**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 106-38-7 |4-Bromotoluene | 99.0 | 203-391-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully
investigated. Causes gastrointestinal tract irritation.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation.
Storage:
Keep away from heat, sparks, and flame. Keep container closed when
not in use. Store in a tightly closed container. Store in a cool,
dry, well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 106-38-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: 1.15 mm Hg @deg C
Viscosity: Not available.
Boiling Point: 184 deg C @ 760.00mmHg
Freezing/Melting Point: 26.00 - 29.00 deg C
Autoignition Temperature: Not available.
Flash Point: 85 deg C ( 185.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble in ethanol, ether, and acetone
Specific Gravity/Density: 1.3900g/cm3
Molecular Formula: C7H7Br
Molecular Weight: 171.04
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide, bromine fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 106-38-7: XS7965600
LD50/LC50:
CAS# 106-38-7: Inhalation, mouse: LC50 = 2460 mg/m3; Inhalation,
rat: LC50 = 6800 mg/m3; Oral, mouse: LD50 = 1860 mg/kg; Oral, rat:
LD50 = 1540 mg/kg.
Carcinogenicity:
4-Bromotoluene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 1.46-2.53 mg/L; 5,15,30
Minutes; Microtox test, 15 degrees C
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 39 Wear eye/face protection.
WGK (Water Danger/Protection)
CAS# 106-38-7: No information available.
Canada
CAS# 106-38-7 is listed on Canada's DSL List.
CAS# 106-38-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 106-38-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/05/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Methyl-5-Methoxycarbonyl-1-Benzyl-4-Piperidone Hydrochloride, 99%
| 0-01-1 |
|
4-Decanol, 99%
| 2051-31-2 |
|
5-Chloro-1,3-dimethoxybenzene, 97+%
| 7051-16-3 |
|
Bis-(Benzonitrile)-Palladium(II)Chloride, 99+%
| 14220-64-5 |
|
N-(1-Anilinonaphthyl-4)-Maleimide
| 50539-45-2 |
|
4-Chloro-O-Anisic Acid, 99%
| 57479-70-6 |
|
Furfuryl Mercaptan, 97%
| 98-02-2 |
|
4-Methoxybenzenethiol, 98%
| 696-63-9 |
|
6-Dimethylaminopurine
| 938-55-6 |
|
2-Amino-4,6-Dichloropyrimidine, Tech.
| 56-05-3 |
|
2,4-Dihydroxy-n-(2-Hydroxyethyl)benzamide, 99% (TLC)
| 24207-41-8 |
|
Brucine dihydrate, 99%
| 145428-94-0 |
|
2-Indanol, 99%
| 4254-29-9 |
|
Trifluoroacetic Acid, Ammonium Salt, 98%
| 3336-58-1 |
|
10-Methylphenothiazine
| 1207-72-3 |
|
Trimethyl Phosphate, P.A.
| 512-56-1 |
|
4-Bromotoluene, 99%
| 106-38-7 |
|
Ethylenediaminetetraacetic Acid Copper, Disodium Salt Dihydrate, 98%
| 61916-40-3 |
|
3-Methylsalicylic acid, 99%
| 83-40-9 |
|
5-Benzyloxytryptamine hydrochloride, 98%
| 52055-23-9 |
|
3-Formylsalicylic acid, 97%
| 610-04-8 |
|
3-Methylcyclopentanol, 99%, mixture of isomers
| 18729-48-1 |
|
L(-)-Dibenzoyl-L-tartaric acid monohydrate , 98%
| 2743-38-6 |
|
1-Phenoxy-2-propanol,97%
| 770-35-4 |
|
Ethyl 2(2-Aminothiazole-4-yl)-2-Methoxyiminoacetate, 98%
| 64485-88-7 |
|
Borane-tetrahydrofuran complex, 1M solution in tetrahydrofuran
| 109-99-9 |
|
N-Phenyl-P-Phenylenediamine Monohydro-Chloride, 99% (Titr.)
| 2198-59-6 |
|
Dipentaerythritol, 90%
| 126-58-9 |
|
2,4'-Dipyridyl, 97+%
| 581-47-5 |
|
N,N-Bis(2-Cyanoethyl)Formamide
| 3445-84-9 |
|
L-(+)-Lysine Monohydrate 99%
| 39665-12-8 |
|
Albizziin, 98%
| 1483-07-4 |
|
2-Methyltetrahydrofuran-3-one, 98%
| 3188-00-9 |
|
N-Acryloyltris(Hydroxymethyl)aminomethane (Nat)
| 13880-05-2 |
|
Sulforhodamine 101 (Free Acid), Laser Grade, 99% (UV-Vis)
| 82354-19-6 |
|
Progesterone, 98%
| 57-83-0 |
|
5-Bromo-2-Fluorobenzaldehyde, 98%
| 93777-26-5 |
|
5-Amino-3-Methylisothiazole Hydrochloride
| 52547-00-9 |
|
Pentafluoropropionic Anhydride
| 356-42-3 |
|
Albumine bovine serum,additional reagent for igss, protease free
| |
|
D-(+)-Methioninol
| 87206-44-8 |
|
alpha-Chloro-o-xylene, 99%
| 552-45-4 |
|
2-(5-Bromo-2-Pyridylazo)-5- (Diethylamino)Phenol, 99+% (Titr.)
| 14337-53-2 |
|
(S)-(+)-alpha-Methoxy-alpha-trifluoro-methylphenylacetyl chloride,
| 20445-33-4 |
|
(1S,2S,3R,5S)-(+)-2,3-Pinanediol, 98%
| 18680-27-8 |
|
Molecular Sieves, 3A, 8 to 12 Mesh
| 308080-99-1 |
|
1-Methyl-4-piperidone, 98%
| 1445-73-4 |
|
2-Amino-6,7-Dimethyl-4-Hydroxypteridine
| 611-55-2 |
|
Dinonyl Phthalate
| 84-76-4 |
|
Phenyl sulfoxide, 97%
| 945-51-7 |
|
|