**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2524-04-1 |Diethylthiophosphoryl chloride | 97% | 219-755-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+
Risk Phrases: 21/22 26 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. Very toxic by
inhalation. Causes burns.Corrosive.Highly toxic.Stench.Moisture
sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Harmful if absorbed through the skin. Causes skin burns.
Ingestion:
Harmful if swallowed.
Inhalation:
May be fatal if inhaled. Causes chemical burns to the respiratory
tract.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 2524-04-1:
Russia: 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to light yellow
Odor: Stench
pH: Not available.
Vapor Pressure: 1.4 mm Hg @ 50 deg
Viscosity: Not available.
Boiling Point: 45 deg C @ 3.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 97 deg C ( 206.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: immiscible in water
Specific Gravity/Density: 1.2000g/cm3
Molecular Formula: C4H10ClO2SP
Molecular Weight: 188.61
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of sulfur, oxides of
phosphorus, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2524-04-1: TD1780000
LD50/LC50:
CAS# 2524-04-1: Inhalation, mouse: LC50 = 725 mg/m3/2H; Inhalation,
rat: LC50 = 20 ppm/4H; Oral, mouse: LD50 = 800 mg/kg; Oral, rabbit:
LD50 = 900 mg/kg; Oral, rat: LD50 = 1340 mg/kg.
Carcinogenicity:
Diethylthiophosphoryl chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DIETHYLTHIOPHOSPHORYL CHLORIDE
Hazard Class: 8
UN Number: 2751
Packing Group: II
IMO
Shipping Name: DIETHYLTHIOPHOSPHORYL CHLORIDE
Hazard Class: 8
UN Number: 2751
Packing Group: II
RID/ADR
Shipping Name: DIETHYLTHIOPHOSPHORYL CHLORIDE
Hazard Class: 8
UN Number: 2751
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 26 Very toxic by inhalation.
R 34 Causes burns.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 2524-04-1: 2
Canada
CAS# 2524-04-1 is listed on Canada's DSL List.
CAS# 2524-04-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2524-04-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Isopilocarpine nitrate
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4-Ethylcyclohexanone, 97%
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Pentane
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Pepsin
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Perchloric acid, 50-72%
| 7601-90-3 |
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4-Amino-2,6-Dibromophenol, 99% (TLC)
| 609-21-2 |
|
Calcon, pract.
| 2538-85-4 |
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4-Nitrophenyl phosphate di(cyclohexylamine) salt
| 52483-84-8 |
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1-Aminopyrene, 97%
| 1606-67-3 |
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Periodic Acid
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Tribenzylamine, 99+%
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Petrolatum, White
| 8009-03-8 |
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Petroleum Ether
| 71-43-2 |
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N-Amylamine , 99%
| 110-58-7 |
|
4-Formylcinnamic acid, 98%, predominantly trans
| 23359-08-2 |
|
Cresyl Violet perchlorate, laser grade, 99%
| 41830-80-2 |
|
1-Octyne, 99%
| 629-05-0 |
|
Phenol, Crystallized
| 108-95-2 |
|
Phenol Liquid
| 108-95-2 |
|
Dodecylphenol, mixture of isomers
| 104-43-8 |
|
Phenolphthalein
| 77-09-8 |
|
N-Methyl Pyrrolecarboxylate, 95%, Remainder Mainly Pyrrole
| 4277-63-8 |
|
2,6-Diphenylpyridine, 97+%
| 3558-69-8 |
|
n-(Phenylseleno)-phthalimide, 98%
| 71098-88-9 |
|
Ethyl 3-(2,2-dichlorovinyl)-2,2-dimethyl-1
| 59609-49-3 |
|
Phenylacetic acid
| 103-82-2 |
|
Phenylthiotrimethylsilane, 97%
| 4551-15-9 |
|
Tetrakis(2-Hydroxyethyl)Ammonium Bromide, 99% (Titr.)
| 4328-04-5 |
|
n-Hexane-d14, 99.5+ atom % D
| 110-54-3 |
|
Calycanthine
| 595-05-1 |
|
2,2-Dichloropentanoic acid, 92%
| 18240-68-1 |
|
2-Chloro-5-Nitropyridine, 99%
| 4548-45-2 |
|
3,6-Endoxo-1,2,3,6-tetrahydrophthalic anhydride, 98%
| 5426-09-5 |
|
Linolenoyl Chloride (Pract)
| 59044-29-0 |
|
2-Amino-2-Thiazoline, 98%
| 1779-81-3 |
|
7-Trifluoromethyl-4-Quinolinethiol, Tech.
| 322-97-4 |
|
4-Piperidinoacetophenone, 97%
| 10342-85-5 |
|
4-Chloro-2,6-diaminopyrimidine, 98%
| 156-83-2 |
|
4-Heptylphenol, 98% (Titr.)
| 1987-50-4 |
|
Tetracosanol 99+%
| 506-51-4 |
|
4-Maleimido-Tempo,Free Radical
| 15178-63-9 |
|
2-Chloroethyl ethyl sulfide, 95%
| 693-07-2 |
|
Titanium (II) Hydride, 98%
| 7704-98-5 |
|
Phenyl Salicylate
| 118-55-8 |
|
Rhodanine, 99%
| 141-84-4 |
|
3,4-Dichlorophenyl Isocyanate, 99+% (GC)
| 102-36-3 |
|
|