl Violet perchlorate, laser grade, 99%
| 41830-80-2 |
1-Octyne, 99%
| 629-05-0 |
Phenol, Crystallized
| 108-95-2 |
Phenol Liquid
| 108-95-2 |
Dodecylphenol, mixture of isomers
| 104-43-8 |
Phenolphthalein
| 77-09-8 |
N-Methyl Pyrrolecarboxylate, 95%, Remainder Mainly Pyrrole
| 4277-63-8 |
2,6-Diphenylpyridine, 97+%
| 3558-69-8 |
n-(Phenylseleno)-phthalimide, 98%
| 71098-88-9 |
Ethyl 3-(2,2-dichlorovinyl)-2,2-dimethyl-1
| 59609-49-3 |
Phenylacetic acid
| 103-82-2 |
Phenylthiotrimethylsilane, 97%
| 4551-15-9 |
Tetrakis(2-Hydroxyethyl)Ammonium Bromide, 99% (Titr.)
| 4328-04-5 |
n-Hexane-d14, 99.5+ atom % D
| 110-54-3 |
Calycanthine
| 595-05-1 |
2,2-Dichloropentanoic acid, 92%
| 18240-68-1 |
2-Chloro-5-Nitropyridine, 99%
| 4548-45-2 |
3,6-Endoxo-1,2,3,6-tetrahydrophthalic anhydride, 98%
| 5426-09-5 |
Linolenoyl Chloride (Pract)
| 59044-29-0 |
2-Amino-2-Thiazoline, 98%
| 1779-81-3 |
7-Trifluoromethyl-4-Quinolinethiol, Tech.
| 322-97-4 |
4-Piperidinoacetophenone, 97%
| 10342-85-5 |
4-Chloro-2,6-diaminopyrimidine, 98%
| 156-83-2 |
4-Heptylphenol, 98% (Titr.)
| 1987-50-4 |
Tetracosanol 99+%
| 506-51-4 |
4-Maleimido-Tempo,Free Radical
| 15178-63-9 |
2-Chloroethyl ethyl sulfide, 95%
| 693-07-2 |
Titanium (II) Hydride, 98%
| 7704-98-5 |
Phenyl Salicylate
| 118-55-8 |
Rhodanine, 99%
| 141-84-4 |
3,4-Dichlorophenyl Isocyanate, 99+% (GC)
| 102-36-3 |
|
|